4 Emergency Response Guidebook A GUIDEBOOK FOR FIRST RESPONDERS DURING THE IMHAL PHASE OF A DANGEROUS GOODS/ HAZARDOUS MATERIALS INCIDENT SHIPPING DOCUMENTS (PAPERS) * The shipping document provides vital information when responding to a hazardous materials/dangerous goods** incident. The shipping document contains information needed to identify the materials involved. Use this information to initiate protective actions for your own safety and the safety of the public. The shipping document contains the proper shipping name (see blue-bordered pages), the hazard class or division of the material(s), ID number (see yellow-bordered pages), and, where appropriate, the Packing Group. In addition, there must be information available that describes the hazards of the material which can be used in the mitigation of an incident. The information must be entered on or be with the shipping document. This requirement may be satisfied by attaching a guide from the ERG2004 to the shipping document, or by having the entire guidebook available for ready reference. Shipping documents are required for most dangerous goods in transportation. Shipping documents are kept in • the cab of the motor vehicle, • the possession of the train crew member, • a holder on the bridge of a vessel, or • an aircraft pilot's possession. EMERGENCY CONTACT 1-000-000-0000 "* EXAMPLE OF EMERGENCY RESPONSE TELEPHONE NUMBER HAZARD CLASS OR DIVISION NO. NO. & TYPE DESCRIPTION OF OF PACKAGES ARTICLES QUANTITY T 1 TANK TRUCK ^ISOPROPANOL 3 ^UN1219 II v 3,000 LITERS SHIPPING NAME ID NUMBER PACKING GROUP EXAMPLE OF PLACARD AND PANEL WITH ID NUMBER The 4-digit ID Number may be shown on the diamond-shaped placard or on an adjacent orange panel displayed on the ends and sides of a cargo tank, vehicle or rail car. * For the purposes of this book, the terms shipping document/shipping paper are synonymous. * For the purposes of this book, the terms hazardous materials/dangerous goods are synonymous. RESIST RUSHING IN ! APPROACH INCIDENT FROM UPWIND STAY CLEAR OF ALL SPILLS, VAPORS, FUMES AND SMOKE HOW TO USE THIS GUIDEBOOK DURING AN INCIDENT INVOLVING DANGEROUS GOODS ONE IDENTIFY THE MATERIAL BY FINDING ANY ONE OF THE FOLLOWING: THE 4-DIGIT ID NUMBER ON A PLACARD OR ORANGE PANEL THE 4-DIGIT ID NUMBER (after UN/NA) ON A SHIPPING DOCUMENT OR PACKAGE THE NAME OF THE MATERIAL ON A SHIPPING DOCUMENT, PLACARD OR PACKAGE IF AN ID NUMBER OR THE NAME OF THE MATERIAL CANNOT BE FOUND, SKIP TO THE NOTES BELOW. TWO LOOK UP THE MATERIAL'S 3-DIGIT GUIDE NUMBER IN EITHER: THE ID NUMBER INDEX. .(the yellow-bordered pages of the guidebook) THE NAME OF MATERIAL INDEX. .(the blue-bordered pages of the guidebook) If the guide number is supplemented with the letter "P", itindicates thatthe material may undergo violent polymerization if subjected to heatorcontamination. If the index entry is highlighted (in eitfieryellow orblue), it is a TIH (Toxic Inhalation Hazard) material, a chemical warfare agent or a Dangerous Water R eactive M aterial (produces toxic gas upon contact with water). LOOK FOR THE ID NUMBER AND NAME OF THE MATERIAL IN THE TABLE OF INITIALISOLATION AND PROTECTIVE ACTION DISTANCES (ttie green-bordered pages). Then, if necessary, BEGIN PROTECTIVE ACTIONS IMMEDIATELY (see Protective Actions on page 298), If protective action is notrequired, use the information jointly with the 3-digitguide. USE GUIDE 112 FOR ALL EXPLOSIVES EXCEPT FOR EXPLOSIVES 1.4 (EXPLOSIVES C) WHERE GUIDE 114 IS TO BE CONSULTED. THREE TURN TO THE NUMBERED GUIDE (the orange-bordered pages) AND READ CAREFULLY. NOTES IF A NUMBERED GUIDE CANNOT BE OBTAINED BY FOLLOWING THE ABOVE STEPS, AND A PLACARD CAN BE SEEN, LOCATE THE PLACARD IN THE TABLE OF PLACARDS (pages 16-17), THEN GO TO THE 3-DIGIT GUIDE SHOWN NEXT TO THE SAMPLE PLACARD. IF A REFERENCE TO A GUIDE CANNOT BE FOUND AND THIS INCIDENT IS BELIEVED TO INVOLVE DANGEROUS GOODS, TURN TO GUIDE 111 NOW, AND USE IT UNTIL ADDITIONAL INFORMATION BECOMES AVAILABLE. If the shipping document lists an emergency response telephone number, call thatnumber. If the shipping document is notavailable, or no emergency response telephone numberis listed, IMMEDIATELY CALL the appropriate emergency response agency listed on the inside back cover of this guidebook. Provide as much information as possible, such as the name of the carrier (trucking company or railroad) and vehicle number. AS A LAST RESORT, CONSULT THE TABLE OF RAIL CAR AND ROAD TRAILER IDENTIFICATION CHART (pages 18-19). IF THE CONTAINER CAN BE IDENTIFIED, REMEMBER THAT THE INFORMATION ASSOCIATED WITH THESE CONTAINERS IS FOR THE WORST CASE POSSIBLE. Page 1 ERG2004 USER'S GUIDE The 2004 Emergency Response Guidebook (ERG 2004) was developed jointly by Transport Canada (TC), the U.S. Departmentof Transportation (DOT), the Secretariat of Transportand Communications of Mexico (SCT) and with the collaboration of C IQUIM E (Centra de Informacion Quimica para Emergencias) of Argentina, for use by fire fighters, police, and otheremergency services personnel who may be the first to arrive at the scene of a transportation incident involving dangerous goods. It is primarily a guide to aid first responders in quickly identifying the specific or generic hazards of the material(s) involved in the incident, and protecting themselves and the general public during the initial response phase of the incident. For the purposes of this guidebook, the "initial response phase" is that period following arrival atthe scene of an incidentduring which the presence and/or identification of dangerous goods is confirmed, protective actions and area securement are initiated, and assistance of qualified personnel is requested. It is notintended to provide information on the physical orchemical properties of dangerous goods. This guidebook will assist responders in making initial decisions upon arriving atthe scene of a dangerous goods incident. Itshould notbe considered as a substitute foremergency response training, knowledge or sound judgment. ERG 2004 does not address all possible circumstances thatmay be associated with a dangerous goods incident. Itis primarily designed foruse ata dangerous goods incident occurring on a highway or railroad. Be mindful thatthere may be limited value in its application atfixed facility locations. ERG2004 incorporates dangerous goods lists from the most recent United Nations Recommendations as well as from other international and national regulations. Explosives are not listed individually by either proper shipping name or ID Number. They do, however, appear under the general heading "Explosives" on the first page of the ID Number index (yellow-bordered pages) and alphabetically in the Name of Material index (blue-bordered pages). Also, the letter "P" following the guide number in the yellow-bordered and blue- bordered pages identifies those materials which presenta polymerization hazard under certain conditions, forexample: Acrolein, stabilized 131 P. First responders atthe scene of a dangerous goods incidentshould seek additional specific information aboutany material in question as soon as possible. The information received by contacting the appropriate emergency response agency, the emergency response number on the shipping document, or by consulting the information on or accompanying the shipping document, may be more specific and accurate than this guidebook in providing guidance forthe materials involved. BECOME FAMILIAR WITH THIS GUIDEBOOK BEFORE USING IT DURING AN EMERGENCY! In the U.S., according to the requirements of the U.S. Departmentof Labor's Occupational Safety and Health Administration (OSHA, 29 CFR 1910.120), and regulations issued by the U.S. Environmental Protection Agency (EPA, 40 CFR Part 311), first responders mustbe trained regarding the use of this guidebook. Page 2 GUIDEBOOK CONTENTS 1 - Yellow-bordered pages: Index listof dangerous goods in numerical orderof ID number. This section quickly identifies the guide to be consulted from the ID Number of the material involved. This list displays the 4-digit ID number of the material followed by its assigned emergency response guide and the material name. For example: ID No. GUIDE No. Name of Material 1090 127 Acetone 2- Blue-bordered pages: Index list of dangerous goods in alphabetical order of material name. This section quickly identifies the guide to be consulted from the name of the material involved. This list displays the name of the material followed by its assigned emergency response guide and 4-digit ID number. For example: Name of Material GUIDE No. ID No. Sulfuric acid 137 1830 3- Orange-bordered pages: This section is the most important section of the guidebook because itis where all safety recommendations are provided. Itcomprises a total of 62 individual guides, presented in a two-page format. Each guide provides safety recommendations and emergency response information to protectyourselfandthe public. The left hand page provides safety related information whereas the righthand page provides emergency response guidance and activities forfire situations, spill or leak incidents and firstaid. Each guide is designed to covera group of materials which possess similarchemical and toxicological characteristics. The guide title identifies the general hazards of the dangerous goods covered. For example: GUIDE 124- Gases-Toxic and/or Corrosive-Oxidizing. Each guide is divided into three main sections: the firstsection describes potential hazards thatthe material may display in terms of fire/explosion and health effects upon exposure. The highestpotential is listed first. The emergency respondershould consult this section first. This allows the responderto make decisions regarding the protection of the emergency response team as well as the surrounding population. The second section outlines suggested public safety measures based on the situation at hand. It provides general information regarding immediate isolation of the incidentsite, recommended type of protective clothing and respiratory protection. Suggested evacuation distances are listed forsmall and large spills and forfire situations (fragmentation hazard). Italso directs the readerto consultthe tables listing Toxic Inhalation Hazard materials (TIH), chemical warfare agents and water-reactive materials (green-bordered pages) when the material name is highlighted in the yellow-bordered and blue-bordered pages. The third section covers emergency response actions, including firstaid. It outlines special precautions for incidents which involve fire, spill or chemical exposure. Several recommendations are listed undereach partwhich will further assist in the decision making process. The information on firstaid is general guidance priorto seeking medical care. Page 3 4-Green-bordered pages: This section contains a table which lists, by ID number, TIH materials, including certain chemical warfare agents, and water-reactive materials which produce toxic gases upon contactwith water. The table provides two differenttypes of recommended safe distances which are "Initial isolation distances" and "Protective action distances." The materials are highlighted for easy identification in both numeric (yellow-bordered pages) and alphabetic (blue-bordered pages) lists of the guidebook. The table provides distances for both small (approximately 200 liters or less) and large spills (more than 200 liters) for all highlighted materials. The listis further subdivided into daytime and nighttime situations. This is necessary due to varying atmospheric conditions which greatly affectthe size of the hazardous area. The distances change from daytime to nighttime due to differentmixing and dispersion conditions in the air. During the night, the air is generally calmer and this causes the chemical to disperse less and therefore create a toxicity zone which is greater than would usually occur during the day. During the day, the chemical is generally dispersed by a more active atmosphere. The chemical will be presentin a largerarea; however, the actual area where toxic levels are reached will be smaller (due to increased dispersion). It is the quantity or concentration of the chemical vapor thatposes problems not its mere presence. The "Initial Isolation Distance" is a distance within which all persons should be considered for evacuation in all directions from the actual spill/leak source. It is a distance (radius) which defines a circle (Initial Isolation Zone) within which persons may be exposed to dangerous concentrations upwind of the source and may be exposed to life threatening concentrations downwind of the source. Forexample, in the case of Compressed gas, toxic, n.o.s., ID No. 1955, Inhalation Hazard Zone A, the isolation distance forsmall spills is 600 meters, therefore, representing an evacuation circle of 1200 meters in diameter. Forthesame material, the "Protective Action Distance" is 5.9 kilometers fora daytime incident and 11.0+ kilometers for a nighttime incident, these distances representa downwind distance from the spill/leak source within which Protective Actions could be implemented. Protective Actions are those steps taken to preserve the health and safety of emergency responders and the public. People in this area could be evacuated and/or sheltered in-place. For more information, consult the INTRODUCTION TO THE TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES (pages 295-296). What is a TIH? It is a gas or volatile liquid which is known to be so toxic to humans as to pose a hazard to health during transportation, or in the absence of adequate data on human toxicity, is presumed to be toxic to humans because when tested on laboratory animals it has an LC50 value of not more than 5000 ppm. Itis importantto note thateven though the term zone is used, the hazard zones do not represent any actual area or distance. The assignment of the zones is strictly a function of their Lethal Concentration 50 (LC50); forexample, TIH Zone A is more toxic than Zone D. All distances which are listed in the green-bordered pages are calculated by the use of mathematical models foreach TIH material. Page 4 Assignment of hazard zones: HAZARD ZONE A: Gases: LC50 of less than or equal to 200 ppm, Liquids: V equal to or greater than 500 LC50 and LC50 less than or equal to 200 ppm, HAZARD ZONE B: Gases: LC50 greater than 200 ppm and less than or equal to 1000 ppm, Liquids: V equal to or greater than 10 LC50; LC50 less than or equal to 1000 ppm and criteria for Hazard Zone A are not met, HAZARD ZONE C: LC50 greater than 1000 ppm and less than or equal to 3000 ppm, HAZARD ZONE D: LC50 greaterthan 3000 ppm and less than or equal to 5000 ppm. ISOLATION AND EVACUATION DISTANCES Isolation or evacuation distances are shown in the guides (orange-bordered pages) and in the Table of Initial Isolation and Protective Action Distances (green-bordered pages). This may confuse users not thoroughly familiar with ERG2004. It is important to note that some guides refer only to non-TIH materials (36 guides), some refer to both TIH and non-TIH materials (21 guides) and some (5 guides) refer only to TIH or Water- reactive materials (WRM). A guide refers to both TIH and non-TIH materials (for example see GUIDE 131) when the following sentence appears underthe title EVACUATIO N-Spill: "See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non- highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under 'PUBLIC SAFETY."' A guide refers only to TIH or WRM materials (for example see GUIDE 124) when the following sentence appears under the title EVACUATION-S pill: "See the Table of Initial Isolation and Protective Action Distances". Ifthe previous sentences do not appear in a guide, then this particular guide refers only to non-TIH materials (for example see GUIDE 128). In order to identify appropriate isolation and protective action distances, use the following: If you are dealing with a TIH/WRM/Chemical warfare material (highlighted entries in the index lists), the isolation and evacuation distances are found directly in the green-bordered pages. The guides (orange-bordered pages) also remind the user to refer to the green-bordered pages for evacuation specific information involving highlighted materials. If you are dealing with a non-TIH material but the guide refers to both TIH and non-TIH materials, an immediate isolation distance is provided underthe heading PUBLIC SAFETY as a precautionary measure to prevent injuries. It applies to the non-TIH materials only. In addition, for evacuation purposes, the guide informs the userunderthe title E VAC UATIO N-S pill to increase, for non-highlighted substances, in the downwind direction, if necessary, the immediate isolation distance listed under "PUBLIC SAFETY". For example, GUIDE 131 - Flammable Liquids-Toxic, instructs the user to: "As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions." In case of a large spill, the isolation area could be expanded from 50 meters to a distance deemed as safe by the On-scene- commander and emergency responders. If you are dealing with a non-TIH material and the guide refers only to non-TIH materials, the immediate isolation and evacuation distances are specified as actual distances in the guide (orange-bordered pages) and are not referenced in the green-bordered pages. Page 5 SAFETY PRECAUTIONS APPROACH CAUTIOUSLY FROM UPWIND. Resistthe urge to rush in; others cannot be helped until the situation has been fully assessed. SECURE THE SCENE. Without entering the immediate hazard area, isolate the area and assure the safety of people and the environment, keep people away from the scene and outside the safety perimeter. Allow enough room to move and remove yourown equipment. IDENTIFY THE HAZARDS. Placards, container labels, shipping documents, material safety data sheets, Rail Car and Road Trailer Identification Charts, and/or knowledgeable persons on the scene are valuable information sources. Evaluate all available information and consult the recommended guide to reduce immediate risks. Additional information, provided by the shipper or obtained from another authoritative source, may change some of the emphasis or details found in the guide. Remember, the guide provides only the most importantand worstcase scenario information forthe initial response in relation to a family or class of dangerous goods. As more material-specific information becomes available, the response should be tailored to the situation. ASSESS THE SITUATION. Consider the following: Is there a fire, a spill ora leak? Whatarethe weatherconditions? Whatis the terrain like? Who/whatis atrisk: people, property orthe environment? Whatactions should be taken: Is an evacuation necessary? Is diking necessary? Whatresources (human and equipment) are required and are readily available? Whatcan be done immediately? OBTAIN HELP. Advise your headquarters to notify responsible agencies and call for assistance from qualified personnel. DECIDE ON SITE ENTRY. Any efforts made to rescue persons, protect property or the environment mustbe weighed againstthe possibility thatyou could become partof the problem. Enterthe area only when wearing appropriate protective gear (see PROTECTIVE CLOTHING, page 350). RESPOND. Respond in an appropriate manner. Establish a command post and lines of communication. Rescue casualties where possible and evacuate if necessary. Maintain control of the site. Continually reassess the situation and modify the response accordingly. The first duty is to considerthe safety of people in the immediate area, including yourown. ABOVE ALL- Do notwalk into ortouch spilled material. Avoid inhalation of fumes, smoke and vapors, even if no dangerous goods are known to be involved. Do notassume thatgases or vapors are harmless because of lack of a smell- odorless gases or vapors may be harmful. Use CAUTION when handling empty containers because they may still present hazards until they are cleaned and purged of all residues. Page 6 WHO TO CALL FOR ASSISTANCE Upon arrival atthe scene, a first responder is expected to recognize the presence of dangerous goods, protectoneself and the public, secure the area, and call forthe assistance of trained personnel as soon as conditions permit. Follow the steps outlined in your organization's standard operating procedures and/or local emergency response planforobtaining qualified assistance. Generally, the notification sequence and requests fortechnical information beyond what is available in this guidebook should occur in the following order: 1. ORGANIZATION/AGENCY Notify your organization/agency. This will set in motion a series of events based upon the information provided. Actions may range from dispatching additional trained personnel to the scene to activating the local emergency response plan. Ensure that local fire and police departments have been notified. 2. EMERGENCY RESPONSE TELEPHONE NUMBER Locate and call the telephone number listed on the shipping document. The person answering the phone atthe listed emergency response number must be knowledgeable of the materials and mitigation actions to be taken, or musthave immediate access to a person who has the required knowledge. 3. NATIONAL ASSISTANCE Contact the appropriate emergency response agency listed on the inside back coverof this guidebook when the emergency response telephone number is notavailable. Uponreceiptof a call describing the nature of the incident the agency will provide immediate advice on handling the early stages of the incident. The agency will also contactthe shipper or manufacturer of the material for more detailed information and requeston-scene assistance when necessary. Collectand provide as much of the following information as can safely be obtained to yourchain-of- command and specialists contacted fortechnical guidance: Yourname, call backtelephone number, FAX number Location and nature of problem (spill, fire, etc.) Name and identification numberof material(s) involved Shipper/consignee/pointof origin Carrier name, rail car or truck number Containertype and size Quantity of mate rial transported/released Local conditions (weather, terrain, proximity to schools, hospitals, waterways, etc.) Injuries and exposures Local emergency services thathave been notified Page 7 CANADA 1. CANUTEC CANUTEC is the Canadian Transport Emergency Centre operated by theTransport Dangerous Goods Directorate ofTransportCanada. CANUTEC provides a national bilingual (French and English) advisory service and is staffed by professional scientists experienced and trained in interpreting technical information and providing emergency response advice. In an emergency, CANUTEC may be called collect at 613-996-6666 (24 hours) *666 cellular (Press Star 666, Canada only) In a non-emergency situation, please call the information line at 613-992-4624 (24 hours). 2. PROVINCIAL AGENCIES Although technical information and emergency response assistance can be obtained from CANUTEC, there are federal and provincial regulations requiring the reporting of dangerous goods incidents to certain authorities. The following list of provincial agencies is supplied foryourconvenience. Province Emergency Authority and/or Telephone Number A Ihprta 1 nral Pnliro and Prnwinrial A i ifhn rifioc 1-800-272-9600* or 780-422-9600 British Columbia Local Police and Provincial Authorities 1-800-663-3456 Manitoba Provincial Authority 204-945-4888 and Local Police or fire brigade, as appropriate New Brunswick Local Police or 1-800-565-1633** or 902-426-6030 Newfoundland Local Police and 709-772-2083 Northwest Territories 867-920-8130 Nova Scotia Local Police or 1-800-565-1633** or 902-426-6030 Nunavut Territory Local Police and 1-800-693-1666 or 867-979-6262 Ontario Local Police Prince Edward Island Local Police or 1-800-565-1633** or 902-426-6030 Quebec Local Police Saskatchewan Local Police or 1-800-667-7525 Yukon Territory 867-667-7244 * This numberis notaccessible from outsideAlberta. ** This numberis notaccessible from outside of New Brunswick, Nova Scotia or Prince Edward Island. Page 8 NOTE 1, The appropriate federal agency mustbe notified in the case of rail, air or marine incidents. 2, The nearest police department must be notified in the case of lost, stolen or misplaced explosives, radioactive materials orinfectious substances, 3, CANUTEC must be notified in the case of: a. lost, stolen ormisplaced infectious substances; b. an incident involving infectious substances; c. an accidental release from a cylinder tinat has suffered a catastrophic failure; d. an incident where the shipping documents display CANUTEC's telephone number 613-996- 6666 as the emergency telephone number; or e. a dangerous goods incident in which a railway vehicle, a ship, an aircraft, an aerodrome or an air cargo facility is involved. Page 9 UNITED STATES 1. CHEMTREC®, a 24-hour emergency response communication service, can be reached as follows: CALL CHEMTREC®(24 hours) 1-800-424-9300 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) For calls originating elsewhere: 703-527-3887 (Collect calls are accepted) or 2. CHEM-TEL, INC., a 24-hour emergency response communication service, can be reached as follows: CALL CHEM-TEL, INC. (24 hours) 1-800-255-3924 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) For calls originating elsewhere: 813-248-0585 (Collect calls are accepted) or 3. INFOTRAC, a 24-hour emergency response communication service, can be reached as follows: CALL INFOTRAC (24 hours) 1-800-535-5053 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) For calls originating elsewhere: 352-323-3500 (Collect ca Ms are accepted) or 4. 3E COMPANY, a 24-houremergency response communication service, can be reached as follows: CALL 3E COMPANY (24 hours) 1-800-451-8346 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) For calls originating elsewhere: 760-602-8703 (Collect ca Ms are accepted) The emergency response information services shown above have requested to be listed as providers of emergency response information and have agreed to provide emergency response information to all callers. They maintain periodically updated lists of state and Federal radiation authorities who provide information and technical assistance on handling incidents involving radioactive materials. Page 10 NATIONAL RESPONSE CENTER (NRC) The NRC, which is operated by the U.S. CoastGuard, receives reports required when dangerous goods and hazardous substances are spilled, Afterreceiving notification of an incident, the NRC will immediately notify the appropriate Federal On-Scene Coordinator and concerned Federal agencies, Federal law requires that anyone who releases into the environment a reportable quantity of a hazardous substance (including oil when wateris, ormay be affected) ora material identified as a marine pollutant, must immediately notify the NRC. When in doubtas to whether the amount released equals the required reporting levels for these materials, the NRC should be notified. CALL NRC (24 hours) 1-800-424-8802 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) 202-267-2675 in the Districtof Columbia Calling the emergency response telephone number, CHEMTREC®,CHEM-TEL, INC., INFOTRAC or 3E COMPANY, does notconstitute compliance with regulatory requirements to call the NRC. MILITARY SHIPMENTS For assistance atincidents involving materials being shipped by, for, or to the Departmentof Defense (DO D), call one of the following numbers (24 hours): 703-697-0218 (call collect) (U.S. Army Operations Center) for incidents involving explosives and ammunition. 1-800-851-8061 (toll-free in the U.S.) (Defense Logistics Agency) for incidents involving dangerous goods otherthan explosives and ammunition. NATIONWIDE POISON CONTROL CENTER (United States Only) Emergency and information calls are answered by the nearest Poison Center (24 hours): 1-800-222-1222 (toll-free in the U .S .). The above numbers are foremergenciesonly. Page11 MEXICO 1. SETIQ(EmergencyTransportation System forthe Chemical Industry), a service ofthe National Association ofChemical Industries (ANIQ), can be reached as follows: CALLSETIQ(24 hours) 01-800-00-214-00 in the Mexican Republic For calls originating in Mexico City and the Metropolitan Area 5559-1588 For calls originating elsewhere, call 011-52-555-559-1588 2. CENACOM, the National Centerfor Communications of the Civil Protection Agency, can be reached as follows: CALL CENACOM (24 hours) 01-800-00-413-00 in the Mexican Republic For calls originating in Mexico City and the Metropolitan Area 5550-1496, 5550-1552, 5550-1485, or 5550-4885 F or ca lis originating elsewhere, call 01 1 -52-555-550-1 496, or 01 1 -52-555-550-1 552 011-52-555-550-1485, or 011-52-555-550-4885 ARGENTINA 1. CIQUIME (InformationCenterforChemical Emergencies) a 24-hour emergency response information service, can be reached as follows: CALL CIQUIME (24 hours) 0-800-222-2933 in the Republic of Argentina For calls originating elsewhere, call +54-11-4613-1100 BRAZIL 1. PRO-QUl'MICA a 24-hour emergency response information service, can be reached as follows: CALL PRO-QUI'MICA (24 hours) 0-800-118270 in the Federal Republic of Brazil For calls originating elsewhere, call +55-11-232-1144 Page 12 COLOMBIA 1. CISPROQUIM a 24-houremergency response information service, can be reached as follows: CALL CISPROQUIM (24 hours) 01-800-091-6012 in Colombia For ca lis originating in Bogota, Colombia call 288-6012 F or ca lis originating elsewhere, call 011-57-1-288-6012 Page 13 HAZARD CLASSIFICATION SYSTEM The hazard class of dangerous goods is indicated either by its class (ordivision) number orname. Fora placard corresponding to the primary hazard class of a material, the hazard class ordivision number must be displayed in the lower corner of the placard. However, no hazard class ordivision number may be displayed on a placard representing the subsidiary hazard of a material. For other than Class 7 or the OXYGEN placard, text indicating a hazard (for example, "CORROSIVE") is not required. Text is shown only in the U .S , The hazard class ordivision number must appear on the shipping document after each shipping name. Class 1 ■ Explosives Division 1.1 Explosives with a mass explosion hazard Division 1.2 Explosives with a projection hazard Division 1.3 Explosives with predominantly a fire hazard Division 1.4 Explosives with no significantblasthazard Division 1.5 Very insensitive explosives with a mass explosion hazard Division 1.6 Extremely insensitive articles Class 2- Gases Division 2.1 Flammable gases Division 2.2 Non-flammable, non-toxic* gases Division 2.3 Toxic*gases Class 3- Flammable liquids (and Combustible liquids [U.S.]) Class 4 ■ Flammable solids; Spontaneously combustible materials; and Dangerous when wet materials/Water-reactive substances Division 4.1 Flammable solids Division 4.2 Spontaneously combustible materials Division 4.3 Water-reactive substances/Dangerous when wetmaterials Class 5 - Oxidizing substances and Organic peroxides Division 5.1 Oxidizing substances Division 5.2 Organic peroxides Class 6 ■ Toxic* substances and Infectious substances Division 6.1 Toxic*substances Division 6.2 Infectious substances Class 7 ■ Radioactive materials Class 8 ■ Corrosive substances Class 9 ■ Miscellaneous hazardous materials/Products, Substances or Organisms * The words "poison" or "poisonous" are synonymous with the word "toxic". Page 14 INTRODUCTION TO THE TABLE OF PLACARDS USE THIS TABLE ONLY IF YOU HAVE NOT BEEN ABLE TO IDENTIFY THE MATERIAL(S) IN TRANSPORT BY ID NUMBER OR NAME The next two pages display the placards used on transport vehicles carrying dangerous goods. As you approach a reported or suspected dangerous goods incident involving a placarded vehicle: 1 . Approach the incident cautiously from upwind to a point from which you can safely identify and/or read the placard or orange panel information. If wind direction allows, consider approaching the incident from uphill. Use binoculars, if available. 2. Match the vehicle placard(s) with one of the placards displayed on the following pages. 3. Consult the numbered guide associated with the sample placard. Use that information for now. For example, a FLAMMABLE (Class 3) placard leads to GUIDE 127. ACORROSIVE (Class 8) placard leads to GUIDE 153. If multiple placards point to more than one guide, initially use the most conservative guide (i.e., the guide requiring the greatest degree of protective actions). 4. Remember that the guides associated with the placards provide the most significant risk and/or hazard information. 5. When specific information, such as ID number or shipping name, becomes available, the more specific guide recommended for that material must be consulted. 6. If GUIDE 111 is being used because only the DANGER/DANGEROUS placard is d isplayed or the nature of the spilled, leaking, or burning material is not known, as soon as possible, get more specific information concerning the material(s) involved. 7. Asterisks (*) on orange placards represent explosives "Compatibility Group" letters; refer to the Glossary (page 359). 8. Double asterisks (**) on orange placards represent the division of the explosive. Page 15 TABLE OF PLACARDS AND INITIAL USE THIS TABLE ONLY IF MATERIALS CANNOT BE SPECIFICALLY IDENTIFIED BY Page 16 RESPONSE GUIDE TO USE ON-SCENE USING THE SHPPING DOCUIVENT, NUMBERED PLACARD, OR ORANGE PANEL NUMBER PageU RAIL CAR IDENTIFICATION CHART* Pressure tank car s — v Non-pressure Compressed (117) tank car (131) liquified gases Liquids V / / REPORTING MARKS 8, CAR NUMBER /CAPACITY IN GALLONS OR LITERS /PLACARD HOLDER* CAUTION: Emergency response personnel must be aware that rail tank cars vary widely in construction, fittings and purpose. Tank cars could transport products that may be solids, liquids or gases. The products may be under pressure. It is essential that products be identified by consulting shipping documents ortrain consistorcontacting dispatch centers before emergency response is initiated. The information stenciled on the sides or ends of tank cars, as illustrated above, may be used to identify the product utilizing: a. the commodity name shown; or b. the other information shown, especially reporting marks and car numberwhich, when supplied to a dispatch center, will facilitate the identification of the product. * The recommended guides should be considered as last resort if product cannot be identified by any other means. Page 18 ROAD TRAILER IDENTIFICATION CHART* DOT406,TC406 Non-pressure Liquid Tank (131] (MC306,TC306) DOT407,TC407 Low pressure Chemical Tank (MC307,TC307) MC338,TC338 Cryogenic Liquid Tank (MC306.TC306) Tube Trailer DOT412,TC412 Corrosive Liquid Tank (MC312,TC312) Dry Bulk Cargo M «.. Trailer DOT407,TC407 Vacuum Loaded Tank DOT412,TC412, (TC350) CAUTION: This chart depicts only the most general shapes of road trailers. Emergency response personnel must be aware thatthere are many variations of road trailers, not illustrated above, thatare used forshipping chemical products. The suggested guides are forthe most hazardous products thatmay be transported in these trailertypes. * The recommended guides should be considered as last resort if product cannot be identified by any other means. Page 19 HAZARD IDENTIFICATION CODES DISPLAYED ON SOME INTERMODAL CONTAINERS Hazard identification codes, referred to as "hazard identification numbers"underEuropean and some SouthAmerican regulations, may be found in the top half of an orange panel on some intermodal bulk containers. The 4-digit identification number is in the bottom half of the orange panel. 33 1203 The hazard identification code in the top half of the orange panel consists of two orthree digits. In general, the digits indicate the following hazards: 2 - EMISSION OF GAS DUE TO PRESSURE OR CHEMICAL REACTION 3 - FLAMMABILITY OF LIQUIDS (VAPORS)AND GASES OR SELF-HEATING LIQUID 4 - FLAMMABILITY OF SOLIDS OR SELF-HEATING SOLID 5 - OXIDIZING (FIRE-INTENSIFYING) EFFECT 6 - TOXICITY OR RISK OF INFECTION 7 - RADIOACTIVITY 8 - CORROSIVITY 9 - MISCELLANEOUS DANGEROUS SUBSTANCE • Doubling ofa digit indicates an intensification ofthatparticularhazard (i.e. 33, 66, 88). • Where the hazard associated with a material can be adequately indicated by a single digit, the digitis followed by a zero (i.e. 30,40, 50). • A hazard identification code prefixed by the letter "X" indicates thatthe material will reactdangerously with water (i.e. X88). • When 9 appears as a 2 nd or 3 rd digit, this may presenta risk of spontaneous violent reaction. Page 20 HAZARD IDENTIFICATION CODES DISPLAYED ON SOME INTERMODAL CONTAINERS The hazard identification codes listed below have the following meanings: 20 L\J I n p rf ri a c II IC 1 L LjU J 77 LL R pfrinpratpH nac r\ c 1 1 1 u c i d lc u y a d LLJ R pfrinpratpH nac f la m ma hip r\ ell iy cl d LcU Ljdj, 1 Id 1 1 II I IdUlc LL J R pfrinp rafprl na^ nyirl 17 inn (firp-intprKifvinn^ 1 \ C 1 1 1 UC 1 □ LC U UQ j, UAIUIUIIU \IIIC 1 1 1 LC 1 1 J 1 ! y 1 1 1 U / 23 LJ F lammahlp na^ 1 lull III lUUICUUJ 236 Flammable gas, toxic 239 Flammable gas which can spontaneously lead to violentreaction 25 Oxidizing (fire-intensifying) gas 26 Toxic gas 263 Toxic gas, flammable 265 Toxic gas, oxidizing (fire-intensifying) 266 Highly toxic gas 268 Toxic gas, corrosive 30 F lammahlp limiirl r id 1 1 ii i id u ic nuu iu 323 F la mmahlp lini lirl whirh rpartc; with watpr pmittinn f la mmahlp nac ridiiiiiiduic iiuuiu vviiilii iccilu wiui vvdici, c 1 1 1 1 in 1 1 y iidiiniiduic y d j X393 AJiJ F la mma hip 1 im i iH w hirh rpa rtc Ha nnp rm ic l\/ with watpr pmittinn flammahlpnac r idiiiniduic iiijuiu wiiilii led Lib Udiiyciuubiy wiui WdLci, ciniLUiiy iidiiniiduic ydb 33 H inhk/ flammahlp liniiiH iiiyiny i id 1 1 ii i id uic iiuuiu J J J Pvrnnhnrir liniiiH r y i upi iui il iiijuiu X333 A J J J Pvrnnhnrir liniiiH whirh rparK Ha nnp rni kIv with watpr ryiuuiiuiiL. iiuuiu vviiilii icuiu uaiiyciuujiy vvilii vvaici JJO l-l in hl\/ fla mma hip liniiiH tnvir niyiiiy iidiiniiduic iiijuiu, luail JJO l-l in h l\/ fla mma hip liniiiH rn rrnc i\/p niyiiiy iidiiniiduic iiijuiu, luiiloivc A J JO l-l in h k/ fla mma hip liniiiH rnrrnc wio w h \c h rpa rtc Ha nnp rm ic l\/ with watp r myiny iidiiniiduic iiijuiu, LUiiubivc, wiiilii icdLLb udiiyciuubiy wiui WdLci 339 H inhlv flammahlp 1 inn iH whir h ran ^nontanpou^lv IpaH to violpnt rpartinn 1 1 IM 1 1 1 y IIUIIIIIIUUI 1 — IIUUIU V V 1 1 1<- 1 1 V.UII J [J U 1 1 LU 1 UU J 1 y ILUU LU V 1 \J 1 v. 1 1 L 1 LULUWI 1 36 Flammable liquid, toxic, orself-heating liquid, toxic 362 Flammable liquid, toxic, which reacts with water, emitting flammable gas X362 Flammable liquid, toxic, which reacts dangerously with water, emitting flammable gas 368 Flammable liquid, toxic, corrosive 38 Flammable liquid, corrosive 382 Flammable liquid, corrosive, which reacts with water, emitting flammable gas X382 Flammable liquid, corrosive, which reacts dangerously with water, emitting flammable gas 39 Flammable liquid which can spontaneously lead to violentreaction 40 Flammable solid, orself-reactive material, orself-heating material 423 Solid which reacts with water, emitting flammable gas Page 21 HAZARD IDENTIFICATION CODES DISPLAYED ON SOME INTERMODAL CONTAINERS X423 Flammable solid which reacts dangerously with water, emitting flammable gas 43 Spontaneously flammable (pyrophoric) solid 44 F lammable solid, in the molten state atan elevated temperature 446 F lammable solid, toxic, in the molten state atan elevated temperature 46 Flammable solid, toxic, orself-heating solid, toxic 462 T" ' 1 1 ■ 1 1 1 i_ 1 1_| i_ 1 ii 1 r\ 1 1 Toxic solid which reacts with water, emitting flammable gas X462 Solid which reacts dangerously with water, emitting toxic gas 48 Flammable orself-heating solid, corrosive 482 Corrosive solid which reacts with water, emitting flammable gas X482 Solid which reacts dangerously with water, emitting corrosive gas 50 Oxidizing (fire-intensifying) substance 539 Flammable organic peroxide 55 Strongly oxidizing (fire-intensifying) substance 556 Strongly oxidizing (fire-intensifying) substance, toxic 558 Strongly oxidizing (fire-intensifying) substance, corrosive 559 Strongly oxidizing (fire-intensifying) substance which can spontaneously lead to violent reaction 56 /■* ■ 1' ■ IC ' 1_ '£ 1 \ 1 1_ 1_ 1 Oxidizing (fire-intensifying) substance, toxic 568 Oxidizing (fire-intensifying) substance, toxic, corrosive 58 /\ ■ i ■ ■ i c 1 i_ 1 c ' \ ii_ 1 Oxidizing (fire-intensifying) substance, corrosive 59 Oxidizing (fire intensifying) substance which can spontaneously lead to violent reaction 60 Toxic material 606 Infectious substance 623 Toxic liquid which reacts with water, emitting flammable gas 63 Toxic liquid, flammable 638 Toxic liquid, flammable, corrosive 639 Toxic liquid, flammable, which can spontaneously lead to violent reaction 64 Toxic solid, flammable orself-heating 642 Toxic solid which reacts with water, emitting flammable gas 65 Toxic material, oxidizing (fire-intensifying) 66 Highly toxic material 663 Highly toxic liquid, flammable 664 Highly toxic solid, flammable orself-heating 665 Highly toxic material, oxidizing (fire-intensifying) 668 Highly toxic material, corrosive Page 22 HAZARD IDENTIFICATION CODES DISPLAYED ON SOME INTERMODAL CONTAINERS 669 1 1 1 1 1 L 1 ■_ 1 1 1 1 1 1_ II 1 1 'll_ J_ r Highly toxic material which can spontaneously lead to violent reaction 68 Toxic material, corrosive 69 Toxic material which can spontaneously lead to violent reaction 70 Radioactive material 72 Radioactive gas 723 Radioactive gas, flammable 73 Radioactive liquid, flammable 74 Radioactive solid, flammable 75 Radioactive material, oxidizing (fire-intensifying) 76 Radioactive material, toxic 78 Radioactive material, corrosive 80 Corrosive material X80 Corrosive material which reacts dangerously with water 823 Corrosive liquid which reacts with water, emitting flammable gas 83 Corrosive liquid, flammable X83 Corrosive liquid, flammable, which reacts dangerously with water 839 Corrosive liquid, flammable, which can spontaneously lead to violent reaction X839 Corrosive liquid, flammable, which can spontaneously lead to violent reaction and which reacts dangerously with water 84 Corrosive solid, flammable or self-heating 842 Corrosive solid which reacts with water, emitting flammable gas 85 Corrosive material, oxidizing (fire-intensifying) 856 Corrosive material, oxidizing and toxic 86 Corrosive material, toxic 88 Highly corrosive material X88 Highly corrosive material which reacts dangerously with water 883 Highly corrosive liquid, flammable 884 i i 1 i i ■ i 1 i [ i ii \r. \ i_' Highly corrosive solid, flammable or self-heating 885 Highly corrosive material, oxidizing (fire-intensifying) 886 Highly corrosive material, toxic X886 Highly corrosive material, toxic, which reacts dangerously with water 89 Corrosive material which can spontaneously lead to violent reaction 90 Miscellaneous dangerous substance; environmentally hazardous substance 99 Miscellaneous dangerous substance transported atelevated temperature Page 23 Note: If an entry is highlighted in either the yellow-bordered or blue-bordered pages AND THERE IS NO FIRE, go directly to the Table of Initial Isolation and Protective Action Distances (green-bordered pages) and look up the ID number and name of material to obtain initial isolation and protective action distances. IF THERE IS A FIRE, or IF A FIRE IS INVOLVED, go directly to the appropriate guide (orange- bordered pages) and use the evacuation information shown under PU BLIC SAF ETY. Page 24 ID Guide Name of Material No. No. 112 Ammonium nitrate-fuel oil mixtures 158 Biological agents 112 Rla^Hnnanpnt n o <; U I CI J L I I I U □ U C 1 I L, I.U.J. 112 E xplos ive A 112 FxnlfKivp R L AUlu J 1 VC U -- 114 Explosive C 112 Explosives, division 1.1, 1,2, 13 1 5 or 1 6 114 F y n In c; iup c; rlivkjnn 1 A L AUIU J 1 VC J | U 1 V 1 J 1 u II ± , ^ 153 Toxins 1001 116 Acetylene 1001 116 Acetylene, dissolved 1002 122 Air, compressed 1003 122 Air, refrigerated liquid (cryogenic liquid) 1003 122 Air, refrigerated liquid ( r rvnn p n ir lin n id ) nnn- \ L 1 y U U C 1 I 1 L IIUU IU / , IUII nrpc c II r\y prj 1005 125 Ammonia anhvdron^ p\iiiiiiuiiici ( ci 1 1 1 1 y u I u u j 1005 125 Ammonia, anhydrous, liquefied 1005 125 Ammonia solution, with more than 50% Ammonia ID Guide No. No. Name of Material 1005 125 Anhydrous ammonia 1005 125 Anhydrous ammonia, liquefied 1006 121 Argon 1006 121 Argon, compressed 1008 125 Boron trifluoride 1008 125 Boron trifluoride, compressed 1009 126 Bromotrifluoromethane 1009 126 Refrigerant gas R-13B1 1010 116P Butadienes, inhibited 1010 1 16P B utadienes , stabilized 1010 116PButadienes and hydrocarbon mixture, stabilized 1011 115 Butane 1011 115 Butane mixture 1012 115 Butylene 1013 120 Carbon dioxide 1013 120 Carbon dioxide, compressed 1014 122 Carbon dioxide and Oxygen mixture 1014 122 Carbon dioxide and Oxygen mixture, compressed 1014 122 Oxygen and Carbon dioxide mixture 1014 122 Oxygen and Carbon dioxide mixture, compressed Carbon dioxide and Nitrous oxide mixture 1015 126 1015 126 Nitrous oxide and Carbon dioxide mixture 1016 119 Carbon monoxide 1016 119 Carbon monoxide, compressed 1017 124 Chlorine 1018 126 Chlorodifluoromethane 1018 126 Refrigerantgas R -22 1020 126 Chloropentafluoroethane 1020 126 Refrigerantgas R-115 1021 126 1-Chloro-l, 2,2,2- tetrafluoroethane 1021 126 Chlorotetrafluoroethane 1021 126 Refrigerantgas R-124 1022 126 Chlorotrifluoromethane 1022 126 Refrigerantgas R -13 1023 119 Coalgas 1023 119 Coal gas, compressed 1026 119 Cyanogen 1026 119 Cyanogen, liquefied 1026 119 Cyanogengas Page 25 ID No. Guide No. Name of Material ID Guide Name of Material No. No. 1027 1027 1028 1028 1029 1029 1030 1030 1030 1032 1033 1035 1035 1036 1037 1038 1039 1039 1040 1040 1041 1041 1041 1041 115 Cyclopropane 115 Cyclopropane, liquefied 126 Dichlorodifluoromethane 126 Refrigerantgas R-12 126 Dichlorofluoromethane 126 Refrigerantgas R-21 115 1,1-Difluoroethane 115 Difluoroethane 115 Refrigerantgas R-152a 118 Dimethylamine, anhydrous 115 Dimethyl ether 115 Ethane 115 Ethane, compressed 118 Ethylamine 115 Ethyl chloride 115 Ethylene, refrigerated liquid (cryogenic liquid) 115 Ethyl methyl ether 115 Methyl ethyl ether 1 1 9P E thylene oxide 119PEthylene oxide with Nitrogen 115 Carbon dioxide and Ethylene oxide mixture, with more than 9% but not more than 87% Ethylene oxide 115 Carbon dioxide and Ethylene oxide mixtures, with more than 6% Ethylene oxide 115 Ethylene oxide and Carbon dioxide mixture, with more than 9% but not more than 87% Ethylene oxide 115 Ethylene oxide and Carbon dioxide mixtures, with more than 6 % Ethylene oxide 1043 125 Fertilizer, ammoniating solution, with free Ammonia 1044 126 Fire extinguishers with compressed gas 1044 126 Fire extinguishers with liquefied gas 1045 124 Fluorine 1045 124 Fluorine, compressed 1046 121 Helium 1046 121 Helium, compressed 1048 125 Hydrogen bromide, anhydrous 1049 115 Hydrogen 1049 115 Hydrogen, compressed 1050 125 Hydrogen chloride, anhydrous 1051 117 AC 1051 117 Hydrocyanic acid, aqueous solutions, with more than 20% Hydrogen cyanide 1051 117 Hydrocyanic acid, liquefied 1051 117 Hydrogen cyanide, anhydrous, stabilized 1051 117 Hydrogen cyanide, stabilized 1052 125 Hydrogen fluoride, anhydrous 1053 117 Hydrogen sulfide 1053 117 Hydrogen sulfide, liquefied 1053 117 Hydrogen sulphide 1053 117 Hydrogen sulphide, liquefied 1055 115 Isobutylene 1056 121 Krypton 1056 121 Krypton, compressed 1057 115 Lighter refills (cigarettes) (flammable gas) 1057 115 Lighters (cigarettes) (flammable gas) 1058 120 Liquefied gas (nonflammable) Page 26 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1058 120 Liquefied gases, non-flammable, charged with Nitrogen, Carbon dioxide or Air 1060 116P Methylacetylene and Propadiene mixture, stabilized 1060 116P Propadiene and Methylacetylene mixture, stabilized 1061 118 Methylamine, anhydrous 1UDZ M ethyl bromide 115 i v i etnyi cn loriae 1063 115 Refrigerantgas R -40 1064 117 Methyl mercaptan 1065 121 Neon 1065 121 Neon, compressed 1066 121 Nitrogen 1066 121 Nitrogen, compressed 1067 124 Dinitrogen tetroxide 1067 124 Dinitrogen tetroxide, liquefied 1067 124 Nitrogen dioxide 1067 124 Nitrogen dioxide, liquefied 1069 125 Nitrosyl chloride 1070 122 Nitrous oxide 1070 122 Nitrous oxide, compressed 1071 119 Oil gas 1071 119 Oil gas, compressed 1072 122 Oxygen 1072 122 Oxygen, compressed 1073 122 Oxygen, refrigerated liquid (cryogenic liquid) 1075 115 Butane 1075 115 Butane mixture 1075 115 Butylene 1075 115 Isobutane 1075 115 Isobutane mixture 1075 115 Isobutylene 1075 115 Liquefied petroleum gas 1075 115 LPG 1075 115 Petroleum gases, liquefied 1075 115 Propane 1075 115 Propane mixture 1075 115 Propylene 1076 125 CG 1076 125 Diphosgene 1076 125 DP 1076 125 Phosgene 1077 115 Propylene 1078 126 Dispersant gas, n.o.s. 1078 126 Refrigerantgas, n.o.s. 1079 125 Sulfurdioxide 1079 125 Sulfurdioxide, liquefiec 1079 125 Sulphurdioxide 1079 125 Sulphurdioxide, liquefied 1080 126 Sulfurhexafluoride 1080 126 Sulphur hexafluoride 1081 116PTetrafluoroethylene, inhibited 1081 1 1 SPTetrafluoroethylene, stabilized 1082 119PTrifluorochloroethylene 1082 119PTrifluorochloroethylene, inhibited 1082 1 1 9P T rifluorochloroethylene, stabilized 1083 118 Trimethylamine, anhydrous 1085 1 1 6P Vinyl bromide, inhibited 1085 1 1 6P Vinyl bromide, stabilized 1086 1 1 6P Vinyl chloride, inhibited 1086 116P Vinyl chloride, stabilized 1087 116P Vinyl methyl ether Page 27 ID Guide Name of Material ID Guide Name of Material No. No. No. No. 1087 1 16P Vinyl methyl ether, inhibited 1127 130 Butyl chloride 1087 116P Vinyl methyl ether, stabilized 1127 130 Chlorobutanes 1088 127 Acetal 1128 129 n-Butyl formate 1089 129 Acetaldehyde 1129 129 Butyraldehyde 1090 127 Acetone 1130 128 Camphoroil 1091 127 Acetone oils 1131 131 C arbon bisulfide 1092 1 31 P Acrolein, inhibited 1131 131 C arbon bisulphide 1092 1 31 P Acrolein, stabilized 1131 131 Carbon disulfide 1093 131 P Acrylonitrile, inhibited 1131 131 Carbon disulphide 1093 131 P Acrylonitrile, stabilized 1133 128 Adhesives (flammable) 1098 131 Allyl alcohol 1134 130 C hlorobenzene 1099 131 A 1 1 y I bromide 1135 131 Ethylene chlorohydrin 1100 131 Allyl chloride 1136 128 Coal tar distillates, flammable 1104 129 Amyl acetates 1139 127 Coating solution 1105 129 Amyl alcohols 1143 131 P C rotonaldehyde, inhibited 1105 129 Pentanols 1143 131 P Crotonaldehyde, stabilized 1106 132 Amylamines 1144 128 Crotonylene 1107 129 Amyl chloride 1145 128 Cyclohexane 1108 128 n-Amylene 1146 128 Cyclopentane 1108 128 1-Pentene 1147 130 Decahydronaphthalene 1109 129 A m vl fn rm ate ^ 1148 129 Diacetone alcohol 1110 127 n-Amyl methyl ketone 1149 128 Butyl ethers 1110 127 Amyl methyl ketone 1149 128 Dibutyl ethers 1110 127 Methyl amyl ketone 1150 130P 1,2-Dichloroethylene 1111 130 Amyl mercaptan 1150 130P Dichloroethylene 1112 140 Amyl nitrate 1152 130 Dichloropentanes 1113 129 Amyl nitrite 1153 127 Ethylene glycol diethyl ether 1114 130 Benzene 1154 132 Diethylamine 1120 129 Butanols 1155 127 Diethyl ether 1123 129 Butyl acetates 1155 127 Ethyl ether 1125 132 n-Butylamine 1156 127 Diethyl ketone 1126 130 1-Bromobutane 1157 128 Diisobutyl ketone 1126 130 n-Butyl bromide 1158 132 Diisopropylamine Page 28 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1159 127 D iiso propyl ether lien llfaU HOI 132 Dimethylamine, aqueous solution 1160 132 Dimethylamine, solution 1161 129 Dimethyl carbonate 1162 155 Dimethyldichlorosilane 1163 131 1,1-Dimethylhydrazine 1163 131 Dimethylhydrazine, unsymmetrical 1164 130 Dimethyl sulfide 1164 130 Dimethyl sulphide 1165 127 Dioxane 1166 127 Dioxolane 1167 128P Divinyl ether, inhibited 1167 19RP Divinyl ether, stabilized 1169 197 I u 1 Extracts, aromatic, liquid 1170 127 Ethanol 1170 I c 1 Ethanol, solution 1170 H 0"7 Ml Ethyl alcohol 1170 127 Ethyl alcohol, solution 1171 127 Ethylene glycol monoethyl ether 1172 129 Ethylene glycol monoethyl ether acetate 1173 129 Ethyl acetate 1175 130 Ethylbenzene 1176 129 Ethyl borate 1177 130 2-Ethylbutyl acetate 1177 130 Ethylbutyl acetate 1178 130 2-Ethylbutyraldehyde 1179 127 Ethyl butyl ether 1180 130 Ethyl butyrate 1181 155 Ethyl chloroacetate 1182 155 Ethyl chloroformate 1183 139 Ethyldichlorosilane 1184 131 Ethylene dichloride 1185 131 P Ethyleneimine, inhibited 1185 131 P Ethyleneimine, stabilized 1188 127 Ethylene glycol monomethyl ether 1189 129 Ethylene glycol monomethyl ether acetate 1190 129 Ethyl formate 1191 129 Fthvlhpxaldphvdes 1191 129 Octyl aldehydes 1192 129 Ethvl lactate 1193 127 Ethyl methyl ketone 1193 127 M ethyl ethyl ketone 1194 131 Ethyl nitrite, solution 1195 129 Ethyl propionate 1196 155 Ethyltrichlorosilane 1197 127 Extracts, flavoring, liquid 1197 127 Extracts, flavouring, liquid 1198 132 Formaldehyde, solution, flammable 1198 132 Formaldehyde, solutions (Formalin) 1199 132P F uraldehydes 1199 1 32P F urfural 1199 132P F urfuraldehydes 1201 127 Fusel oil 1202 128 Diesel fuel 1202 128 Fuel oil 128 Fuel oil, no. 1,2,4,5,6 1202 128 G as oil 1202 128 Heating oil, light 1203 128 Gasohol 1203 128 Gasoline 1203 128 Motorspirit Page 29 ID No. Guide No. Name of Material ID Guide Name of Material No. No. 1228 131 Mercaptans, liquid, flammable, to x i c , n . o . s . 1229 129 M p s i fv I oxirlp 1230 131 M pfh a no 1 I'l C LI 1 □ 1 1 U 1 1230 131 M ethvl alcohol ii t^niyi u i l u 1 1 u i 1231 129 M pthvl arpfafp 1 1 ^ U I y 1 U L C^U 1233 130 Methylamyl acetate 1234 127 Methylal 1235 132 Methylamine, aqueous solution 1237 1 £3 1*1 C LI 1 y 1 U U Ly 1 □ LC 1 23R 1 L J O 1 5 "5 1 OtJ Mpfhvl r h Inrnf n rm a fp I'l C U 1 y 1 LIIIUIUIUIIIIOL.C 1239 131 Mpthvl rhlnrnmpthvl pfhpr I 1 C 1. 1 1 y 1 LIIIUIUIIICLIIyl C L 1 1 C 1 1242 139 Methyldichlorosilane 1 243 i v i c u i y i u 1 1 ii ci lc 1244 131 M ethylhydrazine 1245 127 Methyl isobutyl ketone 1246 127P Methyl isopropenyl ketone, inhibited 1246 127PM ethyl isopropenyl ketone, stabilized 1247 129P Methyl methacrylate monomer, inhibited 1247 129P Methyl methacrylate monomer, stabilized 1248 129 Methyl propionate 1249 127 Methyl propyl ketone 1250 155 Methyltrichlorosilane 1203 1204 128 127 1206 128 1207 130 1208 128 1208 128 1210 129 1210 129 1210 129 1212 129 1212 129 1213 129 1214 132 1216 128 1218 130P 1218 130P 1219 129 1219 129 1220 129 1221 132 1222 130 1223 128 1224 127 1 11 & 1228 131 1228 131 1228 131 1228 131 Petrol Nitroglycerin, solution in alcohol, with not more than 1% Nitroglycerin Heptanes Hexaldehyde Hexanes Neohexane Ink, printer's, flammable Printing ink, flammable Printing ink related material Isobutanol Isobutyl alcohol Isobutyl acetate Isobutylamine Isooctenes Isopropanol Isopropyl alcohol Isopropyl acetate Isopropylamine Isopropyl nitrate Kerosene Ketones, liquid, n.o.s. Lighters forcigars, cigarettes (flammable liquid) Mercaptan mixture, liquid, flammable, poisonous, n.o.s. Mercaptan mixture, liquid, flammable, toxic, n.o.s. Mercaptan mixtures, liquid, n.o.s. Mercaptans, liquid, flammable, poisonous, n.o.s. 1251 131PMethyl vinyl ketone 1251 1 31 P M ethyl vinyl ketone, stabilized 1259 131 Nickel carbonyl 1261 129 Nitromethane 1262 128 Isooctane 1262 128 Octanes 1263 128 Paint(flammable) Page 30 ID Guide Name of Material ID Guide Name of Material No. No. No. No. 1263 128 Paint related material (flammable) 1292 129 Ethyl silicate 1264 129 P araldehyde 1292 129 Tetraethyl silicate 1265 128 Isopentane 1293 127 Tinctures, medicinal 1265 128 n-Pentane 1294 130 Toluene 1265 19ft r ci i La I icj 1295 139 Trichlorosilane 1266 197 I L. 1 P o rf 1 1 m o n/ n rnrl 1 1 r he u/irh rciiuiiiciy [j i u u u l Lb , vviui 1296 132 Triethylamine flammable solvents 1297 132 Trimethylamine, aqueous solution 1267 128 Petroleum crude oil 1298 155 Trimethylchlorosilane 1268 128 Petroleum distillates, n.o.s. 1299 128 Turpentine 1268 128 Petroleum products, n,o,s. 1300 128 Turpentine substitute 1270 128 Oil, petroleum 1301 129P Vinyl acetate 1270 128 Petroleum oil 1301 129P Vinyl acetate, inhibited 1272 129 Pine oil 1301 129P Vinyl acetate, stabilized 1274 129 n-Propanol 1302 127P Vinyl ethyl ether 1274 129 normal Propyl alcohol 1302 127P Vinyl ethyl ether, inhibited 1274 129 Propyl alcohol, normal 1302 127P Vinyl ethyl ether, stabilized 1275 129 Propionaldehyde 1303 130P Vinylidene chloride, inhibited 1276 129 n-Propyl acetate 1303 130P Vinylidene chloride, stabilized 1277 132 Monopropylamine 1304 127P Vinyl isobutyl ether 1277 132 Propylamine 1304 127P Vinyl isobutyl ether, inhibited 1278 129 1-Chloropropane 1304 127P Vinyl isobutyl ether, stabilized 1278 129 Propyl chloride 1305 155P Vinyltrichlorosilane 1279 130 1,2-Dichloropropane 1305 155P Vinyltrichlorosilane, inhibited 1279 130 Dichloropropane 1305 155P Vinyltrichlorosilane, stabilized 1279 130 Propylene dichloride 1306 129 Wood preservatives, liquid 1280 1 27P P ropylene oxide 1307 130 Xylenes 1281 129 Propyl formates 1308 170 Zirconium metal, liquid 1282 129 Pyridine suspension 1286 127 Rosin oil 1308 170 Zirconium suspended in a 1287 127 Rubbersolution flammable liquid 1288 128 Shale oil 1308 170 Zirconium suspended in a liquid (flammable) 1289 132 Sodium methylate, solution in alcohol 1309 170 Aluminum powder, coated Page 31 ID Guide Name of Material ID Guide Name of Material No. No. No. No. 1310 113 Ammonium picrate, wetted with n a t" lac c t"h an 100/, 1*1 •* t-n r IIULIcbb LI 1 ci 11 1U/0 WdLcl 1336 113 Nitroguanidine (Picrite), wetted WILII IIULICbb Llldll L U /0 WdLcl 1312 in 1 00 R a rn a a 1 D Ul llcUl 1336 111 1 1 M itrnnuaniHi no in; p t~t~p rl \A/it"h nnl IM I LI Og U d II IU I II c, WcLLcU WILII MOL 1313 111 loo L d It IU III lcb III d Lc less than 20% water 1314 133 Calcium res in ate, fused 1336 113 P icrite, wetted 1318 133 Cobalt resinate, precipitated 1337 113 N itro starch, wetted with not less than 20% water 1320 113 Dinitronhpnol wpffpd with not LVIIIILIl/kJII^IIl/l, v v ^ I. \X \ \ 1 L 1 1 II v L less than 15% water 1337 113 Nitrostarch, wetted with notless than 30% solvent 1321 113 Dinitrophenolates, wetted with 1338 133 Phosphorus, amorphous n a t" 1 q c c t" h a n 1 ^ 0/* \ki a ho r IIULIcbb Llldll ID /o WdLcl 1322 113 Dinitroresorcinol, wetted with 1338 133 Phosphorus, amorphous, red not less than 15% water 1338 133 Red phosphorus 1323 1 7(1 1 / U rcllOLcllUIll 1338 1 ii 1 00 D o H nhAcnhAnic arviArnhAiic l\ c u pil Ob p II 1 U b , dlllOipilOUb 1324 133 Films, nitrocellulose base 1339 139 Phosphorus heptasulfide, free 1325 133 Flammable solid, n.o.s. from yellow and white P hosphorus 1325 133 Flammable solid, organic, n.o.s. 1339 139 Phosphorus heptasulphide, free 1325 133 F ijc pp (rail or hinhwav) I ujet ^ I u 1 1 \j I 1 1 1 y 1 1 vv u y j from yellow and white 1325 m 1 00 M a rl i I n A r f 1 ^ rvi rvi ^ K 1 A c f\ 1 1 n i v i c u 1 1 1 ii c b , r i a m m a u i e , b o n Q , Phnsnhnrns 1 II UjUMUI U J n.o.s. 1340 139 Phosphorus pentasulfide, free 1326 170 Hafnium powder, wetted with not less than 25% water from yellow and white Phosphorus 1327 133 Bhusa, wet, damp or r A n t"^ rvi i n ^ t"A rl iai i t"ki A i 1 co n La in i n a Leu wilii on 1340 139 Phosphorus pentasulphide, free from vpIIow and whirp 1 1 u i ii yciiuvv ci 1 1 u vviiilc 1327 133 Hay, wet, damp or contaminated P hAcnhArnc r 1 1 u b [j 1 1 u [ Uj with oil 1341 139 Phosphorus sesquisulfide, free 1327 133 Straw, wet, damp or contaminated with oil f r"A m wall am/ a n rl uwhiho iiuiii ycliuw diiu wniic Phosphorus 1328 133 Hexamethylenetetramine 1341 139 P hosphorus sesquisulphide, free from yellow and white 1328 133 Hexamine P hAcnkiANic r 1 1 u j |J 1 1 u l u b 1330 111 M annanptrp rp s i n a fp l v l d 1 1 U d 1 1 C 3 C 1 C J 1 1 1 d LC 1343 ■ion 139 P hosphorus trisulfide, free from 1331 •too loo Matches, "strike anywhere" vpIIow and whifp Pho^nhoru^ y c 1 1 \j w u ii u vviii i 1 1 u j u 1 1 ui u j 1332 loo Metaldehyde 1343 139 P ho^nhoru^ trkulnhidp frpp from 1 1 1 U J U 1 1 U 1 IIJ LllJUIUIIIUCj 1 1 t C IIUIII 1333 170 Cerium, slabs, ingots orrods yellow and white Phosphorus 1334 133 1344 113 Picric acid, wet, with notless Naphthalene, crude than 10% water 1334 133 Naphthalene, refined ID Guide Name of Material ID Guide Name of Material No. No. No. No. 1344 1 1 1 ll 111 LlO pile 110 1, WcLLcO WILll 11 L 1358 I / U 7irrAniiirvi ma ha I nAiA/rlor n, of L\\ LU II IU III lllcLdl, pUWUcI, WcL 1 p c c rhan 30% warpr 1 C j j LI 1 Cl 1 1 JU /0 Vv G LC 1 1358 170 Zirconium powder, wetted with 1345 133 Rubberscrap, powdered or notless than 25% water granulated 1360 139 Calcium phosphide 1345 1 o o R nhhpr c;hnHHv n n w Hp rp H n r granulated 1361 133 Carbon, animal orvegetable orig in 1346 170 Silicon powder, amorphous 1361 133 Charcoal 1347 113 S ilver pic rate, wetted with not 1362 133 Carbon, activated less than 30% water 1363 135 Copra 1348 113 Sodium dinitro-o-cresolate, wetted with not less than 15% 1364 133 f otton waste oilv Q IL IU 1 1 1 II y U MUt 1 4 n S 1 *t U J 11ft C a lr i ii m ^ i Mr irl p ^ G 1 L 1 U 1 1 1 _> 1 1 1 L 1 U C 1406 138 C a lr i ii m c; i 1 i r n n L> □ IL 1 U II 1 JIIIL.L/II 1407 138 C a p c; i ii m •w o c j 1 U 1 II 1407 1 JO C p c; i ii m 1408 139 Ferrosilicon 11ft 1 00 nyuiiucj, iiicLai, it. u.j. 1409 138 Metal hydrides, water-reactive, 1381 136 Phosphorus, white, dryorunder waterorin solution 1381 136 Phosphorus, yellow, dry or under water or in solution 1381 136 White phosphorus, dry 1381 136 White phosphorus, in solution 1381 136 White phosphorus, under water 1381 136 Yellow phosphorus, dry 1381 136 Yellow phosphorus, in solution 1381 136 Yellow phosphorus, underwater 1382 135 Potassium sulfide, anhydrous 1382 135 Potassium sulfide, with less than 30% water of crystallization 1382 135 Potassium sulfide, with less than 30% water of hydration 1382 135 Potassium sulphide, anhydrous 1382 135 Potassium sulphide, with less than 30% water of crystallization 1382 135 Potassium sulphide, with less than 30% water of hydration 1383 135 Aluminum powder, pyrophoric 1383 135 Pyrophoric alloy, n.o.s. 1383 135 Pyrophoric metal, n.o.s. 1384 135 Sodium dithionite 1384 135 Sodium hydrosulfite 1384 135 Sodium hydrosulphite 1385 135 Sodium sulfide, anhydrous 1385 135 Sodium sulfide, with less than 30% water of crystallization 1385 135 Sodium sulphide, anhydrous 1385 135 Sodium sulphide, with less than 30% water of crystallization n.o.s. Page 34 ID Guide Name of Material No. No. ID Guide Name of Material No. No. 1410 138 Lithium aluminum hydride 1411 138 Lithium aluminum hydride, ethereal 1412 139 Lithium amide 1413 138 Lithium borohydride 1414 138 1 ' L 1 . — L. . 1 ' 1 Lithium hydride 1 A 1 C 141b H O O 138 Lithium 1 A 1 7 141 / H O O 138 Lithium silicon 1418 138 Magnesium alloys powder 1418 138 M agnesium powder 1419 139 Magnesium aluminum phosphide 1420 138 Potassium, metal alloys i a 7 n 1420 138 Potassium, metal alloys, liquid 1421 H OO 138 Alkali metal alloy, liquid, n.o.s. 1422 138 Potassium sodium alloys 1422 138 Potassium sodium alloys, liquid 1422 138 Sodium potassium alloys 1422 138 Sodium potassium alloys, liquid 1 A1 7 1423 -too 138 R ubidium 1 A 7 7 1423 -too 138 Rubidium metal 1426 138 Sodium borohydride 142 / 138 Sodium hydride 1428 138 Sodium 1431 138 Sodium methylate 1431 H OO 138 Sodium methylate, dry 1432 139 Sodium phosphide 1433 139 Stannic phosphides 1435 138 Zinc ashes 1 A 7 Z 143b 4 OO 138 Zinc dross 1435 138 Zinc residue 1435 138 Zinc skimmings 1436 138 Zinc dust 1436 138 Zinc powder 1437 138 Zirconium hydride 1/17 H Aft Aluminum nitrate i a 7 n 1433 H A H Ammonium dichromate 1 A At 144Z H A O 143 Ammonium perchlorate 1444 140 Ammonium persulfate 1444 140 Ammonium persulphate 1445 141 Barium chlorate 1 A A C 144b H A 4 141 B arium chlorate, solid 1 A AC 144b H A 4 141 Barium nitrate 1/1/17 144/ H A 4 141 Barium perchlorate 1/1/17 144/ H A H 141 Barium perchlorate, solid 1/1/10 1448 141 Barium permanganate 1449 141 Barium peroxide 1450 141 Bromates, inorganic, n.o.s. 1451 140 Caesium nitrate 1451 140 Cesium nitrate 1452 140 Calcium chlorate 1 A C 7 14ba H A ft 14U Calcium chlorite 1 A C A 14b4 H Aft 14U Calcium nitrate 1 A C C 14bb H Aft 14U C alcium perchlorate 1456 140 Calcium permanganate 1457 140 C alcium peroxide 1458 140 Borate and Chlorate mixtures 1458 140 Chlorate and Borate mixtures 1459 140 Chlorate and Magnesium chloride mixture 1459 140 Chlorate and Magnesium chloride mixture, solid 1459 140 Magnesium chloride and Chlorate mixture 1459 140 Magnesium chloride and Chlorate mixture, solid 1461 140 Chlorates, inorganic, n.o.s. 1462 143 Chlorites, inorganic, n.o.s. ID Guide Name of Material ID Guide Name of Material No. No. No. No. 1463 141 C hromic acid, solid 1488 140 Potassium nitrite 1463 141 Chromium trioxide, anhydrous 1489 140 Potassium perchlorate 1465 140 Didymium nitrate 1490 140 Potassium permanganate 1466 140 Ferric nitrate 1491 144 Potassium peroxide 1467 143 G uanidine nitrate 1492 140 P otassium persulfate 1469 141 Lead nitrate 1492 140 Potassium persulphate 1470 141 Lead perchlorate 1493 140 S ilver nitrate 1470 141 Lead perchlorate, solid 1494 141 Sodium bromate 1470 141 Lead perchlorate, solution 1495 140 Sodium chlorate 1471 140 Lithium hypochlorite, dry 1496 143 Sodium chlorite 1471 140 Lithium hypochlorite mixture 1498 140 Sodium nitrate 1471 140 Lithium hypochlorite mixtures, d ry 1499 140 Potassium nitrate and Sodium n it"i"2 ho in i vhi i tq 11 ILI a Lc 111 IXLU 1 c 1472 141 i to I irhinm norAYirlp l_ I LI 1 1 U 1 1 1 LJCIUAIUC 1499 14(1 I tu QnHinm nitrafo and Pnhacciiim juuiuiii iiiLidLc diiu r ULdbDiuiii 1473 1 4(1 1 tu i*i a y 1 1 c j I u 1 1 1 uiuindic nitrate mixture 1474 14(1 l tu Mannpciiim nit"rat"a l v l d y 1 1 C 3 1 U 1 1 1 1 1 1 LI d Lc 1500 140 Sodium nitrite 1475 14fl I tu I v IOUIICjIUIM uciLiiiuidLC 1502 140 Sodium perchlorate 1476 14(1 I tu Mannaciiim nornyirlo i*i o y 1 1 c j i u i ii [jctuAiud 1503 140 Sodium permanganate 1477 1 4(1 I tu M i tra ho c i n a ta a n i a n a c NILIdLcb, III U 1 y d II 1 L , ll.U.b, 1504 144 Sodium peroxide 1479 140 M edicines, oxidizing 1505 140 Sodium persulfate substances, solid, n.o.s . 1505 140 Sodium persulphate 1479 140 Oxidizing solid, n.o.s. 1506 143 Strontium chlorate 1479 1 4(1 I UXIUIZlUg SUUSLdULcS, SOIIU, 1506 1 40 C 1"^ A n H 1 1 rvi ^hlArafa c n 1 1 n J LIOI1 LIU III CIllOlaLc, SOIIU n.o.s. 1506 1 41 i to Q Ita nHiim rhlAra hp c a 1 1 1 H a n J LI U II LI U III LIIIUIdLc, bUIULIUII 1481 140 Perchlorates, inorganic, n.o.s. 1507 140 S trontium nitrate 1482 140 Permanganates, inorganic, n.o.s. ... P eroxides, inorganic, n.o.s. 1508 140 Strontium perchlorate 1483 140 1509 143 S trontium peroxide 1510 143 Tetranitromethane 1484 140 P otassium bromate Potassium chlorate 1511 140 Urea hydrogen peroxide 1485 140 Potassium nitrate 1512 140 Zinc ammonium nitrite 1486 140 1513 140 Zinc chlorate 1487 140 Potassium nitrate and Sodium nitrite mixture 1514 140 Zinc nitrate 1487 140 Sodium nitrite and Potassium nitrate mixture 1515 14(1 i tu Z.IIIL [JclllldllLjdildLt: ID Guide Name of Material ID Guide Name of Material No. No. No. No. 1516 1 4 J L. I 1 1 L |J c I U A I u c 1557 159 Arconir c 1 1 If i rl p 1517 111 "7 i it a n i 1 1 in nirrainahQ MjaH~arl \A/it"h ZJILUlllUlll piLl CI lIldLc, WcLLcU Willi 1557 159 Arcpnir ciilnhirlp MlbclllL buipniuc not less than 20% water 1557 152 Arsenic trisulfide 1541 155 Acetone cyanohydrin, stabilized 1557 152 Arsenic trisulphide 1544 151 Alkaloids, solid, n.o.s. 1558 152 Arsenic Innir Anniic 1 ^poibunuubj Arsenic pentoxide 1544 1559 151 1^1 A 1 L* a 1 a i rl calhc c a 1 i rl n a c MIKdlUlU bdllb, bOIIU, M.U.b. 1560 (poisonous) 157 Arsenic chloride 1560 1545 155 A 1 1 v 1 Kothiorvanafp inhihitpd 157 Arsenic trichloride 1545 is^ All\/I i c a \\\ i a r \/a n a ho chahili7orl Mllyl 1 3 U LI 1 1 U L y □ 1 1 □ LC , jLaUllliCU 1561 151 Arsenic trioxide 1546 1 51 Ammnniiim arconafp MIMIMUIIIUIM a 1 j C 1 1 a LC 1562 152 Arsenical dust 1547 153 Aniline 1564 154 Barium compound, n.o.s, 1548 153 Anilinp hvdrorhloridp 1565 157 Barium cyanide 1549 157 Antimony compound, inorganic, 1566 154 Beryllium compound, n.o.s. 1549 1 57 n.o.s. 1567 134 Beryllium powder Anfimnnv rnmnnnnH innrnanir MIIUIMUIiy LUIMUUUIIU, IIIUIUCHIIL, 1569 Ion B romoacetone solid, n.o.s. Brucine 1570 1549 157 Antimony tribrom id e, solid 1571 113 Barium azide, wetted with not 1549 157 Antimony tribromide, solution less than 50% water 1549 157 Antimony trifluoride, solid 1572 151 C acodylic acid 1549 157 Antimony trifluoride, solution 1573 151 C air in m arcana ho v^dlLIUIII d I 3 c 1 1 d le 1550 151 Antimony lactate 1574 151 C a \r 1 1 1 m arcpnahp a n H C a r 1 1 1 m LdlLIUIII dlbclldLc dllU LdlLIUIII 1551 1 "51 MlllllllUlly U U Id J J 1 U 1 II LQ 1 U LC arsenite mixture, solid 1553 154 Arsenic acid, liquid 1574 151 falriiim arcpnirp colirl ^ CI 1 L 1 U 1 1 1 □ 1 JUM 1 LC , J v II U 1554 154 Arsenic acid, solid 1574 151 f alrium arsenite and Calcium \rf U 1 L 1 U 1 1 1 U 1 J U 1 1 1 U 1 1 u \^ U 1 L. 1 U 1 II arsenate mixture, solid 1555 151 Arsenic bromide Arsenic compound, liquid, n.o.s. 1575 157 Calcium cyanide 1556 152 1577 153 Chlorodinitrobenzenes 1556 152 Arsenic com pound, liquid, n.o.s., inorganic 1577 153 Chlorodinitrobenzenes, liquid 1577 153 Chlorodinitrobenzenes, solid 1556 152 MD 1556 152 Methyldichloroarsine 1577 153 Dinitrochlorobenzenes 1578 152 Chloronitrobenzenes 1556 152 PD 1557 152 Arsenic compound, solid, n.o.s. 1578 152 Chloronitrobenzenes, liquid 1557 152 Arsenic compound, solid, n.o.s., 1578 152 Chloronitrobenzenes, solid inorganic Page 37 ID Guide No. No. Name of Material ID Guide Name of Material No. No. 1597 152 ninilrohpn7Pnpc; linn id 1597 152 DinilTfihpn7pnpc; ^olirl 1598 153 Dinitro-o-cresol 1599 153 Dinilronhpnol solution 1600 152 Dinitrotoluenes, molten 1601 151 Disinfectant, solid, poisonous, n .o .s . 1601 151 Disinfectant, solid, toxic, n.o.s. 1601 151 Disinfectants, solid, n.o.s. (poisonous) 1602 151 Dve liauid rjoisonous n o s 1602 151 Dye, liquid, toxic, n.o.s. 1602 151 Dye intermediate, liquid, poisonous, n.o.s. 1602 151 Dye intermediate, liquid, toxic, n.o.s. 1603 155 Ethyl bromoacetate 1604 132 F rh vIp n pd i a m i n p i_ uiyiuiiuuiu MIMIC 1605 154 Ffhvlpnp dihromidp l u i y 1 1 1 1 1 u i u i u i ii i u c 1606 151 F p rrir a rc; p n a l"p 1 C 1 1 1 L U 1 J C 1 1 U LC 1607 151 F p rrir a Kpn itp 1 ^. 1 1 IL U 1 J C 1 1 1 LC 1608 151 Ferrous arsenate 1610 159 Halogenated irritating liquid, n.o.s. 1611 151 Hexaethyl tetraphosphate 1611 151 ii j_ i i j_ j_ i i i_ Hexaethyl tetraphosphate, liquid 1611 151 Hexaethyl tetraphosphate, solid 1612 123 Hexaethyl tetraphosphate and compressed gas mixture 1613 154 Hydrocyanic acid, aqueous solution, with less than 5% Hydrogen cyanide 1613 154 Hydrocyanic acid, aqueous solution, with notmore than 20% Hydrogen cyanide 1579 153 4-Chloro-o-toluidine hydrochloride 1579 153 4-Chloro-o-toluidine hydrochloride, solid 1580 154 Chloropicrin 1581 123 Chloropicrin and Methyl bromide mixture 1581 123 Methyl bromide and Chloropicrin mixture 1582 119 Chloropicrin and Methyl chloride mixture 1582 119 1583 154 1585 151 1586 151 1587 151 1588 157 1588 157 1589 125 1589 125 1589 125 1590 153 1590 153 1590 153 1591 152 1593 160 1593 160 1594 152 1594 152 1595 156 1595 156 1596 153 1597 152 Page 38 Methyl chloride and Chloropicrin mixture Chloropicrin mixture, n.o.s. Copper acetoarsenite Copper arsenite Copper cyanide Cyanides, inorganic, n.o.s. Cyanides, inorganic, solid, n.o.s. CK Cyanogen chloride, inhibited Cyanogen chloride, stabilized Dichloroanilines D ic h loroa n ilines , liquid Dichloroanilines, solid o-Dichlorobenzene Dichloromethane Methylene chloride Diethyl sulfate Diethyl sulphate Dimethyl sulfate Dimethyl sulphate Dinitroanilines Dinitrobenzenes ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1613 154 Hydrogen cyanide, aqueous solution, with notmore than 20% Hydrogen cyanide 1614 152 Hydrogen cyanide, anhydrous, stabilized (absorbed) 1614 152 Hydrogen cyanide, stabilized (absorbed) 1616 151 Lead acetate 1617 151 Lead arsenates 1618 151 Lead arsenites 1620 151 Lead cyanide 1621 151 London purple 1622 151 Magnesium arsenate 1623 151 Mercuric arsenate 1624 154 Mercuric chloride 1625 141 Mercuric nitrate 1626 157 Mercuric potassium cyanide 1627 141 Mercurous nitrate 1629 151 Mercury acetate 1630 151 Mercury ammonium chloride 1631 154 Mercury benzoate 1634 154 Mercuric bromide 1634 154 Mercurous bromide 1634 154 Mercury bromides 1636 154 M ercuric cyanide 1636 154 Mercury cyanide 1637 151 M ercury gluconate 1638 151 Mercury iodide 1639 151 Mercury nucleate 1640 151 Mercury oleate 1641 151 Mercury oxide 1642 151 Mercuric oxycyanide 1642 151 Mercury oxycyanide, desensitized 1643 151 Mercury potassium iodide 1644 151 Mercury salicylate 1 C A C 151 M ercuric sulfate 1 C A C 151 Mercuric sulphate 1 C A C 151 Mercury sulfate 1645 151 Mercury sulphate 1646 151 Mercury thiocyanate 1647 151 Ethylene dibromide and Methyl bromide mixture, liquid 1647 151 Methyl bromide and Ethylene dibromide mixture, liquid 1648 127 Acetonitrile 1 C A 1648 1 27 M ethyl cyanide 1649 131 Motor fuel anti-knock mixture 1649 131 Tetraethyl lead, liquid 1650 153 beta-N aphthylamine 1650 153 beta-N aphthylamine, solid 1650 153 N aphthylamine (beta) 1650 153 N aphthylamine (beta), solid i en 1651 153 N aphthylthiourea 1652 153 N aphthylurea 1653 151 N ickel cyanide 1 C C A 1654 151 N icotine 1655 151 Nicotine compound, solid, n.o.s. Idj j 151 Nicotine preparation, solid, n.o.s. ltOD 151 Nicotine hydrochloride lb5b 151 Nicotine hydrochloride, liquid 1656 151 N icotine hydrochloride, solid 1656 151 Nicotine hydrochloride, solution 1657 151 Nicotine salicylate 1658 151 Nicotine sulfate, solid 1658 151 Nicotine sulfate, solution 1658 151 Nicotine sulphate, solid Page 39 ID Guide Name of Material No. No. ID Guide Name of Material No. No. 1658 151 Nicotine sulphate, solution 1659 151 Nicotine tartrate 1660 124 Nitric oxide 1660 124 Nitric oxide, compressed 1661 153 Nitroanilines 1662 152 Nitrobenzene 1663 153 Nitrophenols 1664 152 Nitrotoluenes 1664 152 Nitrotoluenes, liquid 1664 152 Nitrotoluenes, solid 1665 152 N itroxylenes 1665 152 Nitroxylenes, liquid 1665 152 Nitroxylenes, solid 1669 151 Pentachloroethane 1670 157 Perchloromethyl mercaptan 16/1 153 P henol, solid 1672 151 Phenylcarbylamine chloride 1673 153 Phenylenediamines 1674 151 Phenylmercuric acetate 1677 151 Potassium arsenate 1678 154 Potassium arsenite 1679 157 Potassium cuprocyanide 1680 157 Potassium cyanide 1680 157 Potassium cyanide, solid 1683 151 Silverarsenite 1684 151 S ilver cyanide 1685 151 Sodium arsenate 1686 154 Sodium arsenite, aqueous solution 1687 153 Sodium azide i coo 1688 152 Sodium cacodylate 1689 157 Sodium cyanide 1689 157 S odium cyanide, solid 1690 154 Sodium fluoride 1690 154 S odium fluoride, solid 1691 151 Strontium arsenite 1692 151 S trychnine 1692 151 Strychnine salts 1693 159 Tear gas devices 1693 159 Tear gas substance, liquid, n.o.s. 1693 159 Teargas substance, solid, n.o.s. 1694 159 Bromobenzyl cyanides 1694 159 Bromobenzyl cyanides, liquid 1694 159 Bromobenzyl cyanides, solid 1694 159 CA 1695 131 Chloroacetone, stabilized 1697 153 Chloroacetophenone 1697 153 Chloroacetophenone, liquid 1697 153 Chloroacetophenone, solid 1697 153 CN 1698 154 Adamsite 1698 154 Diphenylamine chloroarsine 1698 154 DM 1699 151 DA 1699 151 Diphenylchloroarsine 1699 151 Diphenylchloroarsine, liquid 1699 151 Diphenylchloroarsine, solid 1700 159 Teargas candles 1700 159 Teargas grenades 1701 152 Xylyl bromide 1701 152 Xylyl bromide, liquid 1702 151 1,1,2,2-Tetrachloroethane 1702 151 Tetrachloroethane 1704 153 Tetraethyl dithiopyrophosphate ID Guide Name of Material No. No. ID Guide Name of Material No. No. 1704 153 Tetraethyl dithiopyrophosphate, mixture, dry or liquid 1707 151 Thallium compound, n.o.s. 1707 151 Thallium sulfate, solid 1707 151 Thallium sulphate, solid 1708 153 Toluidines 1708 153 Toluidines, liquid nno 1/08 153 Toluidines, solid 1709 151 2,4-Toluenediamine 1709 151 2,4-Toluylenediamine i "7 n n 1/09 151 2,4-Toluylenediamine, solid 1710 160 Trichloroethylene 1711 153 Xylidines 1711 153 Xylidines, liquid 1711 153 Xylidines, solid 1712 151 Zinc arsenate 1712 151 Zinc arsenate and Zinc arsenite mixture 1712 151 Zinc arsenite 1712 151 Zinc arsenite and Zinc arsenate mixture 1713 151 Zinc cyanide 1714 139 Zinc phosphide 1715 137 Acetic anhydride 1716 156 Acetyl bromide 1717 155 Acetyl chloride 1718 153 Acid butyl phosphate 1718 153 Butyl acid phosphate 1719 154 Caustic alkali liquid, n.o.s. 1722 155 Allyl chlorocarbonate 1722 155 Allyl chloroformate 1723 132 Allyl iodide 1724 155 Allyltrichlorosilane, stabilized 1725 137 Aluminum bromide, anhydrous 1726 137 Aluminum chloride, anhydrous 1727 154 Ammonium bifluoride, solid 1727 154 Ammonium hydrogendifluoride, solid 1727 154 Ammonium hydrogen fluoride, solid 1 1 1 Q 1 / la 133 Amyltrichlorosilane 1729 156 Anisoyl chloride 1730 157 Antimony pentachloride, liquid 1731 157 Antimony pentachloride, solution 1 in 13/ Antimony pentafluoride 1 / ii 13/ Antimony trichloride 1 1 ii 157 Antimony trichloride, liquid 1 / ii 13/ Antimony trichloride, solid 1 / JJ i C7 13/ Antimony trichloride, solution 1 1 3 C 1 / JO 107 10/ Benzoyl chloride 1737 1 1 i 1 ire 130 Benzyl bromide 1738 156 Benzyl chloride 1739 137 Benzyl chloroformate 1740 154 Hydrogendifluorides, n.o.s. 1741 125 Boron trichloride 1742 157 Boron trifluoride acetic acid complex 1742 157 Boron trifluoride acetic acid complex, liquid 1743 157 Boron trifluoride propionic acid complex 1743 157 Boron trifluoride propionic acid complex, liquid 1744 154 Bromine 1744 154 Bromine, solution 1745 144 Bromine pentafluoride Page 41 ID No. Guide No. Name of Material ID Guide Name of Material No. No. 1760 154 Compound, tree or weed killing, lionid (rorrosivp) 1760 154 rorro<;i\/p linnirl n o $ 1760 154 FprrniK rhlnridp c;oliition I CIIUUJ LMIUIIUCjJUIULIUII 1760 154 Mpdirinp^ rorro^ivp linuid n o $ 1760 154 Titanium c,nlfatp c; n 1 1 j fin n 1 KU 1 1 1 U 1 1 1 J U 1 1 U L C , J U 1 U LIU 1 1 1760 154 Titanium sulphate, solution 1761 154 Cupriethylenediairiine, solution 1762 1 JU TurlnhpYpnultrirhlnrnciilanp \* yLIUIICACIiyiLI ILIIIUI Uj 1 1 □ 1 1 C 1763 156 rvrlnhpvvltrirhlnrn^ilanp •w yLIUIItAVIU 1 L 1 1 1 U 1 U J 1 1 U IIC 1764 153 Dichloroacetic acid 1765 156 nirhloroarptvl r h loridp L> ILII1UI UU LCLy 1 L 1 1 1 U 1 J U C 1766 1 JU Dirhlnrnnhpn\/ltrirhlnrnc;ilanp UlLIIIUIUfJIICIiyiUILIIIUIUiMClllC 1767 155 Diethyldich lorosilane 1768 154 Difluorophosphoric acid, a n h vd rn II c; u 1 1 1 1 y u i u u j 1769 156 Diphenyldichlorosilane 1770 153 D i n h pn vl mpth vl hrnmidp L»iuiiciiyiiiicLiiyi u i u ii i iu c 1771 156 Dndprvltrirhlnrn^ilanp L> U U t L J 1 U 1 L 1 1 1 U 1 U J 1 1 CI 1 1 C 1773 157 F p rrir r h In rid p 1 C 1 1 1 L L 1 1 IU 1 IU C 1 773 1 57 Forrir rhlArirlo anhvrlrniic rciiiL l 1 1 1 u 1 1 u c , a 1 1 1 1 y u [ u u b 1774 154 Fire extinguisher charges, 1746 144 Bromine trifluoride 1747 155 R utv tnrh orosi anp 1 1 A P 1 An C al^iiim Vi \f n ft r \\ 1 (\ ri Ypt rl r\i LdiLiuni nypocnioriLc, ury 1 1 A Q 1 /4b Calcium hypochlorite mixture, dry, with more than 39% available Chlorine (8.8% available Oxygen) 1749 124 Chlorine trifluoride 1750 153 Chloroacetic acid, liquid 1750 153 Chloroacetic acid, solution 1751 153 Chloroacetic acid, solid 1752 156 Chloroacetyl chloride 1753 156 Chlorophenyltrich lorosilane 1754 137 Chlorosulfonic acid 1754 137 Chlorosulfonic acid and Sulfur trioxide mixture 1754 137 C hloros ulphonic acid 1754 137 Chlorosulphonic acid and Sulphurtrioxide mixture 1754 137 Sulfurtrioxide and Chlorosulfonic acid mixture 1754 137 Sulphurtrioxide and Chlorosulphonic acid mixture 1755 154 Chromic acid, solution corrosive liquid 1756 154 Chromic fluoride, solid 1775 154 Fluoboric acid 1757 154 Chromic fluoride, solution 1775 154 Fluoroboric acid 1758 137 Chromium oxychloride 1776 154 Fluorophosphoric acid, 1759 154 Corrosive solid, n.o.s. anhydrous 1759 154 Ferrous chloride, solid 1777 137 Fluorosulfonic acid 1759 154 Medicines, corrosive, solid, 1777 137 Fluorosulphonic acid n.o.s. 1778 154 Fluorosilicic acid 1760 154 Chemical kit 1778 154 Fluosilicic acid 1760 154 Compound, cleaning liquid 1778 154 Hydrofluorosilicic acid (corrosive) 1779 153 Formic acid 1780 156 Fumaryl chloride Page 42 ID Guide Name of Material No. No. 1781 156 Hexadecyltrichlorosilane 1782 154 H exafluorophosphoric acid 1 783 1 JO iicAcniicuiyiciicujuiiiMic, j u i u u u 1 1 1784 156 Hexyltrichlorosilane 1786 157 Hydrofluoric acid and Sulfuric acid mixture 1786 157 Hydrofluoric acid and Sulphuric acid mixture 1786 157 Sulfuric acid and Hydrofluoric acid mixture 1786 157 Sulphuric acid and Hydrofluoric acid mixture 1787 154 Hydriodic acid 1787 154 Hydriodic acid, solution 1788 154 Hydrobromic acid 1788 154 Hydrobromic acid, solution 1789 157 H ydrochloric acid 1789 157 H vd rn r h In rir a rirl solution 1789 157 M uriatic acid 1790 157 H vd rnfln n rir arid 1790 157 Hydrofluoric acid, solution 1791 154 Hypochlorite solution 1791 154 Hypochlorite solution, with more than 5% a vail a hip rhlorinp U I CI I I _J /U □ V □ MQ UIC L. 1 1 1 \J 1 1 1 1 C 1792 157 Iodine monochloride 1793 153 Isopropyl acid phosphate 1794 154 Lead sulfate, with more than 3% free acid 1794 154 Lead sulphate, with more than 3% free acid 1796 157 N itrating acid mixture 1798 157 Aqua regia 1798 157 N itrohvdrorhlorir arid 1799 156 Monvltrirhlorosilanp 1800 156 Octadecyltrichlorosilane ID Guide Name of Material No. No. 1801 156 Octyltrichlorosilane 1802 140 Perchloric acid, with notmore than 50% arid LI I U 1 1 Ju /U U L. 1 U 1803 153 P hpnokulfonir arid linuid 1 IIV^IIUIJUHUIIIL, U L IU f MU U 1 u 1 803 1 U J 1 l JO P h p n n 1 c; ii 1 nh n n i r arid linuid r iiciiuijuiuiiuiiil □ l. i u , iiuuiu 1804 156 Phpnvlrrirhloro^ilanp 1805 154 P h os phoric acid 1805 154 Phn^nhnrir arid linuid 1 II u J Ull U 1 IL QLIll, IIUUIU 1805 154 Phn^nhnrir arid ^olid 1 II u J U II ul IL LILIU, J u 1 IU 1805 1 "54 P h n c; nh n rir arid snlntinn rllUjUllUllL □ L. 1 U , J U 1 U LI U 1 1 1806 137 P hn^nhnru^ npnrarhloridp 1 1 1 U J J 1 1 U 1 U J UUIILULIIIUI IUU 1807 137 Phosphorus pentoxide 1 R0.R 1 O U 1 17 Phncnhnnic hrihrninidp r 1 1 u j [j 1 1 u i u j li iui uiiiiuc 1809 137 Phosphorus trichloride 1810 137 Pho^nhorii^ oxvrh oridp 1 1 1 U J U 1 1 U 1 U J U AV L II IUI IU t 1811 154 Potassium hydrogendifluoride 1811 154 Potassium hydrogen difluoride, solid 1812 154 Potassium fluoride 1812 154 Potassium fluoride, solid 1813 154 Caustic potash, dry, solid 1813 154 Potassium hydroxide, dry, solid 1813 154 Potassium hydroxide, flake 1813 154 Potassium hydroxide, solid 1814 154 Caustic potash, liquid 1814 154 Caustic potash, solution 1814 154 Potassium hydroxide, solution 1815 132 Propionyl chloride 1816 155 Propyltrichlorosilane 1817 137 Pyrosulfuryl chloride 1817 137 Pyrosulphuryl chloride 1818 157 Silicon tetrachloride 1819 154 Sodium aluminate, solution Page 43 ID Guide Name of Material No. No. ID Guide Name of Material No. No. 1823 154 Caustic soda, bead 1823 154 Caustic soda, flake 1823 154 C austic soda, granular 1823 154 C austic soda, solid 1823 154 Sodium hydroxide, bead 1823 154 Sodium hydroxide, dry 1823 154 Sodium hydroxide, flake 1823 154 Sodium hydroxide, granular 1823 154 Sodium hydroxide, solid 1824 154 Caustic soda, solution 1824 154 Sodium hydroxide, solution 1825 157 Sodium monoxide 1826 157 Nitrating acid mixture, spent 1827 137 Stannic chloride, anhydrous 1827 137 Tin tetrachloride 1828 137 Sulfurchlorides 1828 137 5 ulphur chlorides 1829 137 Sulfurtnoxide 1829 137 Sulfurtrioxide, inhibited 1829 137 Sulfurtrioxide, stabilized 1829 137 Sulfurtrioxide, uninhibited 1829 137 5 ulphur trioxide 1829 137 Sulphurtrioxide, inhibited 1829 137 Sulphurtrioxide, stabilized 1829 137 Sulphurtrioxide, uninhibited 1830 137 Sulfuric acid 1830 137 Sulfuric acid, with more than 51% acid 1830 137 S ulphuric acid 1830 137 Sulphuric acid, with more than 51% acid 1831 137 Sulfuric acid, fuming 1831 137 Sulfuric acid, fuming, with less than 30% free Sulfurtrioxide 1831 137 Sulfuric acid, fuming, with not less than 30% free Sulfur trioxide 1831 137 Sulphuric acid, fuming 1831 137 Sulphuric acid, fuming, with less than 30% free Sulphur trioxide 1831 137 Sulphuric acid, fuming, with not less than 30% free Sulphur trioxide 1832 137 S ulfuric acid, spent 1832 137 S ulphuric acid, spent 1833 154 S ulfurous acid 1833 154 Sulphurous acid 1834 137 Sulfuryl chloride 1834 137 Sulphuryl chloride 1835 153 Tetramethylammonium hydroxide 1835 153 Tetramethylammonium hydroxide, solution 1836 137 Thionyl chloride 1837 157 Thiophosphoryl chloride 1838 137 Titanium tetrachloride 1839 153 Trichloroacetic acid 1840 154 Zinc chloride, solution 1841 171 Acetaldehyde ammonia 1843 141 Ammonium dinitro-o-cresolate 1843 141 Ammonium dinitro-o-cresolate, solid 1845 120 Carbon dioxide, solid 1845 120 Dry ice 1846 151 Carbon tetrachloride ID Guide Name of Material No. No. 1847 153 Potassium sulfide, hydrated, with notless than 30% waterof crystallization 1847 153 Potassium sulfide, hydrated, with notless than 30% waterof nyaracion 1847 153 Potassium sulphide, hydrated, with not less than 30% water of crystallization 1847 153 Potassium sulphide, hydrated, with not less than 30% water of hydration 1 Q A Q P ropionic acid 1849 153 Sodium sulfide, hydrated, with notless than 30% water 1849 153 Sodium sulphide, hydrated, with not less than 30% water 1851 151 Medicine, liquid, poisonous, n.o.s. 1851 151 Medicine, liquid, toxic, n.o.s. 1 P ^A 101; 1 00 □ diiuiii aiioys, pyropnonc 1855 135 Calcium, metal and alloys, nvronhorir 1855 135 Calcium, pyrophoric 1855 135 Calcium alloys, pyrophoric 1856 133 R a n ^ fi i Iv i \ □ y j , u i i y 1857 133 Textile waste, wet 1858 126 Hexafluoropropylene 1858 126 R pfriripra nl" n ?k R - 1 7 1 fi 1859 125 S iliron rprraflnoridp _> 1 1 IV. \J 1 1 LC LI U 1 1 U U 1 IUC 1859 125 Silicon tetrafluoride, compressed 1860 116P Vinyl fluoride, inhibited 1860 116P Vinyl fluoride, stabilized 1862 130 Ethyl crotonate 1 J 128 Fuel, aviation, turbine engine 1865 131 n-Propyl nitrate ID Guide Name of Material No. No. 1866 127 R PC in CAlnf-jAn r\ c j 1 1 1 j u i u u u 1 1 1868 134 Decaborane 1869 138 Magnesium 1869 138 Magnesium, in pellets, turnings or ribbons 1869 138 Magnesium alloys, with more than 50% Magnesium, in npiipt-c hirninos or rihhons U f LU 1 1 1 1 1 1 U 3 \J 1 1 1 U UU 1 1 J 1870 138 P ora c; c j ii m h n rn h vrl rirl p i U 1 1 u t tnyi cniorotniorormate 2810 153 Toxic liquid, n.o.s. (Inhalation Hazard Zone B) 2823 2826 1 JO loo 2810 153 Toxic liquid, organic, n.o.s. 2829 153 Caproic acid 2810 153 Toxic liquid, organic, n.o.s. (Inhalation Hazard Zone A) 2829 153 Hexanoic acid 2830 2831 139 160 1 ithium fprro^iliron l_ 1 U 1 1 U 1 1 1 ICIIUJIMLUII 1,1,1-Trichloroethane 2810 153 Toxic liquid, organic, n.o.s. (Inhalation Hazard Zone B) 2834 154 Phosphorous acid 2810 153 VX 2834 154 Phosphorous acid, ortho 2811 154 CX Page 68 ID Guide Name of Material ID Guide Name of Material No. No. No. No. 2835 138 Sodium aluminum hydride 2855 151 Zinc fluorosilicate 2837 154 Bisulfates, aqueous solution 2855 151 Zinc silicofluoride 2837 154 Bisulphates, aqueous solution 2856 151 Fluorosilicates, n.o.s. 2837 154 S od in m his n Ifate solution 2856 151 S iliroflnoridps n o s 2837 154 Sodium bisulphate, solution 2857 126 Refrigerating machines, 2837 154 Sodium hydrogen sulfate, solution containing Ammonia solutions (UN2073) 2837 154 Sodium hydrogen sulphate, 2857 126 Refrigerating machines, solution containing Ammonia solutions /II M T C. 1 ~) \ (U N ZD / 1} 2838 129P Vinvl butvrate. inhibited Refrigerating machines, 2857 126 2838 129P Vinyl butyrate, stabilized containing non-flammable, 2839 153 Aldol liniipfipH na^ 2840 129 Butyraldoxime 2857 lib Refrigerating machines, 2841 131 Di-n-amylamine containing non-flammable, n a n - n a ic a n a 1 1 c nacQC I iu 1 1 |ju I j u 1 1 u u j y a b c b 2842 129 Nitroethane Refrigerating machines, 2857 126 2844 138 Calcium manganese silicon containing non-flammable, 2845 135 Ethyl phosphonous dichloride, non-poisonous, liquefied gas a n h \/rl i"a 1 1 c Qiiiiyui v u j 2857 1 £0 R of ri a o H n a marhinoc rxcliiycldUiiy illclLillilcb, 2845 135 Methyl phosphonous dichloride containing non-flammable, 2845 135 Pyrophoric liquid, n.o.s. non-poisonous, non- rni"i"nci\/o linnofioH nac LUiiusivc, ni_|uciicu ycib 2845 135 Pyrophoric liquid, organic, n.o.s. 2857 126 Refrigerating machines, 2846 135 Pyrophoric solid, n.o.s. rnnfaininn nnn-flaminahlp LUIKClllllliy MUM IIC1MIMIC1UIC, 2846 135 Pyrophoric solid, organic, n.o.s. non-toxic gases 2849 153 3-Chloropropanol-l 2857 126 Refrigerating machines, containing non-flammable, 2850 128 Propylene tetramer nnn-hAYir linnofioH nac IIUII LUAIL, liyUCIICU )jQj 2851 157 Boron trifluoride, dihydrate 2857 126 Refrigerating machines, 2852 113 Dipicryl sulfide, wetted with not less than 10% water containing non-flammable, non-fnxir nnn-rnrrnc;i\/p MUM LUAIL, MUM LU II U J 1 V C ( 2852 113 Dipicryl sulphide, wetted with n ii o f p H nac IlljUcllcU y a b not less than 10% water 2858 170 Zirconium, dry, coiled wire, 2853 151 Magnesium fluorosilicate finished metal sheets or strips Ammonium metavanadate 2853 151 Magnesium silicofluoride 2859 104 2854 151 Ammonium fluorosilicate 2861 151 Ammonium polyvanadate 2854 151 Ammonium silicofluoride 2862 151 Vanadium pentoxide Page 69 ID Guide Name of Material ID Guide Name of Material No. No. No. No. 2863 154 Sodium ammonium vanadate 2904 154 Chlorophenar.es, liquid 2864 151 Potassium metavanadate 2904 154 Chlorophenolar.es, liquid 2865 154 Hydroxylamine sulfate 2904 154 P henolates, liquid 2865 154 Hydroxylamine sulphate 2905 154 Chlorophenates, solid 2869 157 Titanium trichloride mixture 2905 154 Chlorophenolar.es, solid 2870 135 Aluminum borohydride 2905 154 P henolates, solid 2870 135 Aluminum borohydride in devices 2907 133 Isosorbide dinitrate mixture 2871 17fl AnHmnnv nnwrlpr Miiuiiiuiiy uwvvuci 2908 R aHinarfivp material pmnrv r\ GUIUQLUVC 1 1 1 u LC 1 1 CI 1 , ClllUly 2872 159 Dibromochloropropanes packages 2873 153 Dibutylaminoethanol 2908 161 Radioactive material, excepted package, empty packaging 2874 153 Furfuryl alcohol 2909 161 Radioactive material, articles 2875 151 H pxa rh loronhpnp I I t AU L II 1 U 1 \J yj 1 1 C 1 1 t manufactured from depleted 2876 130 1 1 ra n ium \J 1 O 1 1 1 U 1 1 1 2878 170 Titaniumspongegranules 2909 161 Radioactive material, articles 2878 170 Titanium sponge powders manufactured from natural Thorium 2879 157 Selenium oxychloride 2909 161 Radioactive material, articles 2880 140 Calcium hypochlorite, hydrated, wil"h nnflpc;c; rhan S S% hnr vv 1 U I IIUl ICjj UICHI JiJ/0 UUl manufactured from natural U ran ium not more than 16% water 2909 161 Radioactive material, excepted 2880 140 Calcium hypochlorite, hydrated mixture, with notless than 5 5% hntnntmnrpthan lfi% J i J /0 UUIIIUIIMUIC UICHI 1U/D package, articles manufactured from depleted U ra n iu m water 2909 161 Radioactive material, excepted 2881 HOC 1 35 Metal catalyst, dry package, articles 2881 HOC 1 35 N ickel catalyst, dry manufactured from natural T h a rii| m 1 1 1 U 1 1 U 1 1 1 2900 158 Infectious substance, affecting animals only 2909 161 Radioactive material, excepted package, articles manufactured from natural 2901 124 Bromine chloride 2902 1 51 PocHrirlo liniiirl nAiCAriAiic r CjULIUc, IILjUlU, |JUIjUIIUUj, 1 1 r n 1 1 1 iyi U 1 d 11 1 U III n a c 1 1 . U . 3 . 2910 161 Radioactive material, excepted 2902 151 Pesticide, liquid, toxic, n.o.s. package, articles 2903 131 Pesticide, liquid, poisonous, flammable, n.o.s. iYi 3 n 1 1 f 3 c t"i i rp H frAm rlpnlphprl III d II U 1 a L LU 1 c U IIUIII UcpicLcU U ran ium 2903 131 Pesticide, liquid, toxic, 2910 161 Radioactive material, excepted flammable, n.o.s. package, articles manufactured from natural Thorium ID Guide No. No. Name of Material ID Guide No. No. Name of Material 2910 161 Radioactive material, excepted package, articles manufactured from natural Uranium 2910 161 Radioactive material, excepted package, empty packaging 2910 161 Radioactive material, excepted package, instruments or articles 2910 161 Radioactive material, excepted package, limited quantity of material 2910 161 Radioactive material, limited quantity, n.o.s. 2911 161 Radioactive material, excepted package, instruments or articles 2911 161 Radioactive material, instruments orarticles 2912 162 Radioactive material, low specific activity (LS A), n.o.s. 2912 162 Radioactive material, low specific activity (LSA-I) 2913 162 Radioactive material, surface contaminated objects (SCO) 2913 162 Radioactive material, surface contaminated objects (SCO-I) 2913 162 Radioactive material, surface contaminated objects (SCO-II) 2915 163 Radioactive material, Type A package 2916 163 Radioactive material, Type B(U) package 2917 163 Radioactive material, Type B(M) package 2918 165 Radioactive material, fissile, n.o.s. 2919 163 Radioactive material, transported underspecial arrangement 2920 132 2920 132 2921 134 2922 154 2922 154 2922 154 2922 154 2923 154 2923 154 2924 132 2925 134 2925 134 2926 134 2926 134 2926 134 2927 154 2927 154 2927 154 Corrosive liquid, flammable, n.o.s. Dichlorobutene Corrosive solid, flammable, n.o.s. Corrosive liquid, poisonous, n.o.s. Corrosive liquid, toxic, n.o.s. Sodium hydrosulfide, solution Sodium hydrosulphide, solution Corrosive solid, poisonous, n.o.s. Corrosive solid, toxic, n.o.s. Flammable liquid, corrosive, n.o.s Flammable solid, corrosive, n.o.s. Flammable solid, corrosive, organic, n.o.s. Flammable solid, poisonous, n.o.s, Flammable solid, poisonous, organic, n.o.s. Flammable solid, toxic, organic, n.o.s. Ethyl phosphonothioic dichloride, anhydrous Ethyl phosphorodichloridate Poisonous liquid, corrosive, n.o.s. 2927 154 Poisonous liquid, corrosive, n.o.s. (Inhalation Hazard Zone A) 2927 154 Poisonous liquid, corrosive, n.o.s. (Inhalation Hazard ZoneB) Toxic liquid, corrosive, organic n.o.s. I 2927 154 2927 154 Toxic liquid, corrosive, organic, n.o.s. (Inhalation Hazard Zone A) 1 Page 71 ID Guide Name of Material No. No. 2927 154 Toxic liquid, corrosive, organic, n.o.s. (Inhalation Hazard Zone B) 2928 154 Poisonous solid, corrosive, n.o.s. 2928 154 Toxic solid, corrosive, organic, n.o.s. 2929 131 Poisonous liquid, flammable, n.o.s. 2929 131 Poisonous liquid, flammable, n.o.s. (Inhalation Hazard Zone A) 2929 131 Poisonous liquid, flammable, n.o.s. (Inhalation Hazard Zone B) 2929 131 Poisonous liquid, flammable, organic, n.o.s. 2929 131 Poisonous liquid, flammable, organic, n.o.s. (Inhalation Hazard Zone A) 2929 131 Poisonous liquid, flammable, organic, n.o.s. (Inhalation Hazard Zone B) 2929 131 Toxic liquid, flammable, n.o.s. 2929 131 Toxic liquid, flammable, n.o.s. (Inhalation Hazard Zone A) 2929 131 Toxic liquid, flammable, n.o.s. (Inhalation Hazard Zone B) 2929 131 Toxic liquid, flammable, organic, n.o.s. 2929 131 Toxic liquid, flammable, organic, n.o.s. (Inhalation Hazard Zone A) 2929 131 Toxic liquid, flammable, organic, n.o.s. (Inhalation Hazard Zone B) 2930 134 Poisonous solid, flammable, n.o.s. 2930 134 Poisonous solid, flammable, organic, n.o.s, ID Guide Name of Material No. No. 2930 134 Toxic solid, flammable, n.o.s. 2930 134 Toxic solid, flammable, organic, n.o.s. 2931 151 Vanadyl sulfate 2931 151 Vanadyl sulphate 2933 129 Methyl 2-chloropropionate 2934 129 Isopropyl 2-chloropropionate 2935 129 Fthul 2-rhloronroninnate 2936 153 Thiolactic acid 2937 153 alpha-Methylbenzyl alcohol 2937 153 II R 1 l_l 1 1 II II alpha-Methylbenzyl alcohol, liquid 2937 153 M pl"hvlhpn7 vl alrohol falnha) iici.iiyiuciii.yi ci i c u 1 1 u i \ u i u 1 1 ci j 2938 152 M ethyl benzoate 2940 135 Cyclooctadiene phosphines 2940 135 Q-P hn^nhahirvrlnnnnanpc; 2941 153 Fluoro anilines 2942 153 2-Trifluoromethylaniline 2943 129 Tetrahydrofurfurylamine 2945 132 N-Methylbutylamine 2946 153 2-Amino-5-diethylaminopentane 2947 155 Isopropyl chloroacetate 2948 153 3-Trifluoromethylaniline 2949 154 Sodium hydrosulfide, with not less than 25% water of crystallization 2949 154 Sodium hydrosulphide, with not less than 25% water of crystallization 2950 138 Magnesium granules, coated 2956 149 5-tert-Butyl-2,4,6-trinitro- m-xylene 7 Q c 1 dQ I 13 M 1 1 c V vvlono l"l u j l\ Ay Icll c 2965 139 Boron trifluoride dimethyl etherate ID Guide Name of Material No. No. 2966 153 T h inn Ivrnl i 1 1 1 u y i y l u i 2967 154 S nlfamir arid -J U I I U I I I I L CI L I U 2967 154 Snlnhamir arid 2968 135 M aneb, stabilized 2968 135 Maneb preparation, stabilized 2969 171 Castor beans, meal, pomace or flake 2974 164 Radioactive material, special form, n .o .s . 2975 162 Thorium metal nvronhorir 1 1 1 \J 1 1 u 1 1 1 IMC lli if yj y 1 \J yj 1 1 \J 1 J V- 2976 162 Thorium nitrate, solid 2977 166 Radioactive material, Uranium hexafluoride, fissile 2977 166 Uranium hexafluoride, fissile containing more than 1% Uranium-235 2978 166 Radioactive material, Uranium hexafluoride 2978 166 Radioactive material, Uranium hexafluoride, non-fissile or ficcilp-pyrpnt-prj 2978 166 Uranium hexafluoride 2978 166 Uranium hexafluoride, fissile- excepted 2978 166 Uranium hexafluoride, low specific activity 2978 166 Uranium hexafluoride, non-fi^ilp nun I I j j I I c 2979 162 Uranium metal, pyrophoric 2980 162 Uranium nitrate, hexahydrate, solution 2980 162 Uranyl nitrate, hexahydrate, solution 1 Q 1 1 CO U ranyl nitrate, solid 2982 163 Radioactive material, n.o.s. ID Guide No. No. Name of Material 2983 129P Ethylene oxide and Propylene oxide mixture, with notmore than 30% Ethylene oxide 2983 129P Propylene oxide and Ethylene oxide mixture, with notmore than 30% Ethylene oxide 2984 140 Hydrogen peroxide, aqueous solution, with not less than 8% but less than 20% Hydrogen peroxide 2985 155 Chlorosilanes, flammable, corrosive, n.o.s. 2985 155 Chlorosilanes, n.o.s. 2986 155 Chlorosilanes, corrosive, flammable, n.o.s. 2986 155 Chlorosilanes, n.o.s. 2987 156 Chlorosilanes, corrosive, n.o.s. 2987 156 Chlorosilanes, n.o.s. 2988 139 Chlorosilanes, n.o.s. 2988 139 Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. 2989 133 Lead phosphite, dibasic 2990 171 Life-saving appliances, self- inflating 2991 131 Carbamate pesticide, liquid, poisonous, flammable 2991 131 Carbamate pesticide, liquid, toxic, flammable 2992 151 Carbamate pesticide, liquid, poisonous 2992 151 Carbamate pesticide, liquid, toxic 2993 131 Arsenical pesticide, liquid, poisonous, flammable 2993 131 Arsenical pesticide, liquid, toxic, flammable Page 73 ID No. Guide No. Name of Material ID Guide Name of Material No. No. 2994 151 Arsenical pesticide, liquid, poisonous 2994 151 Arsenical pesticide, liquid, toxic 2995 131 Organochlorine pesticide, liquid, poisonous, flammable 2995 131 Organochlorine pesticide, liquid, toxic, flammable 2996 151 Organochlorine pesticide, liquid, poisonous 2996 151 Organochlorine pesticide, liquid, toxic 2997 131 Triazine pesticide, liquid, poisonous, flammable 2997 131 Triazine pesticide, liquid, toxic, flammable 2998 151 Triazine pesticide, liquid, poisonous 2998 151 Triazine pesticide, liquid, toxic 2999 131 P henoxy pesticide, liquid, poisonous, flammable 2999 131 P henoxy pesticide, liquid, toxic, flammable 3000 152 P henoxy pesticide, liquid, poisonous 3000 152 P henoxy pesticide, liquid, toxic 3001 131 P henyl urea pesticide, liquid, poisonous, flammable 3001 131 Phenyl urea pesticide, liquid, toxic, flammable 3002 151 P henyl urea pesticide, liquid, poisonous 3002 151 P henyl urea pesticide, liquid, toxic 3003 131 Benzoic derivative pesticide, liquid, poisonous, flammable 3003 131 Benzoic derivative pesticide, liquid, toxic, flammable 3004 151 Benzoic derivative pesticide, liquid, poisonous 3004 151 Benzoic derivative pesticide, liquid, toxic 3005 131 Dithiocarbamate pesticide, liquid, poisonous, flammable 3005 131 Dithiocarbamate pesticide, liquid, toxic, flammable 3005 131 Thiocarbamate pesticide, liquid, poisonous, flammable 3005 131 Thiocarbamate pesticide, liquid, toxic, flammable 3006 151 Dithiocarbamate pesticide, liquid, poisonous 3006 151 Dithiocarbamate pesticide, liquid, toxic 3006 151 Thiocarbamate pesticide, liquid, poisonous 3006 151 Thiocarbamate pesticide, liquid, toxic 3007 131 Phthalimide derivative pesticide, liquid, poisonous, flammable 3007 131 Phthalimide derivative pesticide, liquid, toxic, flammable 3008 151 Phthalimide derivative pesticide, liquid, poisonous 3008 151 Phthalimide derivative pesticide, liquid, toxic 3009 131 Copperbased pesticide, liquid, poisonous, flammable 3009 131 Copper based pesticide, liquid, toxic, flammable 3010 151 Copper based pesticide, liquid, poisonous 3010 151 Copperbased pesticide, liquid, toxic 3011 131 Mercury based pesticide, liquid, poisonous, flammable Page 74 ID Guide Name of Material ID Guide Name of Material No. No. No. No. 3011 131 Mercury based pesticide, liquid, toxic, flammable 3020 153 Organotin pesticide, liquid, poisonous 3012 M o rr 1 1 r\/ hacorl nocHrirlo liniiirl l v l C I L U I y UclbcU [J C b LI L I U C , IILjUlU, 3020 1 00 ("1 rn a n aH n nocHrirlo liniiirl hnvir UlLJdIIUUII (JcjLILIUc, IILjUlU, LU A I L poisonous 3021 131 Pesticide, liquid, flammable, 3012 1 ci M a rni ri/ hacorl n a c M r i rl a liniiirl MclLUly UdbcU [JcbULlUc, MtjUlU, nAicAnAiic n a c pOlbOMUUb, ll.U.b. rn v i r LU A I L 3021 131 Pesticide, liquid, flammable, 3013 131 Substituted nitrophenol toxic, n.o.s. 3013 131 pesticide, liquid, poisonous, flammable Substituted nitrophenol pesticide, liquid, toxic, 3022 3023 127P 1,2-B utylene oxide, stabilized 131 2-Methyl-2-hepthanethiol 3023 131 tert-Octyl mercaptan flammahlp IIUIIIIIILiUI^ 3024 131 Coumarin derivative pesticide, 3014 153 Substituted nitrophenol pesticide, liquid, flammable, poisonous liniiirl nfikfinrnK 1 1 U U I U , U U 1 j U 1 1 U U J 3024 131 Coumarin derivative pesticide, 3014 153 Substituted nitrophenol pesticide, liquid, flammable, toxic linuid toxir 3025 131 Coumarin derivative pesticide, 3015 131 Bipyridilium pesticide, liquid, liquid, poisonous, flammable poisonous, flammable 3025 131 Coumarin derivative pesticide, 3015 131 Bipyridilium pesticide, liquid, toxic flammahlp <\J Al L f IIUIMIIIUUIC 3026 151 liquid, toxic, flammable Coumarin derivative pesticide, 3016 151 Bipyridilium pesticide, liquid, liquid, poisonous poisonous 3026 151 Coumarin derivative pesticide, 3016 151 Bipyridilium pesticide, liquid, liquid, toxic toxic 3027 151 Coumarin derivative pesticide, 3017 131 Organophosphorus pesticide, solid, poisonous liquid, poisonous, flammable 3027 151 Coumarin derivative pesticide, 3017 131 Organophosphorus pesticide, liquid, toxic, flammable 3028 154 solid, toxic Batteries, dry, containing 3018 1 CO Methyl parathion, liquid Potassium hydroxide solid 3018 ICO Organophosphorus pesticide, 3048 157 Aluminum phosphide pesticide liquid, poisonous 3049 138 Metal alkyl halides, n.o.s. 3018 152 Organophosphorus pesticide, liquid, toxic 3049 138 Metal alkyl halides, water- reactive, n.o.s. 3018 152 Tetraethyl pyrophosphate, liquid 3049 138 Metal aryl halides, n.o.s. 3019 131 Organotin pesticide, liquid, poisonous, flammable 3049 138 Metal aryl halides, water- reactive, n.o.s. 3019 131 Organotin pesticide, liquid, toxic, flammable 3050 138 Metal alkyl hydrides, n.o.s. Page 75 ID No. Guide No. Name of Material ID Guide Name of Material No. No. 3050 138 Metal alkyl hydrides, water- reactive, n.o.s. 3050 138 Metal aryl hydrides, n.o.s. 3050 138 Metal aryl hydrides, water- reactive, n.o.s. 3051 135 Aluminum alkyls 3052 135 Aluminum alkyl halides 3052 135 Aluminum alkyl halides, liquid 3052 135 Aluminum alkyl halides, solid 3053 135 Magnesium alkyls 3054 129 Cyclohexanethiol 3054 129 Cyclohexyl mercaptan 3055 154 2-(2-Aminoethoxy)ethanol 3056 129 n-Heptaldehyde 3057 125 Trifluoroacetyl chloride 3064 127 Nitroglycerin, solution in alcohol, with more than 1% but not more than 5% Nitroglycerin 3065 127 Alcoholic beverages 3066 153 Paint(corrosive) 3066 153 Paintrelated material (corrosive) 3070 126 Dichlorodifluoromethane and Ethylene oxide mixture, with not more than 12.5% Ethylene oxide 3070 126 Dichlorodifluoromethane and Ethylene oxide mixtures, with notmore than 12% Ethylene oxide 3070 126 3070 126 Ethylene oxide and Dichlorodifluoromethane mixture, with not more than 12.5% Ethylene oxide Ethylene oxide and Dichlorodifluoromethane mixtures, with not more than 12% Ethylene oxide 3071 131 Mercaptan mixture, liquid, poisonous, flammable, n.o.s. 3071 131 Mercaptan mixture, liquid, toxic, flammable, n.o.s. 3071 131 Mercaptan mixtures, liquid, n.o.s. 3071 131 Mercaptans, liquid, n.o.s. 3071 131 Mercaptans, liquid, poisonous, flammable, n.o.s. 3071 131 Mercaptans, liquid, toxic, flammable, n.o.s. 3072 171 Life-saving appliances, not self- inflating 3073 131 PVinylpyridines, inhibited 3073 131 PVinylpyridines, stabilized 3076 138 Aluminum alkyl hydrides 3077 171 Environmentally hazardous substances, solid, n.o.s. Hazardous waste, solid, n.o.s. 3077 171 3077 171 Otherregulated substances, solid, n.o.s. 3078 138 Cerium, turnings or gritty powder 3079 1 31 P M ethacrylonitrile, inhibited 3079 1 31 P M ethacrylonitrile, stabilized 3080 155 Isocyanate solution, poisonous, flammable, n.o.s. 3080 155 Isocyanate solution, toxic, flammable, n.o.s. 3080 155 Isocyanate solutions, n.o.s. 3080 155 Isocyanates, n.o.s. 3080 155 Isocyanates, poisonous, flammable, n.o.s. 3080 155 Isocyanates, toxic, flammable, n.o.s. 3082 171 E nvironmentally hazardous substances, liquid, n.o.s. Page 76 ID Guide Name of Material ID Guide Name of Material No. No. No. No. 3082 I / I l-l a 7 a rrl a 1 1 c \iw a c ho liniiirl n a c nazaiuuLib vv a b I c , ni|uiu, [ I . u . b . 3095 136 f orro^ivp ^olid ^plf-hpalinn V U I I U J I V L J U I I U | J C 1 1 1 1 w vl LI IIU, 3082 171 Other regulated substances, n.o.s. liquid, n.o.s. 3096 138 Corrosive solid, water-reactive, n.o.s. 3083 124 Perchloryl fluoride 3096 138 3084 140 Corrosive solid, oxidizing, n.o.s. Corrosive solid, which in contact with wateremits flammable 3085 140 Oxidizing solid, corrosive, n.o.s. gases, n.o.s. 3085 140 Oxidizing substances, solid, 3097 Flammable solid, oxidizing, n.o.s. corrosive, n.o.s. Oxidizing liquid, corrosive, n.o.s. 3098 140 3086 141 PnknnniK ^nlirl nxirli7inn I UIjI/IIUUj JU IIU, U A I U I L I I I U , 3098 140 n.o.s. Oxidizing substances, liquid, corros i ve, n.o.s. 3086 141 Toxic solid, oxidizing, n.o.s. 3099 1 AO I 4i uxiuiziny iitjuiu, poibunuub, n.o.b. 3087 141 Oxidizing solid, poisonous, n.o.s. 3099 ■i AO uxiaizing nquia, toxic, n.o.s. 3087 141 Oxidizing solid, toxic, n.o.s. 3099 142 Oxidizing substances, liquid, 3087 141 Oxidizing substances, solid, poisonous, n.o.s. nnknnniK n o <; 3099 142 Oxidizing substances, liquid, 3087 141 Oxidizing substances, solid, toxic , n.o.s. toxic, n.o.s. 3100 135 Oxidizing solid, self-heating, 3088 135 Q plf-hpatinn c;olid ornanir n.o.s. n.o.s. 3100 135 Oxidizing substances, self- 3088 135 S plf-hpaHnn ^uh^tanrp^ q o 1 i ri J 1 II U U LI II U JUUjLUMLLJ| J U 1 1 U i heating, n.o.s. n.o.s. 3100 135 Oxidizing substances, solid, 3089 170 Metal powder, flammable, n.o.s. self-heating, n.o.s. 3090 138 Lithium batteries 3101 146 Organic peroxide type B, liquid 3090 138 Lithium batteries, liquid orsolid cathode 3102 urganic peroxiae type sona 3103 146 Organic peroxide type C, liquid 3091 138 Lithium batteries contained in 3104 146 Organic peroxide type C, solid on 1 1 in mo nf ci| u \\) i lie 1 1 l 3091 138 Lithium batteries packed with 3105 145 Organic peroxide type D, liquid equipment 3106 145 Organic peroxide type D, solid 3092 129 l-Methoxy-2-propanol 3107 145 Organic peroxide type E, liquid 3093 1 *tu rnrrnciup liAnirl Ayirli7inA L Ul [ U j 1 Vc 1 1| U 1 U , U A 1 U 1 L 1 [ I y , 3108 145 O ro an ir neroxide tvne F solid U 1 U U 1 1 IL UC 1 1/AIU L7 LV IJ ^ L. , J U II U n.o.s. 3109 145 Organic peroxide type F, liquid 3094 138 Corrosive liquid, water-reactive, n.o.s. 3110 H AC 14D Organic peroxide type F, solid 3094 138 3111 148 Organic peroxide type B, liquid, Corrosive liquid, which in temperature controlled r a n ha c \ \a/ i t"h \m a t"Q r o rvi i he LU II La L L W ILII WaLcl tr III 1 Lb flammable gases, n.o.s. ID Guide No. No. Name of Material ID Guide Name of Material No. No. 3123 139 Poisonous liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A) 3123 139 Poisonous liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B) 3123 139 Poisonous liquid, which in contact with water emits flammable gases, n.o.s. 3123 139 Poisonous liquid, which in contact with water emits flammable gases, n.o.s. (Inhalation Hazard Zone A) 3123 139 Poisonous liquid, which in contact with water emits flammable gases, n.o.s. (Inhalation Hazard Zone B) 3123 139 Toxic liquid, water-reactive, n.o.s. 3123 139 Toxic liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A) 3123 139 Toxic liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B) 3123 139 Toxic liquid, which in contact with water emits flammable gases, n.o.s. 3123 139 Toxic liquid, which in contact with wateremits flammable gases, n.o.s. (Inhalation Hazard Zone A) 3112 148 Organic peroxide type B, solid, temperature controlled 3113 148 Organic peroxide type C, liquid, temperature controlled 3114 148 Organic peroxide type C, solid, temperature controlled 3115 148 Organic peroxide type D, liquid, temperature controlled 3116 148 Organic peroxide type D, solid, temperature controlled 3117 148 Organic peroxide type E, liquid, temperature controlled 3118 148 Organic peroxide type E, solid, temperature controlled 3119 148 Organic peroxide type F, liquid, temperature controlled 3120 148 Organic peroxide type F, solid, temperature controlled 3121 144 Oxidizing solid, water-reactive, n.o.s. 3121 144 Oxidizing substances, solid, which in contactwith water emit flammable gases, n.o.s. 3122 142 Poisonous liquid, oxidizing, n.o.s. 3122 142 Poisonous liquid, oxidizing, n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, oxidizing, n.o.s. Toxic liquid, oxidizing, n.o.s. (Inhalation Hazard Zone A) Toxic liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B) Poisonous liquid, water- reactive, n.o.s. Page 78 3122 142 3122 142 3122 142 3123 139 Toxic liquid, which in contact with water emits flammable gases, n.o.s. (Inhalation Hazard Zone B) 3124 136 Poisonous solid, self-heating, n.o.s. 3124 136 Toxic solid, self-heating, n.o.s. ID Guide Name of Material ID Guide Name of Material No. No. No. No. 3125 139 Poisonous solid, water-reactive, n.o.s. 3130 139 Substances, which in contact with wateremitflammable 3125 139 Poisonous solid, which in contact with wateremits flammable nacQC liniiiH nAiCAnAiic y db cb , IlLjUlU, pUlbUIIUUb, n .o .s . gases, n.o.s. 3130 139 Substances, which in contact 3125 139 Toxic solid, water-reactive, n.o.s. with wateremitflammable gases, liquid, toxic, n.o.s. 3125 139 Toxic solid, which in contact with wateremits flammable 3130 1 1Ck 1 0? VV d lc [- lc d C U Vc MLjUlLl, poisonous, n.o.s. a a c o c nAC l| a b c b , 1 1 . U . b . 3130 1 \A/ a ho r. ro a r H wo liniiirl hAvir VV d LC I I C d v. Ll V C IILjUlU, LUAIL, 3126 136 Self-heating solid, corrosive, n.o.s. U I Lj G 1 1 I L , I , U , J , 3130 1TQ W afpr-rparHwp c n h c; fa n TP c; v V LC 1 1 Cu L LI VC jLIUjLlHILCj, 3126 136 Self-heating substance, solid, liniiirl nnKfinniK n ac IIUUIU) UUIjUIIUUj, II. U.j. r a rr*A c i \/o n n c L U I I U b I V C , 1 1 . U , J , 3130 1 1 0? W a ho r- rp a r hi \/p ciihcfanrpc VVCILCI 1 C a V. LI V C bUUbLGMLCb, 3127 135 Self-heating solid, oxidizing, MljUlu, LOXIC, ll.O.b. n.o.s. 3131 138 Substances, which in contact 3127 135 Self-heating substances, solid, n x id i 7 i n n n o s U A l\J 1 ^ II 1 U ( 1 1 i U t J i wil"h w a fp r piti if fl a iti iti a h Ip VV 1 LI 1 VV u LC 1 CIIIIL IIGIIIIIIGUIC gases, solid, corrosive, n.o.s. 3128 136 Self-heating solid, organic, 3131 1 «JO W afpr-rparl"i\/p c;nlirl rnrrAci\/p VV CI LC 1 ICGLLIVC b U 1 1 U , L U 1 1 U b 1 V C , n.o.s. poisonous, n.o.s. 3128 136 Self-heating solid, organic, toxic, n.o.s. 3131 1 Tfi I 00 VV d lc 1 1 c d L U vc bUUbldMLcb, solid, corrosive, n.o.s. 3128 136 Self-heating solid, poisonous, 3132 138 Substances, which in contact organic, n.o.s. with water emit flammable gases, solid, flammable, 3128 136 S plf-hpa tin n s olid toxic n.o.s. ornanir n o u i y u 1 1 i v_ i ii i u i j i 3132 138 Water-reactive solid, flammable, 3128 136 Self-heating substances, solid, n.o.s. poisonous, n.o.s, 3132 138 Water-reactive substances, 3128 136 S plf-hpatino si] hstanres solid J ^ 1 1 1 1 ^ U LI 1 1 U jUUJLUIILCJf JUIIUf solid, flammable, n.o.s. toxic, n.o.s. 3133 138 Substances, which in contact 3129 138 Substances, which in contact with water emit flammable with water emit flammable gases, solid, oxidizing, n.o.s. gases, liquid, corrosive, Water-reactive solid, oxidizing, n.o.s. 3133 138 3129 138 Water-reactive liquid, n .o.s , corrosive, n.o.s. 3133 138 Water-reactive substances, solid, oxidizing, n.o.s. 3129 138 Water-reactive substances, liquid, corrosive, n.o.s. Page 79 ID No. Guide No. Name of Material ID Guide Name of Material No. No. 3134 139 Substances, which in contact with wateremitflammable gases, solid, poisonous, n.o.s. 3134 139 Substances, which in contact with wateremitflammable gases, solid, toxic, n.o.s. 3134 139 Water-reactive solid, poisonous, n.o.s. 3134 139 Water-reactive solid, toxic, n.o.s. 3134 139 Water-reactive substances, solid, poisonous, n.o.s. 139 Water-reactive substances, solid, toxic, n.o.s. 3138 115 3134 3135 3135 3135 3136 3137 3137 3138 138 Substances, which in contactwith wateremitflammable gases, solid, self-heating, n.o.s. 138 Water-reactive solid, self- heating, n.o.s. 138 Water-reactive substances, solid, self-heating, n.o.s. 120 Trifluoromethane, refrigerated liquid 140 Oxidizing solid, flammable, n.o.s. 140 Oxidizing substances, solid, flammable, n.o.s. 115 Acetylene, Ethylene and Propylene in mixture, refrigerated liquid containing at least 71.5% Ethylene with notmore than 22.5% Acetylene and not more than 6% Propylene 3138 115 Ethylene, Acetylene and Propylene in mixture, refrigerated liquid containing at least 71.5% Ethylene with notmore than 22.5% Acetylene and not more than 6%i Propylene 3139 140 3139 140 3140 151 3140 151 3141 157 3142 151 3142 151 3142 151 3143 151 3143 151 3143 151 3143 151 3144 151 3144 151 3145 153 3146 153 3147 154 3147 154 Propylene, Ethylene and Acetylene in mixture, refrigerated liquid containing at least 71.5% Ethylene with not more than 22.5%) Acetylene and notmore than 6% Propylene Oxidizing liquid, n.o.s. Oxidizing substances, liquid, n.o.s. Alkaloids, liquid, n.o.s. (poisonous) Alkaloid salts, liquid, n.o.s. (poisonous) Antimony compound, inorganic, liquid, n.o.s. Disinfectant, liquid, poisonous, n.o.s. Disinfectant, liquid, toxic, n.o.s. Disinfectants, liquid, n.o.s. (poisonous) Dye, solid, poisonous, n.o.s. Dye, solid, toxic, n.o.s. Dye intermediate, solid, poisonous, n.o.s. Dye intermediate, solid, toxic, n.o.s. Nicotine compound, liquid, n.o.s. Nicotine preparation, liquid, n.o.s. Alkyl phenols, liquid, n.o.s. (including C2-C12 homologues) Organotin compound, solid, n.o.s. Dye, solid, corrosive, n.o.s. Dye intermediate, solid, corrosive, n.o.s. Page 80 ID Guide No. No. Name of Material ID No. Guide No. Name of Material 3148 138 Substances, which in contact with water emit flammable gases, liquid, n.o.s. Water-reactive liquid, n.o.s. 3148 138 3148 138 Water-reactive substances, liquid, n.o.s. 3149 140 Hydrogen peroxide and Peroxyacetic acid mixture, with acid(s), water and not more than 5% Peroxyacetic acid, stabilized 3150 115 Devices, small, hydrocarbon gas powered, with release device 3150 115 Hydrocarbon gas refills for small devices, with release device 3151 171 Polyhalogenated biphenyls, liquid 3151 171 Polyhalogenated terphenyls, liquid 3152 171 Polyhalogenated biphenyls, solid 3152 171 Polyhalogenated terphenyls, solid 3153 115 Perfluoromethyl vinyl ether 3153 115 Perfluoro(methyl vinyl ether) 3154 115 Perfluoroethyl vinyl ether 3154 115 Perfluoro(ethyl vinyl ether) 3155 154 Pentachlorophenol 3156 122 Compressed gas, oxidizing, n.o.s. 3157 122 Liquefied gas, oxidizing, n.o.s. 3158 120 G as, refrigerated liquid, n.o.s. 3159 126 Refrigerant gas R-134a 3159 126 1,1,1,2-Tetrafluoroethane 3160 119 Liquefied gas, poisonous, flammable, n.o.s. 3160 119 Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone A) 3160 119 Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone B) 3160 119 Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone C) 3160 119 3160 3160 119 119 3160 119 3160 119 3160 119 3161 3162 3162 3162 3162 1162 115 123 123 123 123 123 Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, toxic, flammable, n.o.s. Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard ZoneC) Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard ZoneD) Liquefied gas, flammable, n.o.s. Liquefied gas, poisonous, n.o.s. Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone D) Page 81 ID Guide No. No. Name of Material ID Guide Name of Material No. No. 3162 123 Liquefied gas, toxic, n.o.s. 3162 123 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone A) 3162 123 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone B) 3162 123 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone C) 3162 123 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone D) 3163 126 Liquefied gas, n.o.s. 3164 126 Articles, pressurized, hydraulic (containing non-flammable gas) 3164 126 Articles, pressurized, pneumatic (containing non- flammable gas) 3165 131 Aircraft hydraulic power unit fuel tank 3166 128 Engines, internal combustion, flammable gas powered 3166 128 Engines, internal combustion, flammable liquid powered 3166 128 Engines, internal combustion, including when fitted in machinery or vehicles 3166 128 Vehicle, flammable gas powered 3166 128 Vehicle, flammable liquid powered 3167 115 G as sample, non-pressurized, flammable, n.o.s., not refrigerated liquid 3168 119 Gas sample, non-pressurized, poisonous, flammable, n.o.s. not refrigerated liquid 3168 119 G as sample, non-pressurized, toxic, flammable, n.o.s., not refrigerated liquid 3169 123 Gas sample, non-pressurized, poisonous, n.o.s., not refrigerated liquid 3169 123 Gas sample, non-pressurized, toxic, n.o.s., not refrigerated liquid 3170 138 Aluminum dross 3170 138 Aluminum processing by-products 3170 138 Aluminum remelting by- products 3170 138 Aluminum smelting by-products 3171 154 Battery-powered equipment (wet battery) 3171 154 Battery-powered vehicle (wet battery) 3171 154 Wheelchair, electric, with batteries 3172 153 Toxins, extracted from living sources, liquid, n.o.s. 3172 153 Toxins, extracted from living sources, n.o.s. 3172 153 Toxins, extracted from living sources, solid, n.o.s. 3174 135 Titanium disulfide 3174 135 Titanium disulphide 3175 133 Solids containing flammable liquid, n.o.s. 3176 133 Flammable solid, organic, molten, n.o.s. 3178 133 Flammable solid, inorganic, n.o.s. 3178 133 Smokeless powderfor small arms 3179 134 Flammable solid, poisonous, inorganic, n.o.s. 3179 134 Flammable solid, toxic, inorganic, n.o.s. Page 82 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 3180 134 Flammable solid, corrosive, inorganic, n.o.s. 3180 134 Flammable solid, inorganic, corrosive, n.o.s. 3181 133 Metal salts of organic compounds, flammable, n.o.s. 3182 170 Metal hydrides, flammable, n.o.s. 3183 135 Self-heating liquid, organic, n.o.s. 3184 136 Self-heating liquid, poisonous, organic, n.o.s. 3184 136 Self-heating liquid, toxic, organic, n.o.s. 3185 136 Self-heating liquid, corrosive, organic, n.o.s. 3186 135 Self-heating liquid, inorganic, n.o.s. 3187 136 Self-heating liquid, poisonous, inorganic, n.o.s. 3187 136 Self-heating liquid, toxic, inorganic, n.o.s. 3188 136 Self-heating liquid, corrosive, inorganic, n.o.s. 3189 135 Metal powder, self-heating, n.o.s. 3189 135 Self-heating metal powders, n.o.s. 3190 135 Self-heating solid, inorganic, n.o.s. 3191 136 Self-heating solid, inorganic, poisonous, n.o.s. 3191 136 Self-heating solid, inorganic, toxic, n.o.s. 3191 136 Self-heating solid, poisonous, inorganic, n.o.s. 3191 136 Self-heating solid, toxic, inorganic, n.o.s. 3192 136 Self-heating solid, corrosive, inorganic, n.o.s. 3194 135 Pyrophoric liquid, inorganic, n.o.s. 3200 135 Pyrophoric solid, inorganic, n.o.s. 3203 135 Pyrophoric organometallic compound, n.o.s. 3203 135 Pyrophoric organometallic compound, water-reactive, n.o.s. 3205 135 Alkaline earth metal alcoholates, n.o.s. 3206 136 Alkali metal alcoholates, self- heating, corrosive, n.o.s. 3207 138 Organometallic compound, water-reactive, flammable, n.o.s. 3207 138 Organometallic compound dispersion, water-reactive, flammable, n.o.s. 3207 138 Organometallic compound solution, water-reactive, flammable, n.o.s. Metallic substance, water- reactive, n.o.s. 3208 138 3209 138 3210 140 3211 140 3212 140 3213 140 Metallic substance, water- reactive, self-heating, n.o.s. Chlorates, inorganic, aqueous solution, n.o.s, Perchlorates, inorganic, aqueous solution, n.o.s. Hypochlorites, inorganic, n.o.s. Bromates, inorganic, aqueous solution, n.o.s. 3214 140 Permanganates, inorganic, aqueous solution, n.o.s. 3215 140 Persulfates, inorganic, n.o.s. 3215 140 Persulphates, inorganic, n.o.s. Page 83 ID Guide Name of Material ID Guide Name of Material No. No. No. No. 3216 140 Persulfates, inorganic, aqueous solution, n.o.s. 3238 150 S elf-reactive solid type E , temperature controlled 3216 140 Persulphates, inorganic, aqueous c a 1 1 1 Ha n n a c b U 1 U LIU 1 1 , 1 1 .U .3 . 3239 150 S elf-reactive liquid type F , LC 1 1 1 |J C I d LU I C LUIILIUIICU 3217 14(1 1 tu P p rr a r*h a n a hp c inArnanir n a c rciLdiuuiidLCb, niuiydiiiL, 1 1 . u . b . 3240 1 Rf> I J u Q p If . rp a r Hun caMH h/np F JCll ICdLLIVC b U I I U LyUC \ , 3218 140 Nitrates, inorganic, aqueous temperature controlled cn 1 nHn n n n c; b U 1 U LI U 1 1 , 1 1 ■ U . b . 3241 111 1 JO L UIUIIIU L IIILIUUIUUCIIIC 1 , J 3219 140 Nitrites, inorganic, aqueous diol solution n o ^ J U 1 U U U II | II i U i J i 3242 149 A7odirarhonamidp j \ LUU ILU 1 U \J 1 1 LI 1 1 1 1 U t 3220 1 9fi 1 £0 r e 1 1 La 1 1 U U 1 UC LI 1 d 1 1 C 3243 Q n MH c r a n ha in in a n a i c a n a 1 1 c J U 1 IU b L U II Ld II II II LJ U U 1 b U 1 1 U U b 3220 126 R efrig era n t g a s R - 12 5 liquid, n.o.s. 3221 149 Self-reactive liquid type B 3243 151 Solids containing toxic liquid, n.o.s. 3222 149 Self-reactive solid type B 3244 154 Solids containing corrosive 3223 149 Self-reactive liquid type C lin ii irl n n s IIUUIU, I.U.J. 3224 149 Self-reactive solid type C 3245 1 71 Genetically modified micro- 3225 Q p 1 f- ro a r H \/p liAiiirl h/no n JCll ICdLLIVC II l| U 1 U Ly[JC U organisms 3226 144 Q p|f-rpa,rH\/p cAliH h/np l~l JCll 1 COLLI VC j UIIU Ly U C U 3246 156 M ethanesulfonyl chloride 3227 149 Self-reactive liquid type E 3246 156 Methanesulphonyl chloride 3228 1 AQ C A 1 f i"A"ifl"iwA r n lln h/nQ C J c 1 1 - lc d C LI Vc bUIIU type L 3247 140 Sodium nprnxohnratp 3229 149 Self-reactive liquid type F anhydrous 3230 149 Self-reactive solid type F 3248 131 Medicine, liquid, flammable, poisonous, n.o.s. 3231 Q plf-rparHvP lifinirl l"vnp R JCll ICdLLIVC IIUUIU l y u c u, temperature controlled 3248 131 Medicine, liquid, flammable, toxic, n.o.s. 3232 150 Self-reactive solid type B, 3249 151 Medicine, solid, poisonous, n.o.s. LclTipcldLUlc COll LTOIIcQ 3233 150 Self-reactive liquid type C, 3249 151 Medicine, solid, toxic, n.o.s. Lc III pc 1 a LU 1 c LUIILIUIIcU 3250 153 rhlornarptir arid moltpn 3234 1 50 Self-reactive solid type C, 3251 lcncnrhiHp-R-mnnAnit"rat"P 1 j U j U 1 UIUCJIIIUIIUIIILI O Lc temperature controlled 3252 115 Difluoromethane 3235 150 Self-reactive liquid type D, 3252 115 Refrigerantgas R - 32 temperature controlled 3253 154 Disodium trioxosilicate 3236 150 Self-reactive solid type D, temperature controlled 3253 154 Disodium trioxosilicate, pentahydrate 3237 150 Self-reactive liquid type E, temperature controlled 3254 3254 135 135 Tributylphosphane Tributylphosphine ID Guide No. No. Name of Material ID Guide Name of Material No. No. 3268 171 Air h an morlnlpc; nvrnrprhnir r\ it u u u imuuuicj , u y i u lc l i i i i i l 3268 171 Qpa|-.hp||-mnfilllpc; J CO l UCIL MIuUUICj 1 /I S eat- belt pre- tens ioners 3268 171 Seat-beltpre-tensioners, nvrorprhnir p J 1 U Lt V_ 1 1 1 1 1 \_ 3269 128 Pnl\/pc;rpr rpc;in leir r u i y c j lc i i c _i ii I nil 3270 1 o o N ifrn r p 1 Iii 1 n c; p tnptnhranp filfprc; IMIUULCMUIU3C IMCIMUIClllC III LC 1 3 3271 J L 1 1 127 F fh p rc; n n c; L LI 1 C 1 J | IliUiJt JL 1 L 1 07 I £. 1 P c t"Q r c n a c 3273 131 Nitriles, flammable, poisonous, 3255 135 tert-Butyl hypochlorite 3256 128 Elevated temperature liquid, flammable, n.o.s,, with flash pointabove 37.8°C (100°F), at or above its flash point 3256 128 Elevated temperature liquid, flammable, n.o.s., with flash pointabove 60.5°C (141°F), at or above its flash point 3257 128 Elevated temperature liquid, n.o.s., atorabove 100°C (212°F), and belowits flash point 3258 171 Elevated temperature solid, n.o.s., ator above 240°C (464°F) 3259 154 Amines, solid, corrosive, n.o.s. 3259 154 Polyamines, solid, corrosive, n.o.s. 3260 154 Corrosive solid, acidic, inorganic, n.o.s. 3261 154 Corrosive solid, acidic, organic, n.o.s. 3262 154 Corrosive solid, basic, inorganic, n.o.s. 3263 154 Corrosive solid, basic, organic, n.o.s. 3264 154 Corrosive liquid, acidic, inorganic, n.o.s. 3265 153 Corrosive liquid, acidic, organic, n.o.s. 3266 154 Corrosive liquid, basic, inorganic, n.o.s. 3267 153 Corrosive liquid, basic, organic, n.o.s. 3268 171 Airbag inflators 3268 171 Air bag inflators, pyrotechnic 3268 171 Airbag modules n.o.s. 3273 131 Nitriles, flammable, toxic, n.o.s. 3274 132 Alcoholates solution, n.o.s., in alcohol 3275 131 Nitriles, poisonous, flammable, n.o.s. 3275 131 Nitriles, toxic, flammable, n.o.s. 3276 151 Nitriles, poisonous, liquid, n.o.s. 3276 151 Nitriles, poisonous, n.o.s. 3276 151 Nitriles, toxic, liquid, n.o.s 3276 151 Nitriles, toxic, n.o.s. 3277 154 Chloroformates, poisonous, corrosive, n.o.s. 3277 154 Chloroformates, toxic, corrosive, n.o.s. 3278 151 Organophosphorus compound, poisonous, liquid, n.o.s. 3278 151 Organophosphorus compound, poisonous, n.o.s. 3278 151 Organophosphorus compound, toxic, liquid, n.o.s. 3278 151 Organophosphorus compound, toxic, n.o.s. 3279 131 Organophosphorus compound, poisonous, flammable, n.o.s. Page 85 ID No. Guide No. Name of Material ID Guide Name of Material No. No. 3279 3280 3280 3281 3281 3282 3282 3282 3282 3283 3283 3284 3285 3286 3286 131 Organophosphorous compound, toxic, flammable, n.o.s. 151 Organoarsenic compound, liquid, n.o.s. 151 Organoarsenic compound, n.o.s. 151 Metal carbonyls, liquid, n.o.s. 151 Metal carbonyls, n.o.s. 151 Organometallic compound, poisonous, liquid, n.o.s. 151 Organometallic compound, poisonous, n.o.s. 151 Organometallic compound, toxic, liquid, n.o.s. 151 Organometallic compound, toxic, n.o.s. 151 Selenium compound, n.o.s. 151 Selenium compound, solid, n.o.s. 151 Tellurium compound, n.o.s. 151 Vanadium compound, n.o.s, 131 Flammable liquid, poisonous, corrosive, n.o.s. 131 Flammable liquid, toxic, corrosive, n.o.s. 3287 151 3287 151 3287 151 3287 3287 151 151 3287 151 Page 86 Poisonous liquid, inorganic, n.o.s. Poisonous liquid, inorganic, n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, inorganic, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, inorganic, n.o.s. Toxic liquid, inorganic, n.o.s. (Inhalation Hazard Zone A) Toxic liquid, inorganic, n.o.s. (Inhalation Hazard Zone B) 3288 151 Poisonous solid, inorganic, n.o.s. 3288 151 Toxic solid, inorganic, n.o.s. 3289 154 Poisonous liquid, corrosive, inorganic, n.o.s. 3289 154 Poisonous liquid, corrosive, inorganic, n.o.s. (Inhalation Hazard Zone A) 3289 154 Poisonous liquid, corrosive, inorganic, n.o.s. (Inhalation Hazard Zone B) 3289 154 Toxic liquid, corrosive, inorganic, n.o.s. 3289 154 Toxic liquid, corrosive, inorganic, n.o.s. (Inhalation Hazard Zone A) 3289 154 Toxic liquid, corrosive, inorganic, n.o.s. (Inhalation Hazard Zone B) 3290 154 Poisonous solid, corrosive, inorganic, n.o.s. 3290 154 Toxic solid, corrosive, inorganic, n.o.s. 3291 158 (B io)M edical waste, n.o.s. 3291 158 Clinical waste, unspecified, n.o.s. 3291 158 Medical waste, n.o.s. 3291 158 Regulated medical waste, n.o.s 3292 138 Batteries, containing Sodium 3292 138 Cells, containing Sodium 3293 152 Hydrazine, aqueous solution, with not more than 37% Hydrazine 3294 131 Hydrogen cyanide, solution in alcohol, with not more than 45% Hydrogen cyanide 3295 128 Hydrocarbons, liquid, n.o.s. ID Guide No. No. Name of Material ID Guide No. No. Name of Material 3296 126 H eptafluoropropane 3296 126 Refrigerantgas R-227 3297 126 Chlorotetrafluoroethane and Ethylene oxide mixture, with not more than 8.8% Ethylene oxide 3297 126 Ethylene oxide and Chlorotetrafluoroethane mixture, with notmore than 8.8% Ethylene oxide 3298 126 Ethylene oxide and Pentafluoroethane mixture, with not more than 7.9% Ethylene oxide 3298 126 Pentafluoroethane and Ethylene oxide mixture, with not more than 7.9% Ethylene oxide 3299 126 Ethylene oxide and Tetrafluoroethane mixture, with not more than 5.6% Ethylene oxide 3299 126 Tetrafluoroethane and Ethylene oxide mixture, with notmore than 5.6% Ethylene oxide 3300 119P Carbon dioxide and Ethylene oxide mixture, with more than 87% Ethylene oxide 3300 119P Ethylene oxide and Carbon dioxide mixture, with more than 87% Ethylene oxide 3301 136 Corrosive liquid, self-heating, n.o.s. 3302 152 2-Dimethylaminoethyl acrylate 3303 124 Compressed gas, poisonous, oxidizing, n.o.s. 3303 124 Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A) 3303 124 3303 124 Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone B) Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone C) Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone D) Compressed gas, toxic, oxidizing, n.o.s. Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone A) 3303 124 Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone B) 3303 124 Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone C) 3303 124 Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone D) 3304 123 Compressed gas, poisonous, corrosive, n.o.s. 3304 123 Compressed gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone A) 3304 123 Compressed gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone B) 3304 123 Compressed gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone C) 3304 123 Compressed gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone D) 3304 123 Compressed gas, toxic, corrosive, n.o.s. i Page 87 ID Guide Name of Material No. No. ID Guide Name of Material No. No. 3304 123 Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone A) 3304 123 Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone B) 3304 123 Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone C) 3304 123 3305 119 Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone D) Compressed gas, poisonous, flammable, corrosive, n.o.s. 3305 119 Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) 3305 119 Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) 3305 119 Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) 3305 119 Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) 3305 119 3305 119 3305 119 3305 119 3305 119 Compressed gas, toxic, flammable, corrosive, n.o.s. Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) 3306 124 Compressed gas, poisonous, oxidizing, corrosive, n.o.s. 3306 124 Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) 3306 124 Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) 3306 124 Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) 3306 124 Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) 3306 124 Compressed gas, toxic, oxidizing, corrosive, n.o.s. 3306 124 Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) 3306 124 Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) 3306 124 Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) 3306 124 Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) 3307 124 Liquefied gas, poisonous, oxidizing, n.o.s. 3307 124 Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A) 3307 124 Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone B) 3307 124 Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone C) ID Guide No. No. Name of Material ID Guide No. No. Name of Material 3307 124 Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone D) 3307 124 Liquefied gas, toxic, oxidizing, n.o.s. 3307 124 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone A) 3307 124 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone B) 3307 124 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone C) 3307 124 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone D) 3308 123 Liquefied gas, poisonous, corrosive, n.o.s. 3308 123 Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone A) 3308 123 Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone B) 3308 123 Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone C) 3308 123 Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone D) 3308 123 Liquefied gas, toxic, corrosive, n.o.s. 3308 123 Liquefied gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone A) 3308 123 Liquefied gas, toxic, corrosive, n.o.s. (Inhalation Hazard ZoneB) 3308 123 Liquefied gas, toxic, corrosive n.o.s. (Inhalation Hazard Zone C) 3308 123 Liquefied gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, poisonous, flammable, corrosive, n.o.s. Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) 3309 119 Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) 3309 119 Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) 3309 119 Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) 3309 119 Liquefied gas, toxic, flammable, corrosive, n.o.s. 3309 119 Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) 3309 119 Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) 3309 119 Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) 3309 119 Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) 3310 124 Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. 3310 124 Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) I Page 89 ID Guide No. No. Name of Material ID Guide Name of Material No. No. 3310 124 Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) 3316 3316 171 171 331 7 j j 1 / 113 3310 124 Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) 3318 125 3310 124 Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) 3319 113 3310 124 Liquefied gas, toxic, oxidizing, corrosive, n.o.s. 3310 124 Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation H azard Zone A) 3319 113 3310 124 Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) 3320 157 3310 124 Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) 3310 124 Liquefied gas, toxic, oxidizing, corrosive n o s (Inhalation Hazard Zone D) 3321 162 3311 122 G as, refrigerated liquid, oxidizing, n.o.s. 3322 162 3312 115 G as, refrigerated liquid, flammable, n.o.s. 3323 163 3313 135 Organic pigments, self-heating 3324 165 3314 171 Plastic molding compound 3325 165 3314 171 Plastics moulding compound 3315 151 Chemical sample, poisonous 3326 165 3315 151 Chemical sample, poisonous liquid 3315 151 Chemical sample, poisonous solid 3326 165 3315 151 Chemical sample, toxic 3315 151 Chemical sample, toxic liquid 3327 165 3315 151 Chemical sample, toxic solid Chemical kit Firstaid kit 2-Amino-4,6-dinitrophenol, wetted with not less than 20% water Ammonia solution, with more than 50% Ammonia Nitroglycerin mixture, desensitized, solid, n.o.s., with more than 2% but not more than 10% Nitroglycerin Nitroglycerin mixture with more than 2% but not more than 10% Nitroglycerin, desensitized Sodium borohydride and Sodium hydroxide solution, with not more than 12% Sodium borohydride and not more than 40% Sodium hydroxide Radioactive material, low specific activity (LSA-II) Radioactive material, low specific activity ( L S A - 1 1 1 ) Radioactive material, Type C package Radioactive material, low specific activity (LSA-II), fissile Radioactive material, low specific activity (LS A- III), fissile Radioactive material, surface contaminated objects (SCO-I), fissile Radioactive material, surface contaminated objects (SCO-II), fissile Radioactive material, Type A package, fissile Page 90 ID Guide Name of Material No. No. ID Guide Name of Material No. No. 3328 165 Radioactive material, Type B{U) package, fissile 3329 165 Radioactive material, Type B(M) package, fissile 3330 165 Radioactive material, Type C package, fissile 3331 165 Radioactive material, transported under special arrangement, fissile 3332 164 Radioactive material, Type A package, special form 3333 165 Radioactive material, Type A package, special form, fissile 3334 171 Aviation regulated liquid, n.o.s. 3334 171 Self-defense spray, non- pressurized 3335 171 Aviation regulated solid, n.o.s. 3336 130 Mercaptan mixture, liquid, flammable, n.o.s. 3336 130 Mercaptans, liquid, flammable, n.o.s. 3337 126 Refrigerantgas R-404A 3338 126 Refrigerantgas R-407A 3339 126 Refrigerantgas R-407B 3340 126 Refrigerantgas R-407C 3341 135 Thiourea dioxide 3342 135 Xanthates 3343 113 Nitroglycerin mixture, desensitized, liquid, flammable, n.o.s., with not more than 30% Nitroglycerin 3344 113 Pentaerythritetetranitrate mixture, desensitized, solid, n.o.s., with more than 10% but not more than 20% PETN 3345 153 Phenoxyacetic acid derivative pesticide, solid, poisonous 3345 153 Phenoxyacetic acid derivative pesticide, solid, toxic 3346 131 Phenoxyacetic acid derivative pesticide, liquid, flammable, poisonous 3346 131 Phenoxyacetic acid derivative pesticide, liquid, flammable, toxic 3347 131 Phenoxyacetic acid derivative pesticide, liquid, poisonous, flammable 3347 131 Phenoxyacetic acid derivative pesticide, liquid, toxic, flammable 3348 153 Phenoxyacetic acid derivative pesticide, liquid, poisonous 3348 153 Phenoxyacetic acid derivative pesticide, liquid, toxic 3349 151 Pyrethroid pesticide, solid, poisonous 3349 151 Pyrethroid pesticide, solid, toxic 3350 131 Pyrethroid pesticide, liquid, flammable, poisonous 3350 131 Pyrethroid pesticide, liquid, flammable, toxic 3351 131 Pyrethroid pesticide, liquid, poisonous, flammable 3351 131 Pyrethroid pesticide, liquid, toxic, flammable 3352 151 Pyrethroid pesticide, liquid, poisonous 3352 151 Pyrethroid pesticide, liquid, toxic 3353 126 Airbag inflators, compressed gas 3353 126 Airbag modules, compressed gas 3353 126 Seat-beltpre-tensioners, compressed gas 3354 115 Insecticide gas, flammable, n.o.s. Page 91 ID No. Guide No. Name of Material ID Guide Name of Material No. No. 3355 119 Insecticide gas, poisonous, flammable, n.o.s. 3355 119 Insecticide gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone A) 3355 119 Insecticide gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone B) 3355 119 Insecticidegas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone C) 3355 119 Insecticide gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone D) 3355 119 Insecticide gas, toxic, flammable, n.o.s. 3355 119 Insecticide gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone A) 3355 119 Insecticide gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone B) 3355 119 Insecticide gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone C) 3355 119 Insecticide gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone D) 3356 140 Oxygen generator, chemical 3356 140 Oxygen generator, chemical, spent 3357 113 Nitroglycerin mixture, desensitized, liquid, n.o.s., with not more than 30% Nitroglycerin 3358 115 Refrigerating machines, containing flammable, non- toxic, liquefied gas 3359 171 Fumigated unit 3360 133 Fibers, vegetable, dry 3360 133 Fibres, vegetable, dry 3361 156 Chlorosilanes, poisonous, corrosive, n.o.s. 3361 156 Chlorosilanes, toxic, corrosive, n.o.s. 3362 155 Chlorosilanes, poisonous, corrosive, flammable, n.o.s. 3362 155 Chlorosilanes, toxic, corrosive, flammable, n.o.s. 3363 171 Dangerous goods in apparatus 3363 171 Dangerous goods in machinery 3364 113 P icric acid, wetted with not less than 10% water 3364 113 Trinitrophenol, wetted with not less than 10% water 3365 113 P icryl chloride, wetted with not less than 10% water 3365 113 Trinitrochlorobenzene, wetted with not less than 10% water 3366 113 TNT, wetted with notless than 10% water 3366 113 Trinitrotoluene, wetted with not less than 10% water 3367 113 Trinitrobenzene, wetted with not less than 10% water 3368 113 Trinitrobenzoic acid, wetted with not less than 10% water 3369 113 Sodium dinitro-o-cresolate, wetted with notless than 10% water 3370 113 Urea nitrate, wetted with not less than 10% water 3371 129 2-Methylbutanal 3372 138 Organometallic compound, solid, water-reactive, flammable, n.o.s. Page 92 ID Guide No. No. Name of Material ID Guide Name of Material No. No. 3385 139 Poisonous by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A) 3385 139 Toxic by inhalation liquid, water- reactive, n.o.s. (Inhalation Hazard Zone A) 3386 139 Poisonous by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B) 3386 139 Toxic by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B) 3387 142 Poisonous by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone A) 3387 142 Toxic by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone A) 3388 142 Poisonous by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B) 3388 142 Toxic by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B) 3389 154 Poisonous by inhalation liquid, corrosive, n.o.s. (Inhalation Hazard Zone A) 3389 154 Toxic by inhalation liquid, corrosive, n.o.s. (Inhalation Hazard Zone A) 3390 154 Poisonous by inhalation liquid, corrosive, n.o.s. (Inhalation Hazard Zone B) 3390 154 Toxic by inhalation liquid, corrosive, n.o.s. (Inhalation Hazard Zone B) 3391 135 Organometallic substance, b U 1 1 U , \J y I u p II U 1 1 L 3392 135 Organometallic substance, 3373 158 Clinical specimens 3373 158 Diagnostic specimens 3374 116 Acetylene, solventfree 3375 140 Ammonium nitrate emulsion 3375 140 Ammonium nitrate gel 3375 140 Ammonium nitrate suspension 3376 113 4-N itrophenylhyd razine, with not less than 30% water 3377 140 Sodium perborate monohydrate 3378 140 Sodium carbonate peroxyhydrate 3379 128 Desensitized explosive, liquid, n.o.s. 3380 133 Desensitized explosive, solid, n.o.s. 3381 151 Poisonous by inhalation liquid, n.o.s. (Inhalation Hazard Zone A) 3381 151 Toxic by inhalation liquid, n.o.s. (Inhalation Hazard Zone A) 3382 151 Poisonous by inhalation liquid, n.o.s. (Inhalation Hazard Zone B) 3382 151 Toxic by inhalation liquid, n.o.s. (Inhalation Hazard Zone B) 3383 131 Poisonous by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone A) 3383 131 Toxic by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone A) 3384 131 Poisonous by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone B) 3384 131 Toxic by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone B) liquid, pyrophoric Page 93 ID Guide Name of Material No. No. ID Guide Name of Material No. No. 3393 135 rganometa llic substance, solid, pyrophoric, water-reactive 3394 135 Organometallic substance, liquid, pyrophoric, water-reactive 3395 135 Organometallic substance, solid, water-reactive 3396 138 Organometallic substance, solid, water-reactive, flammable 3397 138 Organometallic substance, solid, water-reactive, self-heating 3398 135 Organometallic substance, liquid, water-reactive 3399 138 Organometallic substance, liquid, water-reactive, flammable 3400 138 Organometallic substance, solid, self-heating 3401 138 Alkali metal amalgam, solid 3402 138 Alkaline earth metal amalgam, solid 3403 138 Potassium, metal alloys, solid 3404 138 Potassium sodium alloys, solid 71 a n A 3404 138 Sodium potassium alloys, solid 3405 141 Barium chlorate, solution 3406 141 Barium perchlorate, solution 3407 140 Chlorate and Magnesium chloride mixture, solution 3407 140 Magnesium chloride and Chlorate mixture, solution 3408 141 Lead perchlorate, solution 3409 152 Chloronitrobenzenes, liquid 3410 153 4-Chloro-o-toluidine hydrochloride, solution 3411 153 beta-N aphthylamine, solution 3411 153 Naphthylamine (beta), solution 3413 157 P otassium cyanide, solution 3414 157 S odium cyanide, solution 3 A 1 C H C A Sodium fluoride, solution 3416 153 Chloroacetophenone, liquid 3417 152 Xylyl bromide, solid 3418 151 2,4-Toluylenediamine, solution 3419 157 Boron trifluoride acetic acid complex, solid 3420 157 Boron trifluoride propionic acid complex, solid 3421 154 Potassium hydrogen difluoride, solution 3422 154 Potassium fluoride, solution 3423 153 Tetramethylammonium hydroxide, solid 3424 141 Ammonium dinitro-o-cresolate, solution 3425 156 Bromoacetic acid, solid 3426 153P Acrylamide, solution 3427 153 Chlorobenzyl chlorides, solid 3428 156 3-Chloro-4-methylphenyl isocyanate, solid 3429 153 Chlorotoluidines, liquid i a z> n 153 Xylenols, liquid 3431 152 Nitrobenzotrifluorides, solid 3432 171 P olychlo rin ated biphenyls, solid 3 A 3 D 3433 135 Lithium alkyls, solid ZlA 1A 3434 153 Nitrocresols, liquid 3435 153 Hydroquinone, solution 3436 151 Hexafluoroacetone hydrate, solid 3437 152 Chlorocresols, solid 3438 153 alpha-Methylbenzyl alcohol, solid 3439 151 Nitriles, poisonous, solid, n.o.s. 3439 151 Nitriles, toxic, solid, n.o.s. 3440 151 Selenium compound, liquid, n.o.s. ID Guide Name of Material No. No. ID Guide Name of Material No. No. 3441 153 C hlorod initrobenzenes, solid 7} A A T 3442 ■ICO 153 Dichloroanilines, solid 3443 152 Dinitrobenzenes, solid 3444 151 N ico tine hydrochloride, solid 3445 151 Nicotine sulfate, solid 3445 151 Nicotine sulphate, solid 3446 152 Nitrotoluenes, solid 3447 152 N itroxylenes, solid 3448 159 Tear gas substance, solid, n.o.s. 3449 159 Bromobenzyl cyanides, solid 3450 151 Diphenylchloroarsine, solid 3451 153 Toluidines, solid 3452 153 Xyhdines, solid 3453 154 Phosphoric acid, solid 3454 152 Dinitrotoluenes, solid 3455 153 C resols, solid 3456 157 Nitrosylsulfuric acid, solid 3456 157 N itrosyls u Iph uric acid, solid 3457 152 Chloronitrotoluenes, solid 3 /I C 345b ■ICO 152 Nitroanisoles, solid 3459 152 Nitrobromobenzenes, solid 3460 153 N-Ethylbenzyltoluidines, solid 3461 135 Aluminum alkyl halides, solid 3462 153 Toxins, extracted from living sources, solid, n.o.s. 3464 151 Organophosphorus compound, poisonous, solid, n.o.s. 3464 151 Organophosphorus compound, toxic, solid, n.o.s. 3465 151 Organoarsenic compound, solid, n.o.s. 3466 151 Metal carbonyls, solid, n.o.s. 3467 151 Organometallic compound, poisonous, solid, n.o.s. 3467 151 Organometallic compound, toxic, solid, n.o.s. 3468 115 Hydrogen, in a metal hydride storage system 8000 171 Consumer commodity 8013 171 Gas generator assemblies 8038 171 Heat producing article 9035 123 G as identification set 9163 171 Zirconium sulfate 9163 171 Zirconium sulphate 9191 143 Chlorine dioxide, hydrate, frozen 9192 167 Fluorine, refrigerated liquid (cryogenic liquid) 9195 135 Metal alkyl, solution, n.o.s. 9202 168 Carbon monoxide, refrigerated liquid (cryogenic liquid) 9206 137 Methyl phosphonic dichloride 9260 169 Aluminum, molten 9263 156 Chloropivaloyl chloride 9264 151 3,5-Dichloro-2,4,6- trifluoropyridine 9269 132 Tnmethoxysilane 9275 158 Regulated medical waste 9279 115 Hydrogen, absorbed in metal hydride Page 95 Note: If an entry is highlighted in eitherthe yellow-bordered or blue-bordered pages AND THERE IS NO FIRE, go directly to the Table of Initial Isolation and Protective Action Distances (green-bordered pages) and look up the ID number and name of material to obtain initial isolation and protective action distances. IF THERE IS A FIRE, orIF AFIRE IS INVOLVED, go directly to the appropriate guide (orange-bordered pages) and use the evacuation information shown underPUBLIC SAFETY. Name of Material Guide ID No. No. AC 117 1051 Accumulators, pressurized, pneumatic orhydraulic 126 1956 Acetal 127 1088 Acetaldehyde 129 1089 Acetaldehyde ammonia 171 1841 Acetaldehyde oxime 129 2332 Acetic acid, glacial 132 2789 Acetic acid, solution, more than 10% but not more than 80% acid 153 2790 Acetic acid, solution, more than 80% acid 132 2789 Acetic anhydride 137 1715 Acetone 127 1090 Acetone cyanohydrin, stabilized 155 1541 Acetone oils 127 1091 Acetonitrile 127 1648 Acetyl bromide 156 1716 Acetyl chloride 155 1717 Acetylene 116 1001 Acetylene, dissolved 116 1001 Acetylene, solventfree 116 3374 Acetylene, Ethylene and Propylene in mixture, refrigerated liquid containing dLlcdbL / l.J/o E Lll yicll c W ILI1 notmore than 22.5% Acetylene and notmore than 6% Propylene 115 3138 Acetylene tetrabromide 159 2504 Acetyl iodide 156 1898 Acetyl methyl carbinol 127 2621 Acid, sludge 153 1906 Acid butyl phosphate 153 1718 Acridine 153 2713 Acrolein, inhibited 131P 1092 Acrolein, stabilized 131P 1092 Name of Material Guide ID No. No. Acrolein dimer, stabilized 129P 2607 Acrylamide 153P 2074 Acrylamide, solid 153P 2074 Acrylamide, solution 153P 3426 Acrylic acid, inhibited 132P 2218 Acrylic acid, stabilized 132P 2218 Acrylonitrile, inhibited 131P 1093 Acrylonitrile, stabilized 131P 1093 Adamsite 154 1698 Adhesives (flammable) 128 1133 Adiponitrile 153 2205 Aerosol dispensers 126 1950 Aerosols 126 1950 Air rnmnrp^pd 122 1002 Air rpfrinpratpd linnid nil, I c 1 1 iuci aicu muuiu (cryogenic liquid) 122 1003 Air, refrigerated liquid (cryogenic liquid), non- pressurized 122 1003 Airbag inflators 171 3268 Airbag inflators, compressed gas 126 3353 Airbag inflators, pyrotechnic 171 3268 Airbag modules 171 i / i JZUO Airbag modules, compressed gas 126 3353 Airbag modules, pyrotechnic 171 3268 Aircrafthydraulic power unitfuel tank 131 3165 Alcoholates solution, n.o.s., in alcohol 132 3274 Alcoholic beverages 127 3065 Alcohols, flammable, poisonous, n.o.s. 131 1986 Alcohols, flammable, toxic, n.o.s. 131 1986 Alcohols, n.o.s, 127 1987 Alcohols, poisonous, n.o.s. 131 1986 Page 97 Name of Material Guide ID NO. * i _ NO. Alcohols, toxic, n.o.s. 131 1986 Aldehydes, flammable, 131 1988 poisonous, n.o.s. Aldehydes, flammable, toxic, 131 1988 n.o.s. Aldehydes, n.o.s. Aldehydes, poisonous, n.o.s. lol 1 QQ Q 1300 Aldehydes, toxic, n.o.s. 131 i no o 1988 Aldol 153 2839 Aldrin, liquid 131 2/62 Aldrin, solid 151 2761 Alkali metal alcoholates, self- 136 3206 heating, corrosive, n.o.s. Alkali metal alloy, liquid, n.o.s 138 1421 Alkali metal amalgam 138 1389 Alkali metal amalgam, liquid 138 1389 Alkali metal amalgam, solid 138 1389 Alkali metal amalgam, solid 138 3401 Alkali metal amides 139 1390 Alkali metal dispersion loo i jyi Alkaline earth metal 135 3205 alcoholates, n.o.s. Alkaline earth metal alloy, n.o. 5. 138 1393 Alkaline earth metal amalgam 138 1392 Alkaline earth metal amalgam, 138 1392 liquid Alkaline earth metal amalgam, 138 3402 solid Alkaline earth metal dispersion loo "1301 1331 Alkaloids, liquid, n.o.s, 151 3140 (poisonous) Alkaloids, solid, n.o.s, 151 1544 (poisonous) Alkaloid salts, liquid, n.o.s. 151 3140 (poisonous) Name of Material Guide ID No. No. Alkaloid salts, solid, n.o.s. 151 (poisonous) Alkylamines, n.o.s, 132 Alkylamines, n.o.s . 132 Alkylamines, n.o.s. 153 Alkyl phenols, liquid, n.o.s. 153 (including C2-C12 homologues) Alkyl phenols, solid, n.o.s. 153 (including C2-C12 homologues) Alkyl sulfonic acids, liquid, with 153 more than 5% free Sulfuric acid Alkyl sulfonic acids, liquid, with 153 not more than 5% free Sulfuric acid Alkyl sulfonic acids, solid, with 153 more than 5% free Sulfuric acid Alkyl sulfonic acids, solid, with 153 notmore than 5% free Sulfuric acid Alkylsulfuric acids 156 Alkyl sulphonic acids, liquid, 153 with more than 5% free Sulphuric acid Alkyl sulphonic acids, liquid, 153 with notmore than 5% free Sulphuric acid Alkyl sulphonic acids, solid, with 153 more than 5% free Sulphuric acid Alkyl sulphonic acids, solid, with 153 notmore than 5% free Sulphuric acid Alkylsulphuric acids 156 Allyl acetate 131 1544 2733 2734 2735 3145 2430 2584 2586 2583 2585 2571 2584 2586 2583 2585 2571 2333 Page 98 Name of Material Guide ID NO. NO. Allyl alcohol 131 1098 Allylamine 131 2334 Allyl bromide 131 1099 Allyl chloride 131 1100 Allyl chlorocarbonate 155 1722 Allyl chloroformate 155 1722 Allyl ethyl ether 131 2335 Allyl formate 131 2336 Allyl glycidyl ether 129 2219 Allyl iodide 132 1723 Allyl isothiocyanate, inhibited 155 1545 Allyl isothiocyanate, stabilized 155 1545 Ally Itric hlo ros i la ne, stabilized 155 1724 Aluminum, molten 169 9260 Aluminum alkyl halides 135 3052 Aluminum alkyl halides, liquid 135 3052 Aluminum alkyl halides, solid 135 3052 Aluminum alkyl halides, solid 135 3461 Aluminum alkyl hydrides 138 3076 Aluminum alkyls 135 3051 Aluminum borohydride 135 2870 Aluminum borohydride in devices 135 2870 Aluminum bromide, anhydrous 137 1725 Aluminum uiomiuc, s o i u u o n L JOU Aluminum carbide 138 1394 Aluminum chloride, anhydrous 137 1726 Aluminum chloride, solution 154 2581 Aluminum dross 138 3170 Aluminumferrosilicon powder 139 1395 Aluminum hydride 138 2463 Aluminum nitrate 140 1438 Aluminum phosphide 139 1397 Name of Material Guide ID No. NO. Aluminum phosphide pesticide 157 3048 Aluminum powder, coated 170 1309 Aluminum powder, pyrophoric 135 1383 Aluminum powder, uncoated 138 1396 Aluminum processing by-prod ucts 138 3170 Aluminum remeltinn hv-nrndnrts rAiuiiiiiiuiii I c 1 1 1 c I li 1 1 u uy ui uuui. lj 138 3170 Aluminum resinate 133 2715 Aluminum silicon powder, uncoated 138 1398 Aluminum smelting by-products 138 3170 Amines, flammable, corrosive, n.o.s. 132 2733 Amines, liquid, corrosive, flammahle n o s 132 2734 Aminps linnirl rnrrnsiwp n n <; n IMMIC J , IIUUIU, L U II U 5 1 V C I.U.J. L 1 J J Amines, solid, corrosive, n.o.s. 154 3259 2-Amino-4-chloro phenol 151 2673 2-Amino-5-diethylaminopentane 153 2946 2-Amino-4,6-dinitrophenol, wetted with not less than 20% water 113 3317 2-(2-Aminoethoxy)ethanol 154 3055 N-Aminoethylpiperazine 153 2815 Aminophenols 152 2512 A m in nrwrirl inp ^ MIMIIIUUyl IUIIIC3 1 JO 2671 MIMIMUIIIu, O 1 1 1 i y U 1 U U J 125 1005 Ammonia, anhydrous, liquefied 125 1005 Ammonia, solution, with more than 10% butnotmore than 35% Ammonia 154 2672 Ammonia, solution, with more than 35% butnotmore than 50% Ammonia 125 2073 Ammonia solution, with more than 50% Ammonia 125 1005 Page 99 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Ammonia solution, with more than 50% Ammonia 125 3318 Ammonium arsenate 151 1546 Ammonium bifluoride, solid 154 1727 Ammonium bifluoride, solution 154 2817 Ammonium dichromate 141 1439 Ammonium dinitro-o-cresolate 141 1843 Ammonium dinitro-o-cresolate, solid 141 1843 Ammonium dinitro-o-cresolate, solution 141 3424 Ammonium fluoride 154 2505 Ammonium fluorosilicate 151 2854 Ammonium hydrogendifluoride, solid 154 1727 Ammonium hydrogendifluoride, solution 154 2817 Ammonium hydrogen fluoride, solid 154 1727 Ammonium hydrogen fluoride, solution 154 2817 Ammonium hydrogen sulfate 104 Ammonium hydrogen sulphate 154 2506 Ammonium hydroxide 154 2672 Ammonium hydroxide, with more than 10% butnotmore than 35% Ammonia 154 2672 Ammonium metavanadate 154 2859 Ammonium nitrate, liquid (hot concentrated solution) 140 2426 Ammonium nitrate, with notmore than 0.2% combustible substances 140 1942 Ammonium nitrate emulsion 140 3375 Ammonium nitrate fertilizer, 140 2072 n.o.s. Ammonium nitrate fertilizer, with notmore than 0,4% combustible material 140 2071 Ammonium nitrate fertilizers 140 2067 Ammonium nitrate fertilizers 140 2071 Ammonium nitrate fertilizers 140 2072 Ammonium nitrate fertilizers, with Ammonium sulfate 140 2069 Ammonium nitrate fertilizers, with Ammonium sulphate 140 2069 Ammonium nitrate fertilizers, with Calcium carbonate 140 2068 Ammonium nitrate fertilizers, with Phosphate orPotash 143 2070 Ammonium nitrate-fuel oil mixtures 112 Ammonium nitrate gel 140 3375 Ammonium nitrate mixed fertilizers 140 2069 Ammonium nitrate suspension 1 1 1 c Ammonium perchlorate 143 1 A A ") 144Z Ammonium persulfate 140 1444 Ammonium persulphate 140 1444 Ammonium picrate, wetted with notless than 10% water 113 1310 Ammonium polysulfide, solution 154 2818 Ammonium polys ulphide, solution 154 2818 Ammonium polyvanadate 151 2861 Ammonium silicofluoride 151 -) C A Z034 Ammonium sulfide, solution 132 2683 Ammonium sulphide, solution 132 2683 Ammunition, poisonous, non-explosive 151 2016 Ammunition, tear-producing, 159 2017 non-explosive Page 100 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Ammunition, toxic, 151 2016 non-explosive Amyl acetates 129 i i n a 11U4 Amyl acid phosphate 153 2819 Amyl alcohols Hon 129 line Amylamines HOO 132 Hub Amyl butyrates H OA 130 2o2U Amyl chloride HOfk 129 111)/ n-Amylene HOO 128 i i no hub Amyl formates 129 i i nn nuy Amyl mercaptan Hon loU 1111 nn n-Amyl methyl ketone H r\—j 127 i i i n niu Amyl methyl ketone 127 1110 Amyl nitrate 140 1112 M [11 y 1 lllLNLc Amyltrichlorosilane 155 1728 Anhydrous ammonia 125 1005 Anhydrous ammonia, liquefied HOC 125 i nn c Aniline 153 1547 Aniline hydrochloride 153 1548 Anisidines 153 2431 Anisidines, liquid 153 2431 Anisidines, solid HCO loo 1A 3 1 Z4 Jl Anisole 128 2222 Anisoyl chloride 156 1729 Antimonycompound, inorganic, 157 3141 liquid, n.o.s. Antimonycompound, inorganic, 157 1549 n.o.s. Antimonycompound, inorganic, 157 1549 solid, n.o.s. Antimony lactate 151 1550 Antimony pentachloride, liquid 157 1730 Antimony pentachloride, solution 157 1731 Antimony penta fluoride 157 1732 Antimony potassium tartrate 151 1551 Antimony powder 170 2871 Antimony tribromide, solid 157 1549 Antimony tribromide, solution 157 1549 Antimony trichloride 157 1733 Antimony trichloride, liquid 157 1733 Antimony trichloride, solid 157 1733 Antimony trichloride, solution 157 1733 Antimony trifluoride, solid 157 1549 Antimony trifluoride, solution 157 1549 Aqua regia 157 1798 Argon 121 1006 Argon, compressed 121 1006 Argon, refrigerated liquid (cryogenic liquid) 120 1951 Arsenic 152 1558 Arsenic acid, liquid 154 1553 Arsenic acid, solid 154 1554 Arsenical dust 152 1562 Arsenical pesticide, liquid, flammable, poisonous 131 2760 Arsenical pesticide, liquid, flammable, toxic 131 2760 Arsenical pesticide, liquid, poisonous 151 2994 Arsenical pesticide, liquid, poisonous, flammable 131 2993 Arsenical pesticide, liquid, toxic 151 2994 Arsenical pesticide, liquid, toxic, 131 flammable 2993 Arsenical pesticide, solid, 151 2759 poisonous Name of Material Guide ID No. NO. Arconiral nocHrirlo caMH t"Avir HlbClllLCll jJcbULlUc, bUMU, LUAIL 1*51 T 7 R Q MlbclllL UlUlIllUc 151 ID I IJJ J Arconir r h 1 a ri H H 1 b C 1 1 IL LIIIUIlUC i J/ i sfin 1 J u u Arsenic compound, liquid, n.o.s. J.JJO Arsenic compound, liquid, 152 1556 n a c i n a fa a n ir 1 1 i U i j r j 1 1 1 U 1 Lj a 1 1 1 L Arsenic compound, solid, n.o.s. 1 j j / Arsenic compound, solid, n.o.s., 152 1557 innrnanir 1 1 1 u l u a 1 1 1 L Arconir nop t"A v i rl a MlbclllL pcllLUXlUc 151 Arcanir c 1 1 1 f i H a HI b ell IL a UlllUc 159 1^7 1 j j / A rc a n i r ciilnhirla Ml bell IL b U ipil IU c 159 1 j j / MlbcltlL LllLNlUllUc 157 1 JUU HI b ell IL LIIUXlUc 151 ID I IJDl Arsenic disulfide 152 1557 Arconir trie 1 1 Inh irlo MlbclllL UlbUipilluc 159 1 j j / Arsine 119 2188 Articles containing P olych lorin ated biphenyls (PCB) 171 2315 Articles, pressurized, hydraulic (containing non-flammable gas) 126 3164 Articles, pressurized, pneumatic (containing non-flammable gas) 126 3164 Aryl sulfonic acids, liquid, with more than 5% free Sulfuric 153 2584 acid Aryl sulfonic acids, liquid, with not more than 5% free Sulfuric 153 2586 acid Aryl sulfonic acids, solid, with more than 5% free Sulfuric 153 2583 acid Aryl sulfonic acids, solid, with 153 2585 not more than 5% free Sulfuric Name of Material Guide ID No. No. Aryl sulphonic acids, liquid, with 153 2584 more than 5% free Sulphuric acid Aryl sulphonic acids, liquid, with not more than 5% free Sulphuric acid 153 2586 Aryl sulphonic acids, solid, with more than 5% free Sulphuric acid 153 2583 Aryl sulphonic acids, solid, with notmore than 5% free Sulphuric acid 153 2585 Asbestos 171 2212 Asbestos, blue 171 2212 Asbestos, brown 171 2212 Asbestos, white 171 2590 Asphalt 130 1999 Aviation regulated liquid, n.o.s, 171 3334 Aviation regulated solid, n.o.s. 171 3335 1-Aziridinyl phosphine oxide (Tris) 152 2501 Azodicarbonamide 149 3242 Barium 138 1400 Barium alloys, pyrophoric 135 1854 Barium azide, wetted with not less than 50% water 113 1571 Barium bromate 141 2719 Barium chlorate 141 1445 Barium chlorate, solid 141 1445 Barium chlorate, solution 141 3405 □ anum compouna, n.o.s. T R a a Barium cyanide 157 1565 Barium hypochlorite, with more than 22% available Chlorine 141 2741 Barium nitrate 141 1446 Barium oxide 157 1884 Name of Material Guide ID Name of Material Guide ID No. No. No. NO. Rarinm nprrhlnratp U □ 1 IU 1 II UCI V. 1 1 IUI □ LC 141 1447 Benzoic derivative pesticide, 131 3003 Barium perchlorate, solid 141 1447 liquid, poisonous, flammable Barium perchlorate, solution 141 3406 Benzoic derivative pesticide, liquid, toxic 151 3004 Barium permanganate 141 1448 141 1449 Benzoic derivative pesticide, 131 3003 Barium peroxide liquid, toxic, flammable Raffprips rnn fa in inn ^ nrl in m □ a LLC 1 IC J, L U 1 1 LCI 1 1 1 1 1 1 U JUUIUIII -I-3Q lOO 3292 Benzoic derivative pesticide, 151 2769 Rahhpripc rlr\/ rAnhaininn D d LLC 1 ICi , u 1 y , LUIILdllllllLj 3028 solid, poisonous Potassium hydroxide solid Benzoic derivative pesticide, 151 2769 Batteries, wet, filled with acid 154 2794 solid, toxic Batteries, wet, filled with alkali 154 2795 Benzonitrile 152 2224 Batteries, wet, non-s pillable 154 2800 Benzoquinone 153 2587 Battery fluid, acid 157 2796 Benzotrichloride 156 2226 Battery fluid, alkali 154 2797 Benzotrifluoride 127 2338 R a ffprv flu irl alkali wifh haffprv □ CI LLC IV IIUIU, CI 1 IS. CI 1 1 , VVILII U CI LLC 1 y 1"54 2797 Benzoyl chloride 137 1736 Battery fluid, alkali, with 154 2797 Benzyl bromide 156 1737 electronic equipmentor Benzyl chloride 156 1738 actuating device Benzyl chloro formate 137 1739 Battery-powered equipment(wet 154 3171 132 2619 u a llci y / Benzyldimethylamine Battery-powered vehicle (wet 104 3171 Benzylidene chloride 156 1886 battery) Benzyl iodide 156 2653 Benzaldehyde 129 1990 Beryllium compound, n.o.s. 154 1566 Benzene 130 1114 Beryllium nitrate 141 2464 Rpn7pnp nhn^nhnriK rlirhlnrirlp □ C 1 1 L C 1 1 C UIILOUIIUIU3 uiliiiuiiuc 1^7 2798 Beryllium powder 134 1567 Benzene phosphorus 137 2799 Bhusa, wet, damp or 133 1327 thiodichloride contaminated with oil Rein7Qneiciilf(*in\/l rhlnrirlo DCIIZ.CIIC3UIIUIiyi LIIIUI i u c ICC loo 2225 Bicyclo[2.2.1]hepta-2,5-diene 128P 2251 Ron7onociilnhAn\/l r h 1 a rirl o DClli.CllCjUI|JIIUIiyi LIIIUI IU C ICC IOD 2225 Bicyclo[2.2.1]hepta-2,5-diene, 128P 2251 Benzidine 153 1885 inhibited Benzoic derivative pesticide, liniiirl flammahlp nfiknnnnc; IIUUIU, IIOIIIIMQUIC, UuljUIIUU J 131 2770 Bicyclo[2.2.1]hepta-2,5-diene, stabilized 128P 2251 Benzoic derivative pesticide, 131 2770 Biological agents 158 linuid flaminahlp toxir (Bio)Medical waste, n.o.s. 158 3291 Benzoic derivative pesticide, 151 3004 Bipyridilium pesticide, liquid, 131 2782 liquid, poisonous flammable, poisonous Name of Material Guide ID No. No. Name of Material Guide ID No. No. B ipyrid ilium pesticide, liquid, 131 2782 flammable, toxic Bipyridilium pesticide, liquid, 151 3016 poisonous Bipyridilium pesticide, liquid, 131 3015 poisonous, flammable Bipyridilium pesticide, liquid, 151 3016 toxic Bipyridilium pesticide, liquid, 131 3015 toxic, flammable Bipyridilium pesticide, solid, 151 2781 poisonous Bipyridilium pesticide, solid, 151 2781 toxic Bisulfates, aqueous solution 154 2837 Bisulfites, aqueous solution, 154 2693 n.o.s. Bisulfites, inorganic, aqueous 154 2693 solution, n.o.s. Bisulphates, aqueous solution 154 2837 Bisulphites, aqueous solution, 154 2693 n.o.s. Bisulphites, inorganic, aqueous 154 2693 solution, n.o.s . Blasting agent, n.o.s, 112 Bleaching powder 140 2208 Blue asbestos 171 2212 Bombs, smoke, non-explosive, 153 2028 with corrosive liquid, without initiating device DOIdLc d 11 U LIllOldLc ITllXLUIcb I4U 1 yi c o 1H J Borneol 133 1312 Boron tribromide 157 2692 Boron trichloride HOC 125 1/41 Boron trifluoride 125 1008 Boron trifluoride, compressed 125 1008 Page 104 Boron trifluoride, dihydrate 157 2851 Boron trifluoride acetic acid 157 1742 complex Boron trifluoride acetic acid 157 1742 complex, liquid Boron trifluoride acetic acid 157 3419 complex, solid Boron trifluoride diethyl etherate 132 2604 Boron trifluoride dimethyl etherate 139 2965 Boron trifluoride propionic acid 157 1743 complex Boron trifluoride propionic acid complex, liquid 157 1743 Boron trifluoride propionic acid complex, solid 157 3420 Bromates, inorganic, aqueous solution, n.o.s. 140 3213 Bromates, inorganic, n.o.s. 141 1450 Bromine 154 1744 Bromine, solution 154 1744 Bromine chloride 124 2901 Bromine penta fluoride 144 1745 Bromine trifluoride 144 1746 Bromoacetic acid 156 1938 Bromoacetic acid, solid 156 3425 Bromoacetic acid, solution 156 1938 Bromoacetone 131 1569 Bromoacetyl bromide 156 2513 Bromobenzene 130 2514 Bromobenzyl cyanides 159 1694 Bromobenzyl cyanides, liquid 159 1694 Bromobenzyl cyanides, solid 159 1694 Bromobenzyl cyanides, solid 159 3449 1-Bromobutane 130 1126 Name of Material Guide No. ID No. Name of Material Guide No. ID NO. 2-Bromobutane 130 2339 n-Butylamine 132 1125 Bromochlorodifluoromethane 126 1974 N - B utyl aniline 153 2738 Bromochloromethane 160 1887 Butylbenzenes 128 2709 l-Bromo-3-chloropropane 159 2688 n-Butyl bromide 130 1126 2-B romoethyl ethyl ether 130 2340 Butyl chloride 130 1127 □ lUIMUIUIIM 2515 n-Butyl chloroformate 155 2743 l-Rromo-3-mpthvlhutanp ± 1 U 1 II U *J lll*_UiyiUU^UIl*_ 130 2341 sec-Butyl chloroformate 155 2742 Rrninnmpthvlnrnnanp^ uiuiiiuiiicLiiyiui uuciiicj 130 2342 tert-Butylcyclohexyl 156 2747 1- R rnm n-?-n itrnnrnna np - 1 inl L. UIUIIIU L. IIILIUUIUIJUIIC ulUI 133 3241 chloroformate L yiUIMUUCIILCIIIC 110 2343 Butylene 115 1012 ?-Rrnmnnrnnanp L. U 1 Ull IUUI UUu IIC 129 2344 Butylene 115 1075 Rrnmnnrnnanpc; u i uimuui uua lie j 129 2344 1,2-Butylene oxide, stabilized 127P 3022 J D [U[IIUfJIU|Jy[!c ■ion 2345 Butyl ethers 128 1149 R rArYiAtTifliiAr"Aot"hvlana DIUIIIULI IIIUUI u c U 1 y 1 C 1 1 c 1 ID 2419 n-Butyl formate 129 1128 R ta in a hrif 1 1 1 a ta iyi a hh ariQ 1009 tert-Butyl hypochlorite 135 3255 Rrnwn ac;hpc;r"Ac □ IUVVII a jUCj L, U j 171 2212 N,n-Butylimidazole 152 2690 R ri i r i n o D I ULlllt. 1570 n-Butyl isocyanate 155 2485 R 1 1 fa H i o n o c inhihihorl D U la U 1 C 1 1 C j , IIIIIIUILCU 11KP i i or 1010 tert-Butyl isocyanate 155 2484 Butadienes, stabilized 116P 1010 Butyl mercaptan 130 2347 Butadienes and hydrocarbon 116P 1010 n-Butyl methacrylate 130P 2227 mixture, stabilized n-Butyl methacrylate, inhibited 130P 2227 Butane 115 1011 n-Butyl methacrylate, stabilized 130P 2227 Butane 115 1075 Butyl methyl ether 127 2350 Butanedione 127 2346 Butyl nitrites 129 2351 Butane mixture 115 1011 Butyl propionates 130 1914 Butane mixture 115 1075 Butyltoluenes 152 2667 Rufannk U U Lu 1 1 U 1 J 129 1120 Butyltrichlorosilane 155 1747 R | j [ft y\/l U U LU A y 1 127 2708 5-tert-Butyl-2,4,6-trinitro- 149 2956 R ii h/l a r pfafp c; -|OQ 1123 m-xylene Rnh/I arid nhficinhafp U U Ly 1 □ L 1 U U 1 1 U J U 1 1 □ LC 1IW loo 1718 Butyl vinyl ether, inhibited 127P 2352 Butyl acrylate 130P 2348 Butyl vinyl ether, stabilized 127P 2352 Butyl acrylates, inhibited 130P 2348 1,4-B utynediol 153 2716 Butyl acrylates, stabilized 130P 2348 Butyraldehyde 129 1129 Page 105 Name of Material Guide ID No. NO. R urvra Id oximp u u iv i u i u u a 1 1 ii u 129 2840 R urvrir arid 153 2820 R urvrir a n h vd rid p u u iy i i l u 1 1 1 1 y u i i u l. 156 2739 B utyronitrile 131 2411 R i itwrwl r h 1 a ri rl o DULyiyiLillUllUc L J J J R 1 1 77 DULL too £ 1 U BZ 153 2810 C A 159 1694 Cacodylic acid 151 1572 Cadmium compound 154 2570 Caesium 138 1407 Caesium hydroxide 157 2682 Caesium hydroxide, solution 154 2681 Caesium nitrate 140 1451 Calcium 138 1401 Calcium, metal and alloys, pyrophoric HOC 135 1 c c 1855 Calcium, pyrophoric 135 1855 Calcium alloys, pyrophoric HOC 135 1855 C alcium arsenate 151 15/3 Calcium arsenate and C alcium arsenite mixture, solid 151 1 C ~l A 15/4 Calcium arsenite, solid 151 1574 Calcium arsenite and Calcium arsenate mixture, solid 151 1574 Calcium carbide 138 1402 Calcium chlorate 140 1452 Calcium chlorate, aqueous solution 140 2429 Calcium chlorate, solution 140 2429 Calcium chlorite 140 1453 Calcium cyanamide, with more than 0.1% Calcium carbide 138 1403 Calcium cyanide 157 1575 Name of Material Guide ID No. No. Calcium dithionite 135 1923 Calcium hydride 138 1404 C alcium hydrosulfite 135 1923 Calcium hydrosulphite 135 1923 Calcium hypochlorite, dry 140 1748 Calcium hypochlorite, hydrated, with notless than 5.5% butnot more than 16% water 140 2880 C alrinm hunArhlArifo h\/HrahoH ^ d 1 L 1 U 1 1 1 MyfJULMIUMLc, 1 1 y U I d L C U mixture, with notless than 5.5% but not more than 16% water 1 4U L U L d ! L 1 U 1 1 1 lly|JULIMUIILt: 1 II 1 ALU 1 C , dry, with more than 10% but notmore than 39% available Chlorine 1 4U L L U O Calcium hvnorhloritp mixhirp dry, with more than 39% available Chlorine (8.8% available Oxygen) 140 1748 Calcium manganese silicon 138 2844 C alcium nitrate 140 1454 C alcium oxide 157 1910 Calcium perchlorate 140 1455 Calcium permanganate 140 1456 Calcium peroxide 140 1457 Calcium phosphide 139 1360 Calcium resinate 133 1313 Calcium resinate, fused 133 1314 C alcium silicide 138 1405 Calcium silicon 138 1406 Camphor 133 2717 Camphor, synthetic 133 2717 Camphoroil 128 1130 Caproic acid 153 2829 Name of Material Guide ID No. kin NO. Carbamate pesticide, liquid, Hon 131 2758 IIGIIIIIIGUIC, UuIjUMUUj Carbamate pesticide, liquid, 131 2758 flammable, toxic Carbamate pesticide, liquid, 151 2992 n ni c a n a 1 1 c |JU1jU 1 IU U j Carbamate pesticide, liquid, Hon 131 2991 nnknnonc; f 1 a m m a h 1 p Carbamate pesticide, liquid, 151 2992 LU A 1 L Carbamate pesticide, liquid, 131 2991 toxic flammahle C a rba mate pesticide, solid, 151 2757 nnic Annn c UUIjUI IUU J Carbamate pesticide, solid, 151 2757 toxic farhfin artivatprl 133 1362 Carbon, animal or vegetable 133 1361 origin Carbon bisulfide 131 1131 Carbon bisulphide 131 11 il Carbon dioxide 120 1013 C arhnn HiAviHo rninnrpccoH V- a 1 U U 1 1 U 1 U Al U c , LUIM^JICJJCU 19(1 mi d 1U13 Carbon dioxide, refrigerated 120 2187 liquid LdlUUII UIUXIUC, bOIIU 1845 Carbon dioxide and Ethylene 115 1041 oxide mixture, with more than 9% but not more than 87% PhhulanQ avi/Hq CUIylcMc UXlUc Carbon dioxide and Ethylene 119P 3300 oxide mixture, with more than 87% Fthvlenp oxidp Carbon dioxide and Ethylene 115 1041 oxide mixtures, with more than 6% Ethylene oxide Name of Material Guide Mn NO. ID NO. Carbon dioxide and Ethylene oxide mixtures, with notmore than 6% Ethylene oxide 126 1952 Carbon dioxide and Ethylene oxide mixtures, with notmore than 9% Ethylene oxide 126 1952 Carbon dioxide and Nitrous oxide mixture 126 1015 Carbon dioxide and Oxygen mixtu re 122 1014 Carbon dioxide and Oxygen mixture, compressed 122 1014 C arbon disulfide 131 1131 Carbon disulphide 131 1131 Carbon monoxide 119 1016 Carbon monoxide, compressed 119 1016 Carbon monoxide, refrigerated liquid (cryogenic liquid) 168 9202 Carbon monoxide and Hydrogen mixture 119 2600 Carbon monoxide and Hydrogen mixture, compressed 119 2600 Carbon tetrabromide 151 2516 C arbon tetrachloride 151 1846 Carbonyl fluoride 125 2417 Carbonyl fluoride, compressed 125 2417 Carbonyl sulfide 119 2204 Carbonyl sulphide 119 2204 Castor beans, meal, pomace or flake 171 2969 Caustic alkali liquid, n,o,s. 154 1719 Caustic potash, dry, solid 154 1813 Caustic potash, liquid 154 1814 Caustic potash, solution 154 1814 Caustic soda, bead 154 1823 Caustic soda, flake 154 1823 Name of Material Guide ID NO. NO. Caustic soda, granular 154 lb7 j Caustic soda, solid 154 1823 Caustic soda, solution 154 1824 Cells, containing S odium loo ii'ii Celluloid, in blocks, rods, rolls, 133 2000 sheets, tubes, etc., except scrap Celluloid, scrap 135 2002 Cerium, slabs, ingots or rods 170 1333 Cerium, turnings orgritty powder 138 b A7 Q loo 1407 C pc hi m hv/rlrAvirlo \, c b i u [ ii [lyuiuAiuc b C O b C ociiim h\/rlrAvirlo colnHnn t~ C b 1 U 1 1 1 llyUIUAlUC, b U 1 U UU 1 1 11d b C O 1 L cb IU 111 n 1 LI d Lc -i /in 1451 191 1076 L lid 1 LUdl I'M 1361 l, nemicai k i l 1760 Chemical kit 171 3316 Chemical sample, poisonous 151 b b i ^ Chemical sample, poisonous 151 3315 liquid Chemical sample, poisonous 151 3315 solid Chemical sample, toxic 151 3315 Chemical sample, toxic liquid 151 3315 Chemical sample, toxic solid 151 3315 Chloral, anhydrous, inhibited 153 2075 Chloral, anhydrous, stabilized 153 2075 Chlorate and Borate mixtures 140 1458 Chlorate and Magnesium 140 1459 chloride mixture Chlorate and Magnesium 140 1459 chloride mixture, solid Chlorate and Magnesium 140 3407 chloride mixture, solution Name of Material Guide ID No. NO. Chlorates, inorganic, aqueous solution, n.o.s. 140 3210 Chlorates, inorganic, n.o.s. 140 1461 Chloric acid, aqueous solution, VV 1 LI 1 1 1 1 u u iy 1 C LI 1 C 1 J 198 114 3 l~l ir h 1 a i"A a roHr arid L> IL. 1 1 IU 1 U a LC LIL. dLJU 153 1 / U4 1,3-Dichloro ace tone 153 2649 n ir h 1 a r"A a r ot"\/l rhlArirlo UlLIIIUIUdLcLyl L. 1 1 1 U 1 I u c ICC ISO 1 7 fi R 1 / U J nirhlACAanilinpc LJlLIIIUIUdlllllllCj 153 i spn 1 J 3 U Dirhlnrnanilinpc; liniiirl LHLIIIUIUdlMMIICj, 1 1 U U 1 U 153 1590 nirhlArA^nilinpc cnlirl LJlLIIIUIUdlllllllCa, 3 U 1 1 u 153 1 J 3 U nirhlArAanilinoc c a 1 i rl L/ILIIIUIUdlllllllCb, 3 U 1 1 u 153 loo J44 £ A.nirhlArAhpn7pnp U UILMIUIUUCMZ.CMC 159 1 SP1 1 J 3 1 Dirhlnrnhntpnp \J 1 L 1 1 1 U 1 Uk/ll LC 1 1 C 132 2920 1 9 n ir h 1 a taH iot"h\/l oHior L,L U IL 1 1 1 U 1 U U 1 C LI 1 y 1 C LI 1 C 1 159 lo^ 1 3 1 U Dichlorodifluoromethane 126 1028 Dichlorodifluoromethane and Difluoroethane azeotropic mixture with approximately 74% Dichlorodifluoromethane 126 2602 Dichlorodifluoromethane and 126 3070 Ethylene oxide mixture, with notmore than 12.5% Ethylene oxide Name of Material Guide ID No. No. Dichlorodifluoromethane and 126 3070 Ethylene oxide mixtures, with notmore than 12% Ethylene oxide Dichlorodimethyl ether, symmetrical 131 2249 1,1-Dichloroethane 130 2362 1,2-Dichloroethylene 130P 1150 Dichloroethylene 130P 1150 Dichloroethyl ether 152 1916 Dichlorofluoromethane 126 1029 Dichloroisocyanuric acid, dry 140 2465 Dichloroisocyanuric acid salts 140 2465 Dichloroisopropyl ether 153 2490 Dichloromethane 160 1593 1,1-Dichloro-l-nitroethane 153 2650 Dichloropentanes 130 1152 uicnioropnenyi isocyanates loo 11 RO. 11 jU Dichlorophenyltrichlorosilane 156 1766 1,2-Dichloropropane 130 1279 Dichloropropane 130 1279 l,3-Dichloropropanol-2 153 2750 nirhlATAnrAnpnpc LJIUIIIUI Lf[JI UJJCIItrZ) 190 1 £o L U4 / Dichlorosilane 119 2189 l,2-Dichloro-l,l,2,2- tetrafluoroethane 126 1958 Dichlorotetrafluoroethane 126 1958 3,5-Dichloro-2,4,6- trifluoropyridine 151 9264 Dicycloheptadiene 128P 2251 Dicyclohexylamine 153 2565 Dicyclohexylammonium nitrite 133 2687 Dicyclopentadiene 130 2048 l,2-Di-(dimethylamino)ethane 129 2372 Page 1 16 Name of Material Guide ID No. NO. D id vtnin in nilrafp LJ IU y 1 1 1 1 U 1 1 1 IIILIuLC 140 1465 Diplrl ri n U 1 C 1 U 1 III 151 ij i 2761 n j p c p i fn p i UICjCI 1 U C 1 12ft 1202 Diesel fuel 128 1993 Diethoxymethane 127 2373 3-Dipthoxvnronpnp 127 2374 Diethylamine 132 1154 2-Diethylaminoethanol 132 2686 Diethylaminoethanol 132 2686 3-Diethylaminopropylamine 132 2684 Die thylaminopropyl amine 132 2684 N N -D ipthvla n iline 153 2432 Diethylbenzene 130 2049 niphh\/l rarhnnafp u ic li i y i l a i u u 1 1 □ lc Diethyldichlorosilane 155 1767 D i p t h v 1 p n p 1" r i a m i n p 154 2079 Diethyl ether 127 1155 N N-Dipthvlpthvlpnpdiaminp 132 2685 Diethyl ketone 127 1156 Diethyl sulfate 152 1594 Diethyl sulfide 129 2375 Diethyl sulphate 152 1594 Diethyl sulphide 129 2375 Diethvlthionhosnhorvl rhloride U 1 C LI 1 yiLII ll/L/lll/JL/IIL/l y 1 1, 1 1 1 \J 1 IUU 155 2751 n i p l"h \/ 1 7 i n r UlCUiyiZ.MIL lis 1366 nifliinrnrhlorfipfhanpc; UIIIUUIULIIIUI U C LI 1 □ 1 1 C 3 115 2517 L J 1 / 1 1 - n ifl 1 1 a rAPfh a np 1,1 LJlllUUIUCLIIGIlC 115 1 U JU Difluoroethane 115 1030 Difluoroethaneand 126 2602 Dichlorodifluoromethane azeotropic mixture with approximately 74% n ir h 1 a ta rl i f 1 1 1 a ta m a t"h ano LJILIIIUIUUIIIUUIUIIlcLlldllc 1,1-Difluoroethylene 116P 1959 Name of Material Guide ID NO. NO. Difluoromethane 115 3252 Difluorophosphoric acid, annyurous 154 1768 2,3-Dihydropyran 1 37£ 15/0 uiisoDutyiamine L 301 Diisobutylene, isomeric compounas 128 2050 Diisobutyl ketone 1 1 R "7 113 / unsoociyi acia pnospnate IRQ loo i cim iyuz Diisopropylamine lljo Diisopropyl ether 127 1159 Diketene, inhibited 131P 2521 Diketene, stabilized 131P 2521 1,1-Dimethoxy ethane 127 2377 i,z-uime en oxye inane 127 2252 Dimethylamine, anhydrous 118 1032 Dimethylamine, aqueous solution 132 1160 Dimethylamine, solution 132 1160 z-uimecnyiaminoace com true 131 2378 2-Dimethylaminoethanol 132 2051 2-Dimethylaminoethyl acrylate 152 3302 2-Dimethylaminoethyl mecnacryiate 153P 2522 Dimethylaminoethyl methacrylate 153P 2522 N,N-Dimethylaniline 153 2253 2,3-Dimethylbutane 128 2457 1,3-Dimethylbutylamine 132 2379 uimetnyicaruamoyi cnionae 156 2262 uimetnyi caruonace 129 1161 Dimethylcyclohexanes 128 2263 N,N-Dimethylcyclohexylamine 132 2264 Dimethylcyclohexylamine 132 2264 Page 117 Name of Material Guide ID No. NO. D i m p 1" h v 1 d i c h 1 o r o $ i 1 a n p u 1 1 1 1 *w l i i y i u i u i m yj i \j J iiuii^- 155 1162 Dimpthvlrlipthnyv^ilanp UMIMCLIiyiUICLIIL/AyjIIUIIC 127 2380 Dimpthvldinxanp^ U I 1 1 1 t LI 1 V IU IU AU MU J 127 2707 Dimpthvl dkulfidp 130 2381 Dimpthvl dkulnhidp u j 1 1 1 c li i y i u uuiuii iu c 130 2381 Dimpthvlpthannlaminp L>IIIILTLIiyiCLIIullL/lullllllLT 132 2051 Dimethyl ether 115 1033 N ,N -D imethylformamide 129 2265 1 1.nimohh\/lh\/rlra7ino ipiuiiiicuiyiiiyui a l \ 1 1 c IO I 1 1 V J ipiiuiiMcLiiyiiiyui d l \ 1 1 c 111 LJOL Dimethylhydrazine, symmetrical 131 2382 Dimethylhydrazine, unsymmetrical 131 1163 2,2-Dimethylpropane 115 2044 [~1 i m o l"h u 1 M nrnnwlaminfl u i in c Liiy i-im -pi u py id in iiic 1°.° ZZOD Dimethyl sulfate 156 1595 Dimethyl sulfide 130 1164 Dimethyl sulphate 156 1595 Dimethyl sulphide 130 1164 Dimethyl thiophosphoryl chloride 156 2267 Dimethylzinc 135 1370 Dinitroanilines 153 1596 Dinitrobenzenes 152 1597 Dinitrobenzenes, liquid 152 1597 Dinitrobenzenes, solid 152 1597 Dinitrobenzenes, solid 152 3443 Dinitrochlorobenzenes 153 1577 Dinitro-o-cresol 153 1598 Dinitrogen tetroxide 124 1067 Dinitrogen tetroxide, liquefied 124 1067 Dinitrogen tetroxide and Nitric oxide mixture 124 1975 Dinitrophenol, solution 153 1599 Name of Material Guide NO. ID INO. Dinitrophenol, wetted with not less than 15% water 113 1320 Dinitrophenolates, wetted with notless than 15% water 113 1321 Dinitroresorcinol, wetted with notless than 15% water 113 1322 Dinitrotoluenes 152 2038 Dinitrotoluenes, liquid 152 2038 Dinitrotoluenes, molten 152 1600 Dinitrotoluenes, solid 152 2038 Dinitrotoluenes, solid 152 3 A Z A 3454 Dioxane 127 1165 Dioxolane -i 0"7 127 1 1 rr 1166 Dipentene ZUjZ Diphenylamine chloroarsine 154 i c no 1698 Diphenylchloroarsine 101 1 £00 loyy Diphenylchloroarsine, liquid 1 £00 Diphenylchloroarsine, solid 151 icon 1699 Diphenylchloroarsine, solid 101 Diphenyldichlorosilane 156 1769 Diphenylmethyl bromide loo 1770 Diphosgene 125 1076 Dipicryl sulfide, wetted with not less than 10% water 113 2852 Dipicryl sulphide, wetted with notless than 10% water 113 2852 Dipropylamine 1o2 IDOD Di-n-propyl ether 10"7 Dipropyl ether 10"7 1 1 QA uipropyi Ketone -|OQ ii i n Disinfectant, liquid, corrosive, n.o.s. 153 1903 Disinfectant, liquid, poisonous, n.o.s, 151 3142 Disinfectant, liquid, toxic, n.o.s 151 3142 Page 1 18 Name of Material Guide ID IMO. NO. Disinfectant, solid, poisonous, n.o s. 151 i c n i Disinfectant, solid, toxic, n.o.s. 151 IbUl Disinfectants, corrosive, liquid, n.o.s. Disinfectants, liquid, n.o.s. 153 1903 151 3142 ^poisonous) Disinfectants, solid, n.o.s. 151 1601 ^poisonous) Disodium trioxosilicate 154 3253 Disodium trioxosilicate, 154 3253 pen canyo rate uispersanc gas, n.o.s. -IOC "1 H7Q 1U/0 Dispersantgas, n.o.s. 115 1954 (flammable) Dithiocarbamate pesticide, 131 2772 uquia, nammauie, poisonous Dithiocarbamate pesticide, 131 2772 liquid, flammable, toxic Dithiocarbamate pesticide, 151 3006 Mquia, poisonous Dithiocarbamate pesticide, 131 3005 uquia, poisonous, nammauie Dithiocarbamate pesticide, 151 3006 liquid, toxic Dithiocarbamate pesticide, 131 3005 liquid, toxic, flammable Dithiocarbamate pesticide, 151 2771 s o ii u , poisonous Dithiocarbamate pesticide, 151 2771 solid, toxic Divinyl ether, inhibited 1 1 CT lib/ Divinyl ether, stabilized 128P 1167 D M 154 1698 Dodecylbenzenesulfonic acid loo 7£Q/I Z_>o4 Dodecylbenzenesulphonic acid loo 7£Q/1 Dodecyltrichlorosilane TOO 1 771 1 / / 1 Name of Material Guide ID No. No. 1076 1845 2801 1602 1602 DP 125 Dry ice 120 Dye, liquid, corrosive, n.o.s. 154 Dye, liquid, poisonous, n.o.s. 151 Dye, liquid, toxic, n.o.s, 151 Dye, solid, corrosive, n.o.s. 154 3147 Dye, solid, poisonous, n.o.s. 151 3143 Dye, solid, toxic, n.o.s. 151 3143 Dye intermediate, liquid, 154 2801 corrosive, n.o.s, Dye intermediate, liquid, 151 1602 poisonous, n.o.s. Dye intermediate, liquid, toxic, 151 1602 n.o.s. Dye intermediate, solid, 154 3147 corrosive, n.o.s, Dye intermediate, solid, 151 3143 poisonous, n.o.s. Dye intermediate, solid, toxic, 151 3143 n.o.s. ED 151 1892 Elevated temperature liquid, 128 3256 flammable, n.o.s., with flash pointabove 37.8°C (100°F), atorabove its flash point Elevated temperature liquid, 128 3256 flammable, n.o.s., with flash pointabove 60.5°C (141°F), atorabove its flash point Elevated temperature liquid, 128 3257 n.o.s., at or above 100°C (212°F), and below its flash point Elevated temperature solid, 171 3258 n.o.s., atorabove 240°C (464°F) Enginestartingfluid 115 1960 Page 1 19 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Engines, internal combustion, flammable gas powered 128 3166 Engines, internal combustion, flammable liquid powered 128 3166 Engines, internal combustion, including when fitted in machineryorvehicles 128 3166 Environmentally hazardous substances, liquid, n.o.s. 171 3082 Environmentally hazardous substances, solid, n.o.s. 171 3077 Epibromohydrin 131 2558 Epichlorohydrin 131P 2023 1, 2- E poxy-3-ethoxy propane 127 2752 Esters, n.o.s. r\—j 127 32/2 E th a n e 115 i n i c Ethane, compressed 115 1035 Ethane, refrigerated liquid 115 1961 Ethane-Propane mixture, refrigerated liquid 115 1961 Ethanol 127 1170 Ethanol, solution 127 1170 Ethanolamine 153 2491 Ethanolamine, solution ■1 CO 153 i a n i 2491 Ethers, n.o.s. 127 3271 Ethyl acetate H Ort 129 1 ITT 11/3 Ethylacetylene, inhibited 116P 2452 Ethylacetylene, stabilized 116P 2452 Ethyl acrylate, inhibited h inn 129r inn Ethyl acrylate, stabilized 4 inn 129P 191 / Ethyl alcohol 127 1170 Ethyl alcohol, solution 127 1170 Ethylamine 118 1036 Ethylamine, aqueous solution, with notless than 50% butnot 132 2270 more than 70% Ethylamine Ethyl amyl ketone h no 128 1 1 "7 1 2.2.11 2-Ethylaniline -i co 153 2215 N-Ethylaniline HCO 153 22 12 E thylbenzene h on 130 1 1 "7 C 11/5 N-Ethyl-N-benzylaniline H CO 153 111 A 22 /4 N-Ethyl benzyl to luidines •4 CO 153 2lbi N-Ethylbenzyltoluidines, liquid -i co 153 ii a 2/53 N -E thylbenzyltoluidines, solid -i co 153 ii a 2/53 N-Ethylbenzyltoluidines, solid ■ICO 153 i a a n E thy 1 borate H OA 129 1 1 1 a 11 /D E thyl bromide 4 OH 131 lo91 E thyl bromoacetate H CC 155 loll:) 2-b thylbutanol 129 1 1 "7 C 22/5 2-Ethylbutyl acetate •4 on 130 1 1 1 1 1111 E thylbutyl acetate h on 130 1 1 1 1 mi E thyl butyl ether 127 i i i n 11/9 2-Ethylbutyraldehyde 4 on 130 I 1 "7 II /o E thyl butyrate 10fi 130 1 1 on 110U Ethyl chloride 115 1037 E thyl chloroacetate •i CC 155 1101 llol Ethyl chloroformate 155 1182 E thyl 2-chloropropion ate -* on 129 z9 j5 E thyl chlo roth ioform ate 155 2826 Ethyl crotonate 130 1862 Ethyl cyanoacetate •4 CC 15o zbbb Ethyldichloroarsine 151 1892 Ethyldichlorosilane 139 1183 Ethylene 116P 1962 Name of Material Guide ID No. NO. 115 3138 116P 1962 115 1038 131 1135 132 1604 154 1605 151 1647 Name of Material Guide ID No. IMO. Ethylene oxide and Carbon 126 1952 dioxide mixtures, with not IIIUIc LI 1 □ 1 1 U /0 ELIiyiClIC UAlUc Ethylene oxide and Carbon 126 1952 dioxide mixtures, with not IIIUIc Llldll y/o C Lily Ic II c UXIU c Ethylene oxide and 126 3297 Chlorotetrafluoroethane mixture, with notmore than Q QOL Prhwlann Avirla o.o /o cinyicnc oxiuc Ethylene oxide and 126 3070 Dichlorodifluoromethane mixture, with notmore than 1Z.J/0 c uiyic lie UXIUC Ethylene oxide and 126 3070 Dichlorodifluoromethane mixtures, with not more than IZ/o CLIIylcllcUAlufc: Ethylene oxide and 126 3298 Pentafluoroethane mixture, with not more than 7.9% □ u i y 1 1. 1 1 c uaiuc Ethylene oxide and Propylene 129P 2983 oxide mixture, with notmore Llldll jU/0 CLIiyicllc UXlUc Ethylene oxide and 126 3299 Tetrafluoroethane mixture, with not more than 5.6% E thylene oxide Ethylene oxide with Nitrogen 119P 1040 Ethyl ether 127 ii-O Ethyl fluoride 115 LHJJ Ethyl formate 129 1 1 on Ethylhexaldehydes 129 1 1 0,1 2-Ethylhexylamine 132 2-Ethylhexyl chloroformate 156 L ;4o Ethyl isobutyrate 129 2385 Ethyl isocyanate 155 1A Q 1 Ethylene, Acetylene and Propylene in mixture, refrigerated liquid containing atleast71.5% Ethylene with notmore than 22,5% Acetylene and notmore than 6% Propylene Ethylene, compressed Ethylene, refrigerated liquid (cryogenic liquid) Ethylene chlorohydrin Ethylenediamine Ethylene dibromide Ethylene dibromide and Methyl bromide mixture, liquid Ethylene dichloride Ethylene glycol diethyl ether Ethylene glycol monobutyl ether Ethylene glycol monoethyl ether Ethylene glycol monoethyl ether acetate Ethylene glycol monomethyl ether Ethylene glycol monomethyl ether acetate Ethyleneimine, inhibited Ethyleneimine, stabilized Ethylene oxide Ethylene oxide and Carbon dioxide mixture, with more than 9% butnotmore than 87% Ethylene oxide Ethylene oxide and Carbon dioxide mixture, with more than 87% Ethylene oxide Ethylene oxide and Carbon dioxide mixtures, with more than 6 % Ethylene oxide 131 1184 127 1153 152 2369 ' 127 1171 129 1172 127 129 1188 1189 131P 1185 131P 1185 119P 1040 115 1041 119P 3300 115 1041 Page 121 Name of Material Guide ID NO. NO. ri.L 1 |_ _f _ t_ beryl lactate non 129 Ethyl mercaptan h on 129 Ethyl methacrylate 130P 2277 Ethyl methacrylate, inhibited 130P 2277 Ethyl methacrylate, stabilized 130P 2277 E thyl methyl ether 115 1039 E thyl methyl ketone 127 1193 Ethyl nitrite, solution 131 1194 Ethyl orthoformate 129 2524 Ethyl oxalate 156 2525 Ethylphenyldichlorosilane 156 2435 Ethyl phosphonothioic dichloride, anhydrous 154 2927 Ethyl phosphonous dichloride, anhydrous 135 2845 Ethyl phosphorodichloridate 154 2927 1-Ethylpiperidine L JOU Ethyl propionate I 1 Q R I I j j E thyl propyl ether 197 L U 1 J Ethyl silicate Ethylsulfuric acid 156 2571 Ethylsulphuric acid 156 2571 N-Ethyltoluidines 153 2754 E thyltrich loros ila n e 155 1196 Explosive A 112 Explosive B 112 E xplos ive C 114 Explosives, division 1.1, 1.2, 112 1.3, 1.5 or 1.6 Explosives, division 1.4 114 Extracts, aromatic, liquid 127 1169 Extracts, flavoring, liquid 127 1197 Extracts, flavouring, liquid 127 1197 Name of Material Guide ID No. NO. Fabrics, animal or vegetable 133 1373 fir svnrhpHr n fi s wirh fiil Ul jyllUICUL, II. U.J. VV 11-11 UN Fabrics impregnated with weakly 133 1353 nitrated Nitrocellulose, n.o.s. Ferric arsenate 151 1606 Ferric arsenite 151 i c m lbO/ Ferric chloride 157 1/ 15 Ferric chloride, anhydrous 157 1773 Ferric chloride, solution 154 2582 Ferric nitrate 140 t A CC 1466 Ferrocerium 170 1323 Ferrosilicon 139 i a no 1408 Ferrous arsenate 151 i c no lb08 Ferrous chloride, solid 154 1759 F prroii s rh Ifirirle sfilntifin 154 1760 Ferrous metal borings, 170 2793 chavinnc hirninnc nrrnttinnc j 1 1 u V 1 1 1 LJ j , LU 1 1 1 1 1 1 Lj J Ul L U LU 1 1 U. 3 Fertilizer, ammoniating solution, 125 1043 u/ifh frpp AmmAnia VV 1 LI 1 1 1 CC H 1 II 1 II U 1 1 1 d Fiber, animal or vegetable, •i OO 133 1372 n a c hiirnf \MPfrir damn II. U.S., UUIIIL, VV C L U 1 U d 1 1 1 U Fibers, animal or vegetable -4 OO 133 1373 at c \/n t"h o Hr n a c \ywit"h aM Ul byllLllcLIL, II. U.b. W 1 LI 1 UN Fibers, animal or vegetable, •i OO 133 1372 burnt, wetordamp i i uc i j i vcuclciuic, u i y 7 7 fifi Fibers impregnated with weakly 133 1353 MILIdLcU N 1 LI U L c 1 1 U 1 U b c , ll.U.b. Fibres, animal or vegetable, 133 1372 hiirnf w/pfArrlamn UUIIIL, VVCLUI UdlllU Fibres, animal or vegetable 133 1373 or synthetic, n.o.s. with oil Fihrpc; \/priphahlp Hru 1 IUI Cj , VCUCLCIUIC, Uly 7 7 fifi Fibres impregnated with weakly 133 1353 n itra ho rl M irrArolhil aco n a c IIILIdLCU \\ 1 LI U L C 1 1 U 1 U 3 C , II.U.j. Films, nitrocellulose base 133 1324 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Fire extinguishercharges, 154 1774 corrosive liquid Fire extinguishers with 126 1044 compressed gas Fire extinguishers with 126 1044 liquefied gas Firelighters, solid, with 133 2623 flammable liquid Firstaid kit 171 3316 Fish meal, stabilized 171 2216 Fish meal, unstabilized 133 1374 Fish scrap, stabilized 171 2216 Fish scrap, unstabilized 133 1374 Flammable liquid, corrosive, 132 2924 n.o.s Flammable liquid, n.o.s. 128 1993 Flammable liquid, poisonous, 131 3286 corrosive, n.o.s. Flammable liquid, poisonous, 131 1992 n.o.s. Flammable liquid, toxic, 131 3286 corrosive, n.o.s. Flammable liquid, toxic, n.o.s. 131 1992 Flammable solid, corrosive, 134 3180 inorganic, n.o.s. Flammable solid, corrosive, 134 2925 n.o.s. Flammable solid, corrosive, 134 2925 organic, n.o.s. Flammable solid, inorganic, 134 3180 corrosive, n.o.s. Flammable solid, inorganic, 133 3178 n.o.s. Flammable solid, n.o.s, 133 1325 Flammable solid, organic, 133 3176 molten, n.o.s. Flammable solid, organic, n.o.s. 133 1325 Flammable solid, oxidizing, 140 3097 n.o.s. Flammable solid, poisonous, 134 3179 inorganic, n.o.s. Flammable solid, poisonous, 134 2926 n.o.s. Flammable solid, poisonous, 134 2926 organic, n.o.s. Flammable solid, toxic, 134 3179 inorganic, n.o.s. Flammable solid, toxic, organic, 134 2926 n.o.s. Fluoboric acid 154 1775 Fluorine 124 1045 Fluorine, compressed 124 1045 Fluorine, refrigerated liquid (cryogenic liquid) 167 9192 Fluoroacetic acid 154 2642 Fluoroanilines 153 2941 Fluorobenzene 130 2387 Fluoroboric acid 154 1775 Fluorophosphoric acid, 154 1776 anhydrous Fluorosilicates, n.o.s. 151 2856 Fluorosilicic acid 154 1778 Fluorosulfonic acid 137 1777 Fluorosulphonic acid 137 1777 Fluorotoluenes 130 2388 Fluosilicic acid 154 1778 Formaldehyde, solution, flammable 132 1198 Formaldehyde, solutions (Formalin) 132 1198 Formaldehyde, solutions (Formalin) (corrosive) 132 2209 Formic acid 153 1779 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Fuel, aviation, turbine engine 128 1863 Fuel oil 128 1202 Fuel oil 128 iyy j r uei on, no. i,z,4,3,b 1ZUZ Fumaryl chloride 156 i Ton 1 /o0 Fumigated unit 171 3359 Furaldehydes 132P 1199 Furan ■1 OO 128 2389 Furfural 1o2r linn nyy Furfuraldehydes 132P linn nyy F urfuryl alcohol H CO 153 1 "7 A 28/4 Furfurylamine 132 2526 Fusee (rail or highway) 133 1325 Fusel oil 127 1201 GA 153 2810 Gallium 172 2803 Gas, refrigerated liquid, flammable, n.o.s. 115 3312 Gas, refrigerated liquid, n.o.s. 120 3158 Gas, refrigerated liquid, oxidizing, n.o.s. 122 3311 G as cartridges 115 2037 /-> * _ ii" Gas genera tor assemblies 171 8013 G as identification set 123 9035 Gasohol 128 1203 Gas oil 128 1202 Gasoline 128 1203 Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid 115 3167 Gas sample, non-pressurized, 119 3168 poisonous, flammable, n.o.s., notrefrigerated liquid Gas sample, non-pressurized, poisonous, n.o.s., not refrigerated liquid 123 3169 Gas sample, non-pressurized, toxic, flammable, n.o.s., not refrigerated liquid 119 3168 Gas sample, non-pressurized, toxic, n.o.s., notrefrigerated liquid 123 3169 GB 153 2810 G D 153 2810 Genetically modified micro- organisms 171 3245 Germane 119 2192 GF 153 2810 G lycerol alpha- monochlorohydrin 153 2689 G lycidaldehyde 131P 2622 G uanidine nitrate 143 1467 H 153 2810 Hafnium powder, dry 135 2545 Hafnium powder, wetted with not less than 25% water 170 1326 Halogenated irritating liquid, n.o.s. 159 1610 Hay, wet, damp or contaminated with oil 133 1327 Hazardous waste, liquid, n.o.s. 171 3082 Hazardous waste, solid, n.o.s. 171 3077 u r\ H D 153 2810 Heating oil, light 128 1202 Heatproducing article 171 8038 Helium 121 1046 Helium, compressed 121 1046 Helium, refrigerated liquid 120 1963 (cryogenic liquid) Page 124 Name of Material Guide ID No. No. Hepta fluoropropane 126 3296 n-H eptaldehyde 129 3056 Heptanes 128 1206 n-Hpntpnp II II 1 1 L. 128 2278 Hpyarhlnrnarpfnnp 153 2661 Hpyarhlnrnhpn7pnp 152 2729 Hpyarhlnrnhntarlipnp 1 1 C A U L 1 1 1 U 1 uUUlUUICIIC 151 2279 Hexachlorocyclopentadiene 151 2646 Hexachlorophene 151 2875 HpyaHprvllrirhlornc;ilarip 1 1 CAuUCLylLI 1 L 1 1 1 U 1 U J M U 1 1 c 156 1781 Hexadiene 130 2458 Hexaethyl tetra phosphate 151 1611 Hexaethyl tetraphosphate, liquid 151 1611 Hexaethyl tetraphosphate, solid 151 1611 Hpyapfhvl fptranhns nhafp and LUIIIUICjjCU y j imialuic -IO-3 1 1612 H exafluoroacetone 125 2420 Hexafluoroacetone hydrate 151 2552 Hexafluoroacetone hydrate, liquid 151 2552 Hexafluoroacetone hydrate, solid 151 3436 H exafluoroethane 126 2193 H exafluoroethane, compressed 126 2193 Hexafluorophosphoric acid 154 1782 Hexafluoro propylene 126 1858 H exafluoropropylen e oxide 126 1956 Hexaldehyde 130 1207 Hexamethylenediamine, solid 153 2280 Hexamethylenediamine, solution 153 1783 Hexamethylene diisocyanate 156 2281 ncAdiiicuiyiciiciiiiiiic Hexamethylenetetramine 133 1328 Name of Material Guide ID No. No. H p y 3 m i np 1 1 L. A CI 1 1 1 1 1 1 L. 133 1328 H p y a n p c MCAQMC3 128 1208 Hpyannir arid IICACHIUIL Q L III 153 1 JO 2829 H pya nn k 1 ICAullUlJ 129 2282 1-HpyptiP 1 1 1 C AC 1 1 C 128 2370 Hpyvllrirhlnrnciilarip 1 1 CAylU ILIIIUI U j 1 10 1 1 C 15fi 1784 H L 153 IOO 2810 HN-1 153 2810 HN-2 153 IOO 2810 H N-3 153 2810 Hydrazine, anhydrous 132 2029 Hydrazine, aqueous solution, with more than 37% Hydrazine 153 2030 Hydrazine, aqueous solution, with notless than 37% butnot more than 64% Hydrazine 153 2030 Hydrazine, aqueous solution, with not more than 37% Hydrazine 152 3293 Hydrazine, aqueous solutions, with more than 64% Hydrazine 132 2029 Hydrazine hydrate 153 2030 Hydrides, metal, n.o.s. 138 1409 Hydriodic acid 154 1787 Hydriodic acid, solution 154 1787 Hydrobromic acid 154 1788 Hydrobromic acid, solution 154 1788 Hydrocarbon gas, compressed, n.o.s. 115 1964 Hydrocarbon gas, liquefied, n.o.s. 115 1965 Hydrocarbon gas mixture, com p 1 cb b cU , It.O.b. 115 1964 Hydrocarbon gas mixture, 115 1965 liquefied, n.o.s. Page 125 Name of Material Guide ID No. NO. III 1 cue II Hydrocarbon gas refills forsmall 115 3150 devices, with release device Hydrocarbons, liquid, n.o.s. 128 3233 Hydrochloric acid 157 1 1 o n H \/H rn r h 1 a rir arirl cnlnHnn nyUIULIIIUIIL a L 1 U , 3UIUUUII i 1 ^ i j/ i /oy Hydrocyanic acid, aqueous 154 1613 solution, with less than 5% Hurlrnnon rvanirlei nyuiuycii l y a \ \ i u c Hydrocyanic acid, aqueous 154 1613 solution, with notmore than 20% Hvdroaen cyanide Hydrocyanic acid, aqueous 117 1051 solutions, with more than 20% Hydrogen cyanide Hydrocyanic acid, liquefied 117 1051 Hydrofluoric acid 157 1790 Hydrofluoric acid, solution 157 1790 Hydrofluoric acid and Sulfuric 157 1786 Name of Material Guide ID No. No. Hydrogen chloride, anhydrous Hydrogen chloride, refrigerated liquid Hydrogen cyanide, anhydrous, stabilized Hydrogen cyanide, anhydrous, stabilized (absorbed) Hydrogen cyanide, aqueous solution, with notmore than 20% Hydrogen cyanide Hydrogen cyanide, solution in alcohol, with notmore than 45% Hydrogen cyanide Hydrogen cyanide, stabilized Hydrogen cyanide, stabilized (absorbed) Hydrogendifluorides, n.o.s. Hydrogen fluoride, anhydrous Hydrogen iodide, anhydrous Hydrogen peroxide, aqueous solution, stabilized, with more than 60% Hydrogen peroxide Hydrogen peroxide, aqueous solution, with notless than 8% butless than 20% Hydrogen peroxide Hydrogen peroxide, aqueous solution, with notless than 20% but not more than 60% Hydrogen peroxide (stabilized as necessary) Hydrogen peroxide, stabilized Hydrogen peroxide and Peroxyacetic acid mixture, with acid(s), waterand not more than 5% Peroxyacetic acid, stabilized Hydrogen selenide, anhydrous Hydrogen sulfide acid mixture Hydrofluoric acid and Sulphuric 157 1786 acid mixture H yd roflu oros i lie ic acid 154 1778 Hydrogen 115 1049 Hydrogen, absorbed in metal 115 9279 hydride Hydrogen, compressed 115 1049 Hydrogen, in a metal hydride 115 3468 storage system Hydrogen, refrigerated liquid 115 1966 (cryogenic liquid) Hydrogen and Carbon monoxide 119 2600 mixture Hydrogen and Carbon monoxide 119 2600 mixture, compressed Hydrogen and Methane mixture, 115 2034 compressed Hydrogen bromide, anhydrous 125 1048 125 1050 125 2186 117 1051 152 1614 154 1613 131 3294 117 1051 152 1614 154 1740 125 1052 125 2197 143 2015 140 2984 140 2014 143 2015 140 3149 117 2202 117 1053 Page 126 Name of Material Guide ID No. No. Hydrogen sulfide, liquefied 117 1053 Hydrogen sulphide 117 1053 Hydrogen sulphide, liquefied 117 1053 Hydroquinone 153 2662 Hydroquinone, solid 153 2662 Hydroquinone, solution 153 3435 Hydroxylamine sulfate 154 2865 Hydroxylamine sulphate 154 2865 Hypochlorite solution 154 1791 Hypochlorite solution, with more 154 1791 than 5% available Chlorine Hypochlorites, inorganic, n.o.s. 140 3,3'-lminodipropylamine 153 Infectious substance, affecting 158 animals only Infectious substance, affecting 158 humans Ink, printer's, flammable 129 Insecticide gas, flammable, n.o.s. 115 Insecticide gas, flammable, n.o.s. 115 Insecticide gas, n.o.s. 126 Insecticide gas, poisonous, 119 flammable, n.o.s. Insecticide gas, poisonous, 119 flammable, n.o.s. (Inhalation Hazard Zone A) Insecticide gas, poisonous, 119 flammable, n.o.s. (Inhalation Hazard Zone B) Insecticide gas, poisonous, 119 flammable, n.o.s. (Inhalation Hazard Zone C) Insecticide gas, poisonous, 119 flammable, n.o.s. (Inhalation Hazard Zone D) Insecticide gas, poisonous, 123 n.o.s. Name of Material Guide ID No. No. Insecticide gas, toxic, flammable, 119 3355 n.o.s. Insecticide gas, toxic, flammable, 119 3355 n.o.s. (Inhalation Hazard Zone A) Insecticide gas, toxic, flammable, 119 3355 n.o.s. (Inhalation Hazard Zone B) Insecticide gas, toxic, flammable, 119 3355 n.o.s. (Inhalation Hazard Zone C) Insecticide gas, toxic, flammable, 119 3355 n.o.s. 3212 (Inhalation Hazard Zone D) 2269 2900 2814 1210 1954 3354 1968 3355 3355 3355 3355 3355 1967 Insecticide gas, toxic, n.o.s. 123 1967 Iodine monochloride 157 1792 Iodine penta fluoride 144 2495 2-lodobutane 129 2390 lodomethylpropanes 129 2391 lodopropanes 129 2392 IPDI 156 2290 Iron oxide, spent 135 1376 Iron pentacarbonyl 131 1994 Iron sponge, spent 135 1376 Isobutane 115 1075 Isobutane 115 1969 Isobutane mixture 115 1075 Isobutane mixture 115 1969 Isobutanol 129 1212 Isobutyl acetate 129 1213 Isobutyl acrylate 130P 2527 Isobutyl acrylate, inhibited 130P 2527 Isobutyl acrylate, stabilized 130P 2527 Isobutyl alcohol 129 1212 Isobutyl aldehyde 130 2045 Page 127 Name of Material Guide ID No. No. Name of Material Guide ID No. No. sobutylamine 132 1 T 1 A 1214 sobutyl chloroformate 155 T "7 A ~l L 142. sobutylene 115 IUj j sobutylene 110 1U / j sobutyl formate 129 2393 sobutyl isobutyrate 130 2528 sobutyl isocyanate 155 2486 sobutyl methacrylate 130P 2283 sobutyl methacrylate, inhibited 130P 2283 sobutyl methacrylate, stabilized 130P 2283 sobutyl propionate 129 2394 sobutyraldehyde 130 2045 sobutyric acid 132 2529 sobutyric anhydride 132 2530 sobutyronitrile 131 2284 sobutyryl chloride 132 2395 socyanate solution, flammable, poisonous, n.o.s. 155 2478 socyanate solution, flammable, toxic, n.o.s. 155 2478 cnrvanafo c a 1 1 1 H a n n a i c a n a 1 1 c 3 U L y □ 1 1 □ LC j U 1 U U U 1 1 , [J U 1 3 U 1 1 U U 3 , flammable, n.o.s. 155 3080 socyanate solution, poisonous, n.o.s. 155 2206 socyanate solution, toxic, flammable, n.o.s. 155 3080 socyanate solution, toxic, n.o.s 155 2206 socyanate solutions, n.o.s. 155 2206 socyanate solutions, n.o.s. 155 2478 socyanate solutions, n.o.s, 155 3080 jULydiidicj, iidiiniiduit:, poisonous, n.o.s. 155 2478 socyanates, flammable, toxic, n.o.s. 155 2478 socyanates, n.o.s. 155 2206 socyanates, n.o.s. 155 2478 socyanates, n.o.s. 155 3080 socyanates, poisonous, flammable, n.o.s. 155 3080 socyanates, poisonous, n.o.s. 155 2206 socyanates, toxic, flammable, n.o.s. 155 3080 socyanates, toxic, n.o.s. 155 2206 socyanatobenzotrifluorides 156 2285 soheptenes 128 2287 sohexenes 128 2288 sooctane h no 128 ncn lzoz sooctenes 128 1216 sopentane 128 1265 sopentenes •4 no 128 2.511 sophoronediamine 153 2289 sophorone diisocyanate 156 2290 soprene, inhibited h inn 130P lzlo soprene, stabilized 130P 1218 sopropanol 129 1219 sopropenyl acetate 129P 2403 sopropenylbenzene 128 2303 sopropyl acetate 129 1220 sopropyl acid phosphate 153 1793 sopropyl alcohol 129 1219 sopropylamine 132 1221 sopropylbenzene 130 1918 sopropyl butyrate 129 2405 sopropyl chloroacetate 155 2947 sopropyl chloroformate 155 2407 sopropyl 2-chloropropionate 129 2934 sopropyl isobutyrate 127 2406 sopropyl isocyanate 155 2483 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Isopropyl nitrate 130 1222 Isopropyl propionate 129 2409 Isosorbide dinitrate mixture 133 2907 lsosorbide-5-mononitrate 133 3251 Kerosene -4 00 128 1 1 1 3 1223 Ketones, liquid, n.o.s. 127 1 1 1 A 1224 Krypton 121 1056 Krypton, compressed 121 1056 Krypton, refrigerated liquid (cryogenic liquid) 120 1970 L (Lewisite) 153 2810 Lead acetate 151 1616 Lead arsenates 151 1617 Lead arsenites 151 1 CIO 1618 Lead compound, soluble, n.o.s. 151 2291 Lead cyanide 151 1620 Lead dioxide 141 1 "7 1 18/2 Lead nitrate 141 1469 Lead perchlorate 141 1470 Lead perchlorate, solid 141 1470 Lead perchlorate, solution 141 1470 Lead perchlorate, solution 141 3408 Lead phosphite, dibasic 133 2989 Lead sulfate, with more than 3% free acid 154 1794 Lead sulphate, with more than 3% free acid 154 1794 Lewisite 153 2810 Life-saving appliances, n ot s elf- inflating 171 3072 Life-saving appliances, self- inflating 171 2990 Lighter refills (cigarettes) 115 1057 (flammable gas) Lighters (cigarettes) (flammable gas) 115 1057 Lighters forcigars, cigarettes (flammable liquid) 128 1226 Liquefied gas (nonflammable) 120 1058 Liquefied gas, flammable, n.o.s. 115 1954 Liquefied gas, flammable, n.o.s. 115 3161 Liquefied gas, flammable, UU 1 jUI IUU J , II. U.J. 119 1953 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation l-l a 7 a rH 7 a n o A \ n □ L CI 1 U Z-U 1 1 C H 1 119 1953 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation H a 7 a rrl 7nnp R) 1 1 L a 1 U £_ U 1 1 C U ) 119 1953 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation H a 7 a rrl 7 nn p C ) 119 1953 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone D) 119 1953 Liquefied gas, flammable, toxic, n o s 119 1953 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard 1— U 1 1 C t\] 119 1953 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard 7nnp R ) L. U 1 1 C U J 119 1953 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone C ) 119 1953 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone D) 119 1953 Liquefied gas, n.o.s. 126 1956 Liquefied gas, n.o.s. 126 3163 Liquefied gas, oxidizing, n.o.s. 122 3157 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Liquefied gas, poisonous, 123 3308 corrosive, n.o.s. Liquefied gas, poisonous, 123 3308 corrosive, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, 123 3308 corrosive, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, 123 3308 corrosive, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, 123 3308 corrosive, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, poisonous, 119 3309 flammable, corrosive, n.o.s. Liquefied gas, poisonous, 119 3309 flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, 119 3309 flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, 119 3309 flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, 119 3309 flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, poisonous, 119 3160 flammable, n.o.s. Liquefied gas, poisonous, 119 3160 flammable, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, 119 3160 flammable, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, 119 3160 flammable, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, poisonous, n.o.s Liquefied gas, poisonous, n.o.s Liquefied gas, poisonous, n.o.s (Inhalation Hazard Zone A) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, poisonous, oxidizing, n.o.s. 119 3160 123 1955 123 3162 123 1955 123 3162 123 1955 123 3162 123 1955 123 3162 123 1955 123 3162 124 3310 124 3310 124 3310 124 3310 124 3310 124 3307 Page 130 Name of Material Guide ID No. No. Liquefied gas, poisonous, 124 oxidizing, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, poisonous, 124 oxidizing, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, poisonous, 124 oxidizing, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, poisonous, 124 oxidizing, n.o.s. (Inhalation Hazard Zone D) Liquefied gas, toxic, corrosive, 123 n.o.s. Liquefied gas, toxic, corrosive, 123 n.o.s. (Inhalation Hazard Zone A) Liquefied gas, toxic, corrosive, 123 n.o.s. (Inhalation Hazard Zone B) Liquefied gas, toxic, corrosive, 123 n.o.s. (Inhalation Hazard Zone C) Liquefied gas, toxic, corrosive, 123 n.o.s. (Inhalation Hazard Zone D) Liquefied gas, toxic, flammable, 119 corrosive, n.o.s. Liquefied gas, toxic, flammable, 119 corrosive, n.o.s. (Inhalation Hazard Zone A) Liquefied gas, toxic, flammable, 119 corrosive, n.o.s. (Inhalation Hazard Zone B) Liquefied gas, toxic, flammable, 119 corrosive, n.o.s. (Inhalation Hazard Zone C) Liquefied gas, toxic, flammable, 119 corrosive, n.o.s. (Inhalation Hazard Zone D) Name of Material Guide ID No. No. 3308 3307 Liquefied gas, toxic, flammable, 119 3160 n.o.s. Liquefied gas, toxic, flammable, 119 3160 3307 n.o.s. (Inhalation Hazard Zone A) Liquefied gas, toxic, flammable, 119 3160 3307 n.o.s. (Inhalation Hazard ZoneB) Liquefied gas, toxic, flammable, 119 3160 3307 n.o.s. (Inhalation Hazard ZoneC) Liquefied gas, toxic, flammable, 119 3160 3308 n.o.s. (Inhalation Hazard Zone D) 3308 Liquefied gas, toxic, n.o.s. 123 1955 Liquefied gas, toxic, n.o.s. 123 3162 Liquefied gas, toxic, n.o.s. 123 1955 (Inhalation Hazard Zone A) Liquefied gas, toxic, n.o.s. 123 3162 (Inhalation Hazard ZoneA) Liquefied gas, toxic, n.o.s. 123 1955 (Inhalation Hazard Zone B) 3308 Liquefied gas, toxic, n.o.s. 123 3162 (Inhalation Hazard Zone B) Liquefied gas, toxic, n.o.s. 123 1955 3309 (Inhalation Hazard Zone C) Liquefied gas, toxic, n.o.s. 123 3162 3309 (Inhalation Hazard Zone C) Liquefied gas, toxic, n.o.s. 123 1955 (Inhalation Hazard Zone D) 3309 Liquefied gas, toxic, n.o.s. 123 3162 (Inhalation Hazard Zone D) Liquefied gas, toxic, oxidizing, 124 3310 3309 corrosive, n.o.s. Liquefied gas, toxic, oxidizing, 124 3310 corrosive, n.o.s. (Inhalation 3309 Hazard ZoneA) Page 131 Name of Material Guide NO. ID NO. Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) 124 3310 Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) 124 3310 Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) 124 3310 Liquefied gas, toxic, oxidizing, n.o.s. 124 3307 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone A) 124 3307 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone B) 124 3307 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone C) 124 3307 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone D) 124 3307 Liquefied gases, non-flammable, charged with Nitrogen, C arbon dioxide or Air 120 1058 Liquefied naturalgas (cryogenic liquid) 115 1972 Liquefied petroleum gas 115 1U / j Lithium 138 1415 Lithium alkyls 135 2445 Lithium alkyls, liquid 135 1 A A C Z44D Lithium alkyls, solid 135 3433 Lithium aluminum hydride 138 141U Lithium aluminum hydride, culclcdl 138 1411 Lithium amide 139 1412 Lithium batteries 138 3090 Name of Material Guide ID No. No. Lithium batteries, liquid orsolid 138 cathode Lithium batteries contained in 138 equipment Lithium batteries packed with 138 equipment Lithium borohydride 138 Lithium ferrosilicon 139 Lithium hydride 138 Lithium hydride, fused solid 138 Lithium hydroxide 154 Lithium hydroxide, monohydrate 154 Lithium hydroxide, solid 154 Lithium hydroxide, solution 154 Lithium hypochlorite, dry 140 Lithium hypochlorite mixture 140 Lithium hypochlorite mixtures, 140 dry Lithium nitrate 140 Lithium nitride 138 Lithium peroxide 143 Lithium silicon 138 LNG (cryogenic liquid) 115 London purple 151 LPG 115 Magnesium 138 Magnesium, in pellets, turnings 138 orribbons Magnesium alkyls 135 Magnesium alloys, with more 138 than 50% Magnesium, in pellets, turnings orribbons Magnesium alloys powder 138 Magnesium aluminum phosphide 139 Magnesium arsenate 151 3090 3091 3091 1413 2830 1414 2805 2680 2680 2680 2679 1471 1471 1471 2722 2806 1472 1417 1972 1621 1075 1869 1869 3053 1869 1418 1419 1622 Page 132 Name of Material Guide ID Name of Material Guide ID No. No. No. No. Magnesium bromate 140 1473 Matches, "strike anywhere" 133 1331 Mannociiim r h 1 a fp ridyncbiuiii l i i i u i a Lc 2723 M a tr h o c "\/oct"a" rldlLllcj, VV a A vcbld it* IOO 1945 l v l d y II cb IU III L 11 10 1 luc d 11 U -i /in 1459 l v l u 1556 Chlorate mixture Medical waste, n.o.s. 158 3291 MannpcMiim r h InriHp and I'IOUIICjIUIII LIIIUIIUC □ 1 1 u 140 l*tV 1459 Medicine, liquid, flammable, 131 3248 C hlorate mixture, solid poisonous, n.o.s. MannQciiirYi r h 1 a r i rl a anrl l v l a y II cb IU III LIIIUIIUC dllu -i /in 3407 Medicine, liquid, flammable, 131 3248 Chlorate mixture, solution t"n y i r n n c LU A 1 L , 1 1 . U . 3 . Magnesium diamide 135 2004 Medicine, liquid, poisonous, 151 1851 Magnesium diphenyl 135 2005 n.o.s. Magnesium fluorosilicate 151 2853 M edicine, liquid, toxic, n.o.s. 151 1851 Mannociiim nraniiloc r a a fori r\ a LJ 1 1 c b 1 U 1 1 1 y 1 d 1 1 U Icb , LUd Lcll IOO loo 2950 Morlirino cnliH nAicAriAiic l v l C U 1 L 1 1 1 C , b U II U , [J U 1 b U 1 1 u u b , lo I 3249 l v l d y II cb IU 111 llyUHUc loo 2010 n.o.s. Magnesium nitrate 140 1474 M edicine, solid, toxic, n.o.s. 151 3249 Magnesium perchlorate 140 1475 Medicines, corrosive, liquid, n.o.s. 154 1760 Magnesium peroxide 140 1476 M edicines, corrosive, solid, 154 1759 Magnesium phosphide 139 2011 n n c 1 1 . U .3 . Maonp^ium nowdpr IIUUMLjIUIII k/\J (J U L 1 138 1418 Medicines, flammable, liquid, 128 1993 Magnesium silicide 138 2624 n.o.s. M a n n o c ii i m cilir Afln Arirlo i v i d y 1 1 ci iu 1 1 1 biiiLUiiuuiiuc ID I 2853 Medicines, flammable, solid, 133 1325 Magnetized material 171 2807 n.o.s. Maleic acid 156 2215 Medicines, oxidizing 140 1479 bUUbLdllLcb, bOMU, ll.O.S. Maleic anhydride 156 2215 Mercaptan mixture, liquid, 130 3336 Maleic anhydride, molten 156 2215 1 1 G 1 1 1 1 1 1 CI U 1 C , 1 1 . U . b . M alnnnnitrilp l"l a 1 u 1 1 u 1 1 1 LI lie IOO 2647 Mercaptan mixture, liquid, H OH lol 1228 Maneb 135 2210 flammahlp nnknnniK n n <; Maneb, stabilized HOC loo 2968 Mercaptan mixture, liquid, 131 1228 flammable, toxic, n.o.s. Maneb preparation, stabilized 135 2968 M erranta n mixture liouid I'lCll-LIIJlLIII 1 II 1 ALU 1 Uf 1 r U U 1 U , 131 3071 Maneb preparation, with notless than 60% Maneb 135 2210 poisonous, flammable, n.o.s. Manganese nitrate 140 2724 Mercaptan mixture, liquid, toxic, 131 3071 flammahlo n a c 1 1 d 1 1 1 1 1 1 d u lc , ll.u.b. Manganese resinate 133 1330 Mercaptan mixtures, liquid, 131 1228 Matches, fusee 133 2254 n.o.s. Matches, safety 133 1944 Page 133 Name of Material Guide ID No. No. Name of Material Guide ID No. No. M rr a nfa n miYhiroc liniiirl l v ICILa|Jlall 1 II 1 A LU 1 , 1 1 1_| U 1 U , n.o.s. IO 1 JU / 1 Mercaptans, liquid, flammable, n.o.s. 130 3336 Mercaptans, liquid, flammable, poisonous, n.o.s. 131 1228 Mercaptans, liquid, flammable, toxic, n.o.s. 131 1228 Mercaptans, liquid, n.o.s. 131 3071 Mercaptans, liquid, poisonous, flammable, n.o.s. 131 3071 Mercaptans, liquid, toxic, flammable, n.o.s. 131 3071 Mercuric arsenate 151 1623 Mercuric bromide 1 C D A Mercuric chloride 154 1624 Mercuric cyanide •i EZA i a i a lb:Jb Mercuric nitrate H /H 141 Ibz 3 Mercuric oxycyanide 151 1642 Mercuric potassium cyanide 157 Ibzb Mercuric sulfate 151 1645 Mercuric sulphate 151 1645 Mercurous bromide 104 1 C 3 A M ercurous nitrate 141 Mercury 172 2809 Mercury acetate 151 1629 Mercury ammonium chloride 151 1630 Mercury based pesticide, liquid, flammable, poisonous 131 2778 Mercury based pesticide, liquid, flammable, toxic 131 2778 Mercury based pesticide, liquid, poisonous 151 3012 Mercury based pesticide, liquid, 131 3011 poisonous, flammable Mercury based pesticide, liquid, toxic 151 3012 Mercury based pesticide, liquid, toxic, flammable 131 3011 Mercury based pesticide, solid, poisonous 151 2777 Mercury based pesticide, solid, toxic 151 2777 Mercury benzoate 154 lbil Mercury bromides 154 lb 34 Mercury compound, liquid, n.o.s 101 -) n -) a Mercury compound, solid, n.o.s. 151 M ercury cyanide 154 lb ib Mercury gluconate 151 1 CTT Ibj/ M ercury iodide 151 lb jo M ercury metal 172 2o09 M ercury nucleate 151 ib jy Mercury oleate 151 1640 Mercury oxide 151 1641 Mercury oxycyanide, desensitized 151 1642 Mercury potassium iodide 151 1 C A 3 lb4j Mercury salicylate 151 1 C A A lb44 Mercury sulfate 151 1 C A C lb45 Mercury sulphate 151 1 C A C lb45 Mercury thiocyanate 151 1646 Mesityl oxide 129 1229 Metal alkyl, solution, n.o.s. 135 9195 Metal alkyl halides, n.o.s. 138 3049 Metal alkyl halides, water- reactive, n.o.s. 138 3049 Metal alkyl hydrides, n.o.s. 138 3050 Metal alkyl hydrides, water- reactive, n.o.s. 138 3050 Metal alkyls, n.o.s. 135 2003 Page 134 Name of Material Guide ID No. NO. Metal a Iky Is , water-reactive, 135 2003 n .o.s . Mohal ar\/l halirloc n n c 1*1 tr Lei i a i y i 1 1 a \\ u c b ( r i . u . o . IOO 3049 Metal aryl halides, water- 138 3049 reactive, n.o.s. Mohal an/I h\/rlrirloc n n c n c ia i □ i y i nyui iucj, i i . u . -> . IOO IOO 3050 Metal aryl hydrides, water- 138 3050 reactive, n.o.s. M fa 1 a n/l c n n c i*i c lci i diyib, ii.u.j IOO 2003 Metal aryls, water-reactive, 135 2003 n.o.s. Metal carbonyls, liquid, n.o.s. 151 3281 i v ietai caruonyis, n.o.s. 1£-| jZoI Metal carbonyls, solid, n.o.s. 151 3466 Metal catalyst, dry 135 2881 Metal catalyst, wetted 170 1378 Metaldehyde 133 1332 Metal hydrides, flammable, n.o.s. 170 3182 Metal hydrides, water-reactive, 138 1409 n.o.s. Metallic substance, water- 138 3208 reactive, n.o.s. Metallic substance, water- 138 3209 reactive, self-heating, n.o.s. Metal powder, flammable, n.o.s 170 3089 Metal powder, self-heating, n.o.s. 135 3189 Metal salts of organic 133 3181 compounds, flammable, n.o.s. Methacrylaldehyde 131P 2396 Methacrylaldehyde, inhibited 131P 2396 Methacrylaldehyde, stabilized 131P 2396 Methacrylic acid, inhibited 153P 2531 Methacrylic acid, stabilized 153P 2531 Methacrylonitrile, inhibited 131P 3079 Methacrylonitrile, stabilized 131P 3079 Name of Material Guide ID No. NO. Methallyl alcohol 129 ZD14 Methane 115 1971 Methane, compressed 115 iy/i Methane, refrigerated liquid (cryogenic liquid) 115 1972 Methane and Hydrogen mixture, compressed 115 2034 Methanesulfonyl chloride 156 3246 Me thanesulphonyl chloride 156 3246 Methanol 131 1230 Methoxymethyl isocyanate 155 2605 4-Methoxy-4-methyl- pentan-2-one 128 2293 l-Methoxy-2-propanol 129 juyz Methyl acetate 129 1 -) D 1 ii ii Methylacetylene and Propadiene mixture, stabilized 116P 1060 Methyl acrylate, inhibited 129P iyiy Methyl acrylate, stabilized 129P i ni n iyiy Methylal 127 Methyl alcohol 131 11 5\J M ethylallyl chloride 130P i r c; a Methylamine, anhydrous 118 lUbl Methylamine, aqueous solution 132 H5j Methylamyl acetate 130 1 TDD 1155 Methylamyl alcohol 129 zU j 5 Methyl amyl ketone 127 1 1 1 A 111U N-Methylaniline 153 11QA Methyl benzoate 152 ly5o alpha-Methylbenzyl alcohol 153 lv5 1 alpha-Methylbenzyl alcohol, liquid 153 2937 alpha-Methylbenzyl alcohol, 153 3438 solid Name of Material Guide ID No. NO. M ohh \/l h o n 7 \/l a lr a h a 1 ( a 1 n h a \ i*icLiiyiuciiz.yi a i l u i ! u i \ a i [J i ! d / 1 JO Lj J ! Methyl bromide 123 1062 Methyl bromide and Chloropicrin mixture 123 1581 Methyl bromide and Ethylene dihromide mixture linuid U 1 U 1 U 1 II IU L 1 1 1 1 A LU 1 L | 1 1 u U 1 u 151 1647 Mpthvl hrnmnarptatp 1 1 1 C LI 1 y 1 U 1 U 1 II U U L U LU 155 2643 7-M ethvlhutanal L. I'lCLIIylUULullul 129 3371 3-Mphhvlhiihan-?-nnp ~> l"l C LI 1 y 1 u LRO 1 1 L. UIIC 127 2397 ?- M phh vl - 1 -hnhpnp L 1*1 C LI 1 y 1 1 U U LC 1 1 c 128 2459 9-Mphhvl-/"-hnhpnp L 1*1 C LI 1 y 1 L UU LC 1 1 C 128 2460 3-Mpthvl-l -hutpnp -J 1 1 \- L 1 1 y 1 ± UUL^I 1 c 128 2561 N-MpthvlhutvlaiYiinp 132 2945 M p hh v 1 hp rt- h i j 1 p hh p r 1*1 C LI 1 ¥ 1 LC IL UULVILTLIILTI 127 2398 M Pth vl hutvratp 1 1 *w L 1 I y 1 U LKy 1 U 129 1237 Methyl chloride 115 1063 Methyl chloride and Chloropicrin mixture 119 1582 Methyl chloride and Methylene chloride mixture V.IIIL/IIULT 1 1 1 1 A LU 1 C 115 1912 Mohhv/I r h 1 a fa a r oha ho 1*1 C LI 1 y 1 LMIUIUdLcldLc too L Lj J M ohh\/l r h 1 a r"Af a fin a ho 1*1 C LI 1 y 1 LIIIUIUIUIIIIdLc ±L JO Methyl chloromethyl ether 131 1239 Mohh\/l 9 - r h 1 a ta n ta n i a n a ho 1*1 C LI 1 y 1 Z.LIIIUI U|JI Lf|JIUIICl Ltr Mpthvlrhloro^ilanp 1*1 LTLIIV IL.MIL/1 U J 1 1 U 1 1 L* 119 2534 M pfh vl r va n idp I I v L_ 1 ! V 1 L y U 1! 1 U L 127 1648 M p th vl eve In hpxanp i t i LTLiiy i l y l i u 1 1 V- a u ii c 128 2296 Mpthvlrvrlohpxanoh 1*1 CLIIylLyLIUIICALIIIUlJ 129 2617 Methylcyclohexanone 128 2297 Methylcyclopentane 128 2298 Mohhvl H i r h 1 a ta a roha ho 1*1 C LI 1 y 1 U IL 1 1 1 U 1 U a LC La LC 199 M o hh \/ 1 rl i r h 1 a ta a rc i n o rlcLliyiUILIIIUIUdlblllC 1M 19^ 1 J J U l v l c Lll y 1 U 1 C II 1 1 b II d II C 109 M ethylene chloride 160 1593 Name of Material Guide ID kin INO. Methylene chloride and Methyl chloride mixture 115 1912 i v i etnyi etnyi etner 110 T 0.30, Methyl ethyl ketone \zl 2-M ethyl- 5-ethylpyrid ine loo 1 3 OA m etnyi riuonoe 110 T/l £ /I Z4 34 M ethyl formate 1 ") A 7 1Z4 j 2-Methylfuran l^o Z3U1 2-Methyl-2-hepthanethiol 131 3023 5-Methylhexan-2-one 127 2302 Methylhydrazine 131 1244 M ethyl iodide 1D1 ZD44 Methyl isobutyl carbinol 129 2053 Methyl isobutyl ketone 127 1245 Methyl isocyanate 155 2480 Methyl isopropenyl ketone, innin it"A rl inn i u lie q 127P 1246 McLliyi lb U pi upcll y 1 KcLUIIc, stabilized 197P 1Z4D Methyl isothiocyanate 131 2477 Methyl isovalerate 130 2400 Methyl magnesium bromide in Ethyl ether 135 1928 Methyl mercaptan 117 1064 Methyl methacrylate monomer, inhibited 129P 1247 Methyl methacrylate monomer, stabilized 129P 1247 4-Methylmorpholine 132 2535 N-Methylmorpholine 132 2535 Methylmorpholine 132 2535 Methyl nitrite 116 2455 Methyl orthosilicate 155 2606 Methyl parathion, liquid 152 3018 Page 136 Name of Material Guide ID No. No. Methyl parath ion, solid 152 2783 M ethylpentadiene 128 2461 ?-Mpthvlnpntan-?-nl L l"l C LI 1 y 1 U C 1 1 LCI 1 1 L Ul -|OQ iJUU Mpt"hvlnhpnvlrlirhlnro^ilanp ricuiyiuiiciiyiuiLiiiuiu.jiiciiic 156 2437 Mpfhvl nhn^nhnnir Hirhlnrirlp rlCUIyl UIIUjUIIUIIIL. UILIIIUIIUC 1^7 9206 Methyl phosphorous dichloride 135 2845 1-Methylpiperidine 132 2399 Methyl propionate 129 1248 M ethyl propyl ether 127 2612 Methyl propyl ketone 127 1249 Methyltetrahydrofuran 127 2536 rlCLIIyl Llll.IIIUIUCIL.CLa LC 1 JU 2533 Methyltrichlorosilane 155 1250 alpha- M ethylvalera Idehyde 130 2367 Mpfhvl \/a Ip IHp h vrl p /alnhM 2367 i*i c li i y i vinyl i\c lu 1 1 c 131P 1251 1 L J 1 Mpfhvl uinvl kpfonp <;t"ahili7prl ii c u 1 y i viiiyi i\ c l.u 1 1 c , jiquiiilcu 131P 1251 M.I. B.C. 129 2053 M nlvhrl pn ii in npntarhlnrirlp I'l UJj UUCIIUIII UCIILULIIIUI IUC 156 2508 Mnnnpfhanolarninp 1*1 UIIUCUIUIIUIUIIIMIC 153 2491 M ononitrotoluidines 153 2660 Monopropylamine 132 1277 M nrnhnlinp 132 2054 Mo tor fuel anti-knock mixture 131 1649 M otor ^nirit 128 1203 Muriatic acid 157 1789 Muck Yvlpnp 1*1 U j K A y 1 C 1 1 c 14Q 2956 L J J U M ii cha rr) I'l U J LCI 1 U loo 2810 M ustard Lewisite 153 2810 N aphthalene, crude 133 1334 N aphthalene, molten 133 2304 M a n h hh a 1 a n a ra f i n o rl \\ a |J 1 1 LI 1 a 1 c 1 1 c , 1 c 1 1 1 1 c U ■loo loo alpha-Naphthylamine 153 2077 Name of Material Suide ID Kin NO. Kin NO. Naphthylamine (alpha) ico loo l\) 1 1 beta-N aphthylamine H CO loo i c c n beta-N aphthylamine, solid A CO loo i c c n ItOU beta-N aphthylamine, solution * CO 153 3411 Naphthylamine (beta) ico loo i k£ n Naphthylamine (beta), solid H CO loo i c c n ItOU Naphthylamine (beta), solution A CO loo O A 1 1 3411 N aphthylthiourea 1CO loo 1 1 N aphthylurea A CO loo 1 C C 1 N atu ra 1 gas , compressed no 1 Q7 1 Natural gas, refrigerated liquid (cryogenic liquid) 115 1972 Neohexane 128 1208 Neon 121 1065 Neon, compressed 1^1 1 ClCC lUtO Neon, refrigerated liquid (cryogenic liquid) 120 1913 Nickel carbonyl 131 1259 N ickel catalyst, dry HOC loo ")QQ1 zool Nickel cyanide 151 1 C C 3 Nickel nitrate 140 2725 Nickel nitrite 140 2726 Nicotine 151 1654 Nicotine compound, liquid, n.o.s. 151 3144 Nicotine compound, solid, n.o.s 151 103 3 Nicotine hydrochloride 101 IDjD Nicotine nyarocnionae, nquia 1CH 101 1 c c c ID JO Nicotine hydrochloride, solid 101 lOjO Nicotine hydrochloride, solid 101 3/1 A A 3444 Nicotine hydrochloride, solution 1 C-1 101 IOjO Nicotine preparation, liquid, 151 3144 n.o.s, Name of Material Guide NO. ID NO. Nicotine preparation, solid, n .o.s . 151 1655 Nicotine salicylate 151 1 C C ~l lob / Nicotine sulfate, solid 151 1658 Nicotine sulfate, solid 151 3445 Nicotine sulfate, solution 151 1658 Nicotine sulphate, solid 151 1658 Nicotine sulphate, solid 151 3445 Nicotine sulphate, solution 151 1 ceo Nicotine tartrate 151 1659 Nitrates, inorganic, aqueous solution, n.o.s. 140 3218 Nitrates, inorganic, n.o.s. 140 1 Al 1 14/ / N itrating acid mixture 157 1/30 Nitrating acid mixture, spent 157 1826 N itric acid, fuming 157 2032 Nitric acid, otherthan red fuming 157 Nitric acid, red fuming 157 2032 Nitric oxide 124 1660 Nitric oxide, compressed 124 1660 Nitric oxide and Dinitrogen tetroxide mixture 124 1975 Nitric oxide and Nitrogen dioxide mixture 124 1975 Nitric oxide and Nitrogen tetroxide mixture 124 1975 Nitriles, flammable, poisonous, n.o.s. 131 3273 Nitriles, flammable, toxic, n.o.s. 131 3273 Nitriles, poisonous, flammable, n.o.s. 131 3275 Nitriles, poisonous, liquid, n.o.s. 151 3276 Nitriles, poisonous, n.o.s. 151 3276 Nitriles, poisonous, solid, n.o.s. 151 3439 Nitriles, toxic, flammable, n.o.s. 131 3275 Name of Material Guide ID No. No. Nitriles, toxic, liquid, n.o.s. 151 3276 Nitriles, toxic, n.o.s. 151 3276 Nitriles, toxic, solid, n.o.s. 151 3439 Nitrites, inorganic, aqueous solution, n.o.s. 140 3219 Nitrites, inorganic, n.o.s. 140 2627 Nitroanilines 153 1661 Nitroanisoles 152 2730 Nitroanisoles, liquid 152 2730 Nitroanisoles, solid 152 2730 Nitroanisoles, solid 152 3458 Nitrobenzene 152 1662 Nitrobenzenesulfonic acid 153 2305 Nitrobenzenesulphonic acid 153 2305 Nitrobenzotrifluorides 152 2306 Nitrobenzotrifluorides, liquid 152 2306 Nitrobenzotrifluorides, solid 152 3431 Nitrobromobenzenes 152 2732 Nitrobromobenzenes, liquid 152 2732 Nitrobromobenzenes, solid 152 2732 Nitrobromobenzenes, solid 152 3459 Nitrocellulose, solution, flammable 127 2059 Nitrocellulose, solution, in a flammable liquid 127 2059 Nitrocellulose membrane filters 133 3270 Nitrocellulose mixture, without plasticizer, withoutpigment 133 2557 Nitrocellulose mixture, without plasticizer, with pigment 133 2557 N itTnrpI In Ins p m i yhi rp wifh IM I LI ULCIIU IU J C IIIIALUIC, VVILII plasticizer, withoutpigment 1 oo L J J 1 Nitrocellulose mixture, with plasticizer, with pigment 133 2557 N itrocellulose with alcohol 113 2556 Page 138 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Nitrocellulose with notless than 25% alcohol 113 2556 Nitrocellulose with plasticizing substance 133 2557 Nitrocellulose with water, not less than 25% water 113 2555 3 - N i tro -4-chlorobenzotrifluoride 152 2307 Nitrocresols 153 2446 Nitrocresols, liquid 153 3434 Nitrocresols, solid H CO loo 1 A AC Z44b Nitroethane 129 2842 Nitrogen 121 1066 Nitrogen, compressed 121 1066 Nitrogen, refrigerated liquid (cryogenic liquid) 120 1977 Nitrogen and Rare gases mixture 121 1981 Nitrogen and Rare gases mixture, compressed 121 1981 Nitrogen dioxide 124 1067 Nitrogen dioxide, liquefied 124 1067 Nitrogen dioxide and Nitric oxide 124 mixture 1975 Nitrogen tetroxide and Nitric oxide mixture 124 1975 Nitrogen trifluoride 122 2451 Nitrogen trifluoride, compressed 122 2451 Nitrogen trioxide 124 2421 Nitroglycerin, solution in alcohol, with more than 1% but not more than 5% Nitroglycerin 127 3064 Nitroglycerin, solution in 127 1204 alcohol, with notmore than 1% Nitroglycerin Nitroglycerin mixture, desensitized, liquid, flammable n.o.s., with not more than 30% Nitroglycerin 113 3343 Nitroglycerin mixture, desensitized, liquid, n.o.s., with notmore than 30% Nitroglycerin 113 3357 Nitroglycerin mixture, desensitized, solid, n.o.s., with more than 2% butnotmore than 10% Nitroglycerin 113 3319 Nitroglycerin mixture with more than 2% butnotmore than 10% Nitroglycerin, desensitized 113 3319 Nitroguanidine (Picrite), wetted with not less than 20% water 113 1336 Nitroguanidine, wetted with not less than 20% water 113 1336 Nitrohydrochloric acid 157 1/98 Nitromethane 129 1261 Nitronaphthalene 133 2538 Nitrophenols 153 1663 4- N itrop hen ylhydraz in e, with not 113 less than 30% water 3376 Nitropropanes 129 2608 p- N itrosod imethyla n iline 135 1369 Nitrostarch, wetted with notless than 20% water 113 1337 Nitrostarch, wetted with notless than 30% solvent 113 1337 Nitrosyl chloride 125 1069 Nitrosylsulfuric acid 157 2308 Nitrosylsulfuric acid, liquid 157 2308 Nitrosylsulfuric acid, solid 157 2308 Nitrosylsulfuric acid, solid 157 3456 Nitrosylsulphuric acid 157 2308 Page 139 Name of Material Guide ID Name of Material Guide ID No. NO. No. No. N itrosyls u Iphuric acid, liquid 157 2308 Oil gas, compressed 119 1071 N itrosyls ulph uric acid, solid 157 2308 Organic peroxide type B, liquid 146 3101 N i tros yls u Ip h u ric acid, solid 157 3456 Organic peroxide type B, liquid, 148 3111 N itrotoluenes 152 1664 temperature controlled Nitrotoluenes, liquid 152 1664 Organic peroxide type B, solid 146 3102 N itrotoluenes, solid 152 1664 Organic peroxide type B, solid, 148 3112 temperature controlled Nitrotoluenes, solid 152 3446 Organic peroxide type C, liquid 146 3103 Nitrotoluidines (mono) 153 2660 148 3113 Organic peroxide type C, liquid, Nitrous oxide 122 1070 temperature controlled Nitrous oxide, compressed 122 1070 Organic peroxide type C, solid 146 3104 Nitrous oxide, refrigerated liquid 122 2201 Organic peroxide type C, solid, 148 3114 Nitrous oxide and Carbon 126 1015 temperature controlled dioxide mixture Organic peroxide type D, liquid 145 3105 N itroxylenes 152 1665 Organic peroxide type D, liquid, 148 3115 Nitroxylenes, liquid 152 1665 temperature controlled Nitroxylenes, solid 152 1665 Organic peroxide type D, solid 145 3106 N ilrnxvlpnp^ ^olirl 152 3447 Organic peroxide type D, solid, 148 3116 Nonanes 128 1920 temperature controlled N onyltric hloros ila ne 156 1799 Organic peroxide type E, liquid 145 3107 2,5-N orbornadiene h ion 128P 2251 Organic peroxide type E, liquid, 148 3117 temperature controlled 2,5-N orbornadiene, inhibited 128P 2251 Organic peroxide type E, solid 145 3108 2,5-Norbornadiene, stabilized 128P 2251 Organic peroxide type E, solid, 148 3118 Octadecyltrichlorosilane 156 1800 temperature controlled Octadiene 128P 2309 Organic peroxide type F, liquid 145 3109 Octafluorobut-2-ene 126 2422 Organic peroxide type F, liquid, 148 3119 Octafluorocyclobutane 126 1976 temperature controlled Octafluoropropane 126 2424 Organic peroxide type F, solid 145 3110 Octanes 128 1262 Ornanir nprnxirlp fvnp F ^nlirl 148 3120 Octyl aldehydes 129 1191 temperature controlled tert-Octyl mercaptan 131 3023 Organic phosphate compound mixed with compressed gas 123 1955 Octyltrichlorosilane 156 1801 Omanir nhncnhafo mivorl uwifh u [ y d 1 1 1 l [J 1 1 u j [J 1 1 d l.c iiiiacu vviui compressed gas 1 Q R R Oil, petroleum 128 1270 Oil gas 119 1071 Name of Material Guide ID Name of Material Guide ID No. No. No. No. Organic phosphorus compound 123 1955 Organometallic compound, 138 3207 tniyprl wil"h rnm n rpc; c; pH nac; water-reactive, flammable, n.o.s. Organic pigments, self-heating 135 3313 Organometallic compound 138 3207 Organoarsenic compound, liquid, n.o.s. 151 3280 dispersion, water-reactive, flammable, n.o.s. Organometallic compound 138 3207 Organoarsenic compound, n.o.s. 151 3280 solution, water-reactive, Organoarsenic compound, 151 3465 flammable, n.o.s. solid, n.o.s. Organometallic substance, 135 3392 Organochlorine pesticide, liquid, 131 2762 liquid, pyrophoric flammable, poisonous Organometallic substance, 135 3394 Organochlorine pesticide, liquid, 131 2762 liquid, pyrophoric, flammable, toxic water-reactive Organochlorine pesticide, liquid, 151 2996 Organometallic substance, 135 3398 poisonous liquid, water-reactive rnanorhlorinp nestiridp liouid 131 2995 Organometallic substance, 138 3399 poisonous, flammable liquid, water-reactive, Organochlorine pesticide, liquid, 151 2996 flammable toxic Organometallic substance, 135 3391 Organochlorine pesticide, liquid, 131 2995 solid, pyrophoric toxic, flammable Organometallic substance, 135 3393 Organochlorine pesticide, solid, 151 2761 solid, pyrophoric, poisonous WaLc ileal ii vc Organochlorine pesticide, solid, 151 2761 Organometallic substance, 138 3400 toxic solid, self-heating Organometallic compound, 151 3282 Organometallic substance, 135 3395 poisonous, liquid, n.o.s. solid, water-reactive Organometallic compound, 151 3282 Organometallic substance, 138 3396 |J U 1 b U 1 1 U U j> , II. U.J. solid, water-reactive, D rn a n n tnpfa llir rnmnnnnH WIUGIIUIIICLGIML LUIMUUUIIU, ■j i 3467 flammable poisonous, solid, n.o.s. Organometallic substance, 138 3397 Organometallic compound, solid water-reactive, flammable, n.o.s 138 3372 solid, water-reactive, cp|f.hpa|-jnrj jlm i ico Liny Organometallic compound, toxic, liquid, n.o.s. 151 3282 Drnannnhn^nhnrnc; mm nnn n d cy i y uiiuuiiu juiiui u j luiiiuuliiiu, poisonous, flammable, n.o.s 131 3279 Organometallic compound, toxic, n.o.s. 151 3282 Organophosphorus compound, poisonous, liquid, n.o.s. 151 3278 Organometallic compound, 151 3467 Organophosphorus compound, 151 3278 toxic, solid, n.o.s. poisonous, n.o.s. Name of Material Guide ID No. No. Name of Material Guide ID No. NO. DrnannHn np^Hrirlp linnirl foxir \J 1 U U 1 I U L 1 1 1 UCjULIUC, IIU U 1 U , LU A 1 V. 153 JUZU Organotin pesticide, liquid, 131 3019 toxic, flammable Organotin pesticide, solid, 153 2786 poisonous Organotin pesticide, solid, toxic 153 L I 00 Osmium ("Ptrnxidp W J 1 1 1 1 U 1 1 1 LC LI UAIUC 154 1/171 24 11 Otherregulated substances, 171 3082 lin ii iH n n c; IIUUIU, IIiUiJi Otherregulated substances, 171 3077 solid, n.o.s. Oxidizing liquid, corrosive, n.o.s. 140 3098 Oxidizing liquid, n.o.s. 140 n jy Oxidizing liquid, poisonous, n.o.s. 142 3000 Oxidizing liquid, toxic, n.o.s. 142 juyy Oxidizing solid, corrosive, n.o.s. 140 30ob Oxidizing solid, flammable, n.o.s. 140 3137 Oxidizing solid, n.o.s. 140 14 /y Oxidizing solid, poisonous, n.o.s. 141 3087 Oxidizing solid, self-heating, n.o.s. 135 3100 Oxidizing solid, toxic, n.o.s. 141 30Q"7 Oxidizing solid, water-reactive, n.o.s. 144 3121 Oxidizing substances, liquid, 140 3098 corrosive, n.o.s. Oxidizing substances, liquid, n.o.s. 140 3139 Oxidizing substances, liquid, 142 3099 nnknnniK n o ^ Oxidizing substances, liquid, 142 3099 toxic, n.o.s . Oxidizing substances, self- 135 3100 Organophosphorus compound, 151 3464 poisonous, solid, n.o.s. Organophosphorus compound, 131 3279 toxic, flammable, n.o.s. Organophosphorus compound, 151 3278 toxic, liquid, n.o.s. Organophosphorus compound, 151 3278 toxic, n.o.s. Organophosphorus compound, 151 3464 toxic, solid, n.o.s. Organophosphorus pesticide, 131 2784 liquid, flammable, poisonous Organophosphorus pesticide, 131 2784 liquid, flammable, toxic Organophosphorus pesticide, 152 3018 liquid, poisonous Organophosphorus pesticide, 131 3017 liquid, poisonous, flammable Organophosphorus pesticide, 152 3018 liquid, toxic Organophosphorus pesticide, 131 3017 liquid, toxic, flammable Organophosphorus pesticide, 152 2783 solid, poisonous Organophosphorus pesticide, 152 2783 solid, toxic Organotin compound, liquid, 153 2788 n.o.s. Organotin compound, solid, 153 3146 n.o.s. Organotin pesticide, liquid, 131 2787 flammable, poisonous Organotin pesticide, liquid, 131 2787 flammable, toxic Organotin pesticide, liquid, 153 3020 poisonous Organotin pesticide, liquid, 131 3019 poisonous, flammable heating, n.o.s, Name of Material Guide ID No. No. Name of Material Guide ID No. No. Oxidizing substances, solid, 140 3085 corrosive, n.o.s. Oxidizing substances, solid, 140 3137 flammable, n.o.s. Oxidizing substances, solid, 140 1479 n.o.s. Oxidizing substances, solid, 141 3087 poisonous, n.o.s. Oxidizing substances, solid, 135 3100 self-heating, n.o.s. Oxidizing substances, solid, 141 3087 toxic, n.o.s. Oxidizing substances, solid, 144 3121 which in contactwith water emit flammable gases, n.o.s. Oxygen 122 1072 Oxygen, compressed 122 1072 Oxygen, refrigerated liquid 122 1073 (cryogenic liquid) Oxygen and Carbon dioxide 122 1014 mixture Oxygen and Carbon dioxide 122 1014 mixture, compressed Oxygen and Rare gases mixture 121 1980 Oxygen and Rare gases mixture, 121 1980 compressed Oxygen difluoride 124 2190 Oxygen difluoride, compressed 124 2190 Oxygen generator, chemical 140 3356 Oxygen generator, chemical, 140 3356 spent Paint(corrosive) 153 3066 Paint(flammable) 128 1263 Paintrelated material 153 3066 (corrosive) Paintrelated material 128 1263 (flammable) P a per, unsaturated oil treated loo Paraformaldehyde 133 2213 Paraldehyde 129 1264 Parathion 152 2783 Parathion and compressed gas mixtu re 123 1967 PCB 171 2315 PD 152 1556 Pentaborane 135 1380 Pentachloroethane 151 1669 Pentachlorophenol 154 3155 Pentaerythritetetranitrate mixtu re, desensitized, solid, n.o.s., with more than 10% butnotmorethan 20% PETN 113 3344 Pentafluoroethane 126 3220 Pentafluoroethane and Ethylene oxide mixture, with notmore rh a n 7 Q% Ffhvlpnp nviHp UICHI / , J /O LUIVICIIC U A 1 U C 126 3298 Pentamethylheptane 128 2286 Pentan-2,4-dione 131 2310 n-Pentane 128 1265 2,4-Pentanedione 131 2310 Pentane-2,4-dione 131 2310 Pentanes 128 1265 Pentanols 129 1105 1-Pentene 128 1108 1-Pentol 153P 2705 Percarbonates, inorganic, n.o.s. 140 3217 Perchlorates, inorganic, aqueous solution, n.o.s. 140 3211 Perchlorates, inorganic, n.o.s. 140 1481 Perchloric acid, with more than 143 1873 50% but not more than 72% acid Page 143 Name of Material Guide ID Name of Material Guide ID No. NO. No. No. Perchloric acid, with notmore 140 1802 Pesticide, solid, toxic, n.o.s. 151 2588 than 50% acid Petrol 128 1203 Perchloroethylene 160 1897 Petroleum crude oil 128 1267 Perchloromethyl mercaptan 157 1670 Petroleum distillates, n.o.s. 128 1268 Perchloryl fluoride 124 3083 Petroleum gases, liquefied Petroleum oil 115 1075 Perfluoroethyl vinyl ether 115 3154 128 1270 Perfluoro(ethyl vinyl ether) 115 3154 Petroleum products, n.o.s. 128 1268 Perfluoromethyl vinyl ether 115 3153 Phenacyl bromide 153 2645 Perfluoro(methyl vinyl ether) 115 3153 Phenetidines 153 2311 Perfumery products, with 127 1266 Phenol, molten 153 2312 flammable solvents Phenol, solid 153 1671 Permanganates, inorganic, 140 3214 aqueous solution, n.o.s. P henol solution 153 2821 Permanganates, inorganic, 140 1482 Phenolates, liquid 154 2904 n.o.s. Phenolates, solid 154 2905 Peroxides, inorganic, n.o.s. 140 1483 Phenolsulfonic acid, liquid 153 1803 Persulfates, inorganic, aqueous 140 3216 Phenolsulphonic acid, liquid 153 1803 solution, n.o.s. Phenoxyacetic acid derivative 131 3346 Persulfates, inorganic, n.o.s. 140 3215 pesticide, liquid, flammable, Persulphates, inorganic, 140 3216 poisonous aqueous solution, n.o.s. Phenoxyacetic acid derivative 131 3346 Persulphates, inorganic, n.o.s. 140 3215 pesticide, liquid, flammable, toxic Pesticide, liquid, flammable, poisonous, n.o.s. 131 3021 3348 Phenoxyacetic acid derivative pesticide, liquid, poisonous 153 Pesticide, liquid, flammable, toxic, n.o.s. 131 3021 Phenoxyacetic acid derivative 131 3347 pesticide, liquid, poisonous, Pesticide, liquid, poisonous, 131 2903 flammable flammable, n.o.s. Phenoxyacetic acid derivative 153 3348 Pesticide, liquid, poisonous, 151 2902 pesticide, liquid, toxic n.o.s. Phenoxyacetic acid derivative 131 3347 Pesticide, liquid, toxic, 131 2903 pesticide, liquid, toxic, flammable, n.o.s. flammable Pesticide, liquid, toxic, n.o.s. 151 2902 Phenoxyacetic acid derivative 153 3345 Pesticide, solid, poisonous 151 2588 pesticide, solid, poisonous Pesticide, solid, poisonous, n.o.s. 151 2588 Phenoxyacetic acid derivative pesticide, solid, toxic 153 3345 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Phenoxy pesticide, liquid, flammable, poisonous 131 2766 Phenoxy pesticide, liquid, flammable, toxic 131 2766 Phenoxy pesticide, liquid, poisonous 152 3000 Phenoxy pesticide, liquid, poisonous, flammable 131 2999 Phenoxy pesticide, liquid, toxic 152 3000 Phenoxy pesticide, liquid, toxic, flammable 131 2999 Phenoxy pesticide, solid, poisonous 152 2765 Phenoxy pesticide, solid, toxic H CO 152 ~i 1 a c L /CO Phenylacetonitrile, liquid 152 2470 Phenylacetyl chloride 156 1 C 1 1 13 1 1 Phenylcarbyl amine chloride 151 1 C 1~) Ib/z Phenyl chloroformate 156 2746 Phenylenediamines 153 1673 Phenylhydrazine 153 2572 Phenyl isocyanate 155 2487 Phenyl mercaptan 131 2337 Phenylmercuric acetate 151 1674 Phenylmercuric compound, n.o.s. 151 2026 P henylmercuric hydroxide 151 1894 Phenylmercuric nitrate 151 1895 Phenylphosphorus dichloride 137 2798 Phenylphosphorus thiodichloride 137 2799 Phenyltrichlorosilane 156 1804 Phenyl urea pesticide, liquid, flammable, poisonous 131 2768 Phenyl urea pesticide, liquid, 131 2768 flammable, toxic Phenyl urea pesticide, liquid, poisonous 151 3002 Phenyl urea pesticide, liquid, poisonous, flammable 131 3001 Phenyl urea pesticide, liquid, toxic 151 3002 Phenyl urea pesticide, liquid, toxic, flammable 131 3001 Phenyl urea pesticide, solid, poisonous 151 2767 Phenyl urea pesticide, solid, toxic 151 2767 Phosgene 125 1076 9-P hosphabicyclononanes 135 2940 Phosphine 119 2199 Phosphoric acid 154 1805 Phosphoric acid, liquid 154 lone 1805 Phosphoric acid, solid 154 1805 Phosphoric acid, solid 154 3453 Phosphoric acid, solution 154 1805 Phosphorous acid 154 2834 Phosphorous acid, ortho 154 2834 Phosphorus, amorphous 133 1338 Phosphorus, amorphous, red 133 1338 Phosphorus, white, dry or under waterorin solution 136 1381 Phosphorus, white, molten 136 2447 Phosphorus, yellow, dry or under 136 waterorin solution 1381 Phosphorus heptasulfide, free from yellow and white Phosphorus 139 1339 Phosphorus heptasulphide, free from yellow and white Phosphorus 139 1339 Phosphorus oxybromide 137 1939 Name of Material Guide ID No. No. Phosphorus oxybromide, molten 137 2576 Phosphorus oxybromide, solid 137 1939 Phosphorus oxychloride 137 1810 Phosphorus pentabromide 137 2691 Phosphorus pentachloride 137 1806 Phosphorus penta fluoride 125 2198 Phosphorus penta fluoride, romnrpssed V- U 1 1 1 IJ 1 J LU 125 2198 Phosphorus pentasulfide, free from yellow and white P hosnhorus 1 1 1 U J U 1 1 U 1 U J 139 1340 Phosphorus pentasulphide, free from yellow and white Phosphorus 139 1340 Phosphorus pentoxide 137 1807 Phosphorus sesquisulfide, free from yellow and white Phosphorus 139 1341 Phosphorus sesquisulphide, free from yellow and white Phosphorus 139 1341 Phosphorus tribromide 137 1808 Phosphorus trichloride 137 1809 Phosphorus trioxide 157 2578 Phosphorus trisulfide, freefrom yellow and white Phosphorus 139 1343 Phosphorus trisulphide, free from yellow and white Phosphorus 139 1343 Phthalic anhydride 156 2214 Phthalimide derivative pesticide, liquid, flammable, poisonous 131 2774 Phthalimide derivative pesticide, liquid, flammable, toxic 131 2774 Phthalimide derivative 151 3008 pesticide, liquid, poisonous Name of Material Guide ID No. No. Phthalimide derivative pesticide, liquid, poisonous, flammable 131 3007 Phthalimide derivative pesticide, liquid, toxic 151 3008 Phthalimide derivative pesticide, liquid, toxic, flammable 131 3007 Phthalimide derivative pesticide, solid, poisonous 151 2773 P hthalimide derivative pesticide, solid, toxic 151 211 i P icolines H Ort 129 2313 Picric acid, wet, with notless than 10% water 113 1344 P icric acid, wetted with notless than 10% water 113 3364 P icrite, wetted 113 1336 Picryl chloride, wetted with not less than 10% water 113 3365 alpha-Pinene 128 2368 Pinene (alpha) 128 2368 Pine oil 129 1272 Piperazine 153 2579 Piperidine 132 2401 Plastic molding compound 171 3314 Plastic, nitrocellulose-based, spontaneously combustible, n.o.s. 135 2006 Plastics moulding compound 1 l\ 3314 Plastics, nitrocellulose-based, self-heating, n.o.s. HOC 135 zUUb roison d , iiquia, n.o.s. ■f CO loo iq i n Poisonous by inhalation liquid, corrosive, n.o.s. (Inhalation 154 3389 Hazard Zone A) Name of Material Guide ID No. No. Name of Material Guide ID No. No. Poisonous by inhalation liquid, 154 3390 corrosive, n.o.s. (Inhalation Hazard Zone B) Poisonous by inhalation liquid, 131 3383 flammable, n.o.s. (Inhalation Hazard Zone A) Poisonous by inhalation liquid, 131 3384 flammable, n.o.s. (Inhalation Hazard Zone B) Poisonous by inhalation liquid, 151 3381 n.o.s. (Inhalation Hazard Zone A) Poisonous by inhalation liquid, 151 3382 n.o.s. (Inhalation Hazard Zone B) Poisonous by inhalation liquid, 142 3387 oxidizing, n.o.s. (Inhalation Hazard Zone A) Poisonous by inhalation liquid, 142 3388 oxidizing, n.o.s. (Inhalation Hazard Zone B) Poisonous by inhalation liquid, 139 3385 water-reactive, n.o.s. (Inhalation Hazard Zone A) Poisonous by inhalation liquid, 139 3386 water-reactive, n.o.s. (Inhalation Hazard Zone B) Poisonous liquid, corrosive, 154 3289 inorganic, n.o.s. Poisonous liquid, corrosive, 154 3289 inorganic, n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, corrosive, 154 3289 inorganic, n.o.s. (Inhalation Hazard Zone B) Poisonous liquid, corrosive, 154 2927 n.o.s. Poisonous liquid, corrosive, 154 2927 n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, corrosive, 154 2927 n.o.s. (Inhalation Hazard Zone B) Poisonous liquid, flammable, 131 2929 n.o.s. Poisonous liquid, flammable, 131 2929 n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, flammable, 131 2929 n.o.s. (Inhalation Hazard ZoneB) Poisonous liquid, flammable, 131 2929 organic, n.o.s. Poisonous liquid, flammable, 131 2929 organic, n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, flammable, 131 2929 organic, n.o.s. (Inhalation Hazard Zone B) Poisonous liquid, inorganic, 151 3287 n.o.s. Poisonous liquid, inorganic, 151 3287 n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, inorganic, 151 3287 n.o.s. (Inhalation Hazard ZoneB) Poisonous liquid, n.o.s. 153 2810 Poisonous liquid, n.o.s. 153 2810 (Inhalation Hazard Zone A) Poisonous liquid, n.o.s. 153 2810 (Inhalation Hazard Zone B) Poisonous liquid, organic, n.o.s. 153 2810 Poisonous liquid, organic, n.o.s. 153 2810 (Inhalation Hazard Zone A) Poisonous liquid, organic, n.o.s. 153 2810 (Inhalation Hazard Zone B) Poisonous liquid, oxidizing, 142 3122 n.o.s. Name of Material Guide ID K 1 „ NO. NO. Poisonous liquid, oxidizing, 142 3122 n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, oxidizing, 142 3122 n.o.s. (Inhalation Hazard Zone B) Poisonous liquid, water- 139 3123 reactive, n.o.s. Poisonous liquid, water- 139 3123 reactive, n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, water- 139 3123 reactive, n.o.s. (Inhalation Hazard Zone B) Poisonous liquid, which in 139 3123 contactwith wateremits flammable gases, n.o.s. Poisonous liquid, which in 139 3123 contactwith wateremits flammable gases, n.o.s. (Inhalation Hazard Zone A) Poisonous liquid, which in 139 3123 contactwith wateremits flammable gases, n.o.s. (Inhalation Hazard Zone B) Poisonous solid, corrosive, 154 3290 inorganic, n.o.s. Poisonous solid, corrosive, 154 2928 n.o.s. Poisonous solid, flammable, 134 2930 n.o.s. Poisonous solid, flammable, 134 2930 organic, n.o.s. Poisonous solid, inorganic, 151 3288 n.o.s. Poisonous solid, organic, n.o.s 154 2811 Poisonous solid, oxidizing, n.o.s. 141 3086 Poisonous solid, self-heating, 136 3124 n.o.s. Name of Material Guide ID No. No. Poisonous solid, water-reactive, 139 3125 n.o.s, Poisonous solid, which in 139 3125 contactwith wateremits flammable gases, n.o.s. P olyalkylamines, n.o.s. 132 2733 P olyalkylamines, n.o.s. 132 2734 D nlwsll/wls rv"i in or n n c r Oly d IKy Id iTllllcb , II. 0.3. loo LIJJ P olyamines, flammable, 132 2733 corros ive, n.o.s. P olyamines, liquid, corrosive, 132 2734 lid I II I II a U 1 c , ll.U.b. Polyamines, liquid, corrosive, 153 2735 n.o.s. Polyamines, solid, corrosive, 154 3259 n.o.s. P olychlorinated biphenyls 171 2315 P olychlorinated biphenyls, liquid 171 2315 P olychlorinated biphenyls, solid 171 2315 P olych lorina ted biphenyls, solid 171 3432 r oiyes ter res in Kit jzoy n i l l i_ l l ■ l l Polyhalogenated biphenyls, 171 3151 liquid Polyhalogenated biphenyls, 171 3152 solid Polyhalogenated terphenyls, 171 3151 liquid Polyhalogenated terphenyls, 171 3152 solid Polymeric beads, expandable 133 2211 Pnlvsh/rpnp h p a H s pynanrlahlp i« 1 oo 2211 P otassium 138 2257 P fite c; c jii m mpl"a 1 1 U LU J J IU 1 II, IIICLUl 138 2257 Potassium metal allovs 1 U LU J J IU 1 II f 1 1 1 C LU 1 LI 1 1 \J ¥ -J 138 1420 PAhacciiim mohal allA\/c liAiiirl ruLdbbiuiii, nicLdi d 1 1 u y b , ntjuiu loo Potassium, metal alloys, solid 138 3403 Name of Material Guide ID No. NO. Potassium arsenate 151 1 C ~I~I lb// Potassium arsenite 154 i c no lb/8 Potassium borohydride 138 lo/U Potassium bromate 140 1/10/1 1484 PAhacciiim rhlAraho r U LCI 3 3 1 U 1 II L 1 1 1 U 1 d Lc 1 A C 1485 Potassium chlorate, aqueous 140 2427 solution Potassium chlorate, solution 140 2427 Potassium cuprocyanide 157 1679 Potassium cyanide 157 1680 Potassium cyanide, solid 157 1680 Potassium cyanide, solution 157 341 i Potassium dithionite 135 1929 Potassium fluoride 154 ion 1812 Potassium fluoride, solid 154 ion 1812 Potassium fluoride, solution 154 3422 Potassium fluoroacetate 151 2b28 Potassium fluorosilicate 151 2655 P Aha c c i 1 1 m huHrAnonrlifliiAnrlo r u id a a i u i ii iiyuiuyciiuiiiuuiiuc i o*t 1 Q 1 1 loll Potassium hydrogen difluoride, 154 1811 solid Potassium hydrogen difluoride, 154 3421 solution Potassium hydrogen sulfate 154 i c: no. Potassium hydrogen sulphate 154 i r no Potassium hydrosulfite 135 iy^y Potassium hydrosulphite 135 1 Q")Q iyzy Potassium hydroxide, dry, solid 154 1 Q 1 ^ J.oJ.3 Potassium hydroxide, flake 154 1 Q 1 3 Potassium hydroxide, solid 154 1 Q 1 3 luJ.3 Potassium hydroxide, solution 154 1 Q 1 A Potassium metavanadate 151 TOC/I zob4 rotassium monoxiae 104 2033 Potassium nitrate 140 1486 Name of Material Guide ID No. NO. Potassium nitrate and Sodium 140 1499 n lira ho m i yh i ro 1 1 1 LI a LC IMIALUIC Potassium nitrate and Sodium 140 1487 nitrite mixture Potassium nitrite 140 1488 Potassium perchlorate 140 1 A P.Q i4oy Potassium permanganate 140 1 A QH 14yU Potassium peroxide 144 1 A Ql i4yi Potassium persulfate 140 1 A Q") i4yz Potassium persulphate 140 1 A Q") i4yz Potassium phosphide 139 2012 Potassium silicofluoride 151 2655 Potassium sodium alloys 138 1422 Potassium sodium alloys, liquid 138 1422 Potassium sodium alloys, solid 138 0) a n A 3404 P a ha c c i 1 1 m cnlfirlo anhurlrnnc r u id j j i u 1 1 1 j u 1 1 1 u c , oiiiiyuiuuo) IOC 1382 Potassium sulfide, hydrated, 153 1847 with not less than 30% water Af r r\/c ha 1 1 17 a H a n U 1 L 1 y 3 Ld 1 1 \L d LI U 1 1 Potassium sulfide, hydrated, 153 1847 with not less than 30% water Af h \/rl ra H a n u I iiyuidLiuii Potassium sulfide, with less than HOC 135 1382 "X CiWr, \m a ho r Af r rvc ha 1 1 17 a H a n j u /o vv d Lc 1 ui l 1 y 3 Ld 1 1 \l d li u i i Potassium sulfide, with less than HOC 135 1382 30% water of hydration P fifa. c; c in m ciilnhiHp anhvrlrniK r UL0 33IUIM 3UIUIIIUC, CI 1 1 1 1 y U 1 U U 3 IOJ Potassium sulphide, hydrated, 153 1847 with not less than 30% water nf r rvc; fa 1 1 17a tin n Potassium sulphide, hydrated, 153 1847 with not less than 30% water of hydration \j i 1 1 y u i u li u 1 1 Potassium sulphide, with less 135 1382 than 30% water of crystallization Name of Material Guide ID NO. NO. Potassium sulphide, with less than 30% waterof hydration 135 1382 Potassium superoxide 143 1 A C C z4bb Printing ink, flammable 129 lzlO P rinting ink related material 1Z1U P ropadiene, inhibited 116P 2200 Propadiene, stabilized 116P 2200 Propadiene and Methylacetylene mixture, stabilized 116P 1060 P ropane 115 1075 P ropane ■ i j 1 P7R ±3/0 Propane-Ethane mixture, refrigerated liquid 115 1961 P ropane mixture 115 1075 P ropane mixture 115 1978 P ropanethiols 130 2402 n-P ropanol 129 1274 Propargyl alcohol 131 1986 P ropionaldehyde 129 1275 Propionic acid 132 1848 Propionic anhydride 156 2496 P ropionitrile 131 2404 P ropionyl chloride 132 1815 n-P ropyl acetate 129 1276 normal Propyl alcohol 129 1274 Propyl alcohol, normal 129 1274 Propylamine 132 1277 n-P ropyl benzene 128 2364 P ropyl chloride 129 1278 n-P ropyl chloroformate 155 2740 P ropylene 115 1075 Propylene 115 1077 Name of Material Guide ID No. No. Propylene, Ethylene and 115 3138 Acetylene in mixture, refrigerated liquid containing at least 71.5% Ethylene with notmore than 22,5% Acetylene and notmore than 6% Propylene Propylene chlorohydrin 131 2611 i,z-r ropyieneuiamine 132 2258 x , j r iu|jyiciicuidiiiMic 132 2258 P rnnulono rl ir h 1 a rirl o r i u \Jy idle uiliiiuiiuc 130 1279 P ropyleneimine, inhibited 131 P 1921 P rnnulonoimino c ha h il 17 o H r lUfjyicMclllllllc, b La U I \\l c U 131P 1921 P ropylene oxide 127P 1280 Propylene oxide and Ethylene UXlUc IIIIXLUIc, WILII MULlllOlc than 30% Ethylene oxide 129P 2983 D r*A h\/m h l"^\l"r"i rvi f\ r r ropyiene teuamer 128 2850 Propyl formates 129 1281 n-Propyl isocyanate 155 2482 n-Propyl nitrate 131 1865 Propyltrichlorosilane 155 1816 Pyrethroid pesticide, liquid, flammable, poisonous 131 3350 Pyrethroid pesticide, liquid, flammable, toxic 131 3350 Pyrethroid pesticide, liquid, poisonous 151 3352 Pyrethroid pesticide, liquid, poisonous, flammable 131 3351 Pyrethroid pesticide, liquid, toxic 151 3352 Pyrethroid pesticide, liquid, toxic, 131 flammable 3351 Pyrethroid pesticide, solid, poisonous 151 3349 Pyrethroid pesticide, solid, toxic 151 3349 Pyridine 129 1282 Page 150 Name of Material Guide ID Name of Material Guide ID No. No. No. No. Pyrophoric alloy, n.o.s. 135 1383 Radioactive material, excepted 161 2909 Pyrophoric liquid, inorganic, n.o.s. 135 3194 package, articles manufactured from natural Thorium Pyrophoric liquid, n.o.s. 135 2845 Radioactive material, excepted 161 2910 package, articles manufactured Pyrophoric liquid, organic, n.o.s. 135 2845 frAtn n a h i ra 1 T h ami i m iiuiii iidiuidi i nullum D \i i-a n h a ri r rviflhal r\ a c ryiupnuiiL ificLdi, ii.u.b. IOO 1383 Radioactive material, excepted 161 2909 Pyrophoric organometallic 135 3203 package, articles manufactured corn po u nu , n.o.s. from natural 11 ran in m IIUIII 1 1 U LU 1 Ul \J 1 U 1 1 1 U 1 1 1 Pyrophoric organometallic 135 3203 Radioactive material, excepted 161 2910 compound, water-reactive, package, articles manufactured n.o.s. from natural 11 ran in m IIUIII 1 1 U LU 1 U 1 UlulllUIII Pyrophoric solid, inorganic, 135 3200 Radioactive material, excepted 161 2908 n.o.s. narlcanp pmnrvnarleaninn U □ L l\ □ U C , CIIIULy U □ L l\u U 1 1 1 U ryropnoric song, n.o.s. -IOC loo 2846 Rarlinartivp ma tp rial pxrpnrprl llUUIuULUVC lllu LC 1 1 U 1 , LALCU LC U 161 2910 Pyrophoric solid, organic, n.o.s. 135 2846 package, empty packaging Pyrosulfuryl chloride 137 1817 Radioactive material, excepted 161 2910 package, instruments or Pyrosulphuryl chloride 137 1817 a rHr lo c d 1 LH_lci> Pyrrolidine -ion 132 1922 Radioactive material, excepted 161 2911 . .. Q u in o line 154 2656 narkaop in^trumpnK or articles Radioactive material, articles 161 2909 manufactured from depleted Radioactive material, excepted 161 2910 Uranium narkanp Mm irpfl n n a nrirv of U u L. I\u U C , llllll LC U UU U 1 1 LI L y U 1 mate rial Radioactive material, articles 161 2909 manufactured from natural R adioactive material, fissile, 1DO 2918 Thorium n.o.s. Radioactive material, articles 161 2909 R adioactive material, 161 2911 manufactured from natural in c: f-ri j mpn fa or a rrirlpc; 1 1 1 J L 1 U 1 1 1 C 1 1 L J U| □ I L 1 L. 1 C J 1 1 ra n inm U 1 UIIIUIII Radioactive material, limited 161 2910 Radioactive material, empty 161 2908 n 1 1 a n f if \/ n a c q U a II ULy, II .0 .b . pd IKdgcb R adioactive material, low 162 2912 Radioactive material, excepted 161 2909 specific activity (LSA), n.o.s. package, articles manuraci-ureci Radioactive material, low 162 2912 frfitn rlpnlprprl 1 1 ran in m 1 1 U 1 II UCUIC LC U U 1 □ 1 1 1 U 1 1 1 specific activity (LSA-I) Radioactive material, excepted 161 2910 Radioactive material, low 162 3321 package, articles manufactured specific activity (LSA-II) from depleted Uranium Name of Material Guide ID No. No. Radioactive material, low 165 3324 specific activity (LSA-II), fissile Radioactive material, low 162 3322 specific activity ( L S A - 1 1 1 ) Radioactive material, low 165 3325 specific activity (LS A-lll), fissile Radioactive material, n.o.s. 163 2982 Radioactive material, special 164 2974 form, n.o.s. Radioactive material, surface 162 2913 contaminated objects (SCO) Radioactive material, surface 162 2913 contaminated objects (SCO-I) Radioactive material, surface 165 3326 contaminated objects (SCO-I), fissile Radioactive material, surface 162 2913 contaminated objects (SCO-II) Radioactive material, surface 165 3326 contaminated objects (SCO-II), fissile Radioactive material, transported 163 2919 underspecial arrangement Radioactive material, transported 165 3331 underspecial arrangement, fissile Radioactive material, Type A 163 2915 package Radioactive material, Type A 165 3327 package, fissile Radioactive material, Type A 164 3332 package, special form Radioactive material, Type A 165 3333 package, special form, fissile Radioactive material, Type B(M) 163 2917 package Name of Material Guide ID No. IMO. Radioactive material, Type B(M) 165 3329 [Jell Kciy c , IIdoMc Radioactive material, Type B(U) 163 2916 n ^ f 1/ ^ r\ q pd LKd y c Radioactive material, Type B(U) 165 3328 r\ i c \/ 1 r\ a tic p 1 1 a pdLKdy", llbbllc R ad io active material, Type C 163 3323 package R a dio active material, Type C 165 3330 package, Tissue Radioactive material, Uranium 166 2977 nexanuoriae, rissne Radioactive material, Uranium 166 2978 hexafluoride Radioactive material, Uranium 166 2978 hexafluoride, non-fissile or fissile-excepted Rags, oily 133 lojb H a ro n a c c a n H Mitrnnon nn i yh i ro r\ □ i c y d j c j a 1 1 u iMiuuycii imialuic I L. I 1 nni R are gases and N itrogen 121 1981 mixture, compressed r\dlc ydbcb d II u U X y y c II lillXLUlc 101 \£. I 1 (inn Rare gases and Oxygen mixture, 121 1980 romnrp^pd R are gases mixture 121 1979 Rarpna^p^mixturp romnrp^pd 121 i mn iy /y Receptacles, small, containing 115 2037 gas Red phosphorus 133 1 J JO Red phosphorus, amorphous 133 1 J JO Q of rin o ra n \ n a c n a c [\ciiiytMaMiycib, M . u . b . I OR i mo Refrigerantgas, n.o.s. 115 1954 (flammable) Rpfrinpranfnac; R-1? r\ciiiyciai!L.yQj r\ x l i mo Refrigerantgas R-12 and 126 2602 Refrigerantgas R-152a azeotropic mixture with 74% Refrigerantgas R-12 Page 152 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Refrigerantgas R-12B1 126 1974 Refrigerantgas R-13 126 1022 Refrigerantgas R-13 and 126 2599 Refrigerantgas R-23 azeotropic mixture with 60% Refrigerantgas R-13 Refrigerantgas R-13B1 126 Refrigerantgas R-14 126 Refrigerant gas R -14, 126 compressed Refrigerantgas R-21 126 Refrigerantgas R-22 126 Refrigerantgas R-23 126 Refrigerantgas R-23 and 126 Refrigerantgas R-13 azeotropic mixture with 60% Refrigerantgas R-13 1009 1982 1982 1029 1018 1984 2599 Refrigerantgas R 32 115 3252 Refrigerantgas R 40 115 1063 Refrigerantgas R 41 115 2454 Refrigerantgas R 114 126 1958 Refrigerantgas R 115 126 1020 Refrigerantgas R 116 126 2193 Refrigerantgas R -116, 126 2193 compressed Refrigerantgas R 124 126 1021 Refrigerantgas R 125 126 3220 Refrigerantgas R 133a 126 1983 Refrigerantgas R 134a 126 3159 Refrigerantgas R 143a 115 2035 Refrigerantgas R 142b 115 2517 Refrigerantgas R 152a 115 1030 Refrigerantgas R 152a and 126 2602 Refrigerantgas R -12 azeotropic mixture with 74% Refrigerantgas R -12 Refrigerantgas R-161 115 2453 Refrigerantgas R-218 126 2424 Refrigerantgas R-227 126 3296 Refrigerantgas R-404A 126 3337 Refrigerantgas R-407A 126 3338 Refrigerantgas R-407B 126 3339 Refrigerantgas R-407C 126 3340 Refrigerantgas R-500 126 2602 (azeotropic mixture of Refrigerantgas R -12 and Refrigerantgas R-152a with approximately 74% Refrigerantgas R-12) Refrigerantgas R-502 126 1973 Refrigerantgas R-503 126 2599 (azeotropic mixture of Refrigerantgas R-13 and Refrigerantgas R-23 with approximately 60% Refrigerantgas R-13) Refrigerantgas R-1132a 116P 1959 Refrigerantgas R-1216 126 1858 Refrigerantgas R-1318 126 2422 Refrigerantgas RC-318 126 1976 Refrigerating machine 128 1993 Refrigerating machines, 126 2857 containing Ammonia solutions (UN2073) Refrigerating machines, 126 2857 containing Ammonia solutions (UN2672) Refrigerating machines, 115 1954 containing flammable, non-poisonous, non- corrosive, liquefied gas Refrigerating machines, containing 115 3358 flammable, non-toxic, liquefied gas Page 153 Name of Material Guide ID No. NO. Refrigerating machines, 126 2857 containing non-flammable, 1 1 n 1 1 o f i o H riac ML] U c 1 lc U Lj db Refrigerating machines, 126 2857 containing non-flammable, llUll"UUIoUllUU b Ljdbcb Refrigerating machines, 126 2857 containing non-flammable, nAn nAicAnAiic liAiiafiaH nac Hull pOlbOIIOUb, liqUcllcU gdb Refrigerating machines, 126 2857 containing non-flammable, non-poisonous, non-corrosive, 1 in 1 1 of io H nac ii L] u c 1 1 c u y a a Refrigerating machines, 126 2857 containing non-flammable, 1 1 U 1 1 LU A 1 L y d b cb Refrigerating machines, 126 2857 containing non-flammable, nnn hnvir liAiiafiaH nac IIUII LUXIC, liqUcllcU gdb Refrigerating machines, 126 2857 containing non-flammable, non-toxic, non-corrosive, liquefied gas Regulated medical waste, n.o.s. 158 R eon la ted medical waste 1 \ L U U 1 U LL U 1 1 1 V- U 1 L U 1 III U J 158 R p^in solution 1 \ U J 1 II J U 1 U U V 1 1 127 1866 R pc nrr in a| l \ U J UIL II IUI 153 2876 D a c i n a i 1 r\ Ub III UN 177 \c.t 1286 Rubberscrap, powdered or 133 1345 y I d 1 1 u I d Lc u Rubbershoddy, powdered or 133 1345 granulated R ubber solution 127 1287 Rubidium 138 1423 Rubidium hydroxide 154 ZD / Rubidium hydroxide, solid 154 -) C 7 Q ZD/0 Rubidium hydroxide, solution ten Rubidium metal 138 1423 Name of Material Guide ID No. No. SA 119 2188 Sarin 153 2810 Seat-beltmodules 171 3268 Seat-beltpre-tensioners 171 3268 Seat-beltpre-tensioners, 126 3353 compressed gas Seat-beltpre-tensioners, 171 3268 pyrotechnic Seed cake, with more than 1.5% 135 1386 oil and notmore than 11% moisture Seed cake, with notmore than 135 2217 1,5% oil and notmore than 11% moisture Selenates 151 2630 Selenic acid 154 1905 Selenites 151 2630 Selenium compound, liquid, 151 3440 n.o.s. Selenium compound, n.o.s. 151 3283 Selenium compound, solid, 151 3283 n.o.s. Selenium disulfide 153 2657 Selenium disulphide 153 2657 Selenium hexafluoride 125 2194 Selenium oxide 154 2811 Selenium oxychloride 157 2879 Selenium powder 152 2658 Self-defense spray, non- 171 3334 pressurized Self-heating liquid, corrosive, 136 3188 inorganic, n.o.s, Self-heating liquid, corrosive, 136 3185 organic, n.o.s. Self-heating liquid, inorganic, 135 3186 n.o.s, Name of Material Guide ID Name of Material Guide ID No. No. No. No. Self-heating liquid, organic, 135 3183 Self-heating substance, solid, 136 3126 n.o.s. corrosive, n.o.s. Self-heating liquid, poisonous, 136 3187 Self-heating substances, solid, 135 3088 inorganic, n.o.s. n.o.s. Self-heating liquid, poisonous, 136 3184 Self-heating substances, solid, 135 3127 organic, n.o.s. oxidizing, n.o.s. Self-heating liquid, toxic, 136 3187 Self-heating substances, solid, 136 3128 inorganic, n.o.s. poisonous, n.o.s. Self-heating liquid, toxic, 136 3184 Self-heating substances, solid, 136 3128 organic, n.o.s. toxic, n.o.s, Self-heating metal powders, 135 3189 Self-reactive liquid type B 149 3221 n.o.s. Self-reactive liquid type B, 150 3231 Self-heating solid, corrosive, 136 3192 temperature controlled inorganic, n.o.s. Self-reactive liquid type C 149 3223 Self-heating solid, corrosive, organic, n.o.s. 136 3126 Self-reactive liquid type C, 150 3233 temperature controlled Self-heating solid, inorganic, n.o.s. 135 3190 Self-reactive liquid type D 149 3225 Self-heating solid, inorganic, 136 3191 Self-reactive liquid type D, 150 3235 poisonous, n.o.s. temperature controlled Self-heating solid, inorganic, 136 3191 Self-reactive liquid type E 149 3227 toxic, n.o.s. Self-reactive liquid type E, 150 3237 Self-heating solid, organic, 135 3088 temperature controlled n.o.s. Self-reactive liquid type F 149 3229 Self-heating solid, organic, 136 3128 Self-reactive liquid type F, 150 3239 poisonous, n.o.s. temperature controlled Self-heating solid, organic, 136 3128 Self-reactive solid type B 149 3222 toxic, n.o.s. Self-reactive solid type B, 150 3232 Self-heating solid, oxidizing, n a c 135 3127 temperature controlled 1 1 . u . j ■ Self-reactive solid type C 149 3224 Self-heating solid, poisonous, 136 3191 inorganic, n.o.s. Self-reactive solid type C, 150 3234 Self-heating solid, poisonous, 136 3128 temperature controlled organic, n.o.s. Self-reactive solid type D 149 3226 Self-heating solid, toxic, 136 3191 Self-reactive solid type D, 150 3236 inorganic, n.o.s. temperature controlled Self-heating solid, toxic, 136 3128 Self-reactive solid type E 149 3228 organic, n.o.s. Self-reactive solid type E, temperature controlled 150 3238 Name of Material Guide ID Name of Material Guide ID No. NO. No. No. Self-reactive solid type F 149 3230 Sfidinmhknlnhat"p ^oliiHon J UUIUMI Ul J U IU 1 1 □ LC f JulULIUII 154 2837 Self-reactive solid type F, 150 3240 ^Arliiim h n rn h \/H rirl d juuiuiii uuiuiiyuiiuc 118 1426 temperature controlled Sodium borohyd ride and Sodium 157 3320 Shale oil 128 1288 hydroxide solution, with not Silane 116 2203 more than 12% Sodium borohydride and notmore S il ic o flu o rides , n.o.s. 151 2856 hh a n AO Q /n ^nrliiim h \/H rri y i rl o UIGII 4U/0 JUUIUIII llyUIUAlUC Silane, compressed 116 2203 JUUIUIII U 1 U 1 II 01 LC 141 1494 Silicon powder, amorphous 170 1346 Sodium cacodylate 152 1688 Silicon tetrachloride 157 1818 Sodium carbonate peroxyhydrate 140 3378 Silicon tetrafluoride 125 1859 Sodium chlorate 140 1495 Silicon tetrafluoride, 125 1859 Sodium chlorate, aqueous 140 2428 compressed solution Silverarsenite 151 1683 Sodium chlorite 143 1496 Silvercyanide 151 1684 Sodium chlorite, solution, with 154 1908 Silver nitrate 140 1493 more than 5% available Chlorine Silverpicrate, wetted with not 113 1347 less than 30% water JUUIUIII LIIIUIUuLCLO LC 1<51 2659 Sludge acid 153 1906 Sodium cuprocyanide, solid 157 2316 Smokeless powderforsmall 133 3178 Sodium cuprocyanide, solution 157 2317 arms Sodium cyanide 157 1689 Soda lime, with more than 4% 154 1907 Sodium cyanide, solid 157 1689 Sodium hydroxide Sodium cyanide, solution 157 3414 Sodium 138 1428 Sodium dichloroisocyanurate 2465 140 Sodium aluminate, solid 154 2812 Sodium dichloro-s-triazinetrione 140 2465 Sodium aluminate, solution 154 1819 Sodium dinitro-o-cresolate, 113 3369 Sodium aluminum hydride 138 2835 wetted with not less than 10% Sodium ammonium vanadate 154 2863 water Sodium arsanilate 154 2473 Sodium dinitro-o-cresolate, 113 1348 wetted with not less than 15% Sodium arsenate 151 1685 water Sodium arsenite, aqueous 154 1686 Sodium dinitro-ortho-cresolate, 113 1348 solution wetted Sodium arsenite, solid 151 2027 Sodium dithionite 135 1384 Sodium azide 153 1687 Sodium fluoride 154 1690 Sodium bisulfate, solution 154 2837 Sodium fluoride, solid 154 1690 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Sodium fluoride, solution 154 3415 Sodium fluoroacetate 151 Ton Sodium fluorosilicate H CA 154 ZD/4 Sodium hydride 138 1427 Sodium hydrogendifluoride 154 2439 Sodium hydrogen sulfate, solution 154 2837 Sodium hydrogen sulphate, solution 154 2837 Sodium hydrosulfide, solid, with less than 25% water of 135 2318 crystallization Sodium hydrosulfide, solution 154 2922 Sodium hydrosulfide, with less than 25% water of 135 2318 crystallization Sodium hydrosulfide, with not less than 25% waterof 154 2949 crystallization Sodium hydrosulfite 135 1384 Sodium hydrosulphide, solid, with less than 25% waterof 135 2318 crystallization Sodium hydrosulphide, solution 154 2922 Sodium hydrosulphide, with less than 25% waterof 135 2318 crystallization Sodium hydrosulphide, with not less than 25% waterof 154 2949 crystallization Sodium hydrosulphite HOC 135 1384 Sodium hydroxide, bead 154 ion 1823 Sodium hydroxide, dry •i CA 104 loZ J Sodium hydroxide, flake 154 1823 Sodium hydroxide, granular 154 1823 Sodium hydroxide, solid 154 1823 Sodium hydroxide, solution 154 1824 Sodium methylate 138 1431 Sodium methylate, dry 138 1431 Sodium methylate, solution in alcohol 132 1289 Sodium monoxide 157 1825 Sodium nitrate 140 1498 Sodium nitrate and Potassium nitrate mixture 140 1499 Sodium nitrite 140 1500 Sodium nitrite and Potassium nitrate mixture 140 1487 Sodium pentachlorophenate 154 2567 Sodium perborate monohydrate 140 3377 Sodium percarbonates •i An 14U Z4b/ Sodium perchlorate H Af\ 140 IDUZ Sodium permanganate 140 1503 Sodium peroxide 144 1504 Sodium peroxoborate, anhydrous 140 3247 Sodium persulfate 140 1505 Sodium persulphate 140 1505 Sodium phosphide 139 1432 Sodium picramate, wetted with not less than 20% water 113 1349 Sodium potassium alloys -too 138 1422 Sodium potassium alloys, liquid 138 1422 Sodium potassium alloys, solid 138 3404 Sodium selenite 151 2630 Sodium silicofluoride 154 2674 Sodium sulfide, anhydrous 135 1385 Sodium sulfide, hydra ted, with 153 1849 not less than 30% water Name of Material Guide ID No. NO. Sodium sulfide, with less than 135 1385 30% waterof crystallization ^Arliiim cnlnhiHo a n hurl rni i c juuiuiii b u 1 |J M 1 u c , el [ I [ I y u I u u b loo 13ob Sodium sulphide, hydrated, with 153 1849 n rtl - lore |-h a n 3 f\ 0/. iai ^ far MUL Ic55 Llldll jU/o WdLcl Sodium sulphide, with less than 135 1385 30% water of crystallization Q n H i 1 1 m c 1 1 n rn y irl JUUIUIII bUUClUAIUt. ■ to T C A 1 Solids containing corrosive 154 3244 1 i n 1 1 i H n a c 1 ll| U IU , M . u . b . Solids containing flammable 133 3175 I in 1 1 irl n n c I I L| U 1 U , II.U.b> Solids containing poisonous 151 3243 liquid, n.o.s. Solids containing toxic liquid, n.o.s. 151 3243 Soman 153 2810 Stannic chloride, anhydrous 137 1827 Stannic chloride, pentahydrate 154 2440 Stannic phosphides 139 1433 C H K i n Q J UD 111 c ny 2676 Straw, wet, damp or 133 1327 contaminated with oil Strontium arsenite 151 1691 Strontium chlorate 143 1506 Strontium chlorate, solid 143 1506 Strontium chlorate, solution 143 1506 Strontium nitrate 140 1507 Strontium perchlorate 140 IjUo Strontium peroxide 143 1509 Strontium phosphide 139 2013 Strychnine 151 i cm 1692 Strychnine salts 151 i cm 1692 S turpnp monom pr inhihitpd J LV 1 CIIC IIIUIIUIIICI, IIIIIIUI LC U 128P 2055 Styrene monomer, stabilized 128P 2055 Name of Material Guide ID No. No. Substances, which in contact 138 3129 with wateremitflammable gases, liquid, corrosive, n.o.s. Substances, which in contact 138 3148 with wateremitflammable gases, liquid, n.o.s. Substances, which in contact 139 3130 with wateremitflammable gases, liquid, poisonous, n.o.s. Substances, which in contact 139 3130 with wateremitflammable gases, liquid, toxic, n.o.s. Substances, which in contact 138 3131 with wateremitflammable gases, solid, corrosive, n.o.s. Substances, which in contact 138 3132 with wateremitflammable gases, solid, flammable, n.o.s. Substances, which in contact 138 2813 with wateremitflammable gases, solid, n.o.s. Substances, which in contact 138 3133 with wateremitflammable gases, solid, oxidizing, n.o.s. Substances, which in contact 139 3134 with wateremitflammable gases, solid, poisonous, n.o.s. Substances, which in contact 138 3135 with wateremitflammable gases, solid, self-heating, n.o.s. Substances, which in contact 139 3134 with wateremitflammable gases, solid, toxic, n.o.s. Substituted nitrophenol 131 2780 pesticide, liquid, flammable, poisonous Page 158 Name of Material Guide ID Substituted nitrophenol 131 pesticide, liquid, flammable, toxic Substituted nitrophenol 153 pesticide, liquid, poisonous Substituted nitrophenol 131 pesticide, liquid, poisonous, flammable Substituted nitrophenol 153 pesticide, liquid, toxic Substituted nitrophenol 131 pesticide, liquid, toxic, flammable Substituted nitrophenol 153 pesticide, solid, poisonous Substituted nitrophenol 153 pesticide, solid, toxic Sulfamic acid 154 Sulfur 133 Sulfur, molten 133 Sulfurchlorides 137 Sulfurdioxide 125 Sulfurdioxide, liquefied 125 Sulfurhexafluoride 126 Sulfuric acid 137 Sulfuric acid, fuming 137 Sulfuric acid, fuming, with less 137 than 30% free Sulfur trioxide Sulfuric acid, fuming, with not 137 less than 30% free Sulfur trioxide Sulfuric acid, spent 137 Sulfuric acid, with more than 137 51% acid Sulfuric acid, with notmore than 157 51% acid Name of Material Guide ID No. No. 2780 3014 3013 3014 3013 2779 2779 2967 1350 2448 1828 1079 1079 1080 1830 1831 1831 1831 1832 1830 2796 Sulfuric acid and Hydrofluoric acid mixture 157 1786 Su Su Su Su Su Su Su i Su Su Su Su Su Su Su Su Su Su Su Su l Su i Su Su Su l Su Su furousacid 154 1833 furtetrafluoride 125 2418 furtrioxide 137 1829 furtrioxide, inhibited 137 1829 furtrioxide, stabilized 137 1829 furtrioxide, uninhibited 137 1829 furtrioxide and 137 1754 Chlorosulfonic acid mixture furyl chloride 137 1834 furyl fluoride 123 2191 phamicacid 154 2967 phur 133 1350 phur, molten 133 2448 phurchlorides 137 1828 phurdioxide 125 1079 phurdioxide, liquefied 125 1079 phurhexafluoride 126 1080 phuricacid 137 1830 phuric acid, fuming 137 1831 phuric acid, fuming, with less 137 1831 than 30% free Sulphur trioxide phuric acid, fuming, with not 137 1831 less than 30% free Sulphur trioxide phuric acid, spent 137 phuric acid, with more than 137 51% acid phuric acid, with notmore than 51% acid phuric acid and Hydrofluoric acid mixture phurous acid Sulphurtetrafluoride 157 157 154 125 1832 1830 2796 1786 1833 2418 Page 159 Name of Material Guide ID Name of Material Guide ID No. NO. No. NO. Sulphur trioxide 137 1829 Tetrafluoroethane and Ethylene 126 3299 S ulphurtrioxide, inhibited 137 1829 oxide mixture, with notmore than 5.6% Ethylene oxide Sulphur trioxide, stabilized 137 1 R?Q Tetrafluoroethylene, inhibited 116P 1081 S ulphur trioxid e, uninhibited 137 1829 Tetrafluoroethylene, stabilized 116P 1081 Sulphurtrioxide and 137 1 7 C hlorosulphonic acid mixture Tetrafluoromethane 126 1982 Sulphuryl chloride 137 1834 Tetrafluoromethane, 126 1982 Sulphuryl fluoride 123 2191 compressed 2498 1,2,3,6-Tetrahydro- 129 Tabun 153 2810 benzaldehyde Tars, liquid 130 1999 Tetrahydrofuran 127 2056 Teargas candles 159 1700 Tetrahydrofurfurylamine 129 2943 Teargas devices 159 1693 Tetrahydrophthalic anhydrides 156 2698 Teargas grenades 159 1700 1,2,3,6-Tetrahydropyridine 129 2410 Teargas substance, liquid, 159 1693 1,2,5,6-Tetrahydropyridine 129 2410 n.o.s. Tetrahydrothiophene 130 2412 Teargas substance, solid, n.o.s. 159 1693 153 1835 Tetramethylammonium Teargas substance, solid, n.o.s. 159 3448 hydroxide Tellurium compound, n.o.s. 151 3284 Tetramethylammonium 153 3423 T a 1 1 1 1 i"i 1 1 iyi kiav^fliirtriHa i enurium ricxaiiuoriuc l£D 2195 hydroxide, solid \ cipciic n yu roc a r uori b , n.o.s. 2319 Tetramethylammonium 153 1835 Terpinolene 2541 hydroxide, solution i ecrauromoecnane 2504 Tetramethylsilane 130 2749 1,1,2,2-Tetrachloroethane 151 1702 Tetranitromethane 143 1510 T o tra r h 1 a rA o t"h a n o 1 CU a L 1 1 IU 1 UCU 1 □ 1 Ic to 1 1702 Tetrapropylorthotitanate 128 2413 Totrar h Ia rAohh \/lo n o 1 CLI CILIIIUI UCLIIylCIIC 1897 Textile waste, wet 133 1857 Tflt"raQt"hwl rlit"hiAnurAnhAcnhat"0 1 cLIdcLllyl UlLIIIUpylUpilUbpildLc ISO 1704 Thallium chlorate 141 2573 Tetraethyl dithiopyrophosphate, 153 1704 Thallium compound, n.o.s. 151 1707 mixture, dry or liquid Thallium nitrate 141 2727 Tetraethylenepentamine 153 2320 Thallium sulfate, solid 151 1707 Tetraethyl lead, liquid 131 1649 Thallium sulphate, solid 151 1707 Tetraethyl pyrophosphate, liquid 152 3018 4-Thiapentanal 152 2785 Tetraethyl pyrophosphate, solid 152 2783 Thia-4-pentanal 152 2785 Tetraethyl silicate 129 1292 Thickened G D 153 2810 1,1,1,2-Tetrafluoroethane 126 3159 Thioacetic acid 129 2436 Page 160 Name of Material Guide ID No. No. Name of Material Guide ID No. No. Thiocarbamate pesticide, liquid, 131 2772 Titaniumspongegranules 170 2878 flammahlp n n k n n n 1 1 <; Titanium sponge powders 170 2878 Thiocarbamate pesticide, liquid, 131 2772 T i ra n i 1 1 m sulfate s ft 1 1 1 H ft n 1 1 LCI 1 1 1 U 1 1 1 J U 1 1 CI LC , J U 1 U LI U 1 1 1760 flammable, toxic Titanium sulphate, solution 154 1760 Thiocarbamate pesticide, liquid, 151 3006 ±030 poisonous Tiraniiim rptrarhlnrirlp 1 ilciiiiuim lcuciliiiuiiuc 1t7 Thiocarbamate pesticide, liquid, 131 3005 Titanium trichloride, pyrophoric 135 2441 poisonous, flammable Titanium trichloride mixture 157 2869 Thiocarbamate pesticide, liquid, 151 3006 Titanium trichloride mixture, 135 2441 toxic pyrophoric Thiocarbamate pesticide, liquid, 131 3005 TNT, wetted with notless than 113 3366 toxic, flammable 10% water Thiocarbamate pesticide, solid, 151 2771 TNT, wetted with notless than 113 1356 poisonous 30% water i niocaruamai.e pes tic iq 6 , sona, 0771 Li / 1 Toe puffs, nitrocellulose base 133 1353 toxic Toluene won 130 1 Tflfl Thioglycol 153 2966 9 A-T aI i ip npH ia m inp £,4 1 Ul UC 1 1 CU Id 1 II II 1 c 1 70Q 1 / U 3 Th inn Ivrn Mr arid 1 llluyiyLUIIL CI L 1 U IJO 1940 Toluenediisocyanate 156 2078 1 M 10 Id I III d L 1 U I DO z y j o Toluene sulfonic acid, liquid, 153 2584 Thinnvl rhlnrirlp 1 1 1 1 U M y 1 L 1 1 1 U 1 1 u c 1*17 iJ/ 1836 with more than 5% free Thiophene 130 2414 Sulfuric acid Thiophosgene 157 2474 Toluene sulfonic acid, liquid, 153 2586 with not more than 5% free Thiophosphoryl chloride 157 lo3/ Sulfuric acid Thiourea dioxide HOC loo 1 1 A 1 Toluene sulfonic acid, solid, with 153 2583 Thorium metal, pyrophoric 162 2975 more than 5% free Sulfuric Thorium nitratp solid 1 IIUIIUMI 1 1 1 LI CI LC , JUI1U 162 2976 acid Tinctures, medicinal 127 1293 Toluene sulfonic acid, solid, with 153 2585 notmore than 5% free Sulfuric Tin tetrachloride 137 1827 acid Tin tetrachloride, pentahydrate •i CA 104 ~i a a n Z44U Toluene sulphonic acid, liquid, 153 2584 Titanium disulfide 135 3174 with more than 5% free Titanium disulphide 135 3174 Sulphuric acid Titanium hvrlrirlp I lci 1 1 1 u 1 1 1 I y u I I u c 170 1871 Toluene sulphonic acid, liquid, with notmore than 5% free 153 2586 Titanium powder, dry 135 2546 Sulphuric acid Titanium powder, wetted with 170 1352 not less than 25% water Page 161 Name of Material Guide NO. ID NO. Toluene sulphonic acid, solid, with more than 5% free S ulphuric acid 153 2583 Toluene sulphonic acid, solid, with not more than 5% free S ulphuric acid 153 2585 Toluidines 153 1708 Toluidines, liquid 153 1708 Toluidines, solid 153 1708 Toluidines, solid 153 3451 2,4-Toluylenediamine H EH 151 i /uy 2,4-Toluylenediamine, solid H EH 151 i /uy 2,4-Toluylenediamine, solution H EH 151 3 A 1 Toxic by inhalation liquid, corrosive, n.o.s. (Inhalation Hazard Zone A) 154 3389 Toxic by inhalation liquid, corrosive, n.o.s. (Inhalation Hazard Zone B) 154 3390 Toxic by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone A) 131 3383 Toxic by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone B) 131 3384 Toxic by inhalation liquid, n.o.s. (Inhalation Hazard Zone A) 151 3381 Toxic by inhalation liquid, n.o.s. (Inhalation Hazard Zone B) 151 3382 Toxic by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone A) 142 3387 Toxic by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B) 142 3388 Name of Material Guide ID No. No. Toxic by inhalation liquid, 139 3385 water-reactive, n.o.s. (Inhalation Hazard Zone A) Toxic by inhalation liquid, 139 3386 water-reactive, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, corrosive, 154 3289 inorganic, n.o.s. Toxic liquid, corrosive, 154 3289 inorganic, n.o.s. (Inhalation Hazard Zone A) Toxic liquid, corrosive, 154 3289 inorganic, n.o.s. (Inhalation Hazard Zone B) Toxic liquid, corrosive, organic, 154 2927 n.o.s. Toxic liquid, corrosive, organic, 154 2927 n.o.s. (Inhalation Hazard Zone A) Toxic liquid, corrosive, organic, 154 2927 n.o.s. (Inhalation Hazard ZoneB) Toxic liquid, flammable, n.o.s. 131 2929 Toxic liquid, flammable, n.o.s. 131 2929 (Inhalation Hazard Zone A) Toxic liquid, flammable, n.o.s. 131 2929 (Inhalation Hazard Zone B) Toxic liquid, flammable, organic, 131 2929 n.o.s. Toxic liquid, flammable, organic, 131 2929 n.o.s. (Inhalation Hazard Zone A) Toxic liquid, flammable, organic, 131 2929 n.o.s. (Inhalation Hazard ZoneB) Toxic liquid, inorganic, n.o.s. 151 3287 Toxic liquid, inorganic, n.o.s. 151 3287 (Inhalation Hazard Zone A) Page 162 Name of Material Guide ID No. No. Toxic liquid, inorganic, n.o.s. (Inhalation Hazard Zone B) 151 3287 Toxic liquid, n.o.s. 153 2810 Toxic liquid, n.o.s. (Inhalation Hazard Zone A) 153 2810 Toxic liquid, n.o.s. (Inhalation Hazard Zone B) 153 2810 Toxic liquid, organic, n.o.s. 153 2810 Toxic liquid, organic, n.o.s. (Inhalation Hazard Zone A) 153 2810 Toxic liquid, organic, n.o.s. (Inhalation Hazard Zone B) 153 2810 Toxic liquid, oxidizing, n.o.s. 142 3122 Toxic liquid, oxidizing, n.o.s. (Inhalation Hazard Zone A) 142 3122 Toxic liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B) 142 3122 Toxic liquid, water-reactive, n n c 139 3123 Toxic liquid, water-reactive, n.o.s. (Inhalation Hazard 7 An o A \ 139 3123 Toxic liquid, water-reactive, n.o.s. (Inhalation Hazard 7nnp R \ Z.UIIC D ] 139 3123 Toxic liquid, which in contact with wateremits flammable gases, n.o.s. 139 3123 Toxic liquid, which in contact with wateremits flammable gases, n.o.s. (Inhalation Hazard Zone A) 139 3123 Toxic liquid, which in contact with wateremits flammable gases, n.o.s. (Inhalation Hazard Zone B) 139 3123 Toxic solid, corrosive, inorganic, 154 3290 n.o.s. Name of Material Guide ID No. IMO. Toxic solid, corrosive, organic, 154 2928 n.o.s. Toxir solid flammahlp n o s I UAIL J U I I U | 1 1 U 1 1 1 1 1 1 U IJ 1 V- i 1 1 . U . J . 134 2930 Toxic solid, flammable, organic, 134 2930 n.o.s. Toxic solid, inorganic, n.o.s. 151 jZoo Toxic solid, organic, n.o.s. 154 Toxic solid, oxidizing, n.o.s. 141 Tnxir ^nlid ^plf-hpatinn n o <; 1 U A 1 U J UMU , JC 1 1 1 C □ LI 1 1 U , I.U.J. 136 j 1 1 A 3124 Toxic solid, water-reactive, 139 3125 n a c II . U .j . Toxic solid, which in contactwith 139 3125 wateremits flammable gases, n.o.s. Toxins 153 Toxins, extracted from living 153 3172 sources, liquid, n.o.s, Toxins, extracted from living 153 3172 c nil rr n o <; .3 U U 1 U C J , I.U.J. Toxins, extracted from living 153 3172 c.ourrpc. c.olid n o $ Toxins, extracted from living 153 3462 sources, solid, n.o.s. Tria llylamine 132 ZDlU Triallvl horatp I I I □ 1 1 y I u u I □ lc 156 zouy Triazine pesticide, liquid, lol 2764 flammahlp noknnnnc; IIUllllllUUIC, UUIJUMUU J Triazine pesticide, liquid, 131 2764 flammable, toxic Triazine pesticide, liquid, 151 2998 poisonous Triazine pesticide, liquid, 131 2997 poisonous, flammable Triazine pesticide, liquid, toxic 151 2998 Triazine pesticide, liquid, toxic, 131 2997 flammable Name of Material Guide ID NO. NO. Triazine pesticide, solid, 151 2763 poisonous Triazine pesticide, solid, toxic H CH 151 ~i 1 a d Tri-(l-aziridinyl)phosphine oxide, solution 152 2501 Tributylamine H CO 153 Zj4Z Tributylphosphane loo 51 _)4 Tributylphosphine HOC 135 3 1 C A 3ZD4 Trichloroacetic acid 153 1839 Trichloroacetic acid, solution 153 2564 Trichloroacetyl chloride 156 2442 Trichlorobenzenes, liquid 153 2321 Trichlorobutene 152 2322 1,1,1-Trichloroethane 160 2831 Trichloroethylene lou 1 /1U Trichloroisocyanuric acid, dry 140 2468 Trichlorosilane 139 1295 (mono)-(Trichloro)-tetra- 140 2468 (monopotassium dichloro)- penta-s-triazinetrione, dry Tricresyl phosphate H CH 151 Zj /4 Triethylamine HOO 132 1296 Triethylenetetramine H CO 153 zzsy Triethyl phosphite loU L5L5 Trifluoroacetic acid 154 2699 Trifluoroacetyl chloride 125 3057 Trifluorochloroethylene 119P 1082 Trifluorochloroethylene, inhibited 119P 1082 Trifluorochloroethylene, stabilized 119P 1082 1,1,1-Trifluoroethane 115 2035 Trifluoroethane, compressed 115 2035 Trifluoromethane 126 1984 Name of Material Guide ID No. No. Trifluoromethane, refrigerated 120 3136 liquid Trifluoromethane and Chlorotrifluoromethane azeotropic mixture with approximately 60% Chlorotrifluoromethane 126 2599 2-Trifluoromethylaniline 153 2942 3-Trifluoromethylaniline 153 2948 Triisobutylene 128 2324 Triisopropyl borate 129 2616 Trimethoxysilane 132 9269 Trimethylacetyl chloride 132 2438 Trimethylamine, anhydrous H H O 118 1083 Trimethylamine, aqueous solution 132 1297 1,3,5-Trimethylbenzene 129 2325 Trimethyl borate 129 2416 T rimethylc hloros ilane 155 1 1 no 129o Trimethylcyclohexylamine 153 2326 Trimethylhexamethylenedia mines 153 2327 Trimethylhexamethylene diisocyanate 156 2328 Trimethyl phosphite 130 2329 Trinitrobenzene, wetted with not less than 10% water 113 3367 Trinitrobenzene, wetted with not less than 30% water 113 1354 Trinitrobenzoic acid, wetted with notless than 10% water 113 3368 Trinitrobenzoic acid, wetted with notless than 30% water 113 1355 Trinitrochlorobenzene, wetted with notless than 10% water 113 3365 Trinitrophenol, wetted with not 113 3364 less than 10% water Name of Material Guide ID Name of Material Guide ID No. No. No. No. Trinitrophenol, wetted with not less than 30% water Trinitrotoluene, wetted with not less than 10% water Trinitrotoluene, wetted with not It j J LI 1 CI 1 1 JU /D vv LC 1 113 113 113 1344 3366 1356 Valeryl chloride Vanadium compound, n.o.s. Vanadium oxytrichloride Vanadium pentoxide Vanadium tetrachloride 132 151 137 151 137 2502 3285 2443 2862 2444 Trinronvlaminp 1 MfJIUUVIUIIIMIC 132 2260 Vanadium trichloride 157 2475 T ri n rnnulo n o i 1 1 |j i u[j y ic 1 1 c 198 2057 Vanadyl sulfate 151 2931 i n s - \ i-azinciinyijpnos pnme 2501 Vanadyl sulphate 151 2931 oxide, solution \/phirlp f 1 a m m a h 1 p nac nnu/prprl VCIIILIC, lldlllllldUIC L) d j |J U W c [ c U 198 3166 Tunn^ten hexafluoride 125 2196 \/phirlp flammahloliniiirl VCIIILIC, lldlllllldUIC 1 1 1| u 1 u 198 3166 Turoentine 1 \J 1 kj ^, 1 1 LI 1 1 \* 128 1299 powered 1 U 1 |J C 1 1 LI 1 1 C j U U j LI LU Lc 1300 Vinyl acetate 129P 1301 U ndecane 128 2330 Vinyl acetate, inhibited 129P 1301 Uranium hovafhiAfirlo U 1 d 1 1 1 U 1 1 1 IICAdllUUIlUC -ICC loo 2978 Vinyl acetate, stabilized 129P 1301 Uranium hexafluoride, fissile 166 2977 Vinyl bromide, inhibited 116P 1085 containing more than 1% Uranium-235 Vinyl bromide, stabilized Vinyl butyrate, inhibited Vinyl butyrate, stabilized 116P 129P 129P 1085 2838 2838 Uranium hexafluoride, fissile- excepted 166 2978 Uranium hexafluoride, low cnorifir arHvih/ j[JCLlllL dLLlVILy 166 2978 Vinyl chloride, inhibited Vinyl chloride, stabilized 116P 116P 1086 1086 Uranium hexafluoride, non- 166 2978 Vinyl chloroacetate 155 2589 fissile Vinul pthvl pthpr v ill y I CLiiyi c u I c Vinyl ethyl ether, inhibited 127P 1302 Uranium metal, pyrophoric 162 2979 127P 1302 Uranium nitrate, hexahydrate, solution Uranyl nitrate, hexahydrate, c n 1 r i f i n n 162 162 2980 2980 Vinyl ethyl ether, stabilized Vinyl fluoride, inhibited Vinyl fluoride, stabilized 127P 116P 116P 1302 1860 1860 Uranyl nitrate, solid 162 2981 Vinylidene chloride, inhibited 130P 1303 Ulcd 11 y u 1 y c 11 pclUXluc Urea nitrate, wetted with not less 1 /in 113 1511 3370 Vinylidene chloride, stabilized Vinyl isobutyl ether 130P 127P 1303 1304 t"h a n 1 0% \m ahor Lll d II 1 U /o W d Lcl \/ i n \/ 1 i c n h 1 1 h/ 1 p t"h p r i n h i h i hp rl v iiiyi ouuuiyi c u i c i , iiiiiiuilcu 197P 1304 1 1 a n i Ira ho w o ffo H \w iHi n a f 1 o c c U I CO IIILIGLC, VVCLLCU VV 1 LI 1 IIULIC33 11"? 1 1 o 1357 Vinvl i^nhnh/l p t"h p r s fa h i 1 i 7 p H V Illyl J U U U Ly CLIICI , J LO U 1 1 1 L c u 127P 1304 than 20% water Vinyl methyl ether 116P 1087 Valeraldehyde Hon 129 2058 Vinyl methyl ether, inhibited 116P 1087 Page 165 Name of Material Guide ID No. No. Vinyl methyl ether, stabilized 116P 1087 Vinylpyridines, inhibited 131P 3073 Vinylpyridines, stabilized 131P 3073 Vinyltoluenes, inhibited 130P 2618 Vinyltoluenes, stabilized 130P 2618 Vinyltrichlorosilane 155P 1305 Vinyltrichlorosilane, inhibited 155P 1305 Vinyltrichlorosilane, stabilized 155P 1305 VX 153 2810 Water-reactive liquid, corrosive, loo 3 1 *) Q n.o.s. Water-reactive liquid, n.o.s. loo 3 1 A Q W at-pr.rpa rHwp linilifl Hon lo9 poisonous, n.o.s. \A/ a|-p r. rp arHwp linnirj ffiYir V V U LC 1 CCIIUVC 1 1 U U 1 U , LU AIL, l09 n.o.s. Water-reactive solid, corrosive, loo 3131 n.o.s. Water-reactive solid, flammable, IOO n.o.s. Water-reactive solid, n.o.s. 138 2813 Water-reactive solid, oxidizing, loo j 1 j j n.o.s. Water-reactive solid, poisonous, jl j4 n.o.s. Water-reactive solid, self- IOO j 1 j J heating, n.o.s. Water-reactive solid, toxic, n.o.s 139 3134 Water-reactive substances, 138 3129 liquid, corrosive, n.o.s. Water-reactive substances, 138 3148 liquid, n.o.s. Water-reactive substances, 139 3130 liquid, poisonous, n.o.s. Water-reactive substances, 139 3130 liquid, toxic, n.o.s. Name of Material Guide ID No. No. Water-reactive substances, 138 solid, corrosive, n.o.s. Water-reactive substances, 138 solid, flammable, n.o.s. Water-reactive substances, 138 solid, n.o.s. Water-reactive substances, 138 solid, oxidizing, n.o.s. Water-reactive substances, 139 solid, poisonous, n.o.s. Water-reactive substances, 138 solid, self-heating, n.o.s. Water-reactive substances, 139 solid, toxic, n.o.s. Wheelchair, electric, with 154 batteries White asbestos 171 White phosphorus, dry 136 White phosphorus, in solution 136 White phosphorus, molten 136 White phosphorus, underwater 136 Wood preservatives, liquid 129 Wool waste, wet 133 Xanthates 135 Xenon 121 Xenon, compressed 121 Xenon, refrigerated liquid 120 (cryogenic liquid) Xylenes 130 Xylenols 153 Xylenols, liquid 153 Xylenols, solid 153 Xylidines 153 Xylidines, liquid 153 Xylidines, solid 153 3131 3132 2813 3133 3134 3135 3134 3171 2590 1381 1381 2447 1381 1306 1387 3342 2036 2036 2591 1307 2261 3430 2261 1711 1711 1711 Page 166 Name of Material Guide ID Name of Material Guide ID No. No. No. No. Xylidines, solid 153 3452 Zinc resinate 133 2714 Xylyl bromide 152 1701 Zinc silicofluoride 151 2855 Y\/l\/l hrAmirlo liniiirl Ayiyi UIUIIIIUC, IILjUlU loi 1701 7 i n r cUmminnc L 1 1 1 L bMMIMIIMyb I op IOO 1435 Ayiyi UIUIIIIUC, J U 1 1 u 152 3417 7irrnninm rlrv rnilprl wirp Z-IILUIIIUIII, U 1 y , L U 1 1 C U Vv 1 1 C , 170 2858 Yellow phosphorus, dry 136 1381 finished metal sheets orstrips Yellow phosphorus, in solution 136 1381 Zirconium, dry, finished sheets, 135 2009 strips orcoiled wire Yellow phosphorus, molten 136 2447 138 1437 Zirconium hydride Yellow phosphorus, underwater 136 1381 Zirconium metal, liquid 170 1308 Zinc ammonium nitrite 140 1512 Clicnpncjnn Zinc arsenate 151 1712 Zirconium metal, powder, wet 170 1358 Zinc arsenate and Zinc arsenite 151 1712 Zirconium nitrate 2728 mixture Zirconium picramate, wetted 113 1517 Zinc arsenite 151 1712 with not less than 20% water Zinc arsenite and Zinc arsenate mixture 151 1712 Zirconium powder, dry loo 2008 Zirconium powder, wetted with 170 1358 Zinc ashes 138 1435 nnHpc;c; than ?S% watpr IIUl ICJJ U 1 U 1 1 L. J /U 111 □ ICI Zinc bromate 140 2469 7irroniiim crran i-IILUIIIUIN b L 1 U IOO 1932 Zinc chlorate 140 1513 7 i rr n n i 1 1 m 1 1 If a fp Z_MLUIMUIII j U 1 1 □ IC 171 9163 Zinc chloride, anhydrous 154 2331 7 i rv a n i 1 1 m c 1 1 1 n h a t~o Z.IILUIIIUIII b u 1 u 1 1 d Lc 171 I f I 9163 Zinc chloride, solution 154 1840 Zirconium suspended in a 170 1308 Zinc cyanide 101 1713 fl a m m ;» h Ip liniiirl iidiiiiiiduic i lUj u iu z.inc aicnionite 1 l\ 1931 7irrnninm cMKnpnrlprl in a liniiirl £-IILUIIIUIII jUjUCIIUCU III □ IIUUIU 170 1308 Zinc dross 138 1435 (flammable) Zinc dust 138 1436 Zirconium tetrachloride 137 2503 Zincfluorosilicate 151 2855 Zinc hydrosulfite 171 1931 Zinc hydrosulphite 171 1931 Zinc nitrate 140 1514 Zinc permanganate 140 1515 Zinc peroxide 143 1516 Zinc phosphide 139 1714 Zinc powder 138 1436 Zinc residue loo 1435 NOTES ERG2004 GUIDE GUIDES GUIDE Mixed Load/Unidentified Cargo ERG2004 111 POTENTIAL HAZARDS FIRE OR EXPLOSION • May explode from heat, shock, friction or contamination. • May react violently or explosively on contact with air, water or foam. • Maybeignitedbyheat, sparks or flames. • Vapors may travel to source of ignition and flash back. • Containers may explode when heated. • Ruptured cylinders may rocket. HEALTH • Inhalation, ingestion or contact with substance may cause severe injury, infection, disease or death. • High concentration of gas may cause asphyxiation withoutwarning. • Contactmaycauseburnstoskinandeyes. • Fire or contact with water may produce irritating, toxic and/or corrosive gases. • Runoff from fire control may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • 5tay upwind. • Keep out of low areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCBA). • Structural firefighters' protective clothing provides limited protection in fire situations N LY ; it may not be effective in spill situations. EVACUATION Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Mixed Load/Unidentified Cargo GUIDE 111 EMERGENCY RESPONSE FIRE CAUTION: Material may react with extinguishing agent. Small Fires • Dry chemical, C0 2 , water spray or regular foam, Large Fires • Waterspray, fog or regularfoam. • Move containers from fire area if you can do it without risk. Fire involving Tanks • Cool containers with flooding quantities of water until well after fire is out. • Do notgetwaterinside containers. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Do not touch or walk thro ugh spilled mate rial. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area), • All equipment used when handling the product must be grounded. • Keep combustibles (wood, paper, oil, etc.) away from spilled mate rial. • Use waterspray to reduce vapors ordivertvaporcloud drift. Avoid allowing water runoff to contact spilled material. • P re vent entry into waterways, sewers, basements or confined areas. Small Spills 'Take up with sand or other non-combustible absorbent material and place into containers for later disposal. Large Spills • Dike far ahead of liquid spill for later disposal. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • G ive artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Shower and wash with soap and water. • Keep victim warm and quiet. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Explosives* -Division 1.1, 1.2, 1.3, 1.5 or ERG2004 112 1 ^' Class A or B POTENTIAL HAZARDS FIRE OR EXPLOSION • MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO. • For information on "Compatibility Group" letters, refer to Glossary section. HEALTH • Fire may produce irritating, corrosive and/or toxic gases. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • Isolate spill or leak area immediately for at least 500 meters (1/3 mile) in all directions. • Move people out of line of sigh t of the scene and a way from windows. • Keep unauthorized personnel away. • Stayupwind. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial evacuation for 800 meters (1/2 mile) in all directions. Fire • If rail car or trailer is involved in a fire and heavily encased explosives such as bombs or artillery projectiles are suspected, ISOLATE for 1600 m (1 mile) in all directions; also, initiate e vacua tion including emergency res ponders for 1600 m (1 mile) in all directions. • When heavily encased explosives are not involved, evacuate the area for 800 meters (1/2 mile) in all directions. * For information on "Compatibility Group" letters, refer to the Glossary section. ERG2004 Explosives* -Division 1.1, 1.2, 1.3, 1.5 or GUIDE 1.6; Class A or B ]]2 EMERGENCY RESPONSE FIRE CARGO Fires • DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! • Stop all traffic and clearthe area foratleast 1600 meters (1 mile) in all directions and let burn. • Do notmove cargo orvehicle if cargo has been exposed to heat. TIRE or VEHICLE Fires • Use plenty of water - FLOOD it! If water is not available, use CO , dry chemical or dirt. • If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum distance to preventfire from spreading to cargo area. • Payspecial attention to tire fires as re-ignition may occur. Stand by with extinguisher ready. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when hand ling the product must be grounded. • Do nottouchorwalk through spilled material. • DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 meters (330 feet) OF ELECTRIC DETONATORS. • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. * For information on "Compatibility Group" letters, refer to the Glossary section. GUIDE Flammable Solids - Toxic 113 (Wet/Desensitized Explosive) ERG2004 POTENTIAL HAZARDS FIRE OR EXPLOSION Flammable/combustible material. May be ignited by heat, sparks or flames. DRIED OUT material may explode if exposed to heat, flame, friction or shock; Treat as an explosive (GUIDE 112). Keep material wet with water or treat as an explosive (GUIDE 112). Runoffto sewer may create fire orexplosion hazard. HEALTH Some a re toxic and may be fata I if inhaled, swallowed or absorbed thro ugh skin. Con tact may cause burns to skin and eyes. Fire mayproduce irritating, corrosive and/or toxic gases. R unoff from fire control or dilution water may cause pollution. PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Isolate spill or leak area immediately for at least 100 meters (330 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Ventilate closed spaces before entering. PROTECTIVE CLOTHING Wear positive pressure self-contained breathing apparatus (SCB A). Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill Consider initial evacuation for 500 meters (1/3 mile) in all directions. Fire If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Flammable Solids -Toxic GUIDE (Wet/Desensitized Explosive) 1 1 ^ EMERGENCY RESPONSE FIRE CARGO Fires • DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! • Stop all traffic and clear the area for at least 800 meters (1/2 mile) in all directions and let burn. • Do not move cargo or vehicle if cargo has been exposed to heat. TIRE or VEHICLE Fires • Use plenty of water - FLOOD it! If water is not available, use CO , dry chemical or dirt. • If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum distance to preventfire from spreading to cargo area. • Payspecial attention to tire fires as re-ignition may occur. Stand by with extinguisher ready. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when hand ling the product must be grounded. • Do nottouchorwalk through spilled material. Small Spills • Flush area with flooding quantities of water. Large Spills • Wet down with water and dike for later disposal. • KEEP "WETTED" PRODUCT WET BY SLOWLY ADDING FLOODING QUANTITIES OF WATER. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Explosives* - Division 1 .4; Class C ERG2004 114 POTENTIAL HAZARDS FIRE OR EXPLOSION • MAY EXPLODE AND THROW FRAGMENTS 500 meters (1/3 MILE) OR MORE IF FIRE REACHES CARGO. • For information on "Compatibility Group" letters, refer to Glossary section. HEALTH • Fire may produce irritating, corrosive and/or toxic gases. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • Isolate spill or leak area immediately for at least 100 meters (330 feet) in all directions. • Move people out of line of sigh t of the scene and a way from windows. • Keep unauthorized personnel away. • Stayupwind. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial evacuation for 250 meters (800 feet) in all directions. Fire • If rail car or trailer is involved in a fire, ISOLATE for 500 meters (1/3 mile) in all directions; also initiate evacuation including emergency res ponders for 500 meters (1/3 mile) in all directions. * For information on "Compatibility Group" letters, refer to the Glossary section. ERG2004 Explosives* - Division 1 .4; Class C GUIDE 114 EMERGENCY RESPONSE FIRE CARGO Fires • DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! • Stop all traffic and clear the area for at least 500 meters (1/3 mile) in all directions and let | burn. • Do not move cargo or vehicle if cargo has been exposed to heat. TIRE or VEHICLE Fires • Use plenty of water - FLOOD it! If water is not available, use CO , dry chemical or dirt. • If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum distance to preventfire from spreading to cargo area. • Payspecial attention to tire fires as re-ignition may occur. Stand by with extinguisher ready. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when hand ling the product must be grounded. • Do nottouchorwalk through spilled material. • DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 meters (330 feet) OF ELECTRIC DETONATORS. • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. SUPPLEMENTAL INFORMATION Packages bearing the 1.4S label or packages containing material classified as 1.4S are designed or packaged in such a manner that when involved in a fire, may burn vigorously with localized detonations and projection of fragments. Effects are usually confined to immediate vicinity of packages. If fire threatens cargo area containing packages bearing the 1.4S label or packages containing material classified as 1.45, consider isolating at least 15 meters (50 feet) in all directions. Fight fire with normal precautions from a reasonable distance. * For information on "Compatibility Group" letters, refer to the Glossary section. Page 177 GUIDE Gases - Flammable ERG2004 11c (Including Refrigerated Liquids) POTENTIAL HAZARDS FIRE OR EXPLOSION • extremely flammable. • Will be easily ignited by heat, sparks or flames. • Will form explosive mixtures with air. • Vapors from liquefied gas are initially heavier than air and spread along ground. CAUTION: Hydrogen (UN1049), Deuterium (UN1957) and Methane (UN1971) are lighter than air and will rise. Hydrogen and Deuterium fires are difficult to detect since they burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.) • Vapors may travel to source of ignition and flash back. • Cylinders exposed to fire may vent and re lease flammable gas thro ugh pressure re lief devices. • Containers may explode when heated. • Ruptured cylinders may rocket. HEALTH • Vapors may cause dizziness or asphyxiation without warning. • Somemaybe irritating if inhaled at high concentrations. • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Fire may produce irritating and/ortoxic gases. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leakarea foratleast 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • Stayupwind. • Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). • Keep out of low areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. • Always wearthermal protective clothing when handling refrigerated/cryogenic liquids. EVACUATION Large Spill • Consider initial downwind evacuation for at least 800 meters (1/2 mile). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions. ERG2004 Gases - Flammable GUIDE (Including Refrigerated Liquids) i 1 c EMERGENCY RESPONSE FIRE • DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. CAUTION: Hydrogen (UN1049) and Deuterium (UN1957) burn with an invisible flame. Small Fires • Dry chemical or C0 2 . Large Fires • Water spray or fog. • Move containers from fire area if you can do it without risk. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Do notdirectwateratsource ofleakorsafety devices; icing mayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when hand ling the product must be grounded. • Do nottouchorwalk through spilled material. • Stop leak if you can do it without risk. • If possible, turn leaking containers so thatgas escapes ratherthan liquid. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • Do not direct wateratspill or source of leak. • Preventspreading of vapors through sewers, ventilation systems and confined areas. • Isolate area until gas has dispersed. CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are likely to break without warning. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • Clothing frozen to the skin should be thawed before being removed. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. • Ensure thatmedical personnel are aware of the material(s) involved and take precautions to protect themselves. GUIDE Gases - Flammable (Unstable) ERG2004 116 POTENTIAL HAZARDS FIRE OR EXPLOSION • EXTREMELY FLAMMABLE. • Will be easily ignited by heat, sparks orflames. • Will form explosive mixtures with air. • Silane will ignite spontaneously in air, • Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. • Vapors from liquefied gas are initially heavier than air and spread a long ground. • Vapors may travel to source of ignition and flash back. • Cylinders exposed to fire may vent and re lease flammable gas thro ugh pressure re lief devices. • Containers may explode when heated. • Ruptured cylinders may rocket. HEALTH • Vapors may cause dizziness or asphyxiation without warning. • Somemaybetoxicifinhaledathighconcentrations. • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Fire may produce irritating and/ortoxic gases, PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • S tay upwind. • Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). • Keep out of low areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 800 meters (1/2 mile). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions. ERG2004 Gases - Flammable (Unstable) GUIDE 116 EMERGENCY RESPONSE FIRE • DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. Small Fires • Dry chemical or C0 2 . Large Fires • Water spray or fog. • Move containers from fire area if you can do it without risk. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Donotdi rectwateratsourceofleakorsafety devices; icingmayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when handling the productmustbe grounded. • Stop leak if you can do it without risk. • Do not touch or walk through spilled material. • Do not direct water at spill or source of leak. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • If possible, turn leaking containers so that gas escapes rather than liquid. • Prevent entry into waterways, sewers, basements or confined areas. • Isolate area until gas has dispersed. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing ifadheringtoskin. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Gases - Toxic - Flammable (Extreme Hazard) ERG2004 117 POTENTIAL HAZARDS HEALTH • TOXIC; Extremely Hazardous. • M ay be fatal if inhaled or absorbed through skin. • Initial odor may be irritating orfoulandmaydeadenyoursenseofsmell. • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Fire will produce irritating, corrosive and/ortoxic gases. • Runoff from fire control may cause pollution. FIRE OR EXPLOSION • These materials are extremely flammable. • M ay form explosive mixtures with air. • Maybeignitedbyheat, sparks or flames. • Vapors from liquefied gas a re initially heavier than air and spread a long ground. • Vapors may travel to source of ignition and flash back. • Runoff may create fire or explosion hazard. • Cylinders exposed to fire may vent and re lease toxic and flammable gas thro ugh pressure relief devices. • Containers may explode when heated. • Ruptured cylinders may rocket. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • Stayupwind. • Many gases are heavierthan airand will spread along ground and collectin low or confined areas (sewers, basements, tanks). • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances. Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions. ERG2004 Gases - Toxic - Flammable (Extreme Hazard) GUIDE 117 EMERGENCY RESPONSE FIRE • DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. Small Fires • Dry chemical, C0 2 , water spray or regular foam, Large Fires • Water spray, fog or regular foam. • Move containers from fire area if you can do it without risk. • Damaged cylinders should be hand led only by specialists. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Do notdirectwateratsource ofleakorsafety devices; icing mayoccur, • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks orflames in immediate area). • All equipment used when handling the product must be grounded. • Fully encapsulating, vapor protective do thing should be worn for spills and leaks with nofire. • Do not touch or walk through spilled material. • Stop leak if you can do it without risk. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • Do notdirectwateratspill orsource ofleak. • If possible, turn leaking containers so thatgas escapes ratherthan liquid. • P re vent entry into waterways, sewers, basements or confined areas. • Isolate area until gas has dispersed. • Consider igniting spill or leak to eliminate toxic gas concerns. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • G ive artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. • Keep victim under observation. • Effects of contactor inhalation may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Gases - Flammable - Corrosive ERG2004 118 POTENTIAL HAZARDS FIRE OR EXPLOSION • EXTREMELY FLAMMABLE. • May be ignited byheat, sparks orflames. • May form explosive mixtures with air. • Vapors from liquefied gas are initially heavier than air and spread along ground. • Vapors may travel to source of ignition and flash back. • S ome of these materials may react violently with water. • Cylinders exposed to fire may vent and re lease flammable gas thro ugh pressure re lief devices . • Containers may explode when heated. • Ruptured cylinders may rocket. HEALTH • M ay cause toxic effects if inhaled. • Vapors are extremely irritating. • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Fire will produce irritating, corrosive and/or toxic gases. • Runoff from fire control may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • 5tay upwind. • Many gases are heavierthan airand will spread along ground and collectin low or confined areas (sewers, basements, tanks). • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Large Spill • Consider initial downwind evacuation for at least 800 meters (1/2 mile). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions. ERG2004 Gases - Flammable - Corrosive GUIDE 118 EMERGENCY RESPONSE FIRE • DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. Small Fires • Dry chemical or C0 2 . Large Fires • Water spray, fog or regular foam. • Move containers from fire area if you can do it without risk. • Damaged cylinders should be hand led only by specialists. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Donotdirectwateratsourceofleakorsafety devices; icingmayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks orflames in immediate area). • All equipment used when handling the product must be grounded. • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. • Do not touch or walk through spilled material. • Stop leak if you can do it without risk. • If possible, turn leaking containers so thatgas escapes ratherthan liquid. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • Do notdirect water at spill or source of leak. • Isolate area until gas has dispersed. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. • Keep victim under observation. • Effects of contactor inhalation may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Gases - Toxic - Flammable ERG2004 119 POTENTIAL HAZARDS HEALTH • TOXIC; may be fatal if Inhaled or absorbed through skin. • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Fire will produce irritating, corrosive and/ortoxic gases. • R unoff from fire control may cause pollution. FIRE OR EXPLOSION • Flammable; may be ignited by heat, sparks or flames. • May form explosive mixtures with air. • Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. • Vapors from liquefied gas a re initially heavier than air and spread along ground. • Vapors may travel to source of ignition and flash back. • Some of these materials may react violently with water. • Cylinders exposed to fire may vent and release toxic and flammable gas through pressure relief devices. • Containers may explode when heated. • Ruptured cylinders may rocket. • Runoffmaycreatefireorexplosionhazard. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • Stay upwind. • Manygases are heavier than airand will spread along ground and collect in low or confined areas (sewers, basements, tanks). • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCBA). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions. ERG2004 Gases -Toxic- Flammable GUIDE 119 EMERGENCY RESPONSE FIRE • DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. Small Fires • D ry chem ic a I, CO v water spray or alcohol- resistant foam. Large Fires • Water spray, fog or alcohol-resistant foam. • FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium expansion foam. • Move containers from fire area if you can do it without risk. • Damaged cylinders should be hand led only by specialists. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Donotdi rectwateratsourceofleakorsafety devices; icingmayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when handling the product must be grounded. • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. • Do not touch or walk thro ugh spilled mate rial. • Stop leak if you can do it without risk. • Do notdirectwater atspill or source of leak. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce vapors. • If possible, turn leaking containers so that gas escapes rather than liquid. • P re vent en try in to waterways, sewers, basements or confined a re as. • Isolate area until gas has dispersed. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. • Keep victim under observation. • Effects of contactor inhalation may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Gases -Inert 1 20 (Including Refrigerated Liquids) ERG2004 POTENTIAL HAZARDS HEALTH • Vapors may cause dizziness or asphyxiation without warning. • Vapors from liquefied gas a re initially heavier than air and spread a long ground. • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. FIRE OR EXPLOSION • Non-flammable gases. • Containers may explode when heated. • Ruptured cylinders may rocket. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • Stayupwind. • Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks), • Keep out of low areas, • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. • Always wearthermal protective clothing when handling refrigerated/cryogenic liquids or solids. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions, ERG2004 Gases -Inert GUIDE (Including Refrigerated Liquids) 1 on EMERGENCY RESPONSE FIRE • Use extinguishing agent suitable for type of surrounding fire. • Move containers from fire area if you can do it without risk. • Damaged cylinders should be handled only by specialists. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Do notdirectwateratsource ofleakorsafety devices; icing mayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Do nottouch or walk through spilled material. • Stop leak if you can do it without risk. • Usewaterspraytoreducevaporsordivertvaporcloud drift. Avoid allowing water runoff to contact spilled material. • Do notdirect water at spill or source of leak. • If possible, turn leaking containers so thatgas escapes ratherthan liquid. • Prevententry into waterways, sewers, basements orconfined areas. • Allow substance to evaporate. • Ventilate the area. CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are likely to break without warning. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service, • G ive artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Clothing frozen to the skin should be thawed before being removed. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Gases -Inert ERG2004 121 POTENTIAL HAZARDS HEALTH • Vapors may cause dizziness or asphyxiation without warning. • Vapors from liquefied gas a re initially heavier than air and spread a long ground. FIRE OR EXPLOSION • Non-flammable gases. • Containers may explode when heated. • Ruptured cylinders may rocket. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the Inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • Stayupwind. • Many gases are heavierthan airand will spread along ground and collectin low or confined areas (sewers, basements, tanks). • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Gases -Inert GUIDE 121 EMERGENCY RESPONSE FIRE • Use extinguishing agent suitable for type of surrounding fire. • Move containers from fire area if you can do it without risk. • Damaged cylinders should be handled only by specialists. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Do notdirectwateratsource ofleakorsafety devices; icing mayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Do nottouch or walk through spilled material. • Stop leak if you can do it without risk. • Usewaterspraytoreducevaporsordivertvaporcloud drift. Avoid allowing water runoff to contact spilled material. • Do notdirect water at spill or source of leak. • If possible, turn leaking containers so thatgas escapes ratherthan liquid. • Prevententry into waterways, sewers, basements orconfined areas. • Allow substance to evaporate. • Ventilate the area. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Gases -Oxidizing ERG2004 1 22 (Including Refrigerated Liquids) POTENTIAL HAZARDS FIRE OR EXPLOSION • Substa nee does not burn but will support combustion. • Some may react explosively with fuels. • May ignite combustibles (wood, paper, oil, clothing, etc.). • Vapors from liquefied gas a re initially heavier than air and spread a long ground. • Runoff may ere ate fire or explosion hazard. • Containers may explode when heated. • Ruptured cylinders may rocket. HEALTH • Vapors may cause dizziness or asphyxiation without warning. • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Fire may produce irritating and/ortoxic gases. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • S tay upwind. • Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. • Always wearthermal protective clothing when handling refrigerated/cryogenic liquids. EVACUATION Large Spill • Consider initial downwind evacuation for at least 500 meters (1/3 mile). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Gases - Oxidizing GUIDE (Including Refrigerated Liquids) 1 99 EMERGENCY RESPONSE FIRE • Use extinguishing agent suitable for type of surrounding fire. Small Fires • Dry chemical or C0 2 . Large Fires • Waterspray, fog or regularfoam. • Move containers from fire area if you can do it without risk. • Damaged cylinders should be hand led only by specialists. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Donotdirectwateratsourceofleakorsafety devices; icingmayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • Keep combustibles (wood, paper, oil, etc.) awayfrom spilled material. • Do not touch or walk through spilled material. • Stop leak if you can do it without risk. • If possible, turn leaking containers so that gas escapes rather than liquid. • Do not direct water at spill or source of leak. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • Prevent entry into waterways, sewers, basements or confined areas. • Allow substance to evaporate. • Isolate area until gas has dispersed. CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are likely to break without warning. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • Clothing frozen to the skin should be thawed before being removed. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Gases -Toxic and/or Corrosive ERG2004 123 POTENTIAL HAZARDS HEALTH • TOXIC; may be fatal If Inhaled or absorbed through skin. • Vapors may be irritating, • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Fire will produce irritating, corrosive and/or toxic gases. • Runoff from fire control may cause pollution. FIRE OR EXPLOSION • Some mayburn, butnone ignite readily. • Vapors from liquefied gas a re initially heavier than air and spread a long ground. • Cylinders exposed to fire may vent and release toxic and/or corrosive gas through pressure relief devices. • Containers may explode when heated. • Ruptured cylinders may rocket. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the Inside back cover. • As an immediate precautionary measure, isolate spill or leakarea foratleast 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • Stayupwind. • Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Gases -Toxic and/or Corrosive GUIDE 123 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical or C0 2 . Large Fires • Water spray, fog or regularfoam. • Do not get water inside containers, • Move containers from fire area if you can do it without risk. • Damaged cylinders should be hand led only by specialists. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Donotdirectwateratsourceofleakorsafety devices; icingmayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. • Do nottouchorwalk through spilled material. • Stop leak if you can do it without risk. • If possible, turn leaking containers so thatgas escapes ratherthan liquid. • Prevent entry into waterways, sewers, basements or confined areas. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • Do not direct water at spill or source of leak. • Isolate area until gas has dispersed. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Keep victim under observation. • Effects of contactor inhalation may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Gases -Toxic and/or Corrosive -Oxidizing ERG2004 124 POTENTIAL HAZARDS HEALTH • TOXIC; may be fatal if inhaled or absorbed through skin. • Fire will produce irritating, corrosive and/ortoxic gases. • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Runoff from fire control may cause pollution. FIRE OR EXPLOSION • Substa nee does not burn but will support combustion. • Vapors from liquefied gas a re initially heavier than air and spread a long ground. • These are strong oxidizers and will react vigorously or explosively with many materials including fuels. • May ignite combustibles (wood, paper, oil, clothing, etc.). • Some will re act violently with air, moist air and/or water. • Cylinders exposed to fire may vent and re lease toxic and/or corrosive gas thro ugh pressure relief devices. • Containers may explode when heated. • Ruptured cylinders may rocket. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leakarea foratleast 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • Stayupwind. • Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances. Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Gases - Toxic and/or Corrosive - Oxidizing GUIDE 124 EMERGENCY RESPONSE FIRE Small Fires: Water only; no dry chemical, C0 2 or Halon® . • Contain fire and letburn. Iffire mustbe fought, waterspray orfog is recommended. • Do notgetwaterinside containers. • Move containers from fire area if you can do it without risk. • Damaged cylinders should be hand led only by specialists. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Donotdi rectwateratsourceofleakorsafety devices; icingmayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. • Do not touch or walk through spilled material. • Keep combustibles (wood, paper, oil, etc.) a way from spilled material. • Stop leak if you can do it without risk. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • Do not direct water at spill or source of leak. • If possible, turn leaking containers so thatgas escapes ratherthan liquid. • Prevent entry into waterways, sewers, basements or confined areas. • Isolate area until gas has dispersed. • Ventilate the area. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Clothing frozen to the skin should be thawed before being removed. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Keep victim under observation. • Effects of contactor inhalation may be delayed. • E nsure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Gases - Corrosive ERG2004 125 POTENTIAL HAZARDS HEALTH • TOXIC; may be fatal If inhaled, Ingested or absorbed through skin. • Vapors are extremely irritating and corrosive. • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Fire will produce irritating, corrosive and/ortoxic gases. • Runoff from fire control may cause pollution. FIRE OR EXPLOSION • Some mayburn, butnone ignite readily. • Vapors from liquefied gas a re initially heavier than air and spread a long ground. • S ome of these materials may react violently with water. • Cylinders exposed to fire may vent and release toxic and/or corrosive gas through pressure relief devices. • Containers may explode when heated. • Ruptured cylinders may rocket. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • 5tay upwind. • Many gases are heavierthan airand will spread along ground and collectin low or confined areas (sewers, basements, tanks). • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions. ERG2004 Gases - Corrosive GUIDE 125 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical or C0 2 . Large Fires • W a ter s pray , fog or regu la r foa m . • Move containers from fire area if you can do it without risk. • Do not get water inside containers. • Damaged cylinders should be hand led only by specialists. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Donotdirectwateratsourceofleakorsafety devices; icingmayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Fully encapsulating, vapor protective do thing should be worn for spills and leaks with no fire. • Do nottouchorwalk through spilled material. • Stop leak if you can do it without risk. • If possible, turn leaking containers so thatgas escapes ratherthan liquid. • Prevent entry into waterways, sewers, basements or confined areas. • Do not direct water at spill or source of leak. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • Isolate area until gas has dispersed, FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • G ive artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • In case of contact with Hydrogen fluoride, anhydrous (UN1052), flush skin and eyes with waterfor 5 minutes; then, forskin exposures rub on a calcium/jelly combination; for eyes flush with a water/calcium solution for 15 minutes. • Keep victim warm and quiet. • Keep victim under observation. • Effects of contactor inhalation may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Gases -Compressed or Liquefied ERG2004 126 (Including Refrigerant Gases) POTENTIAL HAZARDS FIRE OR EXPLOSION • Some mayburn, butnone ignite readily. • Containers may explode when heated. • Ruptured cylinders may rocket. HEALTH • Vapors may cause dizziness or asphyxiation without warning. • Vapors from liquefied gas a re initially heavier than air and spread a long ground. • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Firemayproduce irritating, corrosive and/or toxic gases. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • S tay upwind. • Many gases are heavierthan airand will spread along ground and collectin low or confined areas (sewers, basements, tanks). • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 500 meters (1/3 mile). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Gases - Compressed or Liquefied GUIDE (Including Refrigerant Gases) 196 EMERGENCY RESPONSE FIRE • Use extinguishing agent suitable for type of surrounding fire. Small Fires • Dry chemical or C0 2 . Large Fires • Waterspray, fog or regularfoam. • Move containers from fire area if you can do it without risk. • Damaged cylinders should be hand led only by specialists. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Donotdirectwateratsourceofleakorsafety devices; icingmayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • Some of these materials, if spilled, may evaporate leaving a flammable residue. SPILL OR LEAK • Do nottouch or walk through spilled material. • Stop leak if you can do it without risk. • Do notdirect water at spill or source of leak. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contactspilled material. • If possible, turn leaking containers so thatgas escapes ratherthan liquid. • P re vent entry into waterways, sewers, basements or confined areas. • Allow substance to evaporate. • Ventilate the area. FIRST AID • Move victim to fresh air. • C all 911 or emergency medical service. • G ive artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. • Keep victim warm and quiet. • E nsure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Flammable Liquids ERG2004 127 (Polar/Water-Miscible) POTENTIAL HAZARDS FIRE OR EXPLOSION • HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. • Vapors mayform explosive mixtures with air. • Vapors may travel to source of ignition and flash back. • Mostvapors are heavierthan air. Theywill spread along ground and collectin low or confined areas (sewers, basements, tanks). • Vaporexplosion hazard indoors, outdoors orin sewers. • Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. • Runoff to sewer may create fire or explosion hazard. • Containers may explode when heated. • Many liquids are lighter than water. HEALTH • Inhalation or contact with material may irritate or burn skin and eyes. • Fire may produce irritating, corrosive and/or toxic gases. • Vapors mayca use dizziness or suffocation. • R unoff from fire control may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. • Keep unauthorized personnel away. • Stayupwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 300 meters (1000 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Flammable Liquids GUIDE (Polar/Water-Miscible) 127 EMERGENCY RESPONSE FIRE CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be Inefficient. Small Fires • Dry chemical, CO 2 , water spray or alcohol-resistant foam. Large Fires • Water spray, fog or alcohol-res is tan t foam. • Use water spray or fog; do not use straight streams. • Move containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when hand ling the product must be grounded. • Do nottouchorwalk through spilled material. • Stop leak if you can do it without risk. • Prevent entry into waterways, sewers, basements or confined areas. • A vapor suppressing foam may be used to reduce vapors. • Absorb or cover with dry earth, sand or other non-combustible material and transferto containers. • Use clean non-sparking tools to collect absorbed material. Large Spills • Dike far ahead of liquid spill for later disposal. • Water spray may reduce vapor; but may not prevent ignition in closed spaces. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Wash skin with soap and water. • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Flammable Liquids ERG2004 1 28 (Non-Polar/Water-Immiscible) POTENTIAL HAZARDS FIRE OR EXPLOSION • HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. • Vapors mayform explosive mixtures with air. • Vapors may travel to source of ignition and flash back. • Mostvapors are heavierthan air. Theywill spread along ground and collectin low or confined areas (sewers, basements, tanks). • Vaporexplosion hazard indoors, outdoors orin sewers. • Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. • Runoff to sewer may create fire or explosion hazard. • Containers may explode when heated. • Many liquids are lighter than water. • Substance may be transported hot. • If molten aluminum is involved, refer to GUIDE 169. HEALTH • Inhalation or contact with material may irritate orburnskinandeyes. • Fire may produce irritating, corrosive and/ortoxic gases. • Vapors may cause dizziness or suffocation. • Runoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast50 meters (150 feet) in all directions. • Keep unauthorized personnel away. • S tay upwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 300 meters (1000 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Flammable Liquids GUIDE (Non-Polar/Water-Immiscible) ] Oft EMERGENCY RESPONSE FIRE CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. CAUTION: For mixtures containing a high percentage of an alcohol or polar solvent, alcohol-resistant foam may be more effective. Small Fires • Dry chemical, C0 2 , water spray or regular foam. Large Fires • Waterspray, fog or regular foam. • Usewatersprayorfog;donotusestraightstreams. • Move containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when hand ling the product must be grounded. • Do not touch or walk through spilled material. • Stop leak if you can do it without risk. • Prevententry into waterways, sewers, basements orconfined areas, • Avaporsupp re ssingfoammaybeused to reduce vapors. • Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. • Use clean no n -sparking tools to collect absorbed material. Large Spills • Dike far ahead of liquid spill for later disposal. • Water spray may reduce vapor; but may not pre vent ignition in closed spaces. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • G ive artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Wash skin with soap and water. • Keep victim warm and quiet. • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Flammable Liquids ERG2004 1 29 (Polar/Water-Miscible/Noxious) POTENTIAL HAZARDS FIRE OR EXPLOSION • HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. • Vapors mayform explosive mixtures with air. • Vapors may travel to source of ignition and flash back. • Mostvapors are heavierthan air. Theywill spread along ground and collectin low or confined areas (sewers, basements, tanks). • Vaporexplosion hazard indoors, outdoors orin sewers. • Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. • Runoff to sewer may create fire or explosion hazard. • Containers may explode when heated. • Many liquids are lighter than water. HEALTH • May cause toxic effects if inhaled or absorbed through skin. • Inhalation or contact with material may irritate or burn skin and eyes. • Fire will produce irritating, corrosive and/ortoxic gases. • Vapors mayca use dizziness or suffocation. • Runoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast50 meters (150 feet) in all directions. • Keep unauthorized personnel away. • S tay upwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 300 meters (1000 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Flammable Liquids GUIDE (Polar/Water-Miscible/Noxious) ] 29 EMERGENCY RESPONSE FIRE CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be Inefficient. Small Fires • Dry chemical, CO v water spray or alcohol-resistant foam. • Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Large Fires • Water spray, fog or alcohol-res is tan t foam. • Do not use straight streams. • Move containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when hand ling the product must be grounded. • Do not touch or walk through spilled material. • Stop leak if you can do it without risk. • Prevententry into waterways, sewers, basements orconfined areas, • A vapor suppressing foam may be used to reduce vapors. • Abso rb or co ve r w ith d ry ea rth, sand or othernon -combustible mate rial and transferto containers. • Use clean non-sparking tools to collect absorbed material. Large Spills • Dike far ahead of liquid spill for later disposal. • Water spray may reduce vapor; but may not pre vent ignition in closed spaces. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Wash skin with soap and water. • Keep victim warm and quiet. • In case of burns, immediately cool affected skin for as long as possible with cold water. Donot re move do thing if adhering to skin. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • E nsure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Flammable Liquids ERG2004 1 30 (Non-Polar/Water-Immiscible/Noxious) POTENTIAL HAZARDS FIRE OR EXPLOSION • HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. • Vapors mayform explosive mixtures with air. • Vapors may travel to source of ignition and flash back. • Mostvapors are heavierthan air. Theywill spread along ground and collectin low or confined areas (sewers, basements, tanks). • Vaporexplosion hazard indoors, outdoors orin sewers. • Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. • Runoff to sewer may create fire or explosion hazard. • Containers may explode when heated. • Many liquids are lighter than water. HEALTH • May cause toxic effects if inhaled or absorbed through skin. • Inhalation or contact with material may irritate or burn skin and eyes. • Fire will produce irritating, corrosive and/ortoxic gases. • Vapors mayca use dizziness or suffocation. • Runoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast50 meters (150 feet) in all directions. • Keep unauthorized personnel away. • S tay upwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 300 meters (1000 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Flammable Liquids GUIDE (Non-Polar/Water-Immiscible/Noxious) 1 3Q EMERGENCY RESPONSE FIRE CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. Small Fires • Dry chemical, CO 2 , water spray or regular foam. Large Fires • Waterspray.fog orregularfoam. • Do not use straight streams. • Move containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when hand ling the product must be grounded. • Do nottouchorwalk through spilled material. • Stop leak if you can do it without risk. • Prevent entry into waterways, sewers, basements or confined areas. • A vapor suppressing foam may be used to reduce vapors. • Absorb or cover with dry earth, sand or other non-combustible material and transferto containers. • Use clean non-sparking tools to collect absorbed material. Large Spills • Dike far ahead of liquid spill for later disposal. • Water spray may reduce vapor; but may not prevent ignition in closed spaces. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • G ive artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Wash skin with soap and water. • Keep victim warm and quiet. • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Flammable Liquids - Toxic ERG2004 131 POTENTIAL HAZARDS HEALTH • TOXIC; may be fatal if inhaled, ingested or absorbed through skin. • Inhalation or con tact with some of these mate rials will irritate orburnskinandeyes. • Fire will produce irritating, corrosive and/or toxic gases. • Vapors may cause dizziness or suffocation. • Runoff from fire control or dilution water may cause pollution. FIREOREXPLOSION • HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. • Vapors mayform explosive mixtures with air. • Vapors may travel to source of ignition and flash back. • Mostvapors are heavierthan air. Theywill spread along ground and collectin low or confined areas (sewers, basements, tanks). • Vapor explosion and poison hazard indoors, outdoors or in sewers. • Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. • R unoff to sewer may create fire or explosion hazard. • Containers may explode when heated. • Many liquids are lighter than water. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast50 meters (150 feet) in all directions. • Keep unauthorized personnel away. • Stayupwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations l\l LY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Flammable Liquids - Toxic GUIDE 131 EMERGENCY RESPONSE FIRE CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. Small Fires • Dry chemical, CO 2 , water spray or alcohol-resistant foam. Large Fires • Water spray, fog or alcohol-resistant foam. • Move containers from fire area if you can do it without risk. • Dike fire control water for later disposal; do not scatter the material. • Use water spray or fog; do not use straight streams. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when hand ling the product must be grounded. • Do not touch or walk through spilled material. • Stop leak if you can do it without risk. • Prevententry into waterways, sewers, basements orconfined areas. • A vaporsupp re ssingfoammaybeused to reduce vapors. Small Spills 'Absorb with earth, sand or other non-combustible mate rial and transfer to containers for later disposal. • Use clean non-sparking tools to collect absorbed mate rial. Large Spills • Dike far ahead of liquid spill for later disposal. • Water spray may reduce vapor; but may not pre vent ignition in closed spaces. FIRST AID • Move victim to fresh air. • C all 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Wash skin with soap and water. • Keep victim warm and quiet. • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • E nsure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Flammable Liquids - Corrosive ERG2004 132 POTENTIAL HAZARDS FIRE OR EXPLOSION • Flammable/combustible materials. • May be ignited byheat, sparks orflames. • Vapors mayform explosive mixtures with air. • Vapors may travel to source of ignition and flash back. • Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). • Vapor explosion hazard indoors, outdoors or in sewers. • Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. • Runoffto sewer may create fire or explosion hazard. • Containers may explode when heated. • Many liquids a re lighter than water. HEALTH • Maycause toxic effects if inhaled or ingested/swallowed. • Con tactwith subs tancemaycauseseve re burns to skinandeyes. • Fire will produce irritating, corrosive and/ortoxic gases. • Vapors may cause dizziness or suffocation. • Runoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast50 meters (150 feet) in all directions. • Keep unauthorized personnel away. • Stay upwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCBA). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations N LY ; it is not effective in spill situations where direct con tact with the substance is possible. EVACUATION Large Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail carortank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Flammable Liquids - Corrosive GUIDE 132 EMERGENCY RESPONSE FIRE • Some of these materials may react violently with water. Small Fires • Dry chemical, CO 2 , water spray or alcohol- resistant foam, Large Fires • Water spray, fog or alcohol-resistant foam. • Move containers from fire area if you can do it without risk, • Dike fire control water for later disposal; do not scatter the material. • Do not get water inside containers. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when hand ling the product must be grounded. • Do not touch or walk through spilled material. • Stop leak if you can do it without risk. • P re vent entry into waterways, sewers, basements or confined areas. • A vaporsupp re ssingfoammaybeused to reduce vapors. • Absorb with earth, sand or other non-combustible material and transfer to containers (except for Hydrazine). • Use clean non-sparking tools to collect absorbed material. Large Spills • Dike far ahead of liquid spill for later disposal. • Water spray may reduce vapor; but may not prevent ignition in closed spaces. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service, • G ive artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Flammable Solids ERG2004 133 POTENTIAL HAZARDS FIRE OR EXPLOSION • Flammable/combustible material. • May be ignited by friction, heat, sparks or flames. • S ome may burn rapidly with flare burning effect. • Powders, dusts, shavings, bo rings, turnings or cuttings may explode or burn with explosive violence. • Substance may be transported in a molten form at a temperature that may be above its flash point. • M ay re- ignite after fire is extinguished. HEALTH • Fire may produce irritating and/ortoxic gases. • Contactmaycause burns to skinande yes. • Contact with molten substance may cause severe burns to skin and eyes. • Runoff from fire control may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast25 meters (75 feet) in all directions. • Keep unauthorized personnel away. • S tay upwind. • Keep out of low areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Flammable Solids GUIDE 133 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical, C0 2 ,sand, earth .water spray or regular foam. Large Fires • Water spray, fog or regularfoam. • Move containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • Cool containers with flooding quantities of water until well after fire is out. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Do not touch or walk through spilled material. Small Dry Spills • With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large Spills • Wet down with water and dike for later disposal. • Prevent entry into waterways, sewers, basements or confined areas. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Removal of solidified molten material from skin requires medical assistance. • Keep victim warm and quiet. • E nsure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Flammable Solids -Toxic and/or Corrosive ERG2004 134 POTENTIAL HAZARDS FIRE OR EXPLOSION • Flammable/combustible material. • Maybeignitedbyheat, sparks or flames. • When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. • Con tact with metals may evolve flammable hydrogen gas. • Containers may explode when heated. HEALTH • TOXIC; inhalation, ingestion or skin con tact with mate rial may cause severe injury or death. • Fire will produce irritating, corrosive and/or toxic gases. • Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast25 meters (75 feet) in all directions. • Stayupwind. • Keep unauthorized personnel away. • Keep out of low areas. • Ventilate enclosed areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Flammable Solids -Toxic and/or Corrosive GUIDE 134 EMERGENCY RESPONSE FIRE Small Fires • D ry chem ic a I, CO , water spray or alcohol- resistant foam. Large Fires • W ater spray, fog oralcohol-resistantfoam. • M ove containers from fire area if you can do it without risk. • Use waterspray orfog; do not use straightstreams. • Do not get water inside containers. • Dike fire control water for later disposal; do not scatter the material. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Stop leak if you can do it without risk. • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Prevent entry into waterways, sewers, basements or confined areas, • Use clean non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • For minor skin con tact, a void spreading mate rial on unaffected skin. • Keep victim warm and quiet. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances - Spontaneously Combustible ERG2004 135 POTENTIAL HAZARDS FIRE OR EXPLOSION • Flammable/combustible material. • Mayignite on contactwith moistairormoisture. • May burn rapidly with flare-burning effect. • Some react vigorously or explosively on con tact with water. • Some may decompose explosively when heated or involved in a fire. • M ay re-ignite after fire is extinguished. • Runoff may ere ate fire or explosion hazard. • Containers may explode when heated. HEALTH • Fire will produce irritating, corrosive and/or toxic gases. • Inhalation of decomposition products may cause severe injury or death. • Con tactwith subs tancemaycauseseve re burns to skinandeyes. • Runoff from fire control may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • S tay upwind. • Keep unauthorized personnel away. • Keep out of low areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances - Spontaneously Combustible GUIDE 135 EMERGENCY RESPONSE FIRE • DO NOT USE WATER, C0 2 OR FOAM ON MATERIAL ITSELF. • Some of these mate rials may react violently with water. EXCEPTION: For Xanthates, UN3342 and for Dithionite (Hydrosulfite/ Hydrosulphite) UN1384, UN1923 and UN1929, USE FLOODING AMOUNTS OF WATER for SMALL AND LARGE fires to stop the reaction. Smothering will not work for these materials, they do not need air to burn. Small Fires • Dry chemical, soda ash, lime or DRY sand, EXCEPT for UN1384, UN1923 and UN1929. Large Fires • DRY sand, dry chemical, soda ash or lime, EXCEPT for UN1384, UN1923 and UN1929, orwithdraw from area and letfire burn. • Move containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Do not get water inside containers or in con tact with substance. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Fully encapsulating, vapor protective clothing should be worn for spills and leak with no fire. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Do not touch or walk through spilled material. • Stop leak if you can do it without risk, Small Spills EXCEPTION: For spills of Xanthates, UN3342 and for Dithionite (Hydrosulfite/ Hydrosulphite), UN1384, UN1923 and UN1929, dissolve in 5 parts water and collect for proper disposal. • Cover with DRY earth, DRY sand or other non-combustible mate rial followed with plastic sheet to minimize spreading or con tact with rain. • Use clean non-sparking tools to collect material and place itinto looselycovered plastic containers for later disposal. • Prevent entry into waterways, sewers, basements or confined areas. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances - Spontaneously Combustible - ERG2004 136 Toxic and/or Corrosive (Air-Reactive) POTENTIAL HAZARDS FIRE OR EXPLOSION • Extremely flammable; will ignite itself if exposed to air. • Burns rapidly, releasing dense, white, irritating fumes. • Substance may be transported in a molten form. • M ay re- ignite after fire is extinguished. • Corrosive substances in contact with metals may produce flammable hydrogen gas. • Containers may explode when heated. HEALTH • Fire will produce irritating, corrosive and/or toxic gases. • TOXIC; ingestion of substance or inhalation of decomposition products will cause severe injuryordeath. • Con tact with substance may cause severe burns to skin and eyes. • Some effects may be experienced due to skin absorption. • Runoff from fire control may be corrosive and/or toxic and cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Stayupwind. • Keep unauthorized personnel away. • Keep out of low areas. protective clothing • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. • For Phosphorus (UN1381): Special aluminized protective clothing should be worn when direct contact with the substance is possible. EVACUATION Spill • Consider initial downwind evacuation for at least 300 meters (1000 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances - Spontaneously Combustible - GUIDE Toxic and/or Corrosive (Air-Reactive) 136 EMERGENCY RESPONSE FIRE Small Fires • Water spray, wet sand or wet earth. Large Fires • Water spray or fog. • Do not scatter spilled material with high pressure water streams. • Move containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Do nottouchorwalk through spilled material. • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. Small Spills • Cover with water, sand or earth. S hovel into metal container and keep material under water. Large Spills • Dike for laterdisposal and coverwith wetsand orearth. • Prevententry into waterways, sewers, basements orconfined areas, FIRST AID • Move victim to fresh air. • C all 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • In case of con tact with substance, keep exposed skin areas immersed in water or covered with wet bandages until medical attention is received. • Removal of solidified molten material from skin requires medical assistance. • Remove and isolate contaminated clothing and shoes atthe site and place in metal container filled with water. Fire hazard if allowed to dry. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances - Water- Reactive - Corrosive ERG2004 137 POTENTIAL HAZARDS HEALTH • CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. • Fire will produce irritating, corrosive and/ortoxic gases. • Reaction with water may gene rate much heat which will increase the concentration of fumes in the air. • Contact with molten substance may cause severe burns to skin and eyes. • R unoff from fire control or dilution water may cause pollution. FIRE OR EXPLOSION • EXCEPT FOR ACETIC ANHYDRIDE (UN 1715), THAT IS FLAMMABLE, some of these materials may burn, but none ignite readily. • May ignite combustibles (wood, pa per, oil, do thing, etc.). • Substa nee will re act with water (some violently), re leasing corrosive and/or toxic gases. • Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/ tank cars etc.) • Con tact with metals may evolve flammable hydrogen gas. • Containers may explode when heated or if contaminated with water. • Substance may be transported in a molten form. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stay upwind. • Keep out of low areas. • Ventilate enclosed areas, PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances -Water-Reactive- Corrosive GUIDE 137 EMERGENCY RESPONSE FIRE • When material Is not Involved In fire: do not use water on material Itself. Small Fires • Dry chemical or C0 2 . • Move containers from fire area if you can do it without risk. Large Fires • Flood fire area with large quantities of water, while knocking down vapors with water fog. If insufficient water supply: knock down vapors only. Fire involving Tanks or Car/Trailer Loads • Cool containers with flooding quantities of water until well after fire is out. • Do notgetwaterinside containers. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. • Do not touch damaged containers or spilled mate rial unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • Use watersprayto reduce vapors; do not putwaterdirectly on leak, spill area or inside container. • Keep combustibles (wood, paper, oil, etc.) awayfrom spilled material. Small Spills • Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or con tact with rain. • Use clean non-sparking too Is to collect mate rial and place it in to loosely cove red plastic containers forlaterdisposal. • Prevent entry into waterways, sewers, basements or confined areas. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • For minor skin con tact, a void spreading mate rial on unaffected skin. • Removal of solidified molten material from skin requires medical assistance. • Keep victim warm and quiet. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances- Water- Reactive ERG2004 1 38 (Emitting Flammable Gases) POTENTIAL HAZARDS FIRE OR EXPLOSION • Produce flammable gases on conta ct with water. • Mayigniteoncontactwithwaterormoistair. • Some re act vigorously or explosively on con tact with water. • May be ignited by heat, sparks or flames. • May re-ignite after fire is extinguished. • Some are transported in highly flammable liquids. • Runoff may ere ate fire or explosion hazard. HEALTH • Inhalation or con tact with vapors, substance or decomposition pro ducts may cause severe injury or death. • May produce corrosive solutions on con tact with water. • Fire will produce irritating, corrosive and/ortoxic gases. • Runoff from fire control may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stayupwind. • Keep out of low areas. • Ventilate the area before entry. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Large Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances- Water-Reactive GUIDE (Emitting Flammable Gases) 1 7g EMERGENCY RESPONSE FIRE • DO NOT USE WATER OR FOAM. Small Fires • Dry chemical, soda ash, lime or sand. Large Fires • DRY sand, drychemical, soda ash or lime orwithdraw from area and let fire burn. • Move containers from fire area if you can do it without risk. Magnesium Fires • DRY sand, sodium chloride powder, graphite powder or Met- L-X 8 powder. Lithium Fires • DRY sand, sodium chloride powder, graph ite powder, copper powder or Lith-X® powder. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Do notgetwaterinside containers. • Cool containers with flooding quantities of water until well after fire is out, • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Do not touch or walk thro ugh spilled mate rial. • Stop leak if you can do it without risk. • Use waterspray to reduce vapors ordivertvaporcloud drift. Avoid allowing water runoff to contact spilled material. • DO NOT GET WATER on spilled substance or inside containers. Small Spills • Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or con tact with rain. • Dike for later disposal; do not apply water unless directed to do so. Powder Spills • Co ve r powder spill with plastic sheet or tarp to minimize spreading and keep powderdry. • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, wipe from skin immediately; flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances- Water- Reactive ERG2004 1 39 (Emitting Flammable And Toxic Gases) POTENTIAL HAZARDS FIRE OR EXPLOSION • Produce flammable and toxic gases on contact with water. • Mayigniteoncontactwithwaterormoistair. • Some re act vigorously or explosively on con tact with water. • May be ignited by heat, sparks or flames. • May re-ignite after fire is extinguished. • Some are transported in highly flammable liquids. • Containers may explode when heated. • Runoff may ere ate fire or explosion hazard. HEALTH • Highly toxic: contactwith water produces toxic gas, may be fatal ifinhaled. • Inhalation or con tact with vapors, substance or decomposition pro ducts may cause severe injury or death. • May produce corrosive solutions on con tact with water. • Fire will produce irritating, corrosive and/ortoxic gases. • Runoff from fire control may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • S tay upwind. • Keep out of low areas. • Ventilate the area before entry. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Large Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances- Water-Reactive GUIDE (Emitting Flammable And Toxic Gases) 1 30 EMERGENCY RESPONSE FIRE • DO NOT USE WATER OR FOAM. (FOAM MAYBE USED FOR CHLOROSILANES, SEE BELOW) Small Fires • Dry chemical, soda ash, lime or sand. Large Fires • DRY sand, dry chemical, soda ash or lime orwithdraw from area and let fire burn. • FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium expansion foam; DO NOT USE dry chemicals, soda ash or lime on chlorosilane fires (large orsmall) as they may release large quantities of hydrogen gas that may explode. • M ove containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Do not get water inside containers. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Do not touch or walk thro ugh spilled mate rial. • Stop leak if you can do it without risk. • DO NOT GET WATER on spilled substance or inside containers. • Use waterspray to reduce vapors ordivertvaporcloud drift. Avoid allowing water runoff to contact spilled material. • FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce vapors. Small Spills • Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheetto minimize spreading or contact with rain. • Dike for laterdisposal; do notapply water unless directed to do so. Powder Spills • Co ve r powder spill with plastic sheet or tarp to minimize spreading and keep powderdry. • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • G ive artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, wipe from skin immediately; flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensu re that medical pe rs onnel a re aware of the ma terial(s) involved and take precautions to protect themselves. GUIDE Oxidizers ERG2004 140 POTENTIAL HAZARDS FIRE OR EXPLOSION • These substances will accelerate burning when involved in a fire. • Some may decompose explosively when heated or involved in a fire. • May explode from heat or contamination. • Some will re act explosively with hydrocarbons (fuels). • May ignite combustibles (wood, paper, oil, do thing, etc.). • Containers may explode when heated. • Runoff may ere ate fire or explosion hazard. HEALTH • Inhalation, ingestion or con tact (skin, eyes) with vapors or substance may cause severe injury, burns or death. • Fire may produce irritating, corrosive and/ortoxic gases. • R unoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stayupwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Oxidizers GUIDE 140 EMERGENCY RESPONSE FIRE Small Fires • Use water. Do not use dry chemicals or foams. C0 2 or Halon 8 may provide limited control. Large Fires • Flood fire area with waterfrom a distance. • Move containers from fire area if you can do it without risk. • Donotmo ve cargoor vehicle if cargohasbeenexposed to heat. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • Keep combustibles (wood, paper, oil, etc.) awayfrom spilled material. • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • Do notgetwater inside containers. Small Dry Spills • With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Small Liquid Spills • Use a non-combus tible mate rial like vermiculite or sand to soak up the product and place into a container for later disposal. Large Spills • Dike far ahead of liquid spill for later disposal. • Following product recovery, flush area with water. FIRST AID • Move victim to fresh air. • C all 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • Contaminated clothing may be a fire risk when dry. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Oxidizers -Toxic ERG2004 141 POTENTIAL HAZARDS FIRE OR EXPLOSION • These substances will accelerate burning when involved in a fire. • May explode from heat or contamination. • Some may burn rapidly. • Some will re act explosively with hydrocarbons (fuels). • May ignite combustibles (wood, paper, oil, do thing, etc.). • Containers may explode when heated. • Runoff may ere ate fire or explosion hazard. HEALTH • Toxic by ingestion. • Inhalation of dust is toxic. • Fire may produce irritating, corrosive and/ortoxic gases. • Con tactwith subs tancemaycauseseve re burns to skinandeyes. • R unoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stayupwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Oxidizers - Toxic GUIDE 141 EMERGENCY RESPONSE FIRE Small Fires • Use water. Do not use dry chemicals or foams. C0 2 or Halon 8 may provide limited control. Large Fires • Flood fire area with waterfrom a distance. • Move containers from fire area if you can do it without risk. • Donotmo ve cargoor vehicle if cargohasbeenexposed to heat. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • Keep combustibles (wood, paper, oil, etc.) awayfrom spilled material. • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. Small Dry Spills • With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large Spills • Dike far ahead of spill for later disposal. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • Contaminated clothing may be a fire risk when dry. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Oxidizers - Toxic (Liquid) ERG2004 142 POTENTIAL HAZARDS FIRE OR EXPLOSION • These substances will accelerate burning when involved in a fire. • May explode from heat or contamination. • Some will react explosively with hydrocarbons (fuels). • May ignite combustibles (wood, paper, oil, clothing, etc.). • Containers may explode when heated. • Runoff may create fire or explosion hazard. HEALTH • TOXIC; inhalation, ingestion or con tact (skin, eyes) with vapors or substance may cause severe injury, burns or death. • Fire may produce irritating, corrosive and/ortoxic gases. • Toxic/flammable fumes may accumulate in confined a re as (basement, tanks, tank cars, etc.). • R unoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast50 meters (150 feet) in all directions. • Keep unauthorized personnel away. • S tay upwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Oxidizers - Toxic (Liquid) GUIDE 142 EMERGENCY RESPONSE FIRE Small Fires • Use water. Do not use dry chemicals or foams. C0 2 or Halon 8 may provide limited control. Large Fires • Flood fire area with waterfrom a distance. • Move containers from fire area if you can do it without risk. • Donotmo ve cargoor vehicle if cargohasbeenexposed to heat. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • Keep combustibles (wood, paper, oil, etc.) awayfrom spilled material. • Fully encapsulating, vaporprotective clothing should be worn f o r spills and leaks with no fire. • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • Use waterspray to reduce vapors ordivertvaporcloud drift. • Do notgetwater inside containers. Small Liquid Spills • Use a non-combus tible mate rial like vermiculite or sand to soak up the product and place into a container for later disposal. Large Spills • Dike far ahead of liquid spill for later disposal. FIRST AID • Move victim to fresh air. • C all 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • Contaminated clothing may be a fire risk when dry. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Oxidizers (Unstable) ERG2004 143 POTENTIAL HAZARDS FIRE OR EXPLOSION • May explode from friction, heat or contamination. • These substances will accelerate burning when involved in a fire. • May ignite combustibles (wood, paper, oil, clothing, etc.). • Some will re act explosively with hydrocarbons (fuels). • Containers may explode when heated. • Runoff may ere ate fire or explosion hazard. HEALTH • TOXIC; inhalation, ingestion or con tact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. • Fire may produce irritating and/ortoxic gases. • Toxic fumes or dust may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). • R unoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • S tay upwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Oxidizers (Unstable) GUIDE 143 EMERGENCY RESPONSE FIRE Small Fires • Use water. Do not use dry chemicals or foams. C0 2 or Halon 8 may provide limited control. Large Fires • Flood fire area with waterfrom a distance. • Donotmo ve cargoor vehicle if cargohasbeenexposed to heat. • Move containers from fire area if you can do it without risk. • Do not get water inside containers: a violent reaction may occur. • Cool containers with flooding quantities of water until well after fire is out. • Dike fire-control water for later disposal. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • Keep combustibles (wood, paper, oil, etc.) away from spilled material. • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Use waterspray to reduce vapors ordivertvaporcloud drift. • Prevent entry into waterways, sewers, basements or confined areas. Small Spills • Flush area with flooding quantities of water. Large Spills • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service, • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • Contaminated clothing may be a fire risk when dry. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Oxidizers (Water-Reactive) ERG2004 144 POTENTIAL HAZARDS FIRE OR EXPLOSION • May ignite combustible s (wood, paper, oil, clothing, etc.). • React vigorously and/or explosively with water. • P roduce toxic and/or corrosive substances on contact with water. • Flammable/toxic gases may accumulate in tanks and hopper cars. • Some may produce flammable hydrogen gas upon contactwith metals. • Containers may explode when heated. • Runoff may ere ate fire or explosion hazard. HEALTH • TOXIC; inhalation or contact with vapor, substance, or decomposition products may cause severe injury or death. • Fire will produce irritating, corrosive and/ortoxic gases. • Runoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • 5tay upwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Oxidizers (Water-Reactive) GUIDE 144 EMERGENCY RESPONSE FIRE • DO NOT USE WATER OR FOAM. Small Fires • Dry chemical, soda ash or lime, Large Fires • DRY sand, drychemical, soda ash or lime orwithdraw from area and let fire burn. • Move containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • Usewaterspraytoreducevaporsordivertvaporcloud drift. Avoid allowing water runoff to contact spilled material. • DO NOT GET WATER on spilled substance or inside containers. Small Spills • Cover with DRY earth, DRY sand or other non-combustible mate rial followed with plastic sheetto minimize spreading orcontactwith rain. Large Spills • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • Contaminated clothing may be a fire risk when dry. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Keep victim under observation. • Effects of contactor inhalation may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Organic Peroxides ERG2004 1 45 (Heat and Contamination Sensitive) POTENTIAL HAZARDS FIRE OR EXPLOSION • May explode from heat or contamination. • May ignite combustibles (wood, paper, oil, clothing, etc.). • Maybeignitedbyheat, sparks or flames. • May burn rapidly with flare-burning effect. • Containers may explode when heated. • Runoff may create fire or explosion hazard. HEALTH • Firemayproduce irritating, corrosive and/or toxic gases. • Ingestion or con tact (skin, eyes) with substance may cause severe injury or burns. • Runoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stayupwind. • Keep out of low areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial evacuation for at least 250 meters (800 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Organic Peroxides GUIDE (Heat and Contamination Sensitive) ] AC EMERGENCY RESPONSE FIRE Small Fires • Water spray or fog is preferred; if water not available use dry chemical, C0 2 or regular foam. Large Fires • Flood fire area with waterfrom a distance. • Usewatersprayorfog;donotusestraightstreams. • Move containers from fire area if you can do it without risk. • Donotmo ve cargoor vehicle if cargohasbeenexposed to heat. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Keep combustibles (wood, paper, oil, etc.) a way from spilled material. • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Keep substance wet using water spray. • Stop leak if you can do it without risk. Small Spills • Take up with inert, damp, non-combustible material using clean non-sparking tools and place into loosely covered plastic containers for later disposal. Large Spills • Wetdown with water and dike forlaterdisposal. • Prevententry into waterways, sewers, basements orconfined areas. • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • Contaminated clothing may be a fire risk when dry. • Remove material from skin immediately. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Organic Peroxides (Heat, Contamination ERG2004 146 and Friction Sensitive) POTENTIAL HAZARDS FIRE OR EXPLOSION • May explode from heat, shock, friction or contamination. • May ignite combustibles (wood, paper, oil, clothing, etc.). • Maybeignitedbyheat, sparks or flames. • May burn rapidly with flare-burning effect. • Containers may explode when heated. • Runoff may create fire or explosion hazard. HEALTH • Firemayproduce irritating, corrosive and/or toxic gases. • Ingestion or con tact (skin, eyes) with substance may cause severe injury or burns. • Runoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stayupwind. • Keep out of low areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial evacuation for at least 250 meters (800 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Organic Peroxides (Heat, Contamination and GUIDE Friction Sensitive) 146 EMERGENCY RESPONSE FIRE Small Fires • Water spray or fog is preferred; if water not available use dry chemical, C0 2 or regular foam. Large Fires • Flood fire area with waterfrom a distance. • Usewatersprayorfog;donotusestraightstreams. • Move containers from fire area if you can do it without risk. • Donotmo ve cargoor vehicle if cargohasbeenexposed to heat. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Keep combustibles (wood, paper, oil, etc.) a way from spilled material. • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Keep substance wet using water spray. • Stop leak if you can do it without risk. Small Spills • Take up with inert, damp, non-combustible material using clean non-sparking tools and place into loosely covered plastic containers for later disposal. Large Spills • Wetdown with water and dike forlaterdisposal. • Prevententry into waterways, sewers, basements orconfined areas. • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • Contaminated clothing may be a fire risk when dry. • Remove material from skin immediately. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE 147 ERG2004 Page Intentionally Left Blank ERG2004 GUIDE 147 Page Intentionally Left Blank GUIDE Organic Peroxides (Heat and Contamination ERG2004 1 48 Sensitive/Temperature Controlled) POTENTIAL HAZARDS FIRE OR EXPLOSION • Mayexplode from heat, contamination or loss of temperature control. • These materials are particularly sensitive to temperature rises. Above a given "Control Temperature" they decompose violently and catch fire. • May ignite combustibles (wood, paper, oil, clothing, etc.). • May ignite spontaneously if exposed to air. • May be ignited by heat, sparks or flames. • May burn rapidly with flare-burning effect. • Containers may explode when heated. • Runoff may create fire or explosion hazard. HEALTH • Fire may produce irritating, corrosive and/or toxic gases. • Ingestion or contact (skin, eyes) with substance may cause severe injury or burns. • Runoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • 5tay upwind. • Keep out of low areas. • DO NOT allow the substance to warm up. Obtain liquid nitrogen, dry ice or ice for cooling. If none can be obtained, evacuate the area immediately. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial evacuation for at least 250 meters (800 feet), Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Organic Peroxides (Heat and Contamination GUIDE Sensitive/Temperature Controlled) ] A a EMERGENCY RESPONSE FIRE • The temperature of the substance must be maintained at or below the "Control Temperature" at all times. Small Fires • Water spray or fog is preferred; if water not available use dry chemical, CO 2 or regular foam. Large Fires • Flood fire area with waterfrom a distance, • Use water spray or fog; do not use straight streams. • Move containers from fire area if you can do it without risk. • Do notmove cargo orvehicle if cargo has been exposed to heat. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • BEWARE OF POSSIBLE CONTAINER EXPLOSION. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Keep combustibles (wood, paper, oil, etc.) awayfrom spilled material. • Do not touch or walk through spilled material. • Stop leak if you can do it without risk. Small Spills • Take up with inert, damp, non-combustible material using clean non-sparking tools and place into loosely covered plastic containers for later disposal. Large Spills • Dike far ahead of liquid spill for later disposal. • Prevententry into waterways, sewers, basements orconfined areas. • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • G ive artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • Contaminated clothing may be a fire risk when dry. • Remove material from skin immediately. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • E nsure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances (Self-Reactive) ERG2004 149 POTENTIAL HAZARDS FIRE OR EXPLOSION • Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. • May be ignited by heat, sparks or flames. • Some may decompose explosively when heated or involved in a fire. • M ay burn violently. Decomposition may be self-accelerating and produce large amounts of gases. • Vapors or dust may form explosive mixtures with air. HEALTH • Inhalation or con tact with vapors, substance or decomposition pro ducts may cause severe injury or death. • May produce irritating, toxic and/or corrosive gases. • Runoff from fire control may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stay upwind. • Keep out of low areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCBA). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 250 meters (800 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances (Self-Reactive) GUIDE 149 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical, C0 2 , water spray or regular foam. Large Fires • Flood fire area with waterfrom a distance. • Move containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • BEWARE OF POSSIBLE CONTAINER EXPLOSION. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Do nottouch orwalkthrough spilled material. • Stop leak if you can do it without risk. Small Spills • Take up with inert, damp, non-combustible material using clean non-sparking tools and place in to loosely cove red plastic containers for later disposal. • P re vent en try in to waterways, sewers, basements or confined a re as. FIRST AID • Move victim to fresh air. • C all 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances (Self-Reactive/ ERG2004 150 Temperature Controlled) POTENTIAL HAZARDS FIRE OR EXPLOSION • Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. • Self-accelerating decomposition may occur if the specific control temperature is not maintained. • These materials are particularly sensitive to temperature rises. Above a given "Control Temperature" they decompose violently and catch fire. • May be ignited by heat, sparks or flames. • Some may decompose explosively when heated or involved in a fire. • M ay burn violently. Decomposition may be self-accelerating and produce large amounts of gases. • Vapors ordustmayform explosive mixtures with air. HEALTH • Inhalation or con tact with vapors, substance or decomposition pro ducts may cause severe injury or death. • May produce irritating, toxic and/orcorrosive gases. • Runoff from fire control may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • S tay upwind. • Keep out of low areas. • DO NOT allow the substance to warm up. Obtain liquid nitrogen, dry ice or ice for cooling. If none can be obtained, evacuate the area immediately. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 250 meters (800 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances (Self-Reactive/ GUIDE Temperature Controlled) ] &n EMERGENCY RESPONSE FIRE • The temperature of the substance must be maintained at or below the "Control Temperature" at all times. Small Fires • Dry chemical, CO 2 , water spray or regular foam. Large Fires • Flood fire area with waterfrom a distance. • Move containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • BEWARE OF POSSIBLE CONTAINER EXPLOSION. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Do not touchorwalk through spilled material. • Stop leak if you can do it without risk. Small Spills • Take up with inert, damp, non-combustible material using clean non-sparking tools and place into loosely covered plastic containers for later disposal. • Prevententry into waterways, sewers, basements orconfined areas. • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • G ive artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances -Toxic (Non-Combustible) ERG2004 151 POTENTIAL HAZARDS HEALTH • Highly toxic, may be fata I if inhaled, swallowed or absorbed thro ugh skin. • Avoid any skin contact. • Effects of contact or inhalation may be delayed. • Fire may produce irritating, corrosive and/ortoxic gases. • R unoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. FIRE OR EXPLOSION • Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/ortoxic fumes. • Containers may explode when heated. • Runoffmaypollutewaterways. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stayupwind. • Keep out of low areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances -Toxic (Non-Combustible) GUIDE 151 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical, C0 2 or water spray. Large Fires • Water spray, fog or regularfoam. • Move containers from fire area if you can do it without risk. • Dike fire control water for later disposal; do not scatter the material. • Usewatersprayorfog;donotusestraightstreams. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Do notgetwaterinside containers. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • Prevent entry into waterways, sewers, basements or confined areas. • Coverwith plastic sheetto preventspreading. • Absorb or cover with dry earth, sand or other non-combustible material and transferto containers. • DO NOT GET WATER INSIDE CONTAINERS. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • For minor skin con tact, a void spreading mate rial on unaffected skin. • Keep victim warm and quiet. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances - Toxic (Combustible) ERG2004 152 POTENTIAL HAZARDS HEALTH • Highly toxic, may be fata I if inhaled, swallowed or absorbed thro ugh skin. • Con tact with molten substance may cause severe burns to skin and eyes. • Avoid any skin contact. • Effects of contact or inhalation may be delayed. • Fire may produce irritating, corrosive and/ortoxic gases. • Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. FIRE OR EXPLOSION • Combustible material: may burn but does not ignite readily. • Containers may explode when heated. • Runoff may pollute waterways. • Substance may be transported in a molten form. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stayupwind. • Keep out of low areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances - Toxic (Combustible) GUIDE 152 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical, C0 2 or water spray. Large Fires • Water spray, fog or regularfoam. • Move containers from fire area if you can do it without risk. • Dike fire control water for later disposal; do not scatter the material. • Usewatersprayorfog;donotusestraightstreams. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Do notgetwaterinside containers. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks orflames in immediate area). • Do not touch damaged containers or spilled mate rial unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • P re vent entry into waterways, sewers, basements or confined areas. • Coverwith plastic sheetto prevent spreading. • Abso rb or co ve r w ith d ry ea rth, sand or othernon -combustible mate rial and transferto containers. • DO NOT GET WATER INSIDE CONTAINERS. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service, • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • For minor skin con tact, a void spreading mate rial on unaffected skin. • Keep victim warm and quiet. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • E nsure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances - Toxic and/or Corrosive ERG2004 ] 53 (Combustible) POTENTIAL HAZARDS HEALTH • TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. • Con tact with molten substance may cause severe burns to skin and eyes. • Avoid any skin contact. • Effects of contact or inhalation may be delayed. • Firemayproduce irritating, corrosive and/or toxic gases. • R unoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. FIRE OR EXPLOSION • Combustible material: may burn but does not ignite readily. • When heated, vapors mayform explosive mixtures with air: indoors, outdoors and sewers explosion hazards. • Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. • Contactwith metals mayevolve flammable hydrogen gas. • Containers may explode when heated. • Runoffmaypollutewaterways. • Substance may be transported in a molten form. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stay upwind. • Keep out of low areas. • Ventilate enclosed areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances - Toxic and/or Corrosive GUIDE (Combustible) ] 53 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical, C0 2 or water spray. Large Fires • D ry chem ic a I, CO 2 , ale oho I- resistant foam or water spray. • M ove containers from fire area if you can do it without risk. • Dike fire control water for later disposal; do not scatter the material. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Do notgetwaterinside containers. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks orflames in immediate area). • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • Prevententry into waterways, sewers, basements orconfined areas. • Abso rb or co ve r w ith d ry ea rth, sand or othernon -combustible mate rial and transferto containers. • DO NOT GET WATER INSIDE CONTAINERS. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • G ive artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • For minor skin con tact, a void spreading mate rial on unaffected skin. • Keep victim warm and quiet. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances - Toxic and/or Corrosive ERG2004 1 54 (Non-Combustible) POTENTIAL HAZARDS HEALTH • TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. • Con tact with molten substance may cause severe burns to skin and eyes. • Avoid any skin contact. • Effects of contact or inhalation may be delayed. • Fire may produce irritating, corrosive and/ortoxic gases. • Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. FIRE OR EXPLOSION • Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/ortoxic fumes, • Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). • Contactwith metals mayevolve flammable hydrogen gas. • Containers may explode when heated. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • S tay upwind. • Keep out of low areas. • Ventilate enclosed areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances - Toxic and/or Corrosive GUIDE (Non-Combustible) ] 54 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical, C0 2 or water spray. Large Fires • D ry chem ic a I, CO 2 , ale oho I- resistant foam or water spray. • M ove containers from fire area if you can do it without risk. • Dike fire control water for later disposal; do not scatter the material. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Do notgetwaterinside containers. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks orflames in immediate area). • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • Prevententry into waterways, sewers, basements orconfined areas. • Abso rb or co ve r w ith d ry ea rth, sand or othernon -combustible mate rial and transferto containers. • DO NOT GET WATER INSIDE CONTAINERS. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • G ive artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • For minor skin con tact, a void spreading mate rial on unaffected skin. • Keep victim warm and quiet. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances - Toxic and/or Corrosive ERG2004 1 55 (Flammable/Water-Sensitive) POTENTIAL HAZARDS FIRE OR EXPLOSION • HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. • Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. • Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks), • Vapors may travel to source of ignition and flash back. • Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. • Substa nee will react with water (some violently) re leasing flammable, toxic or corrosive gases and runoff. • Con tact with metals may evolve flammable hydrogen gas. • Containers may explode when heated or if contaminated with water. HEALTH • TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substa nee may cause severe injury, burns or death. • Bromoacetates and chloroacetates are extremely irritating/lachrymators. • Reaction with water or moist air will re lease toxic, corrosive or flammable gases. • Reaction with water may generate much heat which will increase the concentration of fumes in the air. • Fire will produce irritating, corrosive and/ortoxic gases. • Runoff from fire control or dilution water may be corrosive and/ortoxic and cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stay upwind. • Keep out of low areas. • Ventilate enclosed areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCBA). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail carortank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances - Toxic and/or Corrosive GUIDE (Flammable/Water-Sensitive) ] 55 EMERGENCY RESPONSE FIRE • Note: Mostfoams will react with the material and release corrosive/toxic gases. CAUTION: For Acetyl chloride (UN1717), use C0 2 or dry chemical only. Small Fires • C0 2 , dry chemical, dry sand, alcohol- resistant foam. Large Fires • Water spray, fog or alcohol-resistant foam. • FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium expansion foam. • M ove containers from fire area if you can do it without risk. • Use waterspray orfog; do not use straight strea ms . Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Do not get water inside containers. • Cool containers with flooding quantities of water until well after fire is out. • W ithd raw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when handling the product must be grounded. • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • A vaporsuppressing foam maybe used to reduce vapors. • FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce vapors. • DO NOT GET WATER on spilled substance or inside containers. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • P re vent entry into waterways, sewers, basements or confined areas. Small Spills 'Cover with DRY earth, DRY sand or other non-combustible mate rial followed with plastic sheet to minimize spreading or contact with rain. • Use clean non-sparking too Is to collect mate rial and place it into loosely cove red plastic containers for later disposal. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • G ive artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • For minor skin contact, avoid spreading material on unaffected skin. • Keep victim warm and quiet. • Effects of exposure (inhalation, ingestion orskin contact) to substance may be delayed. • E nsure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances - Toxic and/or Corrosive ERG2004 1 56 (Combustible/Water-Sensitive) POTENTIAL HAZARDS FIRE OR EXPLOSION • Combustible mate rial: may burn but does not ignite readily. • S ubsta nee will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. • When heated, vapors mayform explosive mixtures with air: indoors, outdoors and sewers explosion hazards. • Mostvapors are heavierthan air. Theywill spread along ground and collectin low or confined areas (sewers, basements, tanks). • Vapors may travel to source of ignition and flash back. • Contactwith metals mayevolve flammable hydrogen gas. • Containers mayexplode when heated orif contaminated with water. HEALTH • TOXIC; inhalation, ingestion or con tact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. • Contact with molten substance may cause severe burns to skin and eyes. • Reaction with water or moist air will re lease toxic, corrosive or flammable gases. • Reaction with water may gene rate much heat which will increase the concentration of fumes in the air. • Fire will produce irritating, corrosive and/ortoxic gases. • Runoff from fire control or dilution water may be corrosive and/ortoxic and cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stay upwind. • Keep out of low areas. • Ventilate enclosed areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances - Toxic and/or Corrosive GUIDE (Combustible/Water-Sensitive) ] EMERGENCY RESPONSE FIRE • Note: Mostfoams will react with the material and release corrosive/toxic gases. Small Fires • CO 2 , dry chemical, dry sand, alcohol- resistant foam. Large Fires • Water spray, fog or alcohol-resistant foam. • FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium expansion foam. • Move containers from fire area if you can do it without risk. • Use water spray or fog; do not use straight streams. Fire involving Tanks or Car/Trailer Loads • F ight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Do notgetwater inside containers. • Cool containers with flooding quantities of water until well afterfire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when hand ling the product must be grounded. • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • A vapor suppressing foam may be used to reduce vapors. • FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce vapors. • DO NOT GET WATER on spilled substance or inside containers. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • Prevent entry into waterways, sewers, basements or confined areas. Small Spills • Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or con tact with rain. • Use clean non-sparking too Is to collect mate rial and place it in to loosely cove red plastic containers forlaterdisposal. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service, • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • For minor skin con tact, a void spreading mate rial on unaffected skin. • Keep victim warm and quiet. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • E nsure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances - Toxic and/or Corrosive 157 (Non-Combustible/Water-Sensitive) ERG2004 POTENTIAL HAZARDS HEALTH • TOXIC; inhalation, ingestion or con tact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. • Reaction with water or moist air will re lease toxic, corrosive or flammable gases. • Reaction with water may gene rate much heat that will increase the concentration of fumes in the air. • Fire will produce irritating, corrosive and/or toxic gases. • Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. FIRE OR EXPLOSION • Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. • Vapors may accumulate in confined areas (basement, tanks, hopper/tankcars etc.). • Substa nee will re act with water (some violently), re leasing corrosive and/or toxic gases. • Contact with metals may evolve flammable hydrogen gas. • Containers may explode when heated or if contaminated with water. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak a re a in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stayupwind. • Keep out of low areas. • Ventilate enclosed areas. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances - Toxic and/or Corrosive GUIDE (Non-Combustible/Water-Sensitive) 157 EMERGENCY RESPONSE FIRE • Note: Mostfoams will react with the material and release corrosive/toxic gases. Small Fires • CO 2 (except for Cyanides), dry chemical, dry sand, alcohol- resistant foam. Large Fires • Water spray, fog or alcohol-resistant foam. • Move containers from fire area if you can do it without risk. • Use waterspray orfog; do not use straight s trea ms . • Dike fire control water for later disposal; do not scatter the material. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Do not get water inside containers. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when handling the product must be grounded. • Do not touch damaged containers or spilled mate rial unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • Avaporsupp re ssingfoammaybeused to reduce vapors. • DO NOT GET WATER INSIDE CONTAINERS. • Use waterspray to reduce vapors ordivertvaporcloud drift. Avoid allowing water runoff to contact spilled material. • P re vent entry into waterways, sewers, basements or confined areas. Small Spills • Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheetto minimize spreading or contact with rain. • Use clean non-sparking too Is to collect mate rial and place it in to loosely cove red plastic containers for later disposal. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • For minor skin con tact, a void spreading mate rial on unaffected skin. • Keep victim warm and quiet. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Infectious Substances ERG2004 158 POTENTIAL HAZARDS HEALTH • Inhalation or con tact with substance may cause infection, disease or death. • Runoff from fire control may cause pollution. • Note: Damaged packages containing solid CO as a refrigerant may produce water or frost from condensation of air. Do not touch this liquid as it could be contaminated by the contents of the parcel. FIREOREXPLOSION • Some of these materials may burn, butnone ignite readily. • Some may be transported in flammable liquids. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast25 meters (75 feet) in all directions. • Keep unauthorized personnel away. • Stayupwind. • Obtain identity of substance involved. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. ERG2004 Infectious Substances GUIDE 158 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical, soda ash, lime or sand. Large Fires • Use extinguishing agent suitable for type of surrounding fire. • Move containers from fire area if you can do it without risk. • Do not scatter spilled material with high pressure water streams. SPILL OR LEAK • Do nottouch or walk through spilled material. • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Absorb with earth, sand or other non-combustible mate rial. • Cover damaged package or spilled mate rial with damp towel or rag and keep wet with liquid bleach or other disinfectant. • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. FIRST AID • Move victim to a safe isolated area. CAUTION: Victim may be a source of contamination. • Call 911 or emergency medical service. • Remove and isolate contaminated clothing and shoes. • In case of contact with substance, immediately flush skin or eyes with running water for at lea st 2 minutes. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • For further assistance, contact your local Poison Control Center. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances (Irritating) ERG2004 159 POTENTIAL HAZARDS HEALTH • Inhalation of vapors or dust is extremely irritating. • May cause burning ofeyes and flow of tears. • May cause coughing, difficult breathing and nausea. • B rief exposure effects lastonly a few minutes. • Exposure in an enclosed area may be very harmful. • Fire will produce irritating, corrosive and/or toxic gases. • R unoff from fire control or dilution water may cause pollution. FIRE OR EXPLOSION • Some of these materials may burn, butnone ignite readily. • Containers may explode when heated. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stayupwind. • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. EVACUATION Large Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances (Irritating) GUIDE 159 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical, C0 2 , water spray or regular foam. Large Fires • Water spray, fog or regularfoam. • Move containers from fire area if you can do it without risk. • Dike fire control water for later disposal; do not scatter the material. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Do notgetwaterinside containers. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • Do nottouchorwalk through spilled material. • Stop leak if you can do it without risk. • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. Small Spills • Take up with sand or other non-combustible absorbent mate rial and place in to containers for later disposal. Large Spills • Dike far ahead of liquid spill for later disposal. • Prevententry into waterways, sewers, basements orconfined areas. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • For minor skin con tact, a void spreading mate rial on unaffected skin. • Keep victim warm and quiet. • Effects should disappear after individual has been exposed to fresh air for approximately 10 minutes. • E nsure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Halogenated Solvents ERG2004 160 POTENTIAL HAZARDS HEALTH • Toxic by ingestion. • Vapors may cause dizziness or suffocation. • Exposure in an enclosed area may be very harmful. • Contactmayirritateorburnskinandeyes. • Fire may produce irritating and/ortoxic gases. • R unoff from fire control or dilution water may cause pollution. FIRE OR EXPLOSION • Some ofthese materials mayburn, butnone ignite readily. • M ost vapors are heavier than air. • Air/vapor mixtures may explode when ignited. • Con tainermayexp lode in heat of fire. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast50 meters (150 feet) in all directions. • Keep unauthorized personnel away. • S tay upwind. • Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Halogenated Solvents GUIDE 160 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical, C0 2 or water spray. Large Fires • D ry chem ic a I, CO 2 , ale oho I- resistant foam or water spray. • Move containers from fire area if you can do it without risk. • Dike fire control water for later disposal; do not scatter the material. Fire involving Tanks or Car/Trailer Loads • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Stop leak if you can do it without risk. Small Liquid Spills • Take up with sand, earth or other non-combustible absorbent mate rial. Large Spills • Dike far ahead of liquid spill for later disposal. • Prevententry into waterways, sewers, basements orconfined areas. FIRST AID • Move victim to fresh air. • C all 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • For minor skin con tact, a void spreading mate rial on unaffected skin. • Wash skin with soap and water. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Radioactive Materials ERG2004 161 (Low Level Radiation) POTENTIAL HAZARDS HEALTH • Radiation presents minimal risk to transport workers, emergency response personnel and the public during transportation accidents. Packaging durability increases as potential hazard of radioactive content increases. • Very low levels of contained radioactive materials and low radiation levels outside packages result in low risks to people. Damaged packages may release measurable amounts of radioactive material, but the resulting risks are expected to be low. • Some radioactive mate rials cannot be detected by commonly available instruments. • Packages do not have RADIOACTIVE I, II, or III labels. Some may have EMPTY labels or may have the word "R adioactive" in the package marking. FIRE OR EXPLOSION • Some of these materials may burn, but most do not ignite readily. • M any ha ve ca rd boa rd o uter packaging; con tent (physic ally la rge or small) can be of many differentphysical forms. • Radioactivity does not change flam inability or other properties of materials. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority for measuring radiation levels. • Radiation Authority must be notified of accident conditions. Radiation Authority is usually responsible for decisions about radiological consequences and closure of emergencies. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast25 meters (75 feet) in all directions. • S tay upwind. • Keep unauthorized personnel away. • Detain or isolate uninjured persons or equipment suspected to be contaminated; delay decontamination and cleanup until instructions are received from Radiation Authority. PROTECTIVE CLOTHING • Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters' protective clothing will provide adequate protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • When a large quantity of this material is involved in a major fire, consider an initial evacuation distance of 300 meters (1000 feet) in all directions. ERG2004 Radioactive Materials GUIDE (Low Level Radiation) l A l EMERGENCY RESPONSE FIRE • Presence of radioactive mate rial will not influence the fire control pro cesses and should not influence selection of techniques. • Move containers from fire area if you can do it without risk. • Do not move damaged packages; move undamaged packages out of fire zone. Small Fires • D ry chemical, CO 2 , water spray or regular foam. Large Fires • Water spray, fog (flooding amounts). SPILL OR LEAK • Do not touch damaged packages or spilled mate rial. • Cover liquid spill with sand, earth or other non-combustible absorbent mate rial. • Co ve r powder spill with plastic sheet or tarp to minimize spreading. FIRST AID • Medical problems take priority over radiological concerns. • Use first aid treatment according to the nature of the injury. • Do not delay care and transport of a seriously injured person. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Injured persons contaminated by con tact with re leased mate rial a re not a serious hazard to health care personnel, equipment or facilities. • E nsure that medical personnel are aware of the materia l(s) involved, take precautions to protectthemselves and preventspread of contamination. GUIDE Radioactive Materials 162 (Low to Moderate Level Radiation) ERG2004 POTENTIAL HAZARDS HEALTH • Radiation presents minimal risk to transport workers, emergency response personnel and the public during transportation accidents. Packaging durability increases as potential hazard of radioactive content increases. • Undamaged packages are safe. Contents of damaged packages may cause higher externa I radiation exposure, or both external and internal radiation exposure if contents are released. • Low radiation hazard when material is inside container. If material is released from package or bulk container, hazard will vary from low to moderate. Level of hazard will depend on the type and a mount of radioactivity, the kind of material it is in, and/or the surfaces it is on. • Some mate rial may be re leased from packages during accidents of mode rate severity but risks to people are notgreat. • Released radioactive materials or contaminated objects usually will be visible if packaging fails. • Some exclusive use shipments of bulk and packaged materials will not have "RADIOACTIVE" labels. Placards, markings and shipping papers provide identification. • Some packages may have a "RADIOACTIVE "label and a second hazard label. The second hazard is usually greaterthan the radiation hazard; so follow this GUIDE as well as the response GUIDE forthe second hazard class label. • Some radio active mate rials cannot be detected by commonly available instruments. • R unoff from control of cargo fire may cause low-level pollution. FIRE OR EXPLOSION • Some ofthese materials may burn, butmostdo notignite readily. • Uranium and Thorium metal cuttings may ignite spontaneously if exposed to air (see GUIDE 136). • Nitrates are oxidizers and may ignite other combustibles (see GUIDE 141), PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority for measuring radiation levels. • Radiation Authority must be notified of accident conditions. Radiation Authority is usually responsible for decisions about radiological consequences and closure of emergencies. • As an immediate precautionarymeasure, isolate spillor leakarea foratleast25 meters (75 feet) in all directions. • Stay upwind. • Keep unauthorized personnel away. • Detain or isolate uninjured persons or equipment suspected to be contaminated; delay decontamination and cleanup until instructions are received from Radiation Authority, PROTECTIVE CLOTHING • Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters' protective clothing will provide adequate protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • When a large quantity of this material is involved in a major fire, consider an initial evacuation distance of 300 meters (1000 feet) in all directions. ERG2004 Radioactive Materials GUIDE (Low to Moderate Level Radiation) 162 EMERGENCY RESPONSE FIRE • Presence of radioactive mate rial will not influence the fire control pro cesses and should not influence selection of techniques. • Move containers from fire area if you can do it without risk. • Do not move damaged packages; move undamaged packages out of fire zone. Small Fires • D ry chemical, CO 2 , water spray or regular foam. Large Fires • Water spray, fog (flooding amounts). • Dike fire-control water for later disposal. SPILL OR LEAK • Do not touch damaged packages or spilled mate rial. • Cover liquid spill with sand, earth or other non-combustible absorbent mate rial. • Dike to collect large liquid spills. • Co ve r powder spill with plastic sheet or tarp to minimize spreading. FIRST AID • Medical problems take priority over radiological concerns. • Use first aid treatment according to the nature of the injury. • Do notdelaycare and transportof a seriously injured person. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • In case of con tact with substance, wipe from skin immediately; flush skin or eyes with running waterforatleast20 minutes. • Injured persons contaminated by con tact with released material are not a serious hazard to health care personnel, equipmentorfacilities. • Ensure thatmedical personnel are aware of the material(s) involved, take precautions to protectthemselves and preventspread of contamination. GUIDE Radioactive Materials 163 (Low to High Level Radiation) ERG2004 POTENTIAL HAZARDS HEALTH • Radiation presents minimal risk to transportworkers, emergency response personnel and the public during transportation accidents. Packaging durability increases as potential hazard of radioactive content increases. • Undamaged packages are safe. Contents of damaged packages may cause higherexternal radiation exposure, or both external and internal radiation exposure if contents are released. • Type A packages (cartons, boxes, drums, articles, etc.) identified as "Type A" by marking on packages or by shipping papers contain non-life endangering amounts. Partial releases might be expected if 'Type A" packages are damaged in moderately severe accidents. • Type B packages, and the rarely occurring Type C packages, (large and small, usually metal) contain the most hazardous amounts. They can be identified by package markings or by shipping papers. Life threatening conditions may exist only if contents are released or package shielding fails. Because of design, evaluation and testing of packages, these conditions would be expected only foraccidents of utmost severity. • The rarely occurring "Special Arrangement" shipments may be of Type A, Type B orTypeC packages. Package type will be marked on packages, and shipment details will be on shipping papers. • Radioactive White-I labels indicate radiation levels outside single, isolated, undamaged packages are very low (less than 0.005 mSv/h (0.5 mrem/h)). • RadioactiveYellow-ll and Yellow-Ill labeled packages have higherradiation levels. The transportindex (Tl) on the label identifies the maximum radiation level in mrem/h one meterfrom a single, isolated, undamaged package. • Some radioactive materials cannot be detected by commonly available instruments. • Waterfrom cargo fire control may cause pollution. FIRE OR EXPLOSION • Some of these materials may burn, but most do not ignite readily, • Radioactivity does not change fla mma bility or other properties of materials. • Type B packages are designed and evaluated to withstand total engulfment in flames at temperatures of 800 °C (147 5°F) for a period of 30 minutes. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority for measuring radiation levels. • Radiation Authority mustbe notified of accidentconditions. Radiation Authority is usually responsible for decisions about radiological consequences and closure of emergencies. • As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all directions. • Stay upwind. • Keep unauthorized personnel away. • Detain orisolate uninjured persons orequipmentsuspected to be contaminated; delay decontamination and cleanup until instructions are received from Radiation Authority. PROTECTIVE CLOTHING • Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters' protective clothing will provide adequate protection against internal radiation exposure, but not external radiation exposure. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • When a large quantity of this material is involved in a major fire, consider an initial evacuation distance of 300 meters (1000 feet) in all directions. ERG2004 Radioactive Materials GUIDE (Low to High Level Radiation) 163 EMERGENCY RESPONSE FIRE • Presence of radioactive material will not influence the fire control processes and should not influence selection of techniques. • Move containers from fire area if you can do it without risk, • Do notmove damaged packages; move undamaged packages outoffire zone. Small Fires • Dry chemical, CO 2 , water spray or regular foam. Large Fires • Waterspray, fog (flooding amounts). • Dike fire-control water for later disposal. SPILL OR LEAK • Do nottouch damaged packages or spilled material. • Damp surfaces on undamaged or slightly damaged packages are seldom an indication of packaging failure. Most packaging for liquid content have inner containers and/or inner absorbent materials. • Cover liquid spill with sand, earth or other non-combustible absorbent material. FIRST AID • Medical problems take priority over radiological concerns. • Use firstaid treatmentaccording to the nature of the injury. • Do not delay care and trans port of a seriously injured person. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • In case of contactwith substance, immediately flush skin oreyes with running waterforat least 20 minutes. • Injured persons contaminated by contactwith released material are nota serious hazard to health care personnel, equipmentorfacilities. • Ensure that medical personnel are aware of the materia l(s) involved, take precautions to protect themselves and preventspread of contamination. GUIDE Radioactive Materials (Special Form /Low to ERG2004 1 64 ^ IGH '" EVEL External Radiation) POTENTIAL HAZARDS HEALTH Radiation presents minimal risk to transport workers, emergency response personnel and the public during transportation accidents. Packaging durability increases as potential hazard of radioactive content increases. Undamaged packages are safe; contents ofdamaged packages maycause external radiation exposure, and much higherexternal exposure if contents (source capsules) are released. Contamination and internal radiation hazards are notexpected, butnotimpossible. Type A packages (cartons, boxes, drums, articles, etc.) identified as 'Type A" by marking on packages or by shipping papers contain non-life endangering amounts. Radioactive sources may be released if "Type A" packages are damaged in moderately severe accidents. Type B packages, and the rarely occurring Type C packages, (large and small, usually metal) contain the most hazardous amounts. They can be identified by package markings or by shipping papers. Life threatening conditions may exist only if contents are released or package shielding fails. Because of design, evaluation and testing of packages, these conditions would be expected only for accidents of utmost severity. Radioactive White-I labels indicate radiation levels outside single, isolated, undamaged packages are very low (less than 0.005 mSv/h (0.5 mrem/h)). Radioactive Yellow-ll and Yellow-Ill labeled packages have higher radiation levels. The transport index (Tl) on the label identifies the maximum radiation level in mrem/h one meterfrom a single, isolated, undamaged package. Radiation from the package contents, usually in durable metal capsules, can be detected by most radiation instruments. Waterfrom cargo fire control is notexpected to cause pollution. FIRE OR EXPLOSION Packagings can burn completely without risk of content loss from sealed source capsule. Radioactivity does not change flammability or other properties of materials. Radioactive source capsules and Type B packages are designed and evaluated to withstand total engulfmentin flames at temperatures of 800°C (1475°F). PUBLIC SAFETY CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority for measuring radiation levels. Radiation Authority must be notified of accident conditions. Radiation Authority is usually responsible for decisions aboutradiological consequences and closure of emergencies. As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all directions. Stay upwind. • Keep unauthorized personnel away. Delay final cleanup until instructions oradvice is received from Radiation Authority. PROTECTIVE CLOTHING Positive pressure self-contained breathing apparatus (5 CB A) and structural firefighters' protective clothing will provide adequate protection againstinternal radiation exposure, butnot external radiation exposure. EVACUATION Large Spill Consider initial downwind evacuation for at least 100 meters (330 feet). Fire When a large quantity of this material is involved in a majorfire, consideran initial evacuation distance of 300 meters (1000 feet) in all directions. Page 276 ERG2004 Radioactive Materials (Special Form/Low to GUIDE High Level External Radiation) l A A EMERGENCY RESPONSE FIRE • Presence of radioactive material will not influence the fire control processes and should not influence selection of techniques. • Move containers from fire area if you can do it without risk, • Do notmove damaged packages; move undamaged packages outoffire zone. Small Fires • Dry chemical, CO 2 , water spray or regular foam. Large Fires • Waterspray, fog (flooding amounts). SPILL OR LEAK • Do nottouch damaged packages or spilled material. • Damp surfaces on undamaged or slightly damaged packages are seldom an indication of packaging failure. Contents are seldom liquid. Content is usually a metal capsule, easily seen if released from package. • If source capsule is identified as being out of package, DO NOT TOUCH. Stay away and await advice from Radiation Authority. FIRST AID • Medical problems take priority over radiological concerns. • Use firstaid treatmentaccording to the nature of the injury. • Do not delay care and trans port of a seriously injured person. • Persons exposed to special form sources are notlikely to be contaminated with radioactive material. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult, • Injured persons contaminated by contactwith released material are nota serious hazard to health care personnel, equipmentorfacilities. • Ensure thatmedical personnel are aware of the material(s) involved, take precautions to protect themselves and preventspread of contamination. GUIDE Radioactive Materials 165 (Fissile/Low to High Level Radiation) ERG2004 POTENTIAL HAZARDS HEALTH ■ Radiation presents minimal risk to transport workers, emergency response personnel and the public during transportation accidents. Packaging durability increases as potential radiation and criticality hazards of the content increase. • Undamaged packages are safe. Contents ofdamaged packages maycause higherexternal radiation exposure, or both external and internal radiation exposure if contents are released. • Type AF or IF packages, identified by package markings, do not contain life-threatening amounts of material. External radiation levels are low and packages are designed, evaluated and tested to control releases and to prevent a fission chain reaction under severe transport conditions. • Type B(U)F, B(M)F and CF packages (identified by markings on packages or shipping papers) contain potentially life endangering amounts. Because of design, evaluation and testing of packages, fission chain reactions are prevented and releases are not expected to be life endangering for all accidents except those of utmost severity. • The rarely occurring "Special Arrangement" shipments may be of Type AF, BF orCF packages. Package type will be marked on packages, and shipment details will be on shipping papers, • The transport index (Tl) shown on labels ora shipping papermightnotindicate the radiation level atone meter from a single, isolated, undamaged package; instead, it might relate to controls needed during transport because of the fissile properties of the materials. Alternatively, the fissile nature of the contents may be indicated by a criticality safety index (C5I) on a special FISSILE label oron the shipping paper. • Some radioactive materials cannot be detected by commonly available instruments. • Waterfrom cargo fire control is notexpected to cause pollution. FIRE OR EXPLOSION • These materials are seldom flammable. Packages are designed to withstand fires without damage to contents. • Radioactivity does notchange flammability or other properties of materials. • Type AF, IF, B(U)F, B(M)F and CF packages are designed and evaluated to withstand total engulfment in flames at temperatures of 800 °C (1475° F) for a period of 30 minutes. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority for measuring radiation levels. • Radiation Authority mustbe notified of accidentconditions. Radiation Authority is usually responsible for decisions about radiological consequences and closure of emergencies. • As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all directions. • Stay upwind. • Keep unauthorized personnel away. • Detain orisolate uninjured persons orequipmentsuspected to be contaminated; delay decontamination and cleanup until instructions are received from Radiation Authority. PROTECTIVE CLOTHING • Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters' protective clothing will provide adequate protection against internal radiation exposure, but not external radiation exposure. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • When a large quantity of this material is involved in a major fire, consideran initial evacuation distance of 300 meters (1000 feet) in all directions. ERG2004 Radioactive Materials GUIDE (Fissile/Low to High Level Radiation) 165 EMERGENCY RESPONSE FIRE • Presence of radioactive material will not influence the fire control processes and should not influence selection of techniques. • Move containers from fire area if you can do it without risk, • Do notmove damaged packages; move undamaged packages outoffire zone. Small Fires • Dry chemical, CO 2 , water spray or regular foam. Large Fires • Waterspray, fog (flooding amounts). SPILL OR LEAK • Do nottouch damaged packages or spilled material. • Damp surfaces on undamaged or slightly damaged packages are seldom an indication of packaging failure. Most packaging for liquid content have inner containers and/or inner absorbent materials. Liquid Spills • Package contents are seldom liquid. If any radioactive contamination resulting from a liquid release is present, it probably will be low-level. FIRST AID • Medical problems take priority over radiological concerns. • Use firstaid treatmentaccording to the nature of the injury. • Do not delay care and trans port of a seriously injured person. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • In case of contactwith substance, immediately flush skin oreyes with running waterforatleast 20 minutes. • Injured persons contaminated by contactwith released material are nota serious hazard to health care personnel, equipmentorfacilities. • Ensure thatmedical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. GUIDE Radioactive Materials - Corrosive ERG2004 1 66 (Uranium Hexafluoride/Water-Sensitive) POTENTIAL HAZARDS HEALTH • Radiation presents minimal risk to transport workers, emergency response personnel and the public during transportation accidents. Packaging durability increases as potential radiation and critic a lity hazards of the content increase. • Chemical hazard greatly exceeds radiation hazard. • Substance reacts with water and water vapor in air to form toxic and corrosive hydrogen fluoride gas and an extremely irritating and corrosive, white-colored, water-soluble residue. • If inhaled, may be fatal. • Directcontactcauses burns to skin, eyes, and respiratory tract. • Low-level radioactive material; very low radiation hazard to people. • Runoff from control of cargo fire may cause low-level pollution. FIRE OR EXPLOSION • S ubstance does not burn. • The material may react violently with fuels. • Containers in protective overpacks (horizontal cylindrical shape with short legs for tie- downs), are identified with "AF", "B (U ) F " or "H(U)" on shipping papers or by markings on the overpacks. They are designed and evaluated to withstand severe conditions including total engulfment in flames at temperatures of 800°C (1475 °F). • Bare filled cylinders, identified with U N 2978 as partof the marking (may also be marked H (U) or H (M)), may rupture in heat of engulfing fire; bare empty (except for residue) cylinders will not rupture in fires. • Radioactivity does not change fla mma bility or other properties of materials. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority for measuring radiation levels. • Radiation Authority must be notified of accident conditions. Radiation Authority is usually responsible for decisions about radio logical consequences and closure of emergencies. • As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all directions. • Stay upwind. • Keep unauthorized personnel away. • Detain or isolate uninjured persons or equipment suspected to be contaminated; delay decontamination and cleanup until instructions are received from Radiation Authority, PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCBA). • Wear chemical protective do thing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct con tact with the substance is possible. EVACUATION Large Spill • See the Table of Initial Isolation and Protective Action Distances. Fire • When a large quantity of this material is involved in a majorfire, consideran initial evacuation distance of 300 meters (1000 feet) in all directions. ERG2004 Radioactive Materials - Corrosive GUIDE (Uranium Hexafluoride/Water-Sensitive) ] EMERGENCY RESPONSE FIRE • DO NOT USE WATER OR FOAM ON MATERIAL ITSELF. • Move containers from fire area if you can do it without risk. Small Fires • Dry chemical or C0 2 . Large Fires • Water spray, fog or regular foam. • Cool containers with flooding quantities of water until well after fire is out. • If this is impossible, withdraw from area and let fire burn. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Do not touch damaged packages or spilled mate rial. • Without fire or smoke, leak will be evident by visible and irritating vapors and residue forming atthe pointof release. • Use fine water spray to reduce vapors; do not put water directly on point of material release from container. • Residue buildup may self-seal small leaks. • Dike far ahead of spill to collect runoff water. FIRST AID • Medical problems take priority over radiological concerns. • Use firstaid treatmentaccording to the nature of the injury. • Do not delay care and transport of a seriously injured person. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. • Injured persons contaminated by con tact with re leased mate rial a re not a serious hazard to health care personnel, equipment or facilities. • Ensure that medical personnel are aware of the materia l(s) involved, take precautions to protectthemselves and preventspread of contamination. GUIDE Fluorine (Refrigerated Liquid) ERG2004 167 POTENTIAL HAZARDS HEALTH • TOXIC; may be fatal if inhaled. • Vapors are extremely irritating. • Contact with gas or liquefied gas will cause burns, severe injury and/or frostbite. • Vapors from liquefied gas are initially heavier than air and spread along ground. • Runoff from fire control may cause pollution. FIRE OR EXPLOSION • Substa nee does not burn but will support combustion. • This is a strong oxidizer and will re act vigorously or explosively with many materials including fuels. • May ignite combustibles (wood, paper, oil, clothing, etc.). • Vapor explosion and poison hazard indoors, outdoors or in sewers. • Containers may explode when heated. • R uptured cylinders may rocket. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • Stay upwind. • Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks), • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. • Always wearthermal protective clothing when handling refrigerated/cryogenic liquids. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances. Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions. ERG2004 Fluorine (Refrigerated Liquid) GUIDE 167 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical, soda ash, lime or sand. Large Fires • Water spray, fog (flooding amounts). • Do not get water inside containers. • Move containers from fire area if you can do it without risk. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well after fire is out. • Donotdirectwateratsource of leakorsafety devices; icingmayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and letfire burn. SPILL OR LEAK • Do not touch or walk through spilled material. • If you have not donned special protective clothing approved for this material, do not expose yourself to any risk of this material touching you. • Do not direct water at spill or source of leak. • A fine water spray remotely directed to the edge of the spill pool can be used to direct and maintain a hot flare fire which will burn the spilled material in a controlled manner. • Keep combustibles (wood, paper, oil, etc.) a way from spilled material. • Stop leak if you can do it without risk. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • If possible, turn leaking containers so thatgas escapes ratherthan liquid. • Prevent entry into waterways, sewers, basements or confined areas. • Isolate area until gas has dispersed. • Ventilate the area. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service, • G ive artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Clothing frozen to the skin should be thawed before being removed. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Keep victim under observation. • Effects of contactor inhalation may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Carbon Monoxide (Refrigerated Liquid) ERG2004 168 POTENTIAL HAZARDS HEALTH • TOXIC; Extremely Hazardous. • Inhalation extremely dangerous; may be fatal. • Contact with gas or liquefied gas may cause burns, 5 eve re injury and/or frostbite. • Odorless, will not be detected by sense ofsmell. FIRE OR EXPLOSION • EXTREMELY FLAMMABLE. • May be ignited byheat, sparks orflames. • Flame may be invisible. • Containers may explode when heated. • Vapor explosion and poison hazard indoors, outdoors or in sewers. • Vapors from liquefied gas a re initially heavier than air and spread a long ground. • Vapors may travel to source of ignition and flash back. • Runoff may ere ate fire or explosion hazard. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leakarea foratleast 100 meters (330 feet) in all directions. • Keep unauthorized personnel away. • Stayupwind. • Many gases a re heavier than air and will spread a long ground and collect in low or confined areas (sewers, basements, tanks). • Keep out of low areas. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. • Always wearthermal protective clothing when handling refrigerated/cryogenic liquids. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances. Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Carbon Monoxide (Refrigerated Liquid) GUIDE 168 EMERGENCY RESPONSE FIRE • DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. Small Fires • Dry chemical, C0 2 or water spray. Large Fires • Water spray, fog or regular foam. • Move containers from fire area if you can do it without risk. Fire involving Tanks • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. • Cool containers with flooding quantities of water until well afterfire is out. • Donotdi rectwateratsourceofleakorsafety devices; icingmayoccur. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • All equipment used when handling the product must be grounded. • Fully encapsulating, vapor protective do thing should be worn for spills and leaks with no fire. • Do not touch or walk thro ugh spilled mate rial. • Stop leak if you can do it without risk. • Use waterspray to reduce vapors ordivertvaporcloud drift. Avoid allowing water runoff to contact spilled material. • Do notdirect water at spill or source of leak. • If possible, turn leaking containers so thatgas escapes ratherthan liquid. • Prevententry into waterways, sewers, basements orconfined areas. • Isolate area until gas has dispersed. FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service, • Give artificial respiration if victim is not breathing, • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. • Keep victim warm and quiet. • Keep victim under observation. • Effects of contactor inhalation may be delayed. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Aluminum (Molten) ERG2004 169 POTENTIAL HAZARDS FIRE OR EXPLOSION • Substance is transported in moltenform ata temperature above 705°C (1300°F). • Violent reaction with water; con tact may cause an explosion or may produce a flammable gas. • Will ignite combustible materials (wood, paper, oil, debris, etc.). • Contact with nitrates or other oxidizers may cause an explosion. • Con tact with containers or other mate rials, including co Id, wet or dirty too Is, may cause an explosion. • Con ta ct with cone re te will cause spalling and small pops. HEALTH • Contact causes severe burns to skin and eyes. • Fire may produce irritating and/ortoxic gases. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. • Keep unauthorized personnel away. • Ventilate closed spaces before entering. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A), • Wear flame retardant structural firefighters' protective clothing, including fa ceshie Id, helmet and gloves, this will provide limited thermal protection. ERG2004 Aluminum (Molten) GUIDE 169 EMERGENCY RESPONSE FIRE • Do Not Use Water, except in life threatening situations and then only in a fine spray. • Do not use halogenated extinguishing agents or foam. • Move combustibles outofpath ofadvancing pool ifyou can do so withoutrisk. • Extinguish fires started by molten material by using appropriate method for the burning material; keep water, halogenated extinguishing agents and foam away from the molten material. SPILL OR LEAK • Do nottouchorwalk through spilled material. • Do notattemptto stop leak, due to dangerof explosion. • Keep combustibles (wood, paper, oil, etc.) awayfrom spilled material. • Substance is very fluid, spreads quickly, and maysplash. Do nottry to stop itwith shovels orotherobjects. • Dike far ahead of spill; use dry sand to con tain the flow of material. • Where possible allow molten material to solidify naturally. • Avoid contact even after material solidifies. Molten, heated and cold aluminum look a like; do not touch unless you know it is cold. • Clean up under the supervision of an expert after material has solidified. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service, • G ive artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • For severe burns, immediate medical attention is required. • Removal of solidified molten material from skin requires medical assistance. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. GUIDE Metals (Powders, Dusts, Shavings, Borings, ERG2004 170 Turnings, or Cuttings, etc.) POTENTIAL HAZARDS FIRE OR EXPLOSION • May react violently or explosively on con tact with water. • Some are transported in flammable liquids. • May be ignited by friction, heat, sparks or flames. • Some of these materials will burn with intense heat. • Dusts or fumes may form explosive mixtures in air. • Containers may explode when heated. • M ay re-ignite after fire is extinguished. HEALTH • Oxides from metallic fires are a severe health hazard. • Inhalation or contactwith substance or decomposition products maycause severe injury ordeath. • Fire may produce irritating, corrosive and/or toxic gases. • Runoff from fire control or dilution water may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Stayupwind. • Keep unauthorized personnel away. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 50 meters (160 feet). Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Metals (Powders, Dusts, Shavings, Borings, GUIDE Turnings, or Cuttings, etc.) ] 7 Q EMERGENCY RESPONSE FIRE • DO NOT USE WATER, FOAM OR C0 2 . • Dousing metallic fires with water may gene rate hydrogen gas, an extremely dangerous explosion hazard, particularly if fire is in a confined environment (i.e., building, cargo hold, etc.). • Use DRY sand, graphite powder, dry sodium chloride based extinguishers, G-l 8 orMet-L-X 8 powder. • Confining and smothering metalfires is preferable ratherthan applying water. • Move containers from fire area if you can do it without risk. Fire involving Tanks or Car/Trailer Loads • If impossible to extinguish, protect surroundings and allow fire to burn itself out. SPILL OR LEAK • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). • Do nottouchorwalk through spilled material. • Stop leak if you can do it without risk. • Prevent entry into waterways, sewers, basements or confined areas. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service, • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Substances (Low to Moderate Hazard) ERG2004 171 POTENTIAL HAZARDS FIRE OR EXPLOSION • Some may burn butnone ignite readily. • Containers may explode when heated. • Some may be transported hot. HEALTH • Inhalation of material may be harmful. • Contactmaycause burns to skinande yes. • Inhalation of Asbestos dust may have a damaging effect on the lungs. • Firemayproduce irritating, corrosive and/or toxic gases. • Some liquids produce vapors that may cause dizziness or suffocation. • Runoff from fire control may cause pollution. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Keep unauthorized personnel away. • Stayupwind. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Spill • See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY". Fire • If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. ERG2004 Substances (Low to Moderate Hazard) GUIDE 171 EMERGENCY RESPONSE FIRE Small Fires • Dry chemical, C0 2 , water spray or regular foam. Large Fires • Water spray, fog or regularfoam. • Move containers from fire area if you can do it without risk. • Do not scatter spilled material with high pressure water streams. • Dike fire-control water for later disposal. Fire involving Tanks • Cool containers with flooding quantities of water until well afterfire is out. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. • ALWAYS stay away from tanks engulfed in fire. SPILL OR LEAK • Do nottouch or walk through spilled material. • Stop leak if you can do it without risk. • P revent dust cloud. • Avoid inhalation of asbestos dust. Small Dry Spills • With clean shove I place mate rial in to clean, dry container and cover loosely; move containers from spill area. Small Spills • Take up with sand or other non-combustible absorbent mate rial and place into containers forlaterdisposal. Large Spills • Dike far ahead of liquid spill for later disposal. • Cover powder spill with plastic sheet or tarp to minimize spreading. • Prevent entry into waterways, sewers, basements or confined areas. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service, • G ive artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • E nsure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. GUIDE Gallium and Mercury ERG2004 172 POTENTIAL HAZARDS HEALTH • Inhalation of vapors or con tact with substance will result in contamination and potential harmful effects. • Fire will produce irritating, corrosive and/ortoxic gases. FIRE OR EXPLOSION • Non-combustible, substance itself does not burn but may react upon heating to produce corrosive and/ortoxic fumes. • R unoff may pollute waterways. PUBLIC SAFETY • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. • As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. • S tay upwind. • Keep unauthorized personnel away. PROTECTIVE CLOTHING • Wear positive pressure self-contained breathing apparatus (SCB A). • Structural firefighters' protective clothing will only provide limited protection. EVACUATION Large Spill • Consider initial downwind evacuation for at least 100 meters (330 feet). Fire • When any large container is involved in a fire, consider initial evacuation for 500 meters (1/3 mile) in all directions. ERG2004 Gallium and Mercury GUIDE 172 EMERGENCY RESPONSE FIRE • Use extinguishing agent suitable for type of surrounding fire. • Do not direct water at the heated metal. SPILL OR LEAK • Do nottouch or walk through spilled material. • Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. • Stop leak if you can do it without risk. • Prevententry into waterways, sewers, basements orconfined areas, • Donotusesteeloraluminumtoolsorequipment. • Cover with earth, sand or other non-combustible material followed with plastic sheet to minimize spreading orcontactwith rain. • For mercury, use a mercury spill kit. • Mercury spill areas may be subsequently treated with calcium sulphide/calcium sulfide or with sodium thiosulphate/sodium thiosulfate wash to neutralize any residual mercury. FIRST AID • Move victim to fresh air. • Call 911 oremergency medical service. • Give artificial respiration if victim is not breathing. • Administer oxygen if breathing is difficult. • Remove and isolate contaminated clothing and shoes. • In case of con tact with substance, immediately flush skin or eyes with running water for at least 20 minutes. • Keep victim warm and quiet. • Ensure that medical personnel are aware of the materia l(s) involved and take precautions to protect themselves. NOTES Page294 INTRODUCTION TO THE TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES The Table of Initial Isolation and Protective Action Distances suggests distances useful to protect people from vapors resulting from spills involving dangerous goods which are considered toxic by inhalation (TIH), including certain chemical warfare agents, orwhich produce toxic gases upon contactwith water. TheTable provides firstresponders with initial guidance until technically qualified emergency response personnel are available. Distances show areas likely to be affected during the first 30 minutes after materials are spilled and could increase with time. The Initial Isolation Zone defines an area SURROUNDING the incident in which persons may be exposed to dangerous (upwind) and life threatening (downwind) concentrations of material. The Protective Action Zone defines an area DOWNWIND from the incident in which persons may become incapacitated and unable to take protective action and/or incur serious or irreversible health effects. The Table provides specific guidance for small and large spills occurring day or night. Adjusting distances fora specific incidentinvolves many interdependentvariables and should be made only by personnel technically qualified to make such adjustments. Forthis reason, no precise guidance can be provided in this documentto aid in adjusting the table distances; however, general guidance follows. Factors That May Change the Protective Action Distances The guide for a material (orange-bordered pages) clearly indicates under the section EVACUATION - Fire, the evacuation distance required to protectagainstfragmentation hazard of a large container. If the material becomes involved in a FIRE, the toxic hazard may become less importantthan the fire or explosion hazard. If more than one tank car, cargo tank, portable tank, or large cylinder involved in the incident is leaking, LARGE SPILL distances may need to be increased. Fora material with a protective action distance of 11.0+ km (7.0+miles), the actual distance can be larger in certain atmospheric conditions. If the dangerous goods vapor plume is channeled in a valley or between many tall buildings, distances may be larger than shown in the Table due to less mixing of the plume with the atmosphere. Daytime spills in regions with known strong inversions or snow cover, or occurring near sunset, accompanied by a steady wind, may require an increase in protective action distance. When these conditions are present, airborne contaminants mix and disperse more slowly and may travel much farther downwind. In addition, protective action distances may be larger for liquid spills when either the material or outdoor temperature exceeds 30°C (86°F ). Materials which reactwith waterto produce large amounts of toxic gases are included in the Table of Initial Isolation and P rotective Action Distances. Note thatsome water-reactive materials P3Q3295 (WRM) which are also TIH (e.g., Bromine trifluoride (1746), Thionyl chloride (1836), etc.) produce additionalTIH materials when spilled in water. Forthese materials, two entries are provided in the Table of Initial Isolation and Protective Action Distances (i.e., forspills on land and forspills in water). If it is not clear whether the spill is on land or in water, or in cases where the spill occurs both on land and in water, choose the larger Protective Action Distance. Following the Table of Initial Isolation and Protective Action Distances is a table that lists the materials which, when spilled in water, produce toxic gases. The toxic gases thatthese water-reactive materials (WRM) produce are also included in the Table. When a water-reactive TIH producing material is spilled into a river orstream, the source of the toxic gas may move with the currentand stretch from the spill point downstream fora substantial distance. Certain chemical warfare agents have been added to the Table of Initial Isolation and Protective Action Distances. The distances shown were calculated using worstcase scenarios forthese agents when used as a weapon. Initial isolation and protective action distances in this guidebook are derived from historical data on transportation incidents and the use of statistical models. For worstcase scenarios involving the instantaneous release of the entire contents of a package (e.g., as a resultof terrorism, sabotage orcatastrophic accident) the distances may increase. The increase can be estimated by multiplying the distances by a factorof two (2). Page296 PROTECTIVE ACTION DECISION FACTORS TO CONSIDER The choice of protective actions fora given situation depends on a number of factors. Forsome cases, evacuation may be the bestoption; in others, sheltering in-place may be the bestcourse. Sometimes, these two actions may be used in combination. In any emergency, officials need to quickly give the public instructions. The public will need continuing information and instructions while being evacuated orsheltered in-place. Properevaluation of the factors listed below will determine the effectiveness of evacuation or in- place protection. The importance of these factors can vary with emergency conditions. In specific emergencies, other factors may need to be identified and considered as well. This list indicates whatkind of information may be needed to make the initial decision. The Dangerous Goods Degree of health hazard Chemical and physical properties Amountinvolved Containment/control of release Rate of vapor movement The Population Threatened Location Numberof people Time available to evacuate orshelter in-place Ability to control evacuation or shelter in-place Building types and availability Special institutions or populations, e.g., nursing homes, hospitals, prisons Weather Conditions Effecton vaporand cloud movement Potential forchange Effecton evacuation or protection in-place Page297 PROTECTIVE ACTIONS Protective Actions are those steps taken to preserve the health and safety of emergency responders and the public during an incident involving releases of dangerous goods. The Table of Initial Isolation and Protective Action Distances (green-bordered pages) predicts the size of downwind areas which could be affected by a cloud of toxic gas. People in this area should be evacuated and/or sheltered in-place inside buildings. Isolate Hazard Area and Deny Entry means keep everybody away from the area if they are not directly involved in emergency response operations. Unprotected emergency re- sponders should not be allowed to enterthe isolation zone. This "isolation" task is done first to establish control over the area of operations. This is the first step for any protective actions that may follow. See the Table of Isolation and Protective Action Distances (green- bordered pages) for more detailed information on specific materials. Evacuate means move all people from a threatened area to a safer place. To perform an evacuation, there must be enough time for people to be warned, to get ready, and to leave an area. If there is enough time, evacuation is the best protective action. Begin evacuating people nearby and those outdoors in direct view of the scene. When additional help ar- rives, expand the area to be evacuated downwind and crosswind to at least the extent recommended in this guidebook. Even after people move to the distances recommended, they may not be completely safe from harm. They should not be permitted to congregate at such distances. Send evacuees to a definite place, by a specific route, far enough away so they will not have to be moved again if the wind shifts. Shelter In-Place means people should seek shelter inside a building and remain inside until the danger passes. Sheltering in-place is used when evacuating the public would cause greater risk than staying where they are, or when an evacuation cannot be performed. Direct the people inside to close all doors and windows and to shut off all ventilating, heating and cooling systems. In-place protection may not be the best op- tion if (a) the vapors are flammable; (b) if it will take a long time for the gas to clear the area; or (c) if buildings cannot be closed tightly. Vehicles can offer some protection for a short period if the windows are closed and the ventilating systems are shut off. Vehicles are not as effective as buildings for in-place protection. It is vital to maintain communications with competent persons inside the building so thatthey are advised about changing conditions. Persons protected-in-place should be warned to stay far from windows because of the danger from glass and projected metal fragments in a fire and/or explosion. Every dangerous goods incident is different. Each will have special problems and con- cerns. Action to protect the public must be selected carefully. These pages can help with initial decisions on how to protect the public. Officials must continue to gather information and monitor the situation until the threat is removed. Page298 BACKGROUND ON THE INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCE TABLE Initial Isolation and Protective Action Distances in this guidebook were determined for small and large spills occurring during day or night. The overall analysis was statistical in nature and utilized state-of-the-art emission rate and dispersion models; statistical release data from the U.S. DOT H M IS (Hazardous Materials Incident Reporting System) database; 5 years of meteorological observations from over 120 locations in United States, Canada and Mexico; and the most current toxicological exposure guidelines. For each chemical, thousands of hypothetical releases were modeled to account for the statistical variation in both release amountand atmospheric conditions. Based on this statistical sample, the 90% percentile Protective Action Distance for each chemical and category was selected to appear in the Table. A brief description of the analysis is provided below. A detailed report outlining the methodology and data used in the generation of the Initial Isolation and Protective Action Distances may be obtained from the U.S. Departmentof Transportation, Research and Special Programs Administration. Release amounts and emission rates into the atmosphere were statistically modeled based on (1) data from the U.S. DOT HMIS database; (2) containertypes and sizes authorized fortransport as specified in 49 CFR §172.101 and Partl73; (3) physical properties of the materials involved, and (4) atmospheric data from a historical database. The emission model calculated the release of vapor due to evaporation of pools on the ground, direct release of vapors from the container, or a combination of both, as would occur for liquefied gases which can flash to form both a vapor/ aerosol mixture and an evaporating pool. In addition, the emission model also calculated the emission of toxic vapor by-products generated from spilling water-reactive chemicals in water. S pills that involve releases of approximately 200 liters or less are considered S mall S pills, while spills that involve quantities greaterthan 200 liters are considered Large Spills. Downwind dispersion of the vapor was estimated for each case modeled. Atmospheric parameters affecting the dispersion, and the emission rate, were selected in a statistical fashion from a database containing hourly meteorological data from 120 cities in United States, Canada and Mexico. The dispersion calculation accounted for the time dependent emission rate from the source as well as the density of the vapor plume (i.e., heavy gas effects). Since atmospheric mixing is less effective at dispersing vapor plumes during nighttime, day and night were separated in the analysis. In the Table, "Day" refers to time periods after sunrise and before sunset, while "Night" includes all hours between sunsetand sunrise. Toxicological short-term exposure guidelines forthe chemicals were applied to determine the downwind distance to which persons may become incapacitated and unable to take protective action ormay incurserious health effects. Toxicological exposure guidelines were chosen from (1) emergency response guidelines, (2) occupational health guidelines, or (3) lethal concentrations determined from animal studies, as recommended by an independent panel of toxicological experts from industry and academia. Page299 HOW TO USE THE TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES (1) The responder should already have: Identified the material by its ID Numberand Name; (if an ID Number cannot be found, use the Name of Material index in the blue-bordered pages to locate that number.) Found the three-digit guide for that material in order to consult the emergency actions recommended jointly with this table; Noted the wind direction. (2) Look in this Table (the green-bordered pages) for the ID Number and Name of the Material involved in the incident. Some ID Numbers have more than one shipping name listed-look for the specific name of the material. (If the shipping name is not known and the Table lists more than one name forthe same ID Number, use the entry with the largest protective action distances.) (3) Determine if the incident involves a SMALL or LARGE spill and if DAY or NIGHT. Generally, a SMALL SPILL is one which involves a single, small package (e.g., a drum containing up to approximately 200 liters), a small cylinder, or a small leak from a large package. A LARGE SPILL is one which involves a spill from a large package, or multiple spills from many small packages. DAY is any time after sunrise and before sunset. NIGHT is anytime between sunsetand sunrise. (5) Look up the initial PROTECTIVE ACTION DISTANCE shown in the Table. For a given material, spill size, and whether day or night, the Table gives the downwind distance- in kilometers and miles- forwhich protective actions should be considered. Forpractical purposes, the Protective Action Zone (i.e., the area in which people are at risk of harmful exposure) is a square, whose length and width are the same as the downwind distance shown in the Table. Initial Isolation (4) Look up the initial ISOLATION distance. Direct all persons to move, in a crosswind direction, away from the spill to the distance specified- in meters and feet. Spill (6) Initiate Protective Actions to the extent possible, beginning with those closest to the spill site and working away from the site in the downwind direction. When a water- reactive TIH producing material is spilled into a river or stream, the source of the toxic gas may move with the currentorstretch from the spill point downstream fora substantial distance. The shape of the area in which protective actions should be taken (the Protective Action Zone) is shown in this figure. The spill is located at the center of the small circle. The larger circle represents the INITIAL ISOLATION zone around the spill. Wind Direction NOTE: See "Introduction To The Table Of Initial Isolation And Protective Action Distances" for factors which may increase or decrease Protective Action Distances. Call the emergency response telephone number listed on the shipping paper, or the appropriate response agency as soon as possible for additional information on the material, safety precautions, and mitigation procedures. TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 1005 Ammonia, anhydrous 1005 Ammonia, anhydrous, liquefied 1005 Ammonia, solution, with more than 50% Ammonia 1005 Anhydrous ammonia 1005 Anhydrous ammonia, liquefied 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi) 1008 Boron trifiuoride 1008 Boron trifiuoride, compressed 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 180 m (600 ft) 1.8 km (1.1 mi) 4.8 km (3.0 mi) 1016 Carbon monoxide 1016 Carbon monoxide, compressed 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.4 km (1.5 mi) 1017 Chlorine 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 7.4 km (4.6 mi) 1023 Coal gas 1023 Coal gas, compressed 30 m (100 ft) fi "") /fi 1 m\\ u.z Ktn (u.i mi) fi ~) in i mi) u.z Km (u.i mi) 60 m (200 ft) fi A l/m /fi ") wy\\ u.4Km (u.z mi) fi C \yyy\ /fi 1 mi\ u.d Km (ujmi) 1026 Cyanogen 1026 Cyanogen, liquefied 1026 Cyanogen gas 30 m (100 ft) fi "") l/hvi /fi ") rvy\\ u.z Km \u.i mi) 1 ~) l,m in Q mi) i.z Km (u.o mi) 120 m (400 ft) 1 1 Lm /CI 1 mil i.i Km [u.i mi) A 1 \ym 11 1 mi\ 4J Km (z./mi) 1040 Ethylene oxide 1040 Ethylene oxide with Nitrogen 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 1045 Fluorine 1045 Fluorine, compressed 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi) 1048 Hydrogen bromide, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 180 m (600 ft) 1.8 km (1.1 mi) 5.7 km (3.6 mi) 1050 Hydrogen chloride, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 360 m (1200 ft) 3.6 km (2.2 mi) 10.4 km (6.5 mi) 1051 AC (when used as a weapon) 60 m (200 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 500 m (1500 ft) 1.7 km (1.0 mi) 3.9 km (2.4 mi) 1051 Hydrocyanic acid, aqueous solutions, with more than 20% Hydrogen cyanide 1051 Hydrocyanic acid, liquefied 1051 Hydrogen cyanide, anhydrous, stabilized 1051 Hydrogen cyanide, stabilized 30 m (100 ft) 0.1km (0.1 mi) 0.4 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.7 km (2.3 mi) 1052 Hydrogen fluoride, anhydrous 30 m (100 ft) 0.1km (0.1 mi) 0.5 km (0.3 mi) 210 m (700 ft) 1.9 km (1.2 mi) 4.3 km (2.7 mi) 1053 Hydrogen sulfide 1053 Hydrogen sulfide, liquefied 1053 Hydrogen sulphide 1053 Hydrogen sulphide, liquefied 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 210 m (700 ft) 2.1km (1.3 mi) 6.2 km (3.9 mi) 1062 Methyl bromide 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.2 km (1.4 mi) 1064 Methyl mercaptan 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 150 m (500 ft) 1.3 km (0.8 mi) 4.5 km (2.8 mi) 1067 Dinitrogen tetroxide 1067 Dinitrogen tetroxide, liquefied 1067 Nitrogen dioxide 1067 Nitrogen dioxide, liquefied 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 150 m (500 ft) 1.6 km (1.0 mi) 4.1km (2.5 mi) 1069 N itrosyl chloride 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 450 m (1500 ft) 4.3 km (2.7 mi) 11.0 km (6.9 mi) 1071 Oil gas 1071 Oil gas, compressed 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi) 1076 C G (when used as a weapon) 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.0 mi) 800 m (2500 ft) 7.3 km (4.5 mi) 11.0+ km (7.0+ mi) 1076 Diphosgene 90 m (300 ft) 0.9 km (0.6 mi) 4.1km (2.6 mi) 800 m (2500 ft) 6.6 km (4.1 mi) 11.0+ km (7.0+ mi) 1076 DP (when used as a weapon) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 180 m (600 ft) 1.7 km (1.0 mi) 4.6 km (2.8 mi) 1076 Phosgene 90 m (300 ft) 0.9 km (0.6 mi) 4.1km (2.6 mi) 800 m (2500 ft) 6.6 km (4.1 mi) 11.0+km (7.0+mi) 1079 Sulfur dioxide 1079 Sulfur dioxide, liquefied 1079 Sulphur dioxide 1079 Sulphur dioxide, liquefied 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 210 m (700 ft) 2.0 km (1.3 mi) 6.3 km (3.9 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 1082 Trifluorochloroethylene 1082 Trifluorochloroethylene, inhibited 1082 Trifluorochloroethylene, stabilized 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi) 1092 Acrolein, inhibited 1092 Acrolein, stabilized 60 m (200 ft) 0.5 km (0.3 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.8 km (3.0 mi) 10.2 km (6.3 mi) 1098 Allyl alcohol 30 m (100 ft) 0.1km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.6 km (0.4 mi) 1135 Ethylene chlorohydrin 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.5 km (1.0 mi) 1143 Crotonaldehyde, inhibited 1143 Crotonaldehyde, stabilized 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi) 1162 Dimethyldichlorosilane (when spilled in water) 30 m (100 ft) 0.2 km (0.2 mi) 1.1 km (0.7 mi) 300 m (1000 ft) 3.0 km (1.9 mi) 7.9 km (4.9 mi) 1163 1,1-Dimethylhydrazine 1163 Dimethylhydrazine, unsymmetrical 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.2 km (0.8 mi) 1182 Ethyl chloroformate 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.8 km (1.1 mi) 1185 Ethyleneimine, inhibited 1185 Ethyleneimine, stabilized 30 m (100 ft) 0.2 km (0.2 mi) 0.7 km (0.5 mi) 180 m (600 ft) 1.8 km (1.2 mi) 4.0 km (2.5 mi) 1196 Ethyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.2 km (0.2 mi) 1.1 km (0.7 mi) 300 m (1000 ft) 3.0 km (1.9 mi) 7.9 km (4.9 mi) 1238 Methyl chloroformate 30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 180 m (600 ft) 1.8 km (1.1 mi) 3.9 km (2.4 mi) 1239 Methyl chloromethyl ettier 30 m (100 ft) 0.3 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi) 1242 Methyldichlorosilane (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 4.8 km (3.0 mi) 1244 Methylhydrazine 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.4 km (0.9 mi) 2.9 km (1.8 mi) 1250 M ethyltrich lorosila ne (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 4.0 km (2.5 mi) 1251 Methyl vinyl ketone 1251 Methyl vinyl ketone, stabilized 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 1259 Nickel carbonyl 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 9.8 km (6.1 mi) 1295 Trichlorosilane (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 6.5 km (4.1 mi) 1298 Trimethylchlorosilane (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.7 km (1.7 mi) 1305 Vinyltrichlorosilane (when spilled in water) 1305 Vinyltrichlorosilane, inhibited (when spilled in water) 1305 Vinyltrichlorosilane, stabilized (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.5 mi) 180 m (600 ft) 1.8km (1.1 mi) 5.0 km (3.1 mi) 1340 Phosphorus pentasulfide, free from yellow or white Phosphorus (when spilled in water) 1340 Phosphorus pentasulphide, free from yellow or white Phosphorus (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.0 km (0.6 mi) 3.9 km (2.4 mi) 1360 Calcium phosphide (when spilled in water) 60 m (200 ft) 0.5 km (0.3 mi) 2.1km (1.3 mi) 800 m (2500 ft) 6.3 km (3.9 mi) 11.0+km (7.0+ mi) 1380 Pentaborane 90 m (300 ft) 0.9 km (0.6 mi) 3.3 km (2.1 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi) 1384 Sodium dithionite (when spilled in water) 1384 Sodium hydrosulfite (when spilled in water) 1384 Sodium hydrosulphite (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi) 1397 Aluminum phosphide (when spilled in water) 90 m (300 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi) 1000 m (3000 ft) 9.0 km (5.6 mi) 11.0+km (7.0+mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 1412 Lithium amide (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.2 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.6 km (1.0 mi) 1419 Magnesium aluminum phosphide (when spilled in water) 60 m (200 ft) 0.6 km (0.4 mi) 2.5 km (1.6 mi) 1000 m (3000 ft) 7.9 km (4.9 mi) 11.0+ km (7.0+ mi) 1432 Sodium phosphide (when spilled in water) 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 11.0+ km (7.0+ mi) 1510 Tetranitromethane 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi) 1541 Acetone cyanohydrin, stabilized Awhpn QnillpH in watprl IVVIIUII OMIIICU III IIQIEII 30 m (100 ft) 0.1km (0.1 mi) 0.3 km (0.2 mi) 240 m (800 ft) 0.8 km (0.5 mi) 3.0 km (1.9 mi) 1 S S fi M n ( whpn i lopri ft w/pannnl 1JJU 1 \J IDIICI 1 UjCU do u VHCQUUIIl 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.1 km (0.7 mi) 1556 MpthvlHirhloroarsinp 1JJU 1 Cll lyiUILI 1 1 U 1 uO 1 J II 1 C 30 m (100 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 120 m (400 ft) 1.3 km (0.8 mi) 3.6 km (2.2 mi) 1556 P D (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 1560 Arsenic chloride 1560 Arsenic trichloride 30 m (100 ft) 0.2 km (0.2 mi) 0.4 km (0.2 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.8 km (1.1 mi) 1569 Bromoacetone 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.3 km (1.5 mi) 1580 Chloropicrin 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi) 210 m (700 ft) 1.9 km (1.2 mi) 3.6 km (2.2 mi) 1581 Chloropicrin and Methyl bromide mixture 1581 Methyl bromide and Chloropicrin mixture 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 210 m (700 ft) 2.1km (1.3 mi) 5.9 km (3.7 mi) 1582 Chloropicrin and Methyl chloride mixture 1582 Methyl chloride and Chloropicrin mixture 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 1583 Chloropicrin mixture, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi) 210 m (700 ft) 1.9 km (1.2 mi) 3.6 km (2.2 mi) 1589 C K (when used as a weapon) 60 m (200 ft) 0.7 km (0.4 mi) 2.5 km (1.5 mi) 420 m (1300 ft) 4.1km (2.5 mi) 8.1km (5.0 mi) 1589 Cyanogen chloride, inhibited 1589 Cyanogen chloride, stabilized 60 m (200 ft) 0.6 km (0.4 mi) 2.8 km (1.8 mi) 450 m (1400 ft) 4.3 km (2.7 mi) 10.1km (6.3 mi) 1595 Dimethyl sulfate 1595 Dimethyl sulphate 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi) 1605 Ethylene dibromide 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi) 1612 Hexaethyl tetraphosphate and compressed gas mixture 90 m (300 ft) 0.8 km (0.5 mi) 2.7 km (1.7 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.1km (5.1 mi) 1613 Hydrocyanic acid, aqueous solution, with not more than 20% Hydrogen cyanide 1613 Hydrogen cyanide, aqueous solution, with not more than 20% Hydrogen cyanide 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 120 m (400 ft) 0.5 km (0.3 mi) 1.3 km (0.8 mi) 1614 Hydrogen cyanide, anhydrous, stabilized (absorbed) 1614 Hydrogen cyanide, stabilized (absorbed) 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.7 km (1.1 mi) 1647 Ethylene dibromide and Methyl bromide mixture, liquid 1647 Methyl bromide and Ethylene dibromide mixture, liquid 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi) 1660 Nitric oxide 1660 Nitric oxide, compressed 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi) 1670 Perchloromethyl mercaptan 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.2 km (0.8 mi) 1680 Potassium cyanide (when spilled in water) 1680 Potassium cyanide, solid (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 300 m (1000 ft) 1.0 km (0.6 mi) 3.9 km (2.4 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 1689 Sodium cyanide (when spilled in water) 1689 Sodium cyanide, solid (when spilled in water) 60 m (200 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 390 m (1300 ft) 1.3 km (0.8 mi) 4.9 km (3.0 mi) 1694 CA (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.7 km (1.0 mi) 4.2 km (2.6 mi) 1695 C hloroacetone stabilized 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 1.5 km (0.9 mi) 1697 C N (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.2 km (0.7 mi) 3.3 km (2.0 mi) 1698 Adamsite (when used as a weapon) 1 698 DM (whpn uopri ft wpannnl 60 m (200 ft) 0.4 km (0.2 mi) 1.2 km (0.7 mi) 180 m (600 ft) 2.3 km (1.4 mi) 5.2 km (3.2 mi) 1699 DA (when used as a weapon) 60 m (200 ft) 0.4 km (0.2 mi) 1.2 km (0.7 mi) 180 m (600 ft) 2.3 km (1.4 mi) 5.2 km (3.2 mi) 1716 Acetyl bromide (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.3 km (1.4 mi) 1717 Acetyl chloride (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.1km (0.7 mi) 3.5 km (2.2 mi) 1722 Allyl chlorocarbonate 1722 Allyl chloroformate 30 m (100 ft) 0.4 km (0.2 mi) 0.8 km (0.5 mi) 210 m (700 ft) 2.0 km (1.2 mi) 3.8 km (2.4 mi) 1724 Allyltrichlorosilane, stabilized (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.5 mi) 180 m (600 ft) 1.8 km (1.2 mi) 5.4 km (3.4 mi) 1725 Aluminum bromide, anhydrous (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.6 km (1.6 mi) 1726 Aluminum chloride, anhydrous (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.5 mi) 120 m (400 ft) 1.2 km (0.7 mi) 4.5 km (2.8 mi) 1728 Amyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.9 km (1.2 mi) 1732 Antimony pentafluoride (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 180 m (600 ft) 1.9 km (1.2 mi) 5.4 km (3.4 mi) 1741 Boron trichloride 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.7 km (1.1 mi) 1744 Bromine 1744 Bromine, solution 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 1745 Bromine pentafluoride (when spilled on land) 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 270 m (900 ft) 2.7 km (1.7 mi) 6.9 km (4.3 mi) 1745 Bromine pentafluoride (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 240 m (800 ft) 2.2 km (1.4 mi) 6.6 km (4.1 mi) 1746 Bromine trifluoride (when spilled on land) 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 180 m (600 ft) 1.8 km (1.1 mi) 4.8 km (3.0 mi) 1746 Bromine trifluoride (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 210 m (700 ft) 1.9 km (1.2 mi) 5.8 km (3.6 mi) 1747 Butyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.3 mi) 1749 Chlorine trifluoride 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 300 m (1000 ft) 2.8 km (1.8 mi) 8.1km (5.1 mi) 1752 Chloroacetyl chloride (when spilled on land) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.4 mi) 150 m (500 ft) 1.4 km (0.9 mi) 2.6 km (1.6 mi) 1752 Chloroacetyl chloride (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.5 km (1.0 mi) 1754 Chlorosulfonic acid (when spilled on land) 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi) 1754 Chlorosulfonic acid (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi) 1754 Chlorosulfonic acid and Sulfur trioxide mixture (when spilled on land) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi) 1754 Chlorosulfonic acid and Sulfur trioxide mixture (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 1754 C hlorosulphonic acid (when spilled on land) 30 m (100 ft) fl 1 l/m /A 1 mil u.i km (u.i mi) u.i Km (U.i mi) 30 m (100 ft) u J km (u.z mi) fi A \sm /fi "D m\\ u.4 km (u .5 mi) 1754 C hlorosulphonic acid (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi) 1754 C hlorosulphonic acid and Sulphur trioxide mixture (when spilled on land) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi) 1754 C hlorosulphonic acid and Sulphur trioxide mixture (when spilled in water) 30 m (100 ft) D 1 \/nn /fi 1 m!\ u.i km (U.i mi) 0.6 km (0.4 mi) 90 m (300 ft) fi 1 \jm /fi C ™l\ U./km (U.b mi) z.okm (l./mi) 1754 Sulfur trioxide and Chlorosulfonic acid mixture (when spilled on land) 60 m (200 ft) fi A l/m /fi "") mi\ u.4 km (u.z mi) 1 fi \sm /fi d rv\'i\ i.u km (u.d mi) 330 m (1000 ft) i.j km 11.3 mi) c rr \sm /An m!l d.j km (4.u mi) 1754 Sulfur trioxide and Chlorosulfonic acid mixture (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi) 1754 Sulphur trioxide and Chlorosulphonic acid mixture (when spilled on land) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi) 1754 Sulphur trioxide and Chlorosulphonic acid mixture (when spilled in water) 30 m (100 ft) u.i km (u.i mi) fi d l/m /fi A m\\ u.o km (u.4 mi) 90 m (300 ft) u./km (u.d mi) t O L™ /I 1 mil Lo km (l./mi) 1758 Chromium oxychloride (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi) 1763 Cyclohexyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.0 km (1.9 mi) 1766 Dichlorophenyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 210 m (700 ft) 2.1km (1.3 mi) 5.7 km (3.6 mi) 1767 Diethlydichlorasilane (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi) 1769 Diphenyldichlorosilane (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 1771 Dodecyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.2 mi) 1777 F luorasulfonic acid (when spilled in water) 1777 F luorosulphonic acid (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.0 km (0.6 mi) 3.4 km (2.1 mi) 1784 Hexyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.0 km (0.7 mi) 3.8 km (2.4 mi) 1799 Nonyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.5 km (1.6 mi) 1800 Octadecyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.9 km (1.8 mi) 1801 Octyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.5 km (1.6 mi) 1804 Phenyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 240 m (800 ft) 2.2 km (1.4 mi) 6.4 km (4.0 mi) 1806 Phosphorus pentachloride (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.1km (1.9 mi) 1809 Phosphorus trichloride (when spilled on land) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.3 mi) 150 m (500 ft) 1.5 km (1.0 mi) 3.5 km (2.2 mi) 1809 Phosphorus trichloride (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 4.8 km (3.0 mi) 1810 Phosphorus oxychloride (when spilled on land) 30 m (100 ft) 0.2 km (0.2 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.0 km (0.7 mi) 2.2 km (1.4 mi) 1810 Phosphorus oxychloride (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 240 m (800 ft) 2.3 km (1.5 mi) 6.3 km (3.9 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 1816 P ropyltrichlorosilane (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.3 km (0.8 mi) 4.1km (2.6 mi) 1818 Silicon tetrachloride (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.5 km (1.0 mi) 4.6 km (2.9 mi) 1828 Sulfur chlorides (when spilled on land) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.7 km (1.1 mi) 1828 Sulfur chlorides (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.4 km (0.9 mi) 4.9 km (3.0 mi) 1828 Sulphur chlorides (when spilled on land) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.7 km (1.1 mi) 1828 Sulphur chlorides (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.4 km (0.9 mi) 4.9 km (3.0 mi) 1829 Sulftjr trioxide 1829 Sulfur trioxide, inhibited 1829 Sulfur trioxide, stabilized 1829 Suffur trioxide, uninhibited 1829 Sulphur trioxide 1829 Sulphur trioxide, inhibited 1829 Sulphur trioxide, stabilized 1829 Sulphur trioxide, uninhibited 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi) 1831 Sulfuric acid, fuming 1831 Sulfuric acid, fuming, with not less than 30% free Sulfur trioxide 1831 Sulphuric acid, fuming 1831 Sulphuric acid, fuming, with not less than 30% free Sulphur trioxide 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi) 1834 Sulfuryl chloride (when spilled on land) 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.7 km (0.5 mi) 1834 Sulfuryl chloride (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.9 km (1.8 mi) 1834 Sulphuryl chloride (when spilled on land) 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.7 km (0.5 mi) 1834 Sulphuryl chloride (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.9 km (1.8 mi) 1836 Thionyl chloride (when spilled on land) 30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 90 m (300 ft) 1.0 km (0.6 mi) 2.2 km (1.4 mi) 1836 Thionyl chloride (when spilled in water) 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 450 m (1500 ft) 4.5 km (2.8 mi) 10.5 km (6.5 mi) 1838 Titanium tetrachloride (when spilled on land) 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi) 1838 Titanium tetrachloride (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.1km (0.7 mi) 3.7 km (2.3 mi) 1859 Silicon tetrafluoride 1859 Silicon tetrafluoride, compressed 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi) 1892 ED (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 120 m (400 ft) 1.3 km (0.8 mi) 2.6 km (1.6 mi) 1892 Ethyldichloroarsine 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.1km (0.7 mi) 1898 Acetyl iodide (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.8 km (1.1 mi) 1911 Diborane 1911 Diborane, compressed 60 m (200 ft) 0.4 km (0.2 mi) 1.6 km (1.0 mi) 180 m (600 ft) 1.8 km (1.1 mi) 5.4 km (3.4 mi) 1923 Calcium dithionite (when spilled in water) 1923 Calcium hydrosulfite (when spilled in water) 1923 Calcium hydrosulphite (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 1931 Zinc dithionite (when spilled in water) 1931 Zinc hydrosulfite (when spilled in water) 1931 Zinc hydrosulphite (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi) 1953 Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone A) 120 m (400 ft) 1.2 km (0.8 mi) 5.1km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi) 1953 Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 1953 Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 1953 Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 1953 Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone A) 120 m (400 ft) 1.2 km (0.8 mi) 5.1km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi) 1953 Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 1953 Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 1953 Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 1953 Compressed gas, poisonous, flammable, n.o.s. 1953 Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone A) 120 m (400 ft) 1.2 km (0.8 mi) 5.1km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi) 1953 Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 1953 Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 1953 Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 1953 Compressed gas, toxic, flammable, n.o.s. 1953 Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone A) 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi) 1953 Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 1953 Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 1953 Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 1953 Liquefied gas, flammable, poisonous, n.o.s. 1953 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone A) ltd™ liinn M 120 m (400 It) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi) 1953 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 1953 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 1953 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 1953 Liquefied gas, flammable, toxic, n.o.s. 1953 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone A) 120 m (400 ft) 1 ~) l^m In Q mil Li Km (u.tj mi) C 1 11 ~) mil j.iKm [5.1 mi) 1000 m (3000 ft) Q 7 Ui IQ A mil tJ./Km \oA mi) 11 ft 1 \sm in fi 1 w\\\ ii.u+Km (/.u+mi) 1953 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 1953 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 1953 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 1955 Compressed gas, poisonous, n.o.s. 1955 Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 1955 Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+km (7.0+ mi) 1955 Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 1955 Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi) 1955 Compressed gas, toxic, n.o.s. 1955 Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+ mi) 1000 m (3000 ft) 11.0+km (7.0+ mi) 11.0+km (7.0+ mi) 1955 Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+km (7.0+ mi) 1955 Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 1955 Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi) 1955 Liquefied gas, poisonous, n.o.s. 1955 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+ mi) 1000 m (3000 ft) 11.0+km (7.0+ mi) 11.0+km (7.0+ mi) 1955 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+km (7.0+ mi) 1955 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 1955 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi) 1955 Liquefied gas, toxic, n.o.s. 1955 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+ mi) 1000 m (3000 ft) 11.0+km (7.0+ mi) 11.0+km (7.0+ mi) 1955 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+km (7.0+ mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 1955 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 1955 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi) 1955 Organic phosphate compound mixed with compressed gas 1955 Organic phosphate mixed with compressed gas 1955 Organic phosphorus compound mixed with compressed gas 120 m (400 ft) 1.0 km (0.7 mi) 3.4 km (2.1 mi) 450 m (1500 ft) 4.4 km (2.7 mi) 9.6 km (6.0 mi) 1967 Insecticide gas, poisonous, n.o.s. 1967 Insecticide gas, toxic, n.o.s. 1967 Parathion and compressed gas mixture 120 m (400 ft) 1.0 km (0.7 mi) 3.4 km (2.1 mi) 450 m (1500 ft) 4.4 km (2.7 mi) 9.6 km (6.0 mi) 1975 Dinitrogen tetroxide and Nitric oxide mixture 1975 Nitric oxide and Dinitrogen tetroxide mixture 1975 Nitric oxide and Nitrogen dioxide mixture 1975 Nitric oxide and Nitrogen tetroxide mixture 1975 Nitrogen dioxide and Nitric oxide mixture 1975 Nitrogen tetroxide and Nitric oxide mixture 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi) 1994 Iron pentacarbonyl 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.6 km (1.0 mi) 3.0 km (1.9 mi) 2004 Magnesium diamide (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.4 km (0.3 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.9 km (1.8 mi) 2011 Magnesium phosphide (when spilled in water) 60 m (200 ft) 0.5 km (0.4 mi) 2.4 km (1.5 mi) 800 m (2500 ft) 7.5 km (4.7 mi) 11.0+ km (7.0+ mi) 2012 Potassium phosphide (when spilled in water) 60 m (200 ft) 0.4 km (0.3 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 11.0+ km (7.0+ mi) 2013 Strontium phosphide (when spilled in water) 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.6 km (2.9 mi) 11.0+ km (7.0+ mi) 2032 Nitric acid, fuming 2032 Nitric acid, red fuming 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.2 km (0.8 mi) 2186 Hydrogen chloride, refrigerated liquid 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 360 m (1200 ft) 3.6 km (2.2 mi) 10.4 km (6.5 mi) 2188 Arsine 60 m (200 ft) 0.6 km (0.4 mi) 3.0 km (1.9 mi) 420 m (1400 ft) 4.1km (2.6 mi) 9.5 km (5.9 mi) 2188 5 A (when used as a weapon) 60 m (200 ft) 0.9 km (0.5 mi) 2.5 km (1.5 mi) 420 m (1300 ft) 4.1km (2.5 mi) 8.1km (5.0 mi) 2189 Dichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 2190 Oxygen difluoride 2190 Oxygen difluoride, compressed 600 m (2000ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 2191 Sulfuryl fluoride 2191 Sulphuryl fluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi) 2192 Germane 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.0 km (1.9 mi) 2194 Selenium hexafluoride 90 m (300 ft) 0.7 km (0.5 mi) 3.2 km (2.0 mi) 450 m (1500 ft) 4.4 km (2.7 mi) 9.0 km (5.6 mi) 2195 Tellurium hexafluoride 90 m (300 ft) 1.0 km (0.6 mi) 4.0 km (2.5 mi) 600 m (2000 ft) 6.0 km (3.7 mi) 11.0+km (7.0+mi) 2196 Tungsten hexafluoride 30 m (100 ft) 0.2 km (0.1 mi) 1.1km (0.7 mi) 120 m (400 ft) 1.0 km (0.6 mi) 3.7 km (2.3 mi) 2197 Hydrogen iodide, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 120 m (400 ft) 1.3 km (0.8 mi) 3.7 km (2.3 mi) 2198 Phosphorus pentafluoride 2198 Phosphorus pentafluoride, compressed 30 m (100 ft) 0.3 km (0.2 mi) 1.6 km (1.0 mi) 180 m (600 ft) 1.6 km (1.0 mi) 4.6 km (2.9 mi) 2199 Phosphine 60 m (200 ft) 0.7 km (0.4 mi) 3.1km (1.9 mi) 450 m (1400 ft) 4.3 km (2.7 mi) 9.6 km (6.0 mi) 2202 Hydrogen selenide, anhydrous 120 m (400 ft) 1.2 km (0.8 mi) 5.1km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+km (7.0+mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY It'll nm chore /M Hoc \ MIUMIcLcib ^"lllcby NIGHT l^ilnmohorc /Milocl MlUlllclcib ^"MlcbJ DAY It* i In mo tare IU\ Hoc \ MIUlllcLcii ^"lllcby NIGHT l^ilnmohorc /Milocl 2204 Carbonyl sulfide 2204 Carbonyl sulphide 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 300 m (1000 ft) 3.0 km (1.9 mi) 8.1km (5.0 mi) 2232 Chloroacetaldehyde 2232 2-f hlnroethanal 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi) 1WA AIMaminp 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.1km (0.7 mi) 2.5 km (1.5 mi) 2337 Phenyl mercaptan 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.6 km (0.4 mi) 2382 1,2-Dimethylhydrazine 2382 Dimethylhydrazine, symmetrical 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.2 km (0.8 mi) 2407 Isopropyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 1.5 km (0.9 mi) 2417 Carbonyl fluoride 2417 Carbonyl fluoride, compressed 30 m (100 ft) 0.2 km (0.1 mi) 1.1km (0.7 mi) 90 m (300 ft) 1.0 km (0.6 mi) 3.6 km (2.3 mi) 2418 Sulfur tetrafluoride 2418 Sulphur tetrafluoride 60 m (200 ft) 0.7 km (0.4 mi) 3.2 km (2.0 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 10.6 km (6.6 mi) 2420 H exafluoroacetone 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi) 2421 Nitrogen trioxide 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.9 km (1.2 mi) 2437 Methylphenyldichlorosilane (whsn spillsd in watsr) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.1 km (0.7 mi) 2438 Trirnethylacetyl chloride 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi) ~) AA~) Trirhlnrnarph/I rhlnriHp L^^L 1 1 1^1 MU 1 UuV-C Ly 1 LINUMUC 30 m (100 ft) 0.2 km (0.2 mi) 0.8 km (0.5 mi) 120 m (400 ft) 1.2 km (0.8 mi) 2.2 km (1.4 mi) 7A1A Thinnhncnpnp 90 m (300 ft) n R km /fl S m'\) u.u m 1 1 yj.j i 1 11/ 2 4 km (1 5 mil £.t l\l 1 1 \X. J 1 1 [1/ 360 m (1200 ft) 3 6 km (2 3 mil J.U M 1 1 \L , J 1 1 11/ fi 8 km (4 2 mil U.U N 1 1 \H,L 1 1 11/ 2477 Methyl isothiocyanate 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.0 km (0.7 mi) 2480 Methyl isocyanate fin m /?nn fri DU III \£U\) 11/ 0.5 km (0.3 mi) 1.9 km (1.2 mi) finn m /i snn fr\ DUU III ^lOUU 11/ 5.4 km (3.3 mi) 11.0+ km (7.0+ mi) 2481 Ethyl isocyanate 60 m (200 ft) 0.6 km (0.4 mi) 2.1km (1.3 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+km (7.0+mi) 2482 n-Propyl isocyanate 120 m (400 ft) 1.0 km (0.7 mi) 2.5 km (1.6 mi) 1000 m (3000 ft) 9.0 km (5.6 mi) 11.0+km (7.0+mi) 2483 Isopropyl isocyanate 120 m (400 ft) 1.1 km (0.7 mi) 2.8 km (1.8 mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) 2484 tert-Butyl isocyanate 90 m (300 ft) 1.0 km (0.6 mi) 2.4 km (1.5 mi) 1000 m (3000 ft) 8.4 km (5.2 mi) 11.0+km (7.0+mi) 2485 n-Butyl isocyanate 90 m (300 ft) 0.7 km (0.5 mi) 1.6 km (1.0 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 8.0 km (5.0 mi) 2486 Isobutyl isocyanate 90 m (300 ft) 0.7 km (0.5 mi) 1.6 km (1.0 mi) 500 m (1600 ft) 4.7 km (3.0 mi) 7.8 km (4.8 mi) 2487 Phenyl isocyanate 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi) 180 m (600 ft) 1.6 km (1.0 mi) 2.9 km (1.8 mi) 2488 Cyclohexyl isocyanate 30 m (100 ft) 0.2 km (0.2 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.6 km (1.0 mi) 2495 Iodine pentafluoride (when spilled in water) 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 210 m (700 ft) 1.9 km (1.2 mi) 5.7 km (3.6 mi) 2521 Diketene, inhibited 2521 Diketene, stabilized 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi) 2534 Methylchlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 2548 Chlorine pentafluoride 30 m (100 ft) 0.3 km (0.2 mi) 1.7 km (1.1 mi) 240 m (800 ft) 2.4 km (1.5 mi) 7.4 km (4.6 mi) 2600 Carbon monoxide and Hydrogen mixture 2600 Carbon monoxide and Hydrogen mixture, compressed 2600 Hydrogen and Carbon monoxide mixture 2600 Hydrogen and Carbon monoxide mixture, compressed 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.4 km (1.5 mi) 2605 Methoxymethyl isocyanate 60 m (200 ft) 0.4 km (0.2 mi) 0.6 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 2.6 km (1.6 mi) 2606 Methyl orthosilicate 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.7 km (0.4 mi) 2644 Methyl iodide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 2646 Hexachlorocyclopentadiene 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.5 km (0.3 mi) 2668 Chloroacetonitrile 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY l^ilnmot _ Qi"c /M Hoc \ MIUMlcLcib ^"MlcbJ NIGHT DAY l^ilnmohorc IU\ Hoc \ MIUMIcLcib ^"lllcby NIGHT l^ilnmohorc /Milocl 2676 Stibine 60 m (200 ft) 0.4 km (0.3 mi) 2.2 km (1.4 mi) 270 m (900 ft) 2.8 km (1.7 mi) 7.5 km (4.7 mi) 2691 Phosphorus pentabromide (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.7 km (0.4 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.8 km (1.7 mi) 2692 Boron tribromide (when spilled on land) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.3 km (0.8 mi) 2692 Boron tribromide (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.6 km (1.6 mi) 2740 n-Propyl chlorofbrmate 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 1.5 km (0.9 mi) 2742 sec-Butyl chlorofbrmate 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.6 km (0.4 mi) 2742 Isobutyl chlorofbrmate 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi) 2743 n-Butyl chlorofbrmate 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi) 2806 Lithium nitride (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.6 km (1.6 mi) 2810 Buzz (when used as a weapon) 2810 BZ (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 0.5 km (0.3 mi) 2.0 km (1.2 mi) 2810 C 5 (when used as a weapon) 60 m (200 ft) 0.4 km (0.2 mi) 1.2 km (0.7 mi) 240 m (800 ft) 2.6 km (1.6 mi) 5.7 km (3.5 mi) 2810 DC (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.5 mi) 240 m (800 ft) 2.3 km (1.4 mi) 5.4 km (3.3 mi) 2810 G A (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.7 km (0.4 mi) 150 m (500 ft) 1.7 km (1.0 mi) 3.1km (1.9 mi) 2810 G B (when used as a weapon) 150 m (500 ft) 1.7 km (1.0 mi) 3.4 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 2810 G D (when used as a weapon) 90 m (300 ft) 0.9 km (0.5 mi) 1.8 km (1.1 mi) 800 m (2500 ft) 6.8 km (4.2 mi) 10.5 km (6.5 mi) 2810 G F (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.7 km (0.4 mi) 240 m (800 ft) 2.3 km (1.4 mi) 5.2 km (3.2 mi) 2810 H (when used as a weapon) 2810 H D (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.2 km (0.7 mi) 2810 H L (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 1.0 km (0.6 mi) 1.8 km (1.1 mi) 2810 H N -1 (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.3 km (0.8 mi) 2810 H N -2 (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.2 km (0.7 mi) 2810 H N -3 (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 2810 L (Lewiste) (when used as a weapon) 2810 Lewisite (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 1.0 km (0.6 mi) 1.8 km (1.1 mi) 2810 Mustard (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 2810 Mustard Lewisite (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 1.0 km (0.6 mi) 1.8 km (1.1 mi) 2810 Poisonous liquid, n.o.s. 2810 Poisonous liquid, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 2810 Poisonous liquid, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 2810 Poisonous liquid, organic, n.o.s. 2810 Poisonous liquid, organic, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 2810 Poisonous liquid, organic, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi) 2810 Sarin (when used as a weapon) 150 m (500 ft) 1.7 km (1.0 mi) 3.4 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 2810 Soman (when used as a weapon) 90 m (300 ft) 0.9 km (0.5 mi) 1.8 km (1.1 mi) 800 m (2500 ft) 6.8 km (4.2 mi) 10.5 km (6.5 mi) 2810 Ta bun (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.7 km (0.4 mi) 150 m (500 ft) 1.7 km (1.0 mi) 3.1km (1.9 mi) 2810 Thickened GD (when used as a weapon) 90 m (300 ft) 0.9 km (0.5 mi) 1.8 km (1.1 mi) 800 m (2500 ft) 6.8 km (4.2 mi) 10.5 km (6.5 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 2810 Toxic liquid, n.o.s. 2810 Toxic liquid, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 2810 Toxic liquid, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) n c Uvi in i mil U.D Km (UJ mi) i.o Km (i.i mi) 330 m (1100 ft) 1 3 Uvi n 1 mil 3.3 Km (z.i mi) 1 3 l,m IA C mil 1.3 Km (4.0 mi) 2810 Toxic liquid, organic, n.o.s. 2810 Toxic liquid, organic, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 2810 Toxic liquid, organic, n.o.s. (Inhalation Hazard Zone B} 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi) 2810 VX (when used 3S 3 w63pon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.0 km (0.6 mi) 2811 C X (whsn used ss 3 wsspon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 1.0 km (0.6 mi) 3.1km (1.9 mi) 2826 Ethyl chlorothioformate 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.0 km (0.6 mi) 2845 Ethyl phosphonous dichloride, anhvrlrous 30 m (100 ft) 0.4 km (0.2 mi) 0.8 km (0.5 mi) 210 m (700 ft) 1.9 km (1.2 mi) 3.6 km (2.2 mi) 2845 Mpth\/I nhosnhonous dirhlorirlp iUU ICUIV! UI IU 3UI IUI IU U J UILIIIUIIUC 60 m (200 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 330 m (1000 ft) 3.1km (1.9 mi) 5.9 km (3.7 mi) 2901 Bromine chloride 30 m (100 ft) 0.2 km (0.2 mi) 0.9 km (0.6 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.3 km (3.9 mi) 2927 Ethyl phosphonothioic dichloride, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 2927 Ethyl phosphorodichloridate 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.2 mi) 2927 Poisonous liquid, corrosive, n.o.s. 2927 Poisonous liquid, corrosive, n.o.s. (Inhalation Hazard Zone A) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+ km (7.0+mi) 2927 Poisonous liquid, corrosive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 2927 Toxic liquid, corrosive, organic, n.o.s. 2927 Toxic liquid, corrosive, organic, n.o.s. (Inhalation Hazard Zone A) 60 m (200 ft) 0.6 km (0.4 mi) 2.1km (1.3 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+km (7.0+mi) 2927 Toxic liquid, corrosive, organic, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 2.9 km (1.8 mi) 2929 Poisonous liquid, flammable, n.o.s. 2929 Poisonous liquid, flammable, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) 2929 Poisonous liquid, flammable, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi) 2929 Poisonous liquid, flammable, organic, n.o.s. 2929 Poisonous liquid, flammable, organic, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) 2929 Poisonous liquid, flammable, organic, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi) 2929 Toxic liquid, flammable, n.o.s. 2929 Toxic liquid, flammable, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) 2929 Toxic liquid, flammable, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi) 2929 Toxic liquid, flammable, organic, n.o.s. 2929 Toxic liquid, flammable, organic, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 2929 Toxic liquid, flammable, organic, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi) 2977 Radioactive material, Uranium hexafluoride, fissile (when spilled in water) 2977 Uranium hexafluoride, fissile containing more than 1% Uranium-235 (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 3.3 km (2.1 mi) 2978 Radioactive material, Uranium hexafluoride (when spilled in water) 2978 Radioactive material, Uranium hexafluoride, non-fissile or fissile-excepted (when spilled in water) 2978 Uranium hexafluoride (when spilled in water) 2978 Uranium hexafluoride, fissile-excepted (when spilled in water) 2978 Uranium hexafluoride, low specific activity (when spilled in water) 2978 Uranium hexafluoride, non-fissile (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 3.3 km (2.1 mi) 2985 Chlorosilanes, flammable, corrosive, n.o.s. (when spilled in water) 2985 Chlorosilanes, n.o.s. (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi) 2986 Chlorosilanes, corrosive, flammable, n.o.s. (when spilled in water) 2986 Chlorosilanes, n.o.s. (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi) 2987 Chlorosilanes, corrosive, n.o.s. (when spilled in water) 2987 Chlorosilanes, n.o.s. (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi) 2988 Chlorosilanes, n.o.s. (when spilled in water) 2988 Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi) 3023 2-Methyl-2-hepthanethiol 3023 tert-Octyl mercaptan 30 m (100 ft) 0.1 km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi) 3048 Aluminum phosphide pesticide (when spilled in water) 90 m (300 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi) 1000 m (3000 ft) 9.0 km (5.6 mi) 11.0+ km (7.0+ mi) 3049 Metal alkyl halides, n.o.s. (when spilled in water) 3049 Metal alkyl halides, water-reactive, n.o.s. (when spilled in water) 3049 Metal aryl halides, n.o.s. (when spilled in water) 3049 Metal aryl halides, water-reactive, n.o.s. (when spilled in water) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi) 3052 Aluminum alkyl halides (when spilled in water) 3052 Aluminum alkyl halides, liquid (when spilled in water) 3052 Aluminum alkyl halides, solid (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi) 3057 Trifluoroacetyl chloride 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 3079 Methacrylonitrile, inhibited 3079 Methacrylonitrile, stabilized 30 m (100 ft) fl 1 l/m /A 1 mil u.i km (u.i mi) uj Km mij 90 m (300 ft) fi l^kvi /fi C wy\\ u.o Ktn iu.j mi) i c Ui n n mil i.okm (i.u mi) 3083 Perchloryl fluoride 30 m (100 ft) n i \jm lr\ 1 mil u.z km (u.i mi) fi C l/m /fi A wt'i\ u.b km [ua mi) 360 m (1200 ft) 3 C L-m n ~> mi\ Q C mil o.o km p.D mi) 3122 Poisonous liquid, oxidizing, n.o.s. 3122 Poisonous liquid, oxidizing, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 3122 Poisonous liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 270 m (900 ft) LI km [LI mi) 6.9 km (4.3 mi) 3122 Toxic liquid, oxidizing, n.o.s. 3122 Toxic liquid, oxidizing, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 3122 Toxic liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 270 m (900 ft) 2.7 km (1.7 mi) 6.9 km (4.3 mi) 3123 Poisonous liquid, water-reactive, n.o.s. 3123 Poisonous liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 3123 Poisonous liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 3123 Poisonous liquid, which in contact with water emfe flammable gases, n.o.s. 3123 Poisonous liquid, which in contact with water emits flammable gases, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 3123 Poisonous liquid, which in contact with water emits flammable gases, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 3123 Toxic liquid, water-reactive, n.o.s. 3123 Toxic liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 3123 Toxic liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 3123 Toxic liquid, which in contact with water emfe flammable gases, n.o.s. 3123 Toxic liquid, which in contact with water emfe flammable gases, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 3123 Toxic liquid, which in contact with water emits flammable gases, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 3160 Liquefied gas, poisonous, flammable, n.o.s. 3160 Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone A) 120 m (400 ft) 1.2 km (0.8 mi) 5.1km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi) 3160 Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 3160 Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3160 Liquefied gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 3160 Liquefied gas, toxic, flammable, n.o.s. 3160 Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone A) 120 m (400 ft) 1.2 km (0.8 mi) 5.1km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+km (7.0+mi) 3160 Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 3160 Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) f\ T l/m /fi 1 mi\ u.z Km (u.i mi) fi \srv\ /fi C mi\ u.o Km (u.d mi) 240 m (800 ft) ~> A l/m /I C mi\ la Km [l.j mi) C A l/m IA fi m!\ b.4 Km (4.u mi) 3160 Liquefied gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) u.i Ktn (u.i mi) n T l/m ir\ 1 mi\ \j.l Km tu.imij 90 m (300 ft) fi l/m /fi C m!\ u.o Km (u.d mi) T A l/m /I C mi\ la Km [l.j mi) 3162 Liquefied gas, poisonous, n.o.s. 3162 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) C l/m /3 7 mi\ D.y Km [5.1 mi) 1 1 fi 1 l/m /7 H 1 mi^ ii.u+Km (/.u+mij 1000 m (3000 ft) 1 1 fi 1 l/m tn fi 1 mi\ ii.u+Km (/.u+rni) 1 1 fi 1 l/m in fi 1 m!^ ii.u+Km (/.u+mi) 3162 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+km (7.0+mi) 3162 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) ft 1 \m\ /ft "i mil u.i Km (u.z mi) 1 T l/m ZD Q mi\ l.l Km (u.o mi) 240 m (800 ft) 1 A /I C mi) la Km (i.Dmij C A l/m /AH m!^ 0.4 Km (4.U mi) 3162 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) ft "> \m\ /ft 1 mi\ u.z Km (u.i mij fi "7 l/m /fi A rv\'i\ u.i Km (u.4mij 120 m (400 ft) 1 ~) brv\ /ft O mil Li Km (u.omij ~3 Q l/m 11 A mi\ 5.0 Km [LA mi) 3162 Liquefied gas, toxic, n.o.s. 3162 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) 3162 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+km (7.0+mi) 3162 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3162 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi) 3246 Methanesuffonyl chloride 3246 Methanesulphonyl chloride 60 m (200 ft) 0.4 km (0.2 mi) 0.5 km (0.4 mi) 150 m (500 ft) 1.6 km (1.0 mi) 2.6 km (1.6 mi) 3275 Nitrites, poisonous, flammable, n.o.s. 3275 Nitrites, toxic, flammable, n.o.s. 30 m (100 ft) 0.1km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi) 3276 Nitrites, poisonous, liquid, n.o.s. 3276 Nitrites, poisonous, n.o.s. 3276 Nitrites, toxic, liquid, n.o.s. 3276 Nitrites, toxic, n.o.s. 30 m (100 ft) 0.1km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi) 3278 Organophosphorus compound, poisonous, liquid, n.o.s. 3278 Organophosphorus compound, poisonous, n.o.s. 3278 Organophosphorus compound, toxic, liquid, n.o.s. 3278 Organophosphorus compound, toxic, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 330 m (1000 ft) 3.1 km (1.9 mi) 5.9 km (3.7 mi) 3279 Organophosphorus compound, poisonous, flammable, n.o.s. 3279 Organophosphorus compound, toxic, flammable, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 330 m (1000 ft) 3.1 km (1.9 mi) 5.9 km (3.7 mi) 3280 Organoarsenic compound, liquid, n.o.s. 3280 Organoarsenic compound, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 210 m (700 ft) 2.1 km (1.3 mi) 5.1km (3.2 mi) 3281 Metal carbonyls, liquid, n.o.s. 3281 Metal carbonyls, n.o.s. 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 9.8 km (6.1 mi) 3287 Poisonous liquid, inorganic, n.o.s. 3287 Poisonous liquid, inorganic, n.o.s. (Inhalation Hazard Zone A) 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi) 3287 Poisonous liquid, inorganic, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 3287 Toxic liquid, inorganic, n.o.s. 3287 Toxic liquid, inorganic, n.o.s. (Inhalation Hazard Zone A) 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi) 3287 Toxic liquid, inorganic, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 3289 Poisonous liquid, corrosive, inorganic, n.o.s. 3289 Poisonous liquid, corrosive, inorganic, n.o.s. (Inhalation Hazard Zone A) 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi) 3289 Poisonous liquid, corrosive, inorganic, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 3289 Toxic liquid, corrosive, inorganic, n.o.s. 3289 Toxic liquid, corrosive, inorganic, n.o.s. (Inhalation Hazard Zone A) 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi) 3289 Toxic liquid, corrosive, inorganic, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 3294 Hydrogen cyanide, solution in alcohol, with not more than 45% Hydrogen cyanide 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 210 m (700 ft) 0.7 km (0.4 mi) 2.1km (1.3 mi) 3300 Carbon dioxide and Ethylene oxide mixture, with more than 87% Ethylene oxide 3300 Ethylene oxide and Carbon dioxide mixture, with more than 87% Ethylene oxide 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 3303 Compressed gas, poisonous, oxidizing, n.o.s. 3303 Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+mi) 11.0+ km (7.0+mi) 3303 Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi) 3303 Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3303 Compressed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi) 3303 Compressed gas, toxic, oxidizing, n.o.s. 3303 Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+mi) 1000 m (3000 ft) 11.0+ km (7.0+mi) 11.0+ km (7.0+mi) 3303 Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi) 3303 Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3303 Compressed gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 3304 Compressed gas, poisonous, corrosive, n.o.s. 3304 Compressed gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 3304 Compressed gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+km (7.0+ mi) 3304 Compressed gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3304 Compressed gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi) 3304 Compressed gas, toxic, corrosive, n.o.s. 3304 Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) Ll.O+km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+km (7.0+ mi) 3304 Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+km (7.0+mi) 3304 Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3304 Compressed gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi) 3305 Compressed gas, poisonous, flammable, corrosive, n.o.s. 3305 Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) 3305 Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 3305 Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3305 Compressed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 3305 Compressed gas, toxic, flammable, corrosive, n.o.s. 3305 Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) 3305 Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 3305 Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3305 Compressed gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 3306 Compressed gas, poisonous, oxidizing, corrosive, n.o.s. 3306 Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 3306 Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi) 3306 Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3306 Compressed gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi) 3306 Compressed gas, toxic, oxidizing, corrosive, n.o.s. 3306 Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) 3306 Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi) 3306 Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3306 Compressed gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi) 3307 Liquefied gas, poisonous, oxidizing, n.o.s. 3307 Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) 3307 Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi) 3307 Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3307 Liquefied gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi) 3307 Liquefied gas, toxic, oxidizing, n.o.s. 3307 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+ mi) 1000 m (3000 ft) 11.0+km (7.0+ mi) 11.0+km (7.0+ mi) 3307 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi) 3307 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3307 Liquefied gas, toxic, oxidizing, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi) 3308 Liquefied gas, poisonous, corrosive, n.o.s. 3308 Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+ mi) 1000 m (3000 ft) 11.0+km (7.0+ mi) 11.0+km (7.0+ mi) 3308 Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+km (7.0+ mi) 3308 Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3308 Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 3308 Liquefied gas, toxic, corrosive, n.o.s. 3308 Liquefied gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) C Ui 11 1 mil D.y Km \5.i mi) 1 1 n i i/m in n i w\\\ ii.u+Km (/.u+mij 1000 m (3000 ft) 1 1 fi 1 l/m tn fi 1 w\'\\ ii.u+Km (/.u+mij 1 1 fi 1 \sYY\ tn fi 1 YV\'\\ ii.u+Km (/.u+mij 3308 Liquefied gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+km (7.0+mi) 3308 Liquefied gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3308 Liquefied gas, toxic, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi) 3309 Liquefied gas, poisonous, flammable, corrosive, n.o.s. 3309 Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+km (7.0+mi) 3309 Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 3309 Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3309 Liquefied gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 3309 Liquefied gas, toxic, flammable, corrosive, n.o.s. 3309 Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+km (7.0+mi) 3309 Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 3309 Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3309 Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 3310 Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. 3310 Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) 3310 Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi) 3310 Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3310 Liquefied gas, poisonous, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi) 3310 Liquefied gas, toxic, oxidizing, corrosive, n.o.s. 3310 Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone A) 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+km (7.0+mi) 1000 m (3000 ft) 11.0+km (7.0+mi) 11.0+km (7.0+mi) 3310 Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 3310 Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3310 Liquefied gas, toxic, oxidizing, corrosive, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi) 3318 Ammonia solution, with more than 50% Ammonia 30 m (100 ft) 0.1km (0.1 mi) 0.1km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi) 3355 Insecticide gas, poisonous, flammable, n.o.s 3355 Insecticide gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone A) 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi) 3355 Insecticide gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 3355 Insecticide gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3355 Insecticide gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 3355 Insecticide gas, toxic, flammable, n.o.s 3355 Insecticide gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone A) 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi) 3355 Insecticide gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi) 3355 Insecticide gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone C) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi) 3355 Insecticide gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone D) 30 m (100 ft) 0.1km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 3381 Poisonous by inhalation liquid, n.o.s. (Inhalation Hazard Zone A) 3381 Toxic by inhalation liquid, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 3382 Poisonous by inhalation liquid, n.o.s. (Inhalation Hazard Zone B) 3382 Toxic by inhalation liquid, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 3383 Poisonous by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone A) 3383 Toxic by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) 3384 Poisonous by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone B) 3384 Toxic by inhalation liquid, flammable, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi) 3385 Poisonous by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A) 3385 Toxic by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi) TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES SMALL SPILLS (From a small package or small leak from a large package) LARGE SPILLS (From a large package or from many small packages) ID No. NAME OF MATERIAL First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- First ISOLATE in all Directions Meters (Feet) Then PROTECT persons Downwind during- DAY Kilometers (Miles) NIGHT Kilometers (Miles) DAY Kilometers (Miles) NIGHT Kilometers (Miles) 3386 Poisonous by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B) 3386 Toxic by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 3387 Poisonous by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone A) 3387 Toxic by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone A) 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+mi) 3388 Poisonous by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B) 3388 Toxic by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B) 30 m (100 ft) 0.4 km (0.2mi) 1.4 km (0.9 mi) 270 m (900 ft) 2.7 km (1.7 mi) 6.9 km (4.3 mi) 3389 Poisonous by inhalation liquid, corrosive, n.o.s. (Inhalation Hazard Zone A) 3389 Toxic by inhalation liquid, corrosive, n.o.s. (Inhalation Hazard Zone A) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+ km (7.0+mi) 3390 Poisonous by inhalation liquid, corrosive, n.o.s. (Inhalation Hazard Zone B) 3390 Toxic by inhalation liquid, corrosive, n.o.s. (Inhalation Hazard Zone B) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi) 3461 Aluminum alkyl halides, solid (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi) 9191 Chlorine dioxide, hydrate, frozen (when spilled in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 9192 Fluorine, refrigerated liquid (cryogenic liquid) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi) 9202 Carbon monoxide, refrigerated liquid (cryogenic liquid) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.4 km (1.5 mi) 9206 Methyl phosphonic dichloride 30 m (100 ft) 0.1km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 9263 Chloropivaloyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi) 9264 3,5-Dichloro-2,4,6- trifluoropyridine 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi) 9269 Trimethoxysilane 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.1km (0.7 mi) 2.2 km (1.4 mi) See Next Page for Table of Water-Reactive Materials Which Produce Toxic Gases TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES Materials Which Produce Large Amounts of Toxic-by-lnhalation (TIH) Gas(es) When Spilled in Water ID Guide TIH Gas(es) No. No. Name of Material Produced 11 CO llOZ ICC 155 Dimethyldichlorosilane u r i H L 1 11 nc ICC 155 Ethyltrichlorosilane u r i H L 1 IT/IT 1242 1 On 139 Mettiyldichlorosilane u r i i Ten 1250 ICC 155 Mettiyltrichlorosilane u r i i one izyb i on 133 Trichlorosilane u C 1 i ono IZyb ICC 155 Trimethylchlorosilane U C 1 1 one UUb 1 C C D Ibbr Vinyltrichlorosilane U C 1 1305 155P Vinyltrichlorosilane, inhibited HCI 1 one 1 c c □ Ibbr Vinyltrichlorosilane, stabilized u r i H L 1 i o/in i on lj» Phosphorus pentasulfide, free from yellow and white Phosphorus u c H 2 S i o/in 134U 1 OQ Phosphorus pentasulphide, free from yellow and white P hosphorus H 2 S 1360 139 Calcium phosphide PH 3 1 OQ/1 1304 1 oe 135 Sodium dittiionite H 2 S b U 1 OO/I 13o4 1 oc 13b Sodium hydrosulfite u c H,S c r\ bU 1 OO/I 13o4 1 oc 13b Sodium hydrosulphite u c H 2 b c r\ bU i im 139/ i on 139 Aluminum phosphide n u PH 3 1 AT) 141Z i on 13» Lithium amide M U i /ii n 1413 i on lj» Magnesium aluminum phosphide D U PH 3 1432 139 Sodium phosphide PH 3 1541 155 Acetone cyanohydrin, stabilized HCN 1680 157 Potassium cyanide HCN 1680 157 Potassium cyanide, solid HCN 1689 157 Sodium cyanide HCN 1689 157 Sodium cyanide, solid HCN Chemical Symbols for TIH Gases: Br 2 B romine HF Hydrogen fluoride PH 3 P hosphine ci, C hlorine HI Hydrogen iodide so 2 Sulfur dioxide HBr Hydrogen bromide H 2 S Hydrogen sulfide so 2 Sulphur dioxide HCI Hydrogen chloride H 2 S Hydrogen sulphide so 3 Sulfur trioxide HCN Hydrogen cyanide N H 3 Ammonia 50 3 Sulphur trioxide Page344 Use this list only when material is spilled in water. TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES Materials Which Produce Large Amounts of Toxic-by-lnhalation (TIH) Gas(es) When Spilled in Water ID Guide No. No. Name of Material 1 71 C 1 /lb 1 cc 130 Acetyl bromide [in. nor 1/1/ 1 cc 133 Acetyl chloride u r i H L 1 1 77/1 1/Z4 ICC 133 Allyltrichloros ilane, stabilized u r i H L 1 1725 137 Aluminum bromide, anhydrous HBr 1 77C 1 07 13/ Aluminum chloride, anhydrous u r l 1 770 ICC 155 Amyltrichlorosilane u r l 1732 157 Antimony penta fluoride H F 1745 144 Bromine penta fluoride H F MAC 11 40 i/i/i 144 Bromine trifluoride u c H r 1/4/ ICC 133 B utyltrichloros ilane U C 1 n L 1 1752 156 Chloroacetyl chloride u r l H C 1 1 7C/I 1/34 1 07 151 Chlorosulfonic acid u r i nc/i 1/34 1 07 lj/ Chlorosulfonic acid and Sulfurtrioxide mixture u r i n L 1 nc/i 1/34 1 07 lj/ Chlorosulphonic acid u r I n L 1 1 7C/1 1/34 1 07 151 Chlorosulphonic acid and Sulphur trioxide mixture u r I n L 1 1 7C/1 1/54 1 07 13/ Sulfurtrioxide and Chlorosulfonic acid u r l HLI 1 7C/I 1/34 1 07 151 Sulphur trioxide and Chlorosulphonic acid u r I n L 1 nco 1/30 1 07 lj/ Chromium oxychloride u r I n L 1 1763 156 Cyclohexyltrichlorosilane HCI 1766 156 Dichlorophenyltrichlorosilane HCI 1767 155 Diethyldichlorosilane HCI 1769 156 Diphenyldichlorosilane HCI 1771 156 Dodecyltrichlorosilane HCI 1777 137 Fluorosulfonicacid HF Chemical Symbols for TIH Gases: Br 2 B romine HF Hydrogen fluoride PH 3 P hosphine ci, C hlorine HI H ydrogen iodide 50 2 Sulfur dioxide HBr Hydrogen bromide H 2 S Hydrogen sulfide 50 2 Sulphur dioxide HCI Hydrogen chloride H 2 S Hydrogen sulphide 50 3 Sulfur trioxide HCN Hydrogen cyanide N H 3 Ammonia so 3 Sulphur trioxide Use this list only when material is spilled in water. Px/e345 TIH Gas(es) Produced TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES Materials Which Produce Large Amounts of Toxic-by-lnhalation (TIH) Gas(es) When Spilled in Water ID Guide TIH Gas(es) No. No. Name of Material Produced 1 111 i n 13/ Fluorosulphonic acid u c n r 1 1Q/I 1/04 1 C£ 150 Hexyltrichlorosilane u r I n L 1 i inn i/yy 1 cc IjD Nonyltrichlorosilane u r i i onn loUU 1 cc 15b Octadecyltrichlorosilane U C 1 n L 1 i om loUl 1 cc IjD Octyltrichlorosilane u r I n L 1 1804 156 Phenyltrichlorosilane HCI 1806 137 Phosphorus pentachloride HCI i onn lsoy 1 01 13/ Phosphorus trichloride u r l loin lolU i oi 137 Phosphorus oxychloride u r I n L 1 1 01 c lolb ICC 155 P ropyltrichlorosilane u r I n L 1 1010 lolb i ci 15/ Silicon tetrachloride u r I n L 1 1828 137 Sulfurchlondes HCI SO 1 0")0 lo7o i oi 13/ Sulphurchlo rides U C 1 n L 1 c r\ 1834 137 Sulfuryl chloride HCI SO 100/1 1034 i oi 13/ Sulphuryl chloride U C 1 n L 1 c r\ 1 ooc 1 01 137 Thionyl chloride u r l H L 1 SO 1838 137 Titanium tetrachloride HCI i ono 1 cc 150 Acetyl iodide U 1 H 1 1923 135 Calcium dithionite H 2 S so 1923 135 Calcium hydrosulfite H 2 S so 1923 135 Calcium hydrosulphite H 2 S so 1931 171 Zinc dithionite H 2 S so 1931 171 Zinc hydrosulfite H 2 S so 1931 171 Zinc hydrosulphite H 2 S so H 2 S H,S Chemical Symbols for TIH Gases: Br 2 B romine HF Hydrogen fluoride PH 3 P hosphine ci, C hlorine HI Hydrogen iodide so 2 Sulfur dioxide HBr Hydrogen bromide H 2 S Hydrogen sulfide so 2 Sulphur dioxide HCI Hydrogen chloride H 2 S Hydrogen sulphide so 3 Sulfur trioxide HCN Hydrogen cyanide N H 3 Ammonia 50 3 Sulphur trioxide Page346 Use this list only when material is spilled in water. ABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES Materials Which Produce Large Amounts of Toxic-by-lnhalation (TIH) Gas(es) When Spilled in Water ID No. Guide No. Name of Material TIH Gas(es) Produced 2004 135 Magnesium diamide NH 3 2011 139 Magnesium phosphide PH 3 2012 139 Potassium phosphide PH 3 2013 139 Strontium phosphide PH 3 2437 156 Methylphenyldichlorosilane HCI 2495 144 Iodine pentafluoride HF 2691 137 Phosphorus pentabromide HBr 2692 157 Boron tribromide HBr 2806 138 Lithium nitride NH 3 2977 166 Radioactive material, Uranium hexafluoride, fissile HF 2977 166 1 1 ran in m hPYaflnnridp fk s ilp rnntaininn mnrp ttian 1 % UlalllUIII IICACtllUUIlUC, 1 1 J J 1 It LU 1 1 LCI 1 1 1 II 1 y 1 IU 1 C U 1 1 1 1 /o Uranium-235 H F 1 1 1 2978 166 Radioactive material, Uranium hexafluoride HF 2978 166 Radioactive material, Uranium hexafluoride, non-fissile or fissile-excepted HF 2978 166 Uranium hexafluoride HF 2978 166 Uranium hexafluoride, fissile-excepted HF 2978 166 Uranium hexafluoride, low specific activity HF 2978 166 Uranium hexafluoride, non-fissile HF 2985 155 Chlorosilanes, flammable, corrosive, n.o.s. HCI 2985 155 Chlorosilanes, n.o.s. HCI 2986 155 Chlorosilanes, corrosive, flammable, n.o.s, HCI 2986 155 Chlorosilanes, n.o.s. HCI 2987 156 Chlorosilanes, corrosive, n.o.s. HCI 2987 156 Chlorosilanes, n.o.s. HCI Chemical Symbols for TIH Gases: Br 2 Bromine HF Hydrogen fluoride CI, Chlorine HI H ydrogen iodide HBr Hydrogen bromide H 2 S Hydrogen sulfide HCI Hydrogen chloride H 2 S Hydrogen sulphide HCN Hydrogen cyanide NH 3 Ammonia PH 3 S0 2 so 2 50 3 so 3 P hosphine Sulfur dioxide Sulphur dioxide Sulfur trioxide Sulphur trioxide Use this list only when material is spilled in water. Px/e347 TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES Materials Which Produce Large Amounts of Toxic-by-lnhalation (TIH) Gas(es) When Spilled in Water ID No. Guide No. Name of Material 2988 139 Chlorosilanes, n.o.s. HCI 2988 139 Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. HCI 3048 157 Aluminum phosphide pesticide PH 3 3049 138 Metal alkyl halides, n.o.s. HCI 3049 138 Metal alkyl halides, water-reactive, n.o.s. HCI 3049 138 Metal aryl halides, n.o.s. HCI 3049 138 Metal aryl halides, water-reactive, n.o.s. HCI 3052 135 Aluminum alkyl halides HCI 3052 135 Aluminum alkyl halides, liquid HCI 3052 135 Aluminum alkyl halides, solid HCI 3461 135 Aluminum alkyl halides, solid HCI 9191 143 Chlorine dioxide, hydrate, frozen TIH Gas(es) Produced Chemical Symbols for TIH Gases: Br 2 B romine HF Hydrogen fluoride PH 3 P hosphine ci, C hlorine HI Hydrogen iodide S0 2 Sulfur dioxide HBr Hydrogen bromide H 2 S Hydrogen sulfide so 2 Sulphur dioxide HCI Hydrogen chloride H 2 S Hydrogen sulphide so 3 Sulfur trioxide HCN Hydrogen cyanide N H 3 Ammonia 50 3 Sulphur trioxide Page348 Use this list only when material is spilled in water. TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES Materials Which Produce Large Amounts of Toxic-by-lnhalation (TIH) Gas(es) When Spilled in Water ~ID Guide TIH Gas(es) No. No. Name of Material Produced Page Intentionally Left Blank Chemical Symbols for TIH Gases: B romine HF Hydrogen fluoride PH 3 P hosphine ci, C hlorine HI H ydrogen iodide so 2 Sulfur dioxide H Br Hydrogen bromide H 2 S Hydrogen sulfide S0 2 Sulphur dioxide HCI Hydrogen chloride H 2 S Hydrogen sulphide S0 3 Sulfur trioxide HCN Hydrogen cyanide N H 3 Ammonia S0 3 Sulphur trioxide Use this list only when material is spilled in water. Px/e349 PROTECTIVE CLOTHING Street Clothing and Work Uniforms. These garments, such as uniforms worn by police and emergency medical services personnel, provide almost no protection from the harmful effects of dangerous goods. Structural Fire Fighters' Protective Clothing (SFPC). This category of clothing, often called turnout or bunker gear, means the protective clothing normally worn by fire fighters during structural fire fighting operations. It includes a helmet, coat, pants, boots, gloves and a hood to cover parts of the head not protected by the helmet and facepiece. This clothing mustbe used with full-facepiece positive pressure self-contained breathing apparatus (SCBA). This protective clothing should, ata minimum, meetthe OSHA Fire Brigades Standard (29 CFR 1910.156). Structural fire fighters' protective clothing provides limited protection from heat and cold, but may not provide adequate protection from the harmful vapors or liquids that are encountered during dangerous goods incidents. Each guide includes a statement aboutthe use of SFPC in incidents involving those materials referenced by thatguide. Some guides state thatSFPC provides limited protection. In those cases, the responder wearing SFPCandSCBA may be able to perform an expedient, that is quick "in-and-out", operation. However, this type of operation can place the responder at risk of exposure, injury or death. The incident commander makes the decision to perform this operation only if an overriding benefit can be gained (i.e., perform an immediate rescue, turn off a valve to control a leak, etc.). The coverall-type protective clothing customarily worn to fightfires in forests orwildlands is not SFPC and is not recommended nor referred to elsewhere in this guidebook. Positive Pressure Self-Contained Breathing Apparatus (SCBA). This apparatus provides a constant, positive pressure flow of airwithin the facepiece, even if one inhales deeply while doing heavy work. Use apparatus certified by NIOSH and the Department of Labor/Mine Safety and Health Administration in accordance with 42 CFR Part 84. Use itin accordance with the requirements for respiratory protection specified in OSHA 29 CFR 1910.134 (Respiratory Protection) and/or 29 CFR 1910.156 (f) (Fire Brigades Standard). Chemical- cartridge respirators orotherfiltering masks are notacceptable substitutes for positive pressure self-contained breathing apparatus. Demand-type SCBA does notmeetthe OSHA 29 CFR 1910.156 (f)(l)(i) of the Fire Brigades Standard. Chemical Protective Clothing and Equipment. Safe use of this type of protective clothing and equipment requires specific skills developed through training and experience. It is generally not available to, or used by, first responders. This type of special clothing may protect against one chemical, yet be readily permeated by chemicals for which it was not designed. Therefore, protective clothing should not be used unless it is compatible with the released material. This type of special clothing offers little or no protection against heatand/ or cold. Examples of this type of equipment have been described as (1) Vapor Protective Suits (NF PA 1991), also known as Totally-Encapsulating Chemical Protective (TEC P) Suits or Level A* protection (OS HA 29 C F R 1910.120, AppendixA & B), and (2) Liquid-S plash P rotective S uits (NFPA 1992 & 1993), also known as Level B* or C* protection (OSHA 29 CFR 1910.120, Page 350 Appendix A Si B) or suits for chemical/biological terrorism incidents (NFPA 1994), class 1, 2 or 3 Ensembles. No single protective clothing material will protectyou from all dangerous goods. Do not assume any protective clothing is resistantto cold and/or heat or flame exposure unless it is so certified by the manufacturer. (NFPA 1991 5-3 Flammability Resistance Test and 5-6 Cold Temperature PerformanceTest) *Consultglossary foradditional protection levels underthe heading "Protective Clothing". Page 351 FIRE AND SPILL CONTROL FIRE CONTROL Water is the most common and generally most available fire extinguishing agent. Exercise caution in selecting a fire extinguishing method since there are many factors to be considered in an incident. Water may be ineffective in fighting fires involving some materials; its effectiveness depends greatly on the method of application. Spill fires involving flammable liquids are generally controlled by applying a fire fighting foam to the surface of the burning material. F ighting flammable liquid fires requires foam concentrate which is chemically compatible with the burning material, correctmixinq of the foam concentrate with water and air, and careful application and maintenance of the foam blanket. There are two general types of fire fighting foam: regular and alcohol-resistant. Examples of regular foam are protein-base, fluoroprotein, and aqueous film forming foam (AFFF). Some flammable liquids, including many petroleum products, can be controlled by applying regular foam. Otherflammable liquids, including polarsolvents (flammable liquids which are water soluble) such as alcohols and ketones, have different chemical properties. A fire involving these materials cannot be easily controlled with regular foam and requires application of alcohol-resistant foam. Polar-solvent fires may be difficult to control and require a higher foam application rate than otherflammable liquid fires (see NFPA/ANSI Standards 11 and 11A for further information). Refer to the appropriate guide to determine which type of foam is recommended. Although it is impossible to make specific recommendations forflammable liquids which have subsidiary corrosive or toxic hazards, alcohol-resistant foam may be effective for many of these materials. The emergency response telephone number on the shipping document, orthe appropriate emergency response agency, should be contacted as soon as possible forguidance on the properfire extinguishing agentto use. The final selection of the agentand method depends on many factors such as incident location, exposure hazards, size of the fire, environmental concerns, as well as the availability of extinguishing agents and equipmentatthe scene. WATER REACTIVE MATERIALS Water is sometimes used to flush spills and to reduce or direct vapors in spill situations. Some of the materials covered by the guidebook can react violently or even explosively with water. In these cases, consider letting the fire burn or leaving the spill alone (except to prevent its spreading by diking) until additional technical advice can be obtained. The applicable guides clearly warn you of these potentially dangerous reactions. These materials require technical advice since (1) water getting inside a ruptured or leaking container may cause an explosion; (2) water may be needed to cool adjoining containers to prevent their rupturing (exploding) or further spread of the fires; (3) water may be effective in mitigating an incident involving a water-reactive material only if itcan be applied ata sufficient flooding rate foran extended period; and Page 352 (4) the products from the reaction with water may be more toxic, corrosive, or otherwise more undesirable than the product of the fire withoutwaterapplied. When responding to an incident involving water-reactive chemicals, take into account the existing conditions such as wind, precipitation, location and accessibility to the incident, as well as the availability of the agents to control the fire or spill. Because there are variables to consider, the decision to use wateron fires orspills involving water-reactive materials should be based on information from an authoritative source; for example, a producerofthe material, who can be contacted through the emergency response telephone numberorthe appropriate emergency response agency. VAPOR CONTROL Limiting the amount of vapor released from a pool of flammable or corrosive liquids is an operational concern. It requires the use of proper protective clothing, specialized equipment, appropriate chemical agents, and skilled personnel. Before engaging in vapor control, get advice from an authoritative source as to the proper tactics. There are several ways to minimize the amount of vapors escaping from pools of spilled liquids, such as special foams, adsorbing agents, absorbing agents, and neutralizing agents. To be effective, these vaporcontrol methods must be selected forthe specific material involved and performed in a manner that will mitigate, not worsen, the incident. Where specific materials are known, such as at manufacturing or storage facilities, it is desirable forthe dangerous goods response team to prearrange with the facility operators to select and stockpile these control agents in advance of a spill. In the field, first responders may not have the most effective vapor control agent for the material available. They are likely to have only water and only one type of fire fighting foam on their vehicles. If the available foam is inappropriate for use, they are likely to use water spray. Because the water is being used to form a vaporseal, care mustbe taken notto churn or further spread the spill during application. Vapors that do not react with water may be directed away from the site using the air currents surrounding the water spray. Before using water spray or other methods to safely control vapor emission or to suppress ignition, obtain technical advice, based on specific chemical name identification. Page 353 CRIMINAL/TERRORIST USE OF CHEMICAL/BIOLOGICAL/RADIOLOGICAL AGENTS The following is intended to supply information to first responders for use in making a preliminary assessmentofa situation thatthey suspect involves criminal/terra ristuse of chemical, biological (CB) agents and/or radioactive materials. To aid in the assessment, a listof observable indicators of the use and/or presence of a CB agent or radioactive material is provided in the following paragraphs. DIFFERENCES BETWEEN A CHEMICAL, BIOLOGICAL AND RADIOLOGICAL AGENT Chemical and biological agents as well as radioactive materials can be dispersed in the airwe breathe, the waterwe drink, or on surfaces we physically contact. Dispersion methods may be as simple as opening a container, using conventional (garden) spray devices, or as elaborate as detonating an improvised explosive device. Chemical Incidents are characterized by the rapid onset of medical symptoms (minutes to hours) and easily observed signatures (colored residue, dead foliage, pungent odor, dead insects and animals). Biological Incidents are characterized by the onsetof symptoms in hours to days. Typically, there will be no characteristic signatures because biological agents are usually odorless and colorless. Because of the delayed onset of symptoms in a biological incident, the area affected may be greater due to the movementof infected individuals. Radiological Incidents are characterized by the onsetof symptoms, if any, in days to weeks or longer. Typically, there will be no characteristic signatures because radioactive materials are usually odorless and colorless. S pecialized equipment is required to determine the size of the affected area, and whether the level of radioactivity presents an immediate or long-term health hazard. Because radioactivity is notdetectable withoutspecial equipment, the affected area may be greaterdue to the migration of contaminated individuals. Atthe levels created by most probable sources, notenough radiation would be generated to kill people or cause severe illness. In a radiological incident generated by a "dirty bomb", or Radiological Dispersal Device (RDD), in which a conventional explosive is detonated to spread radioactive contamination, the primary hazard is from the explosion. However, certain radioactive materials dispersed in the air could contaminate up to several city blocks, creating fear and possibly panic, and requiring potentially costly cleanup. INDICATORS OF A POSSIBLE CHEMICAL INCIDENT Dead animals/birds/fish Notjustan occasional road kill, but numerous animals (wild and domestic, small and large), birds, and fish in the same area. Page 354 INDICATORS OF A POSSIBLE CHEMICAL INCIDENT (Continued) Lack of insect life Unexplained odors Unusual numbers of dying or sick people (mass casualties) Pattern of casualties Blisters/rashes Illness in confined area Unusual liquid droplets Different looking areas Low-lying clouds Unusual metal debris If normal insectactivity (ground, air, and/orwater) is missing, checktheground/watersurface/shore linefordead insects. If nearwater, checkfordeadfish/aquatic birds. Smells may range from fruity to flowery to sharp/pungentto garlic/ horseradish-like to bitter almonds/peach kernels to new mown hay. Itis importantto note thatthe particularodor is completely outofcharacterwith its surroundings. Health problems including nausea, disorientation, difficulty in breathing, convulsions, localized sweating, conjunctivitis (reddening of eyes/nerve agent symptoms), erythema (reddening of skin/vesicantsymptoms) and death. Casualties will likely be distributed downwind, or if indoors, by the air ventilation system. Numerous individuals experiencing unexplained water-like blisters, weals (like bee stings), and/or rashes. Differentcasualty rates for people working indoors versus outdoors dependenton where the agentwas released. N umerous surfaces exhibitoily droplets/film; numerous water surfaces have an oily film. (No recentrain.) Not justa patch of dead weeds, buttrees, shrubs, bushes, food crops, and/or lawns that are dead, discolored, or withered. (No currentdrought.) Low-lying cloud/fog-like condition that is notconsistentwith its surroundings. Unexplained bomb/munitions-like material, especially if it contains a liquid. INDICATORS OF A POSSIBLE BIOLOGICAL INCIDENT Unusual numbers of sick or dying people or animals Unscheduled and unusual spray being disseminated Any numberof symptoms may occur. Casualties may occur hours to days after an incident has occurred. The time required before symptoms are observed is dependent on the agentused. Especially if outdoors during periods of darkness. Abandoned spray devices Devices may nothave distinctodors. Page 355 INDICATORS OF A POSSIBLE RADIOLOGICAL INCIDENT Radiation Symbols Containers may display a "propeller" radiation symbol. Unusual metal debris Unexplained bomb/munitions-like material. Heat-emitting material Material that is hotor seems to emit heatwithoutany sign of an external heatsource. Glowing material Strongly radioactive material may emit or cause radioluminescence. Sick people/animals In very improbable scenarios there may be unusual numbers ofsickordying people oranimals. Casualties may occur hours to days orweeks afteran incidenthas occurred. The time required before symptoms are observed is dependent on the radioactive material used, and the dose received. Possible symptoms include skin reddening orvomiting. PERSONAL SAFETY CONSIDERATIONS When approaching a scene that may involve CB agents or radioactive materials, the mostcritical consideration is the safety of oneself and other responders. Protective clothing and respiratory protection of appropriate level of safety mustbe used. Be aware thatthe presence and identification of CB or radioactive materials may not be verifiable, especially in the case of biological or radiological agents. The following actions/measures to be considered are applicable to eithera chemical, biological or radiological incident. The guidance is general in nature, not all encompassing, and its applicability should be evaluated on a case-by-case basis. Approach and response strategies. Protectyourselfand use a safe approach (minimize any exposure time, maximize the distance between you and the item that is likely to harm you, use cover as protection and wear appropriate personal protective equipment and respiratory protection). Identify and estimate the hazard by using indicators as provided above. Isolate the area and secure the scene; potentially contaminated people should be isolated and decontaminated as soon as possible. To the extentpossible, take measures to limitthe spread of contamination. In the eventof a chemical incident the fading of chemical odors is notnecessarily an indication of reduced vaporconcentrations. Some chemicals deaden the senses giving the false perception thatthe chemical is no longerpresent. If there is any indication thatan area may be contaminated with radioactive materials, including the site of any non-accidental explosion, responder personnel should be equipped with radiation detection equipmentthatwould alert them if they are entering a radiologically compromised environment, and should have received adequate training in its use. This equipmentshould be designed in such a way thatit can also alertthe responders when an unacceptable ambient dose rate orambientdose has been reached. Page 356 Decontamination measures. Emergency responders should follow standard decontamination procedures (flush-strip-flush). Mass casualty decontamination should begin as soon as possible by stripping (all clothing) and flushing (soap and water). If biological agents are involved or suspected, careful washing and use of a brush are more effective. If chemical agents are suspected, the most importantand effective decontamination will be thatdone within the firstone or two minutes. If possible, furttierdecontamination should be performed using a 0.5% hypochlorite solution (1 part household bleach mixed with 9 parts water). If biological agents are suspected, a contact time of 10 to 15 minutes should be allowed before rinsing. The solution can be used on softtissue wounds, butmustnotbe used in eyes oropen wounds of the abdomen, chest, brain, orspine. Forfurther information contactthe agencies listed in this guidebook. For persons contaminated with radioactive material, remove them to a low radiation area if necessary. Remove theirclothing and place itin a clearly marked sealed receptacle, such as a plastic bag, forlatertesting. Use decontamination methods described above, butavoid breaking the skin, e.g., from shaving, oroverly vigorous brushing. External radiological contamination on intact skin surface rarely causes a high enough dose to be a hazard to eitherthe contaminated person or the first responders. Forthis reason, except in very unusual circumstances, an injured person who is also radiologically contaminated should be medically stabilized, taking care to minimize the spread of the contamination to the extent possible, before decontamination measures are initiated. NOTE: The above information was developed in partby the Departmentof National Defence (Canada) and the U.S. Department of the Army, Edgewood Arsenal. Page 357 Glossary Alcohol resistantfoam A foam that is resistantto "polar"chemicals such as ketones and esters which may break down other types of foam. Biological agents Living organisms that cause disease, sickness and mortality in humans. Anthrax and Ebola are examples of biological agents. Refer to GUIDE 158. Blisteragents (vesicants) Substances thatcause blistering of the skin. Exposure is through liquid or vapor contactwith any exposed tissue (eyes, skin, lungs). Mustard (H), Distilled Mustard (HD), Nitrogen Mustard (HN) and Lewisite (L) are blisteragents. Symptoms: Red eyes, skin irritation, burning of skin, blisters, upper respiratory damage, cough, hoarseness. Blood agents Substances thatinjure a person by interfering with cell respiration (the exchange of oxygen and carbon dioxide between blood and tissues). Hydrogen cyanide (AC) and Cyanogen chloride (CK) are blood agents. Symptoms: Respiratory distress, headache, unresponsiveness, seizures, coma. Burn Refers to either a chemical or thermal burn, the former may be caused by corrosive substances and the latter by liquefied cryogenic gases, hot molten substances, or flames. Choking agents Substances thatcause physical injury to the lungs. Exposure is through inhalation. In extreme cases, membranes swell and lungs become filled with liquid (pulmonary edema). Death results from lack of oxygen; hence, the victim is "choked". Phosgene (CG) is a choking agent. Symptoms: irritation to eyes/nose/throat, respiratory distress, nausea and vomiting, burning of exposed skin. C0 2 Carbon dioxide gas. Cold zone Area where the command post and support functions that are necessary to control the incidentare located. This is also referred to as the clean zone, green zone orsupportzone in otherdocuments. (EPA Standard Operating Safety Guidelines, OSHA 29 CFR 1910.120, NFPA472) Page 358 Glossary Combustible liquid Liquids which have a flash pointgreaterthan 60.5°C (141°F) and below 93°C (200°F). U.S. regulations permita flammable liquid with a flash pointbetween 38°C (100°F) and 60.5°C (141°F) to be reclassed as a combustible liquid. Compatibility G roup Letters identify explosives thatare deemed to be compatible. C lass 1 materials are considered to be "compatible" if they can be transported together without significantly increasing either the probability of an incident or, for a given quantity, the magnitude of the effects of such an incident. A Substances which are expected to mass detonate very soon after fire reaches them. B Articles which are expected to mass detonate very soon after fire reaches them. C Substances or articles which may be readily ignited and burn violently without necessarily exploding. D Substances or articles which may mass detonate (with blastand/orfragmenthazard) when exposed to fire. E&F Articles which may mass detonate in a fire. G Substances and articles which may mass explode and give off smoke ortoxic gases. H Articles which in a fire may eject hazardous projectiles and dense white smoke. J Articles which may mass explode. K Articles which in a fire may eject hazardous projectiles and toxic gases. L Substances and articles which presenta special riskand could be activated by exposure to airor water. N Articles which contain only extremely insensitive detonating substances and demonstrate a negligible probability of accidental ignition or propagation. S Packaged substances or articles which, if accidentally initiated, produce effects thatare usually confined to the immediate vicinity. Page 359 Glossary Control zones Cryogenic liquid Dangerous Water Reactive Material Decomposition products Decontamination Dry chemical Edema ERPG(s) Designated areas at dangerous goods incidents, based on safety and the degree of hazard. Many terms are used to describe control zones; however, in this guidebook, these zones are defined as the hot/exclusion/restricted zone, warm/contamination reduction/limited access zone, and cold/support/clean zone. (EPA Standard Operating Safety Guidelines, OSHA29 CFR 1910.120, NFPA472) A refrigerated, liquefied gas thathas a boiling pointcolderthan -90°C (-130°F) atatmospheric pressure. Produces significanttoxic gas when itcomes in contactwith water. Products of a chemical or thermal break-down of a substance. The removal of dangerous goods from personnel and equipmentto the extent necessary to prevent potential adverse health effects. Always avoid direct or indirect contact with dangerous goods; however, if contactoccurs, personnel should be decontaminated as soon as possible. S ince the methods used to decontaminate personnel and equipment differ from one chemical to another, contact the chemical manufacturer, through the agencies listed on the inside back cover, to determine the appropriate procedure. Contaminated clothing and equipmentshould be removed after use and stored in a controlled area (warm/contamination reduction/limited access zone) until cleanup procedures can be initiated. In some cases, protective clothing and equipment cannotbe decontaminated and must be disposed of in a propermanner. A preparation designed forfighting fires involving flammable liquids, pyrophoric substances and electrical equipment. Common types contain sodium bicarbonate or potassium bicarbonate. The accumulation of an excessive amountof watery fluid in cells and tissues. Pulmonary edema is an excessive buildup of water in the lungs, for instance, after inhalation of a gas that is corrosive to lung tissue. Emergency Response Planning Guideline(s). Values intended to provide estimates of concentration ranges above which one could reasonably anticipate observing adverse health effects; see ERPG-1, ERPG-2 and ERPG-3. Page 360 Glossary The maximum airborne concentration below which it is believed nearly all individuals could be exposed for up to 1 hour without experiencing more than mild, transientadverse health effects or without perceiving a clearly defined objectionable odor. The maximum airborne concentration below which itis believed nearly all individuals could be exposed for up to 1 hour without experiencing or developing irreversible or other serious health effects orsymptoms thatcould impairan individual's ability to take protective action. The maximum airborne concentration below which itis believed nearly all individuals could be exposed for up to 1 hour without experiencing ordeveloping life-threatening health effects. A liquid thathas a flash pointof 60.5°C (141°F) orlower. Lowesttemperature atwhich a liquid orsolid gives offvapor in such a concentration that, when the vaporcombines with airnearthe surface of the liquid orsolid, a flammable mixture is formed. Hence, the lowerthe flash point, the more flammable the material. HAZARDZONEA: Gases: LC50 of (ess than orequalto 200 ppm, Liquids: V equal to or greater than 500 LC50 and LC50 less than or equal to 200 ppm, HAZARD ZONE B: Gases: LC50 greaterthan 200 ppm and less than or equal to 1000 ppm, Liquids: V equal to orgreaterthan 10 LC50; LC50 less than or equal to 1000 ppm and criteria for Hazard Zone A are not met. HAZARD ZONE C: LC50 greaterthan 1000 ppm and less than or equal to 3000 ppm, HAZARD ZONE D: LC50 greaterthan 3000 ppm and less than or equal to 5000 ppm. Area immediately surrounding a dangerous goods incidentwhich extends far enough to prevent adverse effects from released dangerous goods to personnel outside the zone. This zone is also referred to as exclusion zone, red zone or restricted zone in other documents. (EPA Standard Operating Safety Guidelines, OSHA29 CFR 1910.120, NFPA 472) Page 361 Glossary Immiscible In this guidebook, means thata material does notmix readily with water. LC50 Lethal concentration 50. The concentration of a material administered by inhalation that is expected to cause the death of 50% of an experimental animal population within a specified time. (Concentration is reported in eitherppm ormg/m 3 ) Mass explosion Explosion which affects almost the entire load virtually instantaneously. mg/m 3 Milligrams of a material percubic meterofair. Miscible In this guidebook, means thata material mixes readily with water. mL/m 3 Milliliters of a material percubic meterofair. (1 mL/m 3 equals 1 ppm) Nerve agents Substances thatinterfere with the central nervous system. Exposure is primarily through contactwith the liquid (via skin and eyes) and secondarily through inhalation of the vapor. Tabun (GA), Sarin (GB), Soman (GD) and VX are nerve agents. Symptoms: Pinpointpupils, extreme headache, severe tightness in the chest dyspnea, runny nose, coughing, salivation, unresponsiveness, seizures. See "Immiscible". These letters referto nototherwise specified. The entries which use this description are generic names such as "Corrosive liquid, n.o.s." This means thatthe actual chemical name forthatcorrosive liquid is notlisted in the regulations; therefore, a generic name mustbe used to describe iton shipping papers. In this guidebook, means thata material may be harmful or injurious to health or physical well-being. A chemical which supplies its own oxygen and which helps other combustible material burn more readily. Non-polar n.o.s. Noxious Oxidizer Page 362 Glossary pH PIH Polar Polymerization ppm Protective clothing The letter "P "following a guide number in the yellow-bordered and blue-bordered pages identifies a material which may polymerize violently under high temperature conditions orcontamination with other products. This polymerization will produce heat and high pressure buildup in containers which may explode or rupture. (S ee polymerization below.) pH is a value thatrepresents the acidity oralkalinity of a watersolution. Pure water has a pH of 7. A pH value below 7 indicates an acid solution (a pH of 1 is extremely acidic). A pH above 7 indicates an alkaline solution (a pH of 14 is extremely alkaline). Acids and alkalies (bases) are commonly referred to as corrosive materials. Poison Inhalation Hazard. Term used to describe gases and volatile liquids that are toxic when inhaled. (Same as TIH) See "M iscible". This term describes a chemical reaction which is generally associated with the production of plastic substances. Basically, the individual molecules of the chemical (liquid orgas) reactwith each otherto produce whatcan be described as a long chain. These chains can be formed in many useful applications. A well known example is the styrofoam (polystyrene) coffee cup which is formed when liquid molecules of styrene reactwith each otherorpolymerize forming a solid, therefore changing the name from styrene to polystyrene (poly means many). Parts per million. (1 ppm equals 1 mL/m 3 ) Includes both respiratory and physical protection. Onecannotassign a level of protection to clothing or respiratory devices separately. These levels were accepted and defined by response organizations such as U.S. CoastGuard, NIOSH, and U.S. EPA. Level A: SCBA plus totally encapsulating chemical resistantclothing (permeation resistant). Level B: SCBA plus hooded chemical resistantclothing (splash suit). Level C: Full orhalf-face respirator plus hooded chemical resistant clothing (splash suit). Level D: Coverall with no respiratory protection. Pyrophoric A material which ignites spontaneously upon exposure to air(oroxygen). Page 363 Glossary The property of some substances to emit invisible and potentially harmful radiation. As referred to in GUIDES 161 through 166 for radioactive materials, the Radiation Authority is eithera Federal, state/provincial agency or state/province designated official. The responsibilities of this authority include evaluating radiological hazard conditions during normal operations and during emergencies. If the identity and telephone numberof the authority are not known by emergency responders, orincluded in the local response plan, the information can be obtained from the agencies listed on the inside back cover. They maintain a periodically updated listof radiation authorities. See "Cryogenic liquid". Method used to apply or distribute water from the end of a hose. The water is delivered under pressure for penetration. In an efficient straight (solid) stream, approximately 90% of the water passes through an imaginary circle 38 cm (15 inches) in diameter atthe breaking point. Hose (solid orstraight) streams are frequently used to cool tanks and otherequipmentexposed to flammable liquid fires, or for washing burning spills away from danger points. However, straightstreams will cause a spill fire to spread if improperly used or when directed into open containers of flammable and combustible liquids. Toxic Inhalation Hazard. Term used to describe gases and volatile liquids thatare toxic when inhaled. (Same as PIH) Saturated vaporconcentration in airof a material in mL/m 3 (volatility) at20°C and standard atmospheric pressure. Weight of a volume of pure vapor or gas (with no air present) compared to the weightof an equal volume of dry air atthe same temperature and pressure. A vapordensity less than 1 (one) indicates thatthe vapor is lighter than air and will tend to rise. A vapor density greaterthan 1 (one) indicates thatthe vapor is heavierthan airand may travel along the ground. Pressure atwhich a liquid and its vaporare in equilibrium ata given temperature. Liquids with high vaporpressures evaporate rapidly. Glossary Viscosity Measure of a liquid's internal resistance to flow. This property is importantbecause it indicates howfasta material will leak outthrough holes in containers ortanks. Warm zone Area between Hotand Cold zones where personnel and equipment decontamination and hotzone supporttake place. Itincludes control points forthe access corridor and thus assists in reducing the spread of contamination. Also referred to as the contamination reduction corridor (C RC ), contamination reduction zone (C RZ), yellow zone or limited access zone in other documents. (EPA Standard Operating Safety Guidelines, OSHA29CFR 1910.120, NFPA472) Water-sensitive Substances which may produce flammable and/or toxic decomposition products upon contact with water. Water spray (fog) Method or way to apply or distribute water. The water is finely divided to provide for high heatabsorption. Waterspray patterns can range from about 10 to 90 degrees. Water spray streams can be used to extinguish or control the burning of a fire or to provide exposure protection for personnel, equipment, buildings, etc. (This method can be used to absorb vapors, knock- down vapors or disperse vapors. Direct a water spray (fog), rather than a straight (solid) stream, into the vapor cloud to accomplish any of the above). Waterspray is particularly effective on fires of flammable liquids and volatile solids having flash points above 37.8°C (100°F). Regardless of the above, waterspray can be used successfully on flammable liquids with low flash points. The effectiveness depends particularly on the method of application. With proper nozzles, even gasoline spill fires of some types have been extinguished when coordinated hose lines were used to sweep the flames off the surface of the liquid. Furthermore, waterspray carefully applied has frequently been used with success in extinguishing fires involving flammable liquids with high flash points (orany viscous liquids) by causing frothing to occur only on the surface, and this foaming action blankets and extinguishes the fire. Page 365 PUBLICATION DATA The 2004 Emergency Response Guidebook (ERG2004) was prepared by the staff of Transport Canada, the U.S. Department of Transportation, and the Secretariatof Communications and Transportof Mexico with the assistance of many interested parties from government and industry including the collaboration ofCIQUIME of Argentina. The principal authors of the ERG since its inception have been Transport Canada's Michel Cloutier and U.S. DOT'S George Cushmac. ERG2004 is based on earlierTransportCanada, U.S. DOT, and Secretariatof Communications andTransportemergency response guidebooks. ERG2004 is published in three languages: English, French and Spanish. The Emergency Response Guidebook has been translated and printed in otherlanguages, including Chinese, German, Hebrew,] apanese, Portuguese, Korean, Hungarian, Polish, Turkish and Thai. We encourage countries thatwish to participate in future editions of the Guidebook to provide their emergency response center information for inclusion. Please contactany of the websites or telephone numbers in the paragraph below. DISTRIBUTION OF THIS GUIDEBOOK The primary objective is to place one copy of the ERG2004 in each emergency service vehicle through distribution to Federal, state, provincial and local public safety authorities. The distribution of this guidebook is being accomplished through the voluntary cooperation of a network of key agencies. Emergency service organizations that have not yet received copies of ERG2004 should contactthe respective distribution center in their country, state or province. In the U .S ., information about the distribution centerforyour location may be obtained from the Office of Hazardous Materials Safety web site at http://hazmat.dot.gov or call 202-366-4900. In Canada, contactCANUTEC at613-992-4624 orvia the web site athtlp://www.canutec.gc.ca forinformation. In Mexico, call SCT at 52-555-684-1275 or 684-0188 orvia email at iflores@ sct.gob.mx. In Argentina, call CIQUIME at 011-4613-1100, orvia the web site at http://www.ciquime.org.ar, or via email aterg2004@ ciquime. org. ar REPRODUCTION and RESALE Copies of this documentwhich are provided free of charge to fire, police and otheremergency services may notbe resold. ERG2004 (RSPA P 5800.9) may be reproduced without further permission subject to the following: The names and the seals of the participating governments may not be reproduced on a copy of this document unless thatcopy accurately reproduces the entire content (text, format, and coloration) of this document without modification. In addition, the publisher's full name and address must be displayed on the outside back cover of each copy, replacing the wording placed on the center of the back cover. Page 366 Constructive comments concerning ERG2004 are solicited; in particular, comments concerning its use in handling incidents involving dangerous goods. Comments should be addressed to: In Canada: Director, CANUTEC Transport Dangerous Goods TransportCanada Ottawa, Ontario Canada K1A0N5 Phone: 613-992-4624 (information) FAX: 613-954-5101 Email: canutec@tc.gc.ca In the U.S.: U. S. Departmentof Transportation Research and Special Programs Administration Office of Hazardous Materials Initiatives and Training (DHM-50) Washington, DC 20590-0001 Phone: 202-366-4900 FAX: 202-366-7342 Email: welisten@rspa.dot.gov In Mexico: Secretariatfor Communications and Transport Land TransportDirecto rate Hazardous Materials and Wastes Directorate Calz. de las Bombas No. 411-9 piso Col. San Bartolo Coapa Coyoacan 04800, D.F. Mexico Phone and FAX: 52-555-684-1275 and 684-0188 In Argentina: Information Center for Chemical Emergencies (CIQUIME) J uan Bautista Alberdi 2986 C1406GSS Buenos Aires, Argentina Tel. (Oil) 4613-1100 Fax (Oil) 4613-3707 Email: erg2004@ ciquime.org.ar Page 367 NOTES Page 368 The Emergency Response Guidebook is normally revised and reissued every fouryears. However, in the eventof a significant mistake, omission orchange in the state of knowledge, special instructions to change the guidebook (in pen-and-ink, with paste-overstickers, or with a supplement) may be issued. Users of this guidebook should check periodically (aboutevery 6 months) to make sure their version is current. Changes should be annotated below. Contact: DOT/RSPA http://hazmat.dot.gov/gydebook.htm TRANSPORT CANADA http://www.tc.gc.ca/canutec/en/guide/guide.htm CIQUIME http://www.ciquime.org.ar This guidebook incorporates changes dated: Page 369 ^^^^M EMERGENCY RESPONSE TELEPHONE NUMBERS 1. SETIQ 01-800-00-214-00 in the Mexican Republic For calls originating in Mexico City and the Metropolitan Area 5559-1588 F or ca lis originating elsewhere, call 011-52-555-559-1588 2. CENACOM 01-800-00-413-00 in the Mexican Republic For calls originating in Mexico City and the Metropolitan Area 5550-1496, 5550-1552. 5550-1485 or 5550-4885 F or ca lis originating elsewhere, call 011-52-555-550-1496, or 011-52-555-550-1552 011-52-555-550-1485, or 011-52-555-550-4885 ARGENTINA 1. CIQUIME 0-800-222-2933 in the Republic of Argentina F or ca lis originating elsewhere, call +54-11-4613-1100 BRAZIL 1. PRO-QUl'MICA 0-800-118270 (Toll-free in Brazil) F or ca lis originating elsewhere, ca +55-11-232-1144 (Collectcalls are accepted) COLOMBIA 1. CISPROQUIM 01-800-091-6012 in Colombia F or ca lis originating in Bogota, Colombia call 288-6012 For calls originating elsewhere call 011-57-1-288-6012 Foradditional details see the section entiitled "WHO TO CALL FOR ASSISTANCE." Page 370 EMERGENCY RESPONSE TELEPHONE NUMBERS CANADA 1. CANUTEC UNITED STATES 1. CHEMTREC® 613-996-6666 (Collect calls are accepted) *666 cellular (in Canada only) 1-800-424-9300 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) 703-527-3887 For calls originating elsewhere (Collect calls are accepted) 2. CHEM-TEL, INC. 1-800-255-3924 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) 813-248-0585 For calls originating elsewhere (Collect calls are accepted) 3. INFOTRAC 1-800-535-5053 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) 352-323-3500 For calls originating elsewhere (Collect calls are accepted) 4. 3E COMPANY 1-800-451-8346 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) 760-602-8703 For calls originating elsewhere (Collect calls are accepted) 5. NATIONAL RESPONSE CENTER (NRC) CALLNRC (24 hours) 1-800-424-8802 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) 202-267-2675 in the District of Columbia 6. MILITARY SHIPMENTS 703-697-0218 - Explosives/ammunition incidents (Collect calls are accepted) 1-800-851-8061 - All other dangerous goods incidents 7. NATIONWIDE POISON CONTROL CENTER (United States only) 1-800-222-1222 (toll-free in the U.S.) THIS DOCUMENT SHOULD NOT BE USED TO DETERMINE COMPLIANCE WITH THE DANGEROUS GOODS REGULATIONS OR TO CREATE WORKER SAFETY DOCUMENTS FOR SPECIFIC CHEMICALS NOT FOR SALE This document is distributed free of charge to Public Safety Organizations and may not be resold. Research and Special Programs Administration Canada Safety and Security Transports Canada Securite et surete Secretariat of Transport and Communications